ChemNanoMat最新文献_第10页

Facile Synthesis of Silanol Group Rich Sn-Beta for Highly Efficient Isomerization of Glucose to Fructose 简单合成富含硅醇基团的 Sn-Beta 以实现葡萄糖与果糖的高效异构化

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-31 DOI: 10.1002/cnma.202400322

Meng Li, Tianliang Lu, Dr. Shengqiang Zhou, Prof. Dr. Lipeng Zhou, Xiaomei Yang

{"title":"Facile Synthesis of Silanol Group Rich Sn-Beta for Highly Efficient Isomerization of Glucose to Fructose","authors":"Meng Li, Tianliang Lu, Dr. Shengqiang Zhou, Prof. Dr. Lipeng Zhou, Xiaomei Yang","doi":"10.1002/cnma.202400322","DOIUrl":"10.1002/cnma.202400322","url":null,"abstract":"The isomerization of glucose to fructose is an important process in the conversion of biomass into valuable fuels and chemicals. Development of efficient catalyst for this reaction has attracted much attention. In this study, Sn-Beta zeolites with rich silanols were synthesized for glucose isomerization by solid-state ion-exchange method, where Si-Beta zeolites with different amounts of silanols were applied as the precursors. It is confirmed that open Sn sites show much higher catalytic performance than closed Sn sites for glucose isomerization (about 2.1 times). The silanol amount in Si-Beta not only affects the formation of framework Sn sites in Sn-Beta but also influences the isomerization reaction. More silanols in the catalyst can promote the 1,2-H shift in isomerization and reduce the side reactions of formation of mannose and C3 products. Over 3Sn-Beta-3h with rich silanols, 64 % of fructose yield was obtained. Furthermore, the prepared Sn-Beta catalyst is stable and recyclable. High fructose yield and facile synthesis method of Sn-Beta reported in this work will contribute to the development of biomass and sugar industry.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141193409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Boron Nitride Modified Superhydrophobic Anti-Icing Coating for Electrical Equipment Protection 用于保护电气设备的氮化硼改性超疏水防冰涂层

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-28 DOI: 10.1002/cnma.202400001

Bo Wang, Prof. Xueqin Zhang, Bingkun Li, Yijie Liu, Song Xiao, Yujun Guo, Wenfu Wei, Guoqiang Gao, Guangning Wu

引用次数: 0

Roles of Metal-Organic Framework Supports in Base-Free Oxidation of 5-Hydroxymethylfurfural to Furan-2,5-Dicarboxylic Acid over Pt-Based Catalysts 金属有机框架支撑物在铂基催化剂上将 5-羟甲基糠醛无碱氧化成呋喃-2,5-二羧酸过程中的作用

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-27 DOI: 10.1002/cnma.202400037

Theerada Seehamongkol, Dr. Bunyarat Rungtaweevoranit, Dr. Pongkarn Chakthranont, Dr. Teera Butburee, Weerawan Nimsaila, Dr. Kajornsak Faungnawakij

{"title":"Roles of Metal-Organic Framework Supports in Base-Free Oxidation of 5-Hydroxymethylfurfural to Furan-2,5-Dicarboxylic Acid over Pt-Based Catalysts","authors":"Theerada Seehamongkol, Dr. Bunyarat Rungtaweevoranit, Dr. Pongkarn Chakthranont, Dr. Teera Butburee, Weerawan Nimsaila, Dr. Kajornsak Faungnawakij","doi":"10.1002/cnma.202400037","DOIUrl":"10.1002/cnma.202400037","url":null,"abstract":"The catalytic oxidation of 5-hydroxymethylfurfural (HMF) is an important process for producing a renewable furan-2,5-dicarboxylic acid (FDCA). Although several Pt-based catalysts have been reported to efficiently catalyze the oxidation of HMF, the functional roles of catalyst supports, as corroborated by spectroscopic techniques, have not been fully described. Here, we report on Pt nanoparticles supported on metal-organic frameworks (MOFs) that catalyze the oxidation of HMF to FDCA in the absence of base. Several catalysts are prepared by immobilizing pre-synthesized Pt nanoparticles on supports, allowing for the investigation of the role of the supports without the influence of the size of Pt nanoparticles (Pt NPs). By analyzing the catalytic performances along with the electronic properties using X-ray photoelectron spectroscopy and surface properties of the catalysts using in situ infrared spectroscopy of adsorbed CO2, we find that the presence of Pt NPs in the metallic phase and basic hydroxyl groups on the support promote the HMF oxidation.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141169102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Inorganic-Organic Hybrid Crystals Derived from Polyoxovanadate and Ionic-Liquid toward Promising Conductive Materials 聚氧乙烯钒酸盐和离子液体衍生的无机-有机杂化晶体有望成为导电材料

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-27 DOI: 10.1002/cnma.202400188

Yoshiki Kiyota, Seiji Ono, Dr. Kaito Sasaki, Nanako Tamai, Hironori Sugimoto, Prof. Dr. Yosuke Okamura, Prof. Dr. Shinichi Koguchi, Prof. Dr. Masashi Higuchi, Prof. Dr. Yu Nagase, Prof. Dr. Naoki Shinyashiki, Prof. Dr. Sayaka Uchida, Prof. Dr. Takeru Ito

{"title":"Inorganic-Organic Hybrid Crystals Derived from Polyoxovanadate and Ionic-Liquid toward Promising Conductive Materials","authors":"Yoshiki Kiyota, Seiji Ono, Dr. Kaito Sasaki, Nanako Tamai, Hironori Sugimoto, Prof. Dr. Yosuke Okamura, Prof. Dr. Shinichi Koguchi, Prof. Dr. Masashi Higuchi, Prof. Dr. Yu Nagase, Prof. Dr. Naoki Shinyashiki, Prof. Dr. Sayaka Uchida, Prof. Dr. Takeru Ito","doi":"10.1002/cnma.202400188","DOIUrl":"10.1002/cnma.202400188","url":null,"abstract":"Conductive polyoxovanadate inorganic-organic hybrid crystals comprising alkaline earth metal (divalent) cations were successfully obtained with the use of an ionic-liquid cation having imidazolium and methacryloyl moieties (denoted as MAImC1). Two types of crystals containing decavanadate ([V10O28]6−, V10) anion were obtained as [MAImC1]2Ca2[V10O28] ⋅ 16H2O ⋅ 2 C2H5OH (MAImC1−Ca−V10) and [MAImC1]2Mg2[V10O28] ⋅ 18H2O ⋅ 2 C2H5OH (MAImC1−Mg−V10). Connection modes of the divalent cations were different: Ca2+ cations were connected to V10 to form a {[Ca(H2O)5]2V10O28]}2− anion in MAImC1−Ca−V10, while a discrete [V10O28]6− and hydrated [Mg(H2O)6]2+ were present in MAImC1−Mg−V10. Conductivities under a fully humidified condition at 353 K (80 °C) were high values of 3.0×10−4 S cm−1 for MAImC1−Ca−V10 and 3.3×10−3 S cm−1 for MAImC1−Mg−V10, respectively. The higher conductivity under hydrated conditions suggests proton as a conductive carrier. The better conductivity of MAImC1−Mg−V10 is plausibly derived from the more effective hydrogen-bonded network in the crystal lattice.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141169361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Detoxification of Chemical Warfare Agents by a Zr-Based MOF with High Recycling Ability at Physiological pH 在生理 pH 值下具有高回收能力的锆基 MOF 对化学战剂的解毒作用

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-24 DOI: 10.1002/cnma.202400132

Dr. Subharanjan Biswas, Rémy Gay, Dr. Janek Bzdrenga, Thomas Soirot, Nicolas Belverge, Dr. Nicolas Taudon, Dr. Xavier Brazzolotto, Dr. Mohamed Haouas, Prof. Nathalie Steunou, Prof. Jean-Pierre Mahy, Dr. Rémy Ricoux

{"title":"Detoxification of Chemical Warfare Agents by a Zr-Based MOF with High Recycling Ability at Physiological pH","authors":"Dr. Subharanjan Biswas, Rémy Gay, Dr. Janek Bzdrenga, Thomas Soirot, Nicolas Belverge, Dr. Nicolas Taudon, Dr. Xavier Brazzolotto, Dr. Mohamed Haouas, Prof. Nathalie Steunou, Prof. Jean-Pierre Mahy, Dr. Rémy Ricoux","doi":"10.1002/cnma.202400132","DOIUrl":"10.1002/cnma.202400132","url":null,"abstract":"The neutralization of organophosphorous (OP) chemical agents used in modern warfare is a growing concern due to their extreme toxicity to human cells. In several previous works, although the capability of several Zr-MOF-based catalysts has been showcased to facilitate hydrolysis of OP agents in heterogeneous pathways, their usage appeared to be limited by very slow kinetics at neutral pH. There is still a lack of MOF based catalysts that can detoxify OPs at physiological pH. The recycling ability of MOF-based catalysts has also not been greatly explored. Thus, herein, we explored a Zr-based MOF, MOF-801(Zr) for the detoxification of a series of OP nerve agents and a pesticide with simultaneous adsorption and degradation at pH 7.5 in a buffer solution, close to physiological conditions. This MOF-based catalyst demonstrates significant hydrolysis activity towards several nerve agents, with up to 99 % conversion within 2 h and an excellent half-life of less than 5 minutes. In addition, it can be recycled at least 5 times consecutively with a residual activity of at least 90 %.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnma.202400132","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141102367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Reactivity and Durability of Covalent Organic Frameworks Derived Co-Based Hybrid Bifunctional Electrocatalysts for Zinc-Air Batteries 用于锌-空气电池的共价有机框架衍生钴基混合双功能电催化剂的反应活性和耐久性

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-24 DOI: 10.1002/cnma.202400068

Yuling L. Zhang, Longfei F. Xiao, Yiping P. Mo, Guilin L. Liu, Shanshan S. Liu, Wangyang Y. Lu

{"title":"Reactivity and Durability of Covalent Organic Frameworks Derived Co-Based Hybrid Bifunctional Electrocatalysts for Zinc-Air Batteries","authors":"Yuling L. Zhang, Longfei F. Xiao, Yiping P. Mo, Guilin L. Liu, Shanshan S. Liu, Wangyang Y. Lu","doi":"10.1002/cnma.202400068","DOIUrl":"10.1002/cnma.202400068","url":null,"abstract":"Developing bifunctional non-precious metal electrocatalysts of superior reactivity and durability is essential. Herein, we report a class of phthalocyanine-based covalent organic frameworks as self-sacrificial precursors derived Co-based hybrid electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The fabricated Co-COFs/CNT-700 catalysts displayed highly efficient ORR properties with a half-potential of 0.83 V, while its half-wave potential in alkaline solution at a current density of 10 mA cm−2 is 1.70 V in the OER test, reflecting exceptional OER activity. Moreover, zinc-air batteries assembled with Co-COFs/CNT-700 catalysts exhibit a marginally higher power density (114 mW cm2) than traditional Pt/C−IrO2 batteries in an air atmosphere, along with an enhanced cycling stability (5.1 % potential loss after 65 h). This work may pave a facile and efficient approach for fabricating electrocatalytic materials with controllably introduced metals and heteroatoms.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141099333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Harnessing the Synergy of ZIF-67 Derived Nanohybrid-Based Immunosensing for sensitive Detection of Helicobacter pylori 利用 ZIF-67 衍生纳米杂交技术的协同作用实现幽门螺旋杆菌的灵敏检测

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-22 DOI: 10.1002/cnma.202300511

Kirti Saxena, Puja Bhattacharyya, Akanksha Deshwal, Neeraj Shrivastava, Utkarsh Jain, Bansi Dhar Malhotra, Sandip Chakrabarti, Ravi Mani Tripathi

{"title":"Harnessing the Synergy of ZIF-67 Derived Nanohybrid-Based Immunosensing for sensitive Detection of Helicobacter pylori","authors":"Kirti Saxena, Puja Bhattacharyya, Akanksha Deshwal, Neeraj Shrivastava, Utkarsh Jain, Bansi Dhar Malhotra, Sandip Chakrabarti, Ravi Mani Tripathi","doi":"10.1002/cnma.202300511","DOIUrl":"10.1002/cnma.202300511","url":null,"abstract":"Detection of Helicobacter pylori (H. pylori) infection, a significant risk factor for chronic gastritis, peptic ulcers, and gastric adenocarcinoma, poses a formidable challenge due to the lack of sensitive and selective sensing platforms. Herein, we report the synthesis of a zeolitic imidazolate framework-67 (ZIF-67) derived Co/Co3O4/C (CoNH) porous nanostructure, optimized for the electrochemical immunosensing of H. pylori-specific antigen VacA. By calcining ZIF-67 at elevated temperatures, we obtained CoNH with enhanced electroactivity and conductivity, crucial for signal enhancement. The synthesized CoNH was thoroughly characterized using SEM, TEM, XPS, Raman, and FT-IR techniques. Further signal amplification was achieved by introducing gold nanoparticles (AuNPs) onto CoNH-modified screen-printed carbon electrodes. Systematic investigation at each modification stage led to an optimized immunosensing platform with high sensitivity and selectivity for VacA detection. The developed immunosensor demonstrated the capability to detect low concentrations of VacA (0.1 ng/ml) within a wide linear range (0.1–50 ng/ml) with long-term stability. This highly sensitive and selective biosensor holds promise for early-stage diagnosis of H. pylori infection and gastric cancer.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141109039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Front Cover: Visible Light Mediated Synthesis of 3-Indolmethyl Chromones via the Cyclization of o-Hydroxyaryl Enaminones with 3-Indoleacetic Acids Catalyzed by Graphitic Carbon Nitride Adorned with Copper Nanoparticles (ChemNanoMat 5/2024) 封面：在氮化石墨碳与纳米铜粒子催化下，通过邻羟基芳基烯丙基胺与 3-吲哚乙酸的环化反应，以可见光介导合成 3-吲哚甲基色酮（ChemNanoMat 5/2024）

IF 3.8 4区材料科学

ChemNanoMat Pub Date : 2024-05-21 DOI: 10.1002/cnma.202480501

Nandish Talpada, Anuj S. Sharma, Vinay S. Sharma, Rahul Ahmed, Hitendra Mali, Pranav S. Shrivastav, Achalkumar Ammathnadu Sudhakar, Rajender S. Varma

引用次数: 0

Carrier-Free Disulfiram Based Nanomedicine for Enhanced Cancer Therapy 用于增强癌症治疗的无载体双硫仑纳米药物

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-20 DOI: 10.1002/cnma.202400139

Dr. Meng Dang, Prof. Nan Lu, Dr. Xuzhi Shi, Dr. Qiang Li, Prof. Bin Lin, Heng Dong, Xiaolin Han, Jiaxin Rui, Prof. Junfen Sun, Wei Luo, Dr. Zhaogang Teng, Xiaodan Su

{"title":"Carrier-Free Disulfiram Based Nanomedicine for Enhanced Cancer Therapy","authors":"Dr. Meng Dang, Prof. Nan Lu, Dr. Xuzhi Shi, Dr. Qiang Li, Prof. Bin Lin, Heng Dong, Xiaolin Han, Jiaxin Rui, Prof. Junfen Sun, Wei Luo, Dr. Zhaogang Teng, Xiaodan Su","doi":"10.1002/cnma.202400139","DOIUrl":"10.1002/cnma.202400139","url":null,"abstract":"Numerous nanomedicines have been developed to improve the efficiency and safety of conventional anticancer drugs. However, the carrier materials and intricate nature of multifunctional design always hindered the clinical transformation of nanomedicines. Herein, a novel carrier-free anticancer nanomedicine (CFDC) with tailored morphologies including nanodots, nanorod and nanosheet were prepared using the clinically approved anti-alcoholism drug disulfiram (DSF) via supramolecular assembly process. Our study reveals that CFDC induces the production of reactive oxygen species and activates the downstream apoptosis-related c-Jun N-terminal kinase (JNK) and p-38 pathway. In addition, the CFDC effectively counteract the inhibitory effect of NF-κB expression on ROS-induced cellular cytotoxicity, ultimately resulting in enhanced cell apoptosis, which is not achievable by pure DSF and the simply mixing of DSF and Cu2+ (DSF+Cu). Notably, the CFDC exhibits 3.1-, 3.0-folds increased on cancer cell DNA damage compared with the DSF, and DSF+Cu groups. In vivo experiments conducted on breast- or prostate-bearing mice modals demonstrated that the CFDC exhibits a higher efficacy in suppressing the tumor growth. The remarkable drug delivery efficiency and better anticancer effect of CFDC nanodrug provide promising prospects for the clinical transformation of DSF based nanodrug in cancer therapy.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141119588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Copper-Nickel Alloy Modified-Silicon Photoanodes for Photoelectrochemical Water Oxidation and Urea Oxidation 用于光电化学水氧化和尿素氧化的铜镍合金改性硅光电阳极

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-05-14 DOI: 10.1002/cnma.202400036

Kanokwan Klahan, Dr. Gabriel Loget, Dr. Pichaya Pattanasattayavong

{"title":"Copper-Nickel Alloy Modified-Silicon Photoanodes for Photoelectrochemical Water Oxidation and Urea Oxidation","authors":"Kanokwan Klahan, Dr. Gabriel Loget, Dr. Pichaya Pattanasattayavong","doi":"10.1002/cnma.202400036","DOIUrl":"10.1002/cnma.202400036","url":null,"abstract":"The development of silicon (Si) photoanodes for photoelectrochemical (PEC) oxidation is highly crucial for the progress of solar-driven hydrogen production. Apart from the typical water oxidation reaction or oxygen evolution reaction (OER), the urea oxidation reaction (UOR) is gaining more attention due to favorable thermodynamics. In this work, we study Si photoanodes modified with electrodeposited copper-nickel (CuNi) alloy for OER and UOR. The optimized photoanodes exhibit a low onset potential of 1.15 V vs reversible hydrogen electrode (RHE) and a current density of 6 mA cm−2 at 1.23 V vs RHE (the thermodynamic potential for water oxidation) for OER. Further, CuNi alloy-modified photoanodes can drive the UOR at a lower onset potential (1.05 V vs RHE) and generate a higher current density of 31 mA cm−2 at 1.23 V vs RHE. Importantly, the CuNi alloy can extend the stability for UOR under PEC conditions when compared to a planar Ni film deposited by a vacuum-based process. This work demonstrates that CuNi alloy can further improve the properties of inhomogeneous metal-insulator-semiconductor Si photoanodes which can be efficiently utilized for both OER and UOR.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 8","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140925736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0