International Journal of Materials Research最新文献

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Influence of annealing temperature on the structure, morphology, optical property and antibacterial response of phytochemicals-assisted synthesized zinc oxide nanoparticles 退火温度对植物化学物辅助合成的氧化锌纳米粒子的结构、形态、光学性质和抗菌反应的影响
International Journal of Materials Research Pub Date : 2024-07-26 DOI: 10.1515/ijmr-2023-0243
Buvana Sampath, Julie Charles
{"title":"Influence of annealing temperature on the structure, morphology, optical property and antibacterial response of phytochemicals-assisted synthesized zinc oxide nanoparticles","authors":"Buvana Sampath, Julie Charles","doi":"10.1515/ijmr-2023-0243","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0243","url":null,"abstract":"\u0000 Antibiotic overuse has caused a variety of bacterial pathogens to develop new resistance mechanisms. As a result, discovering an appropriate replacement for the standard antibiotics has become an immediate concern. The present work demonstrates a facile, eco-friendly and economical method for the synthesis of hexagonal wurtzite zinc oxide nanoparticles (ω-ZONPs) using the ethanolic extract of triphala. Gas chromatography–mass spectrometry analysis of the triphala extract proved the presence of certain secondary metabolites, which aids in the formation of ω-ZONPs. The influence of annealing temperature on the antibacterial action of as-synthesized ω-ZONPs was studied for three different annealing temperatures. X-ray diffraction, dynamic light scattering, field emission electron microscopy and energy dispersive X-ray spectroscopy analyses were used to examine the impact of annealing temperature on the structure, particle size and morphology of ω-ZONPs. Fourier transform infrared spectra revealed the change in intensity of the characteristic peaks in ω-ZONPs with different annealing temperatures. From UV–Visible diffuse reflectance spectroscopy, variation in the band gap of ω-ZONPs with increasing annealing temperature was detected. Kirby Bauer disc diffusion was adopted to examine the antibacterial potential of ω-ZONPs against bacterial strains such as Staphylococcus aureus, Enterococcus faecium, Bacillus subtilis, Escherichia coli and Pseudomonas aeruginosa. The ω-ZONPs annealed at 200 °C inhibited the growth of three bacterial pathogens, E. coli, B. subtilis and P. aeruginosa and exhibited effective antibacterial activity in comparison with ω-ZONPs annealed at relatively high temperatures. Thus, the antibacterial potential of ω-ZONPs could be further explored as disease controlling agents and such prototypes could be made available for commercial mass production.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"31 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141801504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the magnetic properties and critical behavior of CoFe2−x Al x O4 (x = 1.0 and 1.2) spinel ferrite CoFe2-x Al x O4(x = 1.0 和 1.2)尖晶石铁氧体的磁性能和临界行为研究
International Journal of Materials Research Pub Date : 2024-07-25 DOI: 10.1515/ijmr-2023-0330
Zonghao Song, Ruiyang Cao, C. Ruan, Xian Zhang, Shou-Yang Wang, Meiling Wang, Yongqing Ma, Ganhong Zheng
{"title":"Study on the magnetic properties and critical behavior of CoFe2−x\u0000 Al\u0000 x\u0000 O4 (x = 1.0 and 1.2) spinel ferrite","authors":"Zonghao Song, Ruiyang Cao, C. Ruan, Xian Zhang, Shou-Yang Wang, Meiling Wang, Yongqing Ma, Ganhong Zheng","doi":"10.1515/ijmr-2023-0330","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0330","url":null,"abstract":"\u0000 We have examined the behavior of CoFe2−x\u0000 Al\u0000 x\u0000 O4 (x = 1.0 and 1.2) ferrite close to the transition from ferromagnetic to paramagnetic phases (T\u0000 C). The findings indicate that at a temperature of T\u0000 C = 314 K (x = 1.0) and T\u0000 C = 224 K (x = 1.2), there is a second order magnetic phase transition. We used various methods, including modified Arrott plot, Kouvel–Fisher method, and critical isotherm analysis, to determine the critical exponents which were found to be similar to those expected for the Tricritical Mean-field model (β = 0.288, γ = 1.057, and δ = 4.665) for the x = 1.0 sample. The critical exponents for the x = 1.2 sample (β = 0.771, γ = 1.081, and δ = 2.403) belonged to a different universality class. These results suggest that the replacement of Fe ions with non-magnetic Al ions decreases the Co–Fe, Fe–Fe, Co–Co interaction sites in the CoFe2O4 spinel ferrite, increasing magnetic disorder.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"37 20","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141805976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wet-chemical synthesis and luminescence studies of nano-crystalline gadolinium gallium garnet 纳米晶钆镓石榴石的湿化学合成和发光研究
International Journal of Materials Research Pub Date : 2024-07-24 DOI: 10.1515/ijmr-2023-0371
P. P. Pal, Soumyajit Sarkar
{"title":"Wet-chemical synthesis and luminescence studies of nano-crystalline gadolinium gallium garnet","authors":"P. P. Pal, Soumyajit Sarkar","doi":"10.1515/ijmr-2023-0371","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0371","url":null,"abstract":"\u0000 This paper reports the photoluminescence studies of pure polycrystalline nano-sized gadolinium gallium garnet (Gd3Ga5O12, GGG) powders synthesized by the method of co-precipitation using ammonium hydrogen carbonate (NH4HCO3, AHC) as the precipitant. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared, ultraviolet, visible, near-infrared (UV–Vis–NIR) spectroscopy and photoluminescence studies. The X-ray diffraction analysis confirms the formation of cubic structure of gadolinium gallium garnet (Gd3Ga5O12). The average particle sizes are found to be in the range of approximately 19 nm–88 nm, for different calcining temperatures. The formation of gadolinium gallium garnet is also confirmed by Fourier transform infrared studies. Scanning electron microscopy image measurement confirms the formation of nanosized particles. The photoluminescence studies of the pure gadolinium gallium garnet sample shows emission peaks around at 441 nm for an excitation wavelength of 350 nm for the sample calcined at 1,100 °C.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"42 14","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141809739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the effect of LuCl3 doping on the characteristics of titanium alloy micro-arc oxidation coatings 掺杂 LuCl3 对钛合金微弧氧化涂层特性的影响研究
International Journal of Materials Research Pub Date : 2024-07-19 DOI: 10.1515/ijmr-2024-0049
Xiangjie Wang, Ping Wang, Yanfei Duan, Xu Luo, Youping Zheng
{"title":"Study on the effect of LuCl3 doping on the characteristics of titanium alloy micro-arc oxidation coatings","authors":"Xiangjie Wang, Ping Wang, Yanfei Duan, Xu Luo, Youping Zheng","doi":"10.1515/ijmr-2024-0049","DOIUrl":"https://doi.org/10.1515/ijmr-2024-0049","url":null,"abstract":"\u0000 The micro-arc oxidation of TC4 titanium alloy was carried out by adding LuCl3. The effect of LuCl3 addition on the properties of the micro-arc oxidized coatings, and the rate of weight loss by erosion under simulated oil field conditions, were analysed. The results show that the increase of oxidation voltage after the addition of LuCl3 makes the surface structure of the coatings denser. The coating is mainly composed of Rutile TiO2, Anatase TiO2, and a small amount of Lu2O3 phase. The kinetic potential polarization curves showed that the addition of LuCl3 can increase the corrosion potential and decrease the corrosion current density of TC4 titanium alloy, and at the same time reduce the rate of erosion weight loss of micro-arc oxidized coatings under simulated oilfield conditions. The overall performance of the coatings is best when the concentration of LuCl3 is 0.3 g L−1.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"115 49","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141822243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of carbon nanotube–iron oxide and silver nanocomposites as photocatalyst in removing carcinogenic aromatic dyes 合成碳纳米管-氧化铁和银纳米复合材料,作为去除致癌芳香族染料的光催化剂
International Journal of Materials Research Pub Date : 2024-07-19 DOI: 10.1515/ijmr-2023-0263
Noor Haider Abdul Ali Al-Shawi, Zh. Ebrahiminejad, Somayeh Asgary
{"title":"Synthesis of carbon nanotube–iron oxide and silver nanocomposites as photocatalyst in removing carcinogenic aromatic dyes","authors":"Noor Haider Abdul Ali Al-Shawi, Zh. Ebrahiminejad, Somayeh Asgary","doi":"10.1515/ijmr-2023-0263","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0263","url":null,"abstract":"\u0000 In this research, a three-component composite was synthesized by using carbon nanotube as the background phase. Iron oxide phase with high magnetization and low coercivity (with particle size of 200 nm) has been coated on the carbon nanotubes. Then, the silver nanoparticles were coated on a conductive and magnetized substrate by an ultrasonic method. Semiconductor photocatalys is a favorable route for the degradation of organic pollutants. Ultraviolet–visible spectrophotometry has been used to investigate the photocatalytic properties of synthesized nanocomposite and control of their dye degradation on methyl blue, methyl orange and methyl red. The obtained nanocomposite is easily collected due to its magnetic property and does not pose a risk to environmental waters. The dye degradation degree has been compared for the produced nanocomposite. The experimental results confirmed that methyl red shows the greatest amount of degradation within 1 h, which was about 90 %, methyl orange shows about 80 %, and methyl blue shows the lowest degradation, around 60 %.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":" December","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141824082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-principles calculations of the mechanical properties of Mg2Si intermetallic via ternary elements doping 掺杂三元元素的 Mg2Si 金属间化合物力学性能的第一性原理计算
International Journal of Materials Research Pub Date : 2024-07-17 DOI: 10.1515/ijmr-2023-0274
Hai-Wei Hu, Tinging Liu, Zhendong Li, Xu Wang, Yanbiao Wang, Shaorong Li
{"title":"First-principles calculations of the mechanical properties of Mg2Si intermetallic via ternary elements doping","authors":"Hai-Wei Hu, Tinging Liu, Zhendong Li, Xu Wang, Yanbiao Wang, Shaorong Li","doi":"10.1515/ijmr-2023-0274","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0274","url":null,"abstract":"\u0000 Site preference, structural stability and mechanical properties of Mg2Si doped by ternary elements were studied by first-principles calculation. Formation enthalpies show that light element impurity Al and rare earth elements Sc and Y tend to occupy the Mg site, while transition element Cu has a preference for the Si site. Shear modulus to bulk modulus ratio (G/B), Poisson’s ratio ν and Cauchy pressure show that the ductility of Mg2Si is improved for ternary element addition. The introduced parameter of ductility factor D indicates that the enhanced dislocation emission but suppressed micro-crack propagation is the key to enhancing ductility. Electronic structure indicates the brittleness is due to the strong covalent interaction between Mg-2p and Si-3p (Mg-3s and Si-3p/3s). While, with the incorporation of alloying elements, abundant electrons are injected into the matrix Mg2Si. Thereby, the covalent interaction is effectively suppressed and the ductility is improved.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":" 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141831030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Blast protection of underwater tunnels with 3D auxetic materials 利用 3D 辅助材料对水下隧道进行防爆保护
International Journal of Materials Research Pub Date : 2024-05-23 DOI: 10.1515/ijmr-2022-0461
Shuwen Zhang, Tao Fan
{"title":"Blast protection of underwater tunnels with 3D auxetic materials","authors":"Shuwen Zhang, Tao Fan","doi":"10.1515/ijmr-2022-0461","DOIUrl":"https://doi.org/10.1515/ijmr-2022-0461","url":null,"abstract":"\u0000 In recent years, the risk of blast attacks on underwater tunnels, important transportation routes, has increased due to the growing prevalence of vicious regional conflicts and global terrorist activities. In this work, we investigate the blast impact behavior of underwater tunnels filled with honeycomb core and covered by solid panels. The core is composed of 3D auxetic materials with high energy absorption compared to conventional honeycombs. In order to improve the stiffness of the auxetic structures, a pair of crossed rods is introduce to each cell. The relative densities of 3D auxetic structures are derived theoretically. The coupling effects of the geometrical parameters on the relative density are investigated. Then the deformation patterns of the underwater tunnels at different blast heights are analyzed. The kinetic energy and absorbed energy are discussed for tunnels with 3D auxetic materials and solid materials. Results show that tunnels composed with 3D reinforced auxetic structures can absorb much more energy than solid ones. Moreover, localized damage is observed which means greater chance of survival and smaller repairs after extreme impact. Finally, a stiffness-improved 3D reinforced auxetic structure is presented to enhance the tunnel’s strength and stability further.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"119 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141105716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of nitrogen content on the static recrystallization and precipitation behaviors of vanadium–titanium microalloyed steels 氮含量对钒钛微合金钢静态再结晶和析出行为的影响
International Journal of Materials Research Pub Date : 2024-05-23 DOI: 10.1515/ijmr-2023-0122
Baochun Zhao, Tan Zhao, Lei Huang, Junbo Li
{"title":"Effect of nitrogen content on the static recrystallization and precipitation behaviors of vanadium–titanium microalloyed steels","authors":"Baochun Zhao, Tan Zhao, Lei Huang, Junbo Li","doi":"10.1515/ijmr-2023-0122","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0122","url":null,"abstract":"\u0000 Double compression tests were performed on vanadium–titanium microalloyed steels with different nitrogen contents by using a Gleeble-3800 thermo-mechanical simulator to study the softening behaviors of the deformed austenite during different time intervals between the two passes. The static recrystallization fractions were calculated by the stress offset method and static recrystallization diagrams for the tested steels were obtained. The effects of deformation temperature and interval time on the softening behaviors were analyzed. Especially, the effect of nitrogen on the softening behaviors of the tested steels is discussed in detail. The results showed that the softening behaviors of the tested steels with various nitrogen contents are different. As far as the steel with low nitrogen content is concerned, the softening fraction increases monotonically with increasing time interval, and higher temperature can promote the static recrystallization. However, with more nitrogen added into vanadium–titanium microalloyed steel, precipitated particles of vanadium titanium carbonitride can be observed in the tested steel at the temperature of 850 °C or 800 °C, which leads to the formation of plateaus on the softening curves. An increase in nitrogen content in the steel is favorable for vanadium titanium carbonitride precipitation, which leads to a stronger prohibition of static recrystallization and a longer plateau on the softening curves. Moreover, the precipitated particles in the tested steel will not play an inhibition role in static recrystallization until the nitrogen content in the steel reaches a critical value.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"21 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141105250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation and thermodynamic analysis of TiC–Fe cermets with Mo additions 添加钼的 TiC-Fe 金属陶瓷的实验研究和热力学分析
International Journal of Materials Research Pub Date : 2024-05-22 DOI: 10.1515/ijmr-2023-0199
Yafei Pan, Lei Huang, Yong Du
{"title":"Experimental investigation and thermodynamic analysis of TiC–Fe cermets with Mo additions","authors":"Yafei Pan, Lei Huang, Yong Du","doi":"10.1515/ijmr-2023-0199","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0199","url":null,"abstract":"\u0000 In this study, the effects of Mo additions on the microstructure, hardness and bending strength of TiC–Fe cermets manufactured by spark plasma sintering were investigated by scanning electron microscopy, X-ray diffraction and mechanical properties tests. Thermodynamic calculations were utilized to analyze the evolution of the microstructure. The results show that the conventional core/rim structure was not formed during the solid-phase sintering of TiC–Fe cermets. The heat-treatment process and reasonable Mo addition can effectively enhance the overall performance of the alloys. With the addition of minor Mo, the hardness of the sintered cermets improved significantly, which was attributed to the solid solution strengthening mechanism of Mo in Fe binder. However, excessive Mo exceeded the solubility range of Fe binder and precipitated in the form of M\u0000 6C and Mo2C phases, which damaged the bending strength of the heat-treated cermets.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"56 51","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141108520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dewetting upside-down: two-sided solid state dewetting of thin gold film on soft KBr substrate 颠倒露化:软 KBr 基底上金薄膜的双面固态露化
International Journal of Materials Research Pub Date : 2024-01-19 DOI: 10.1515/ijmr-2023-0124
Ehud Almog, Chen Nachmias, Nadav Orion, Jonathan Zimmerman, A. Bisht, L. Klinger, E. Rabkin
{"title":"Dewetting upside-down: two-sided solid state dewetting of thin gold film on soft KBr substrate","authors":"Ehud Almog, Chen Nachmias, Nadav Orion, Jonathan Zimmerman, A. Bisht, L. Klinger, E. Rabkin","doi":"10.1515/ijmr-2023-0124","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0124","url":null,"abstract":"\u0000 We deposited a 30 nm-thick Au film on single crystalline KBr substrate and studied the solid state dewetting behavior of the film at a temperature of 350 °C. At this temperature, the ions of the KBr compound exhibit significant mobility along the Au–KBr interface, which affects the morphology and kinetics of the solid state dewetting. We performed statistical morphology analysis of the Au–KBr interface by selectively dissolving the KBr substrate after the dewetting heat treatments and subsequent atomic force microscopy imaging of the “upside-down” oriented Au film. We demonstrated that atomic mobility at the interface leads to embedding of the partially dewetted Au film into the KBr substrate. We proposed a quantitative model of the shape evolution of a disc-shaped Au particle on the KBr substrate under the condition of finite interface mobility of the substrate species. The model predictions were consistent with the experimentally observed sinking rates of Au nanostructures.","PeriodicalId":510356,"journal":{"name":"International Journal of Materials Research","volume":"7 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139524657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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