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Cavity-Induced Optical Nonreciprocity Based on Degenerate Two-Level Atoms 基于退化两级原子的腔诱导光学非互易性
Nanomaterials Pub Date : 2024-07-23 DOI: 10.3390/nano14151236
Chuan-Zhao Qi, Jia-Rui Zheng, Yuan-Hang Tong, Ruo-Nan Li, Dan Wang, Liang-Hui Huang, Hai-Tao Zhou
{"title":"Cavity-Induced Optical Nonreciprocity Based on Degenerate Two-Level Atoms","authors":"Chuan-Zhao Qi, Jia-Rui Zheng, Yuan-Hang Tong, Ruo-Nan Li, Dan Wang, Liang-Hui Huang, Hai-Tao Zhou","doi":"10.3390/nano14151236","DOIUrl":"https://doi.org/10.3390/nano14151236","url":null,"abstract":"We developed and experimentally realized a scheme of optical nonreciprocity (ONR) by using degenerate two-level atoms embedded in an optical ring cavity. For the degenerate transition Fg = 4 ↔ Fe = 3, we first studied the cavity-transmission property in different coupling field configurations and verified that under the strong-coupling regime, the single-dark-state peak formed by electromagnetically induced transparency (EIT) showed ONR. The stable ground-state Zeeman coherence for Λ-chains involved in the degenerate two-level system was found to be important in the formation of intracavity EIT. However, different from the three-level atom–cavity system, in the degenerate two-level system, the ONR effect based on intracavity EIT occurred only at a low probe intensity, because the cavity–atom coupling strength was weakened in the counter-propagating probe and coupling field configuration. Furthermore, ONR transmission with a high contrast and linewidth-narrowing was experimentally demonstrated.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"32 29","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141813994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimized Ammonia-Sensing Electrode with CeO2/rGO Nano-Composite Coating Synthesized by Focused Laser Ablation in Liquid 通过液态聚焦激光烧蚀技术合成的具有 CeO2/rGO 纳米复合涂层的优化氨传感电极
Nanomaterials Pub Date : 2024-07-23 DOI: 10.3390/nano14151238
Mengqi Shi, Hiroyuki Wada
{"title":"Optimized Ammonia-Sensing Electrode with CeO2/rGO Nano-Composite Coating Synthesized by Focused Laser Ablation in Liquid","authors":"Mengqi Shi, Hiroyuki Wada","doi":"10.3390/nano14151238","DOIUrl":"https://doi.org/10.3390/nano14151238","url":null,"abstract":"This study investigated the synthesis of cerium oxide (CeO2) nanoparticles (NPs) and composites with reduced graphene oxide (rGO) for the enhanced electrochemical sensing of ammonia. CeO2 NPs were prepared by the focused laser ablation in liquid (LAL) method, which enabled the production of high-purity, spherical nanoparticles with a uniform dispersion and sizes under 50 nm in a short time. The effects of varying irradiation fluence and time on the nanoparticle size, production yield, and dispersion were systematically studied. The synthesized CeO2 NPs were doped with rGO to form CeO2/rGO composites, which were drop casted to modify the glassy carbon electrodes (GCE). The CeO2/rGO-GCE electrodes exhibited superior electrochemical properties compared with single-component electrodes, which demonstrated the significant potential for ammonia detection, especially at a 4 J/cm2 fluence. The CeO2/rGO composites showed uniformly dispersed CeO2 NPs between the rGO sheets, which enhanced the conductivity, as confirmed by SEM, EDS mapping, and XRD analysis. Cyclic voltammetry data demonstrated superior electrochemical activity of the CeO2/rGO composite electrodes, with the 2rGO/1CeO2 ratio showing the highest current response and sensitivity. The CV response to varying ammonia concentrations exhibited a linear relationship, indicating the electrode’s capability for accurate quantification. These findings highlight the effectiveness of focused laser ablation in enhancing nanoparticle synthesis and the promising synergistic effects of CeO2 and rGO in developing high-performance electrochemical sensors.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"91 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141812417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
LAB-to-FAB Transition of 2D FETs: Available Strategies and Future Trends 二维场效应晶体管的 LAB 到 FAB 过渡:现有策略和未来趋势
Nanomaterials Pub Date : 2024-07-23 DOI: 10.3390/nano14151237
Yury Illarionov, Yezhu Lv, Yehao Wu, Yajing Chai
{"title":"LAB-to-FAB Transition of 2D FETs: Available Strategies and Future Trends","authors":"Yury Illarionov, Yezhu Lv, Yehao Wu, Yajing Chai","doi":"10.3390/nano14151237","DOIUrl":"https://doi.org/10.3390/nano14151237","url":null,"abstract":"The last decade has seen dramatic progress in research on FETs with 2D channels. Starting from the single devices fabricated using exfoliated flakes in the early 2010s, by the early 2020s, 2D FETs being trialed for mass production and vertical stacking of 2D channels made by leading semiconductor companies. However, the industry is focused solely on transition metal dichalcogenide (TMD) channels coupled with conventional 3D oxide insulators such as Al2O3 and HfO2. This has resulted in numerous challenges, such as poor-quality interfaces and reliability limitations due to oxide traps. At the same time, the alternative routes for 2D FETs offered by laboratory (LAB) research have not been appreciated until now, even though the use of the native oxides of 2D channels has recently resulted in the first 2D FinFETs. Considering the research progress achieved in the last decade, from this perspective, we will discuss the main challenges for industry integration of 2D FETs and also suggest possible future steps which could propel these emerging technologies towards market applications.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"35 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141813977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rate-Dependent Stability and Electrochemical Behavior of Na3NiZr(PO4)3 in Sodium-Ion Batteries 钠离子电池中 Na3NiZr(PO4)3随速率变化的稳定性和电化学行为
Nanomaterials Pub Date : 2024-07-16 DOI: 10.3390/nano14141204
Marwa Tayoury, Abdelwahed Chari, M. Aqil, Adil Sghiouri Idrissi, Ayoub El Bendali, J. Alami, Y. Tamraoui, M. Dahbi
{"title":"Rate-Dependent Stability and Electrochemical Behavior of Na3NiZr(PO4)3 in Sodium-Ion Batteries","authors":"Marwa Tayoury, Abdelwahed Chari, M. Aqil, Adil Sghiouri Idrissi, Ayoub El Bendali, J. Alami, Y. Tamraoui, M. Dahbi","doi":"10.3390/nano14141204","DOIUrl":"https://doi.org/10.3390/nano14141204","url":null,"abstract":"In advancing sodium-ion battery technology, we introduce a novel application of Na3NiZr(PO4)3 with a NASICON structure as an anode material. This research unveils, for the first time, its exceptional ability to maintain high specific capacity and unprecedented cycle stability under extreme current densities up to 1000 mA·g−1, within a low voltage window of 0.01–2.5 V. The core of our findings lies in the material’s remarkable capacity retention and stability, which is a leap forward in addressing long-standing challenges in energy storage. Through cutting-edge in situ/operando X-ray diffraction analysis, we provide a perspective on the structural evolution of Na3NiZr(PO4)3 during operation, offering deep insights into the mechanisms that underpin its superior performance.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"3 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141641608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Helical Hybrid Nanostructure Based on Chiral M13 Bacteriophage via Evaporation-Induced Three-Dimensional Process 通过蒸发诱导三维工艺获得基于手性 M13 噬菌体的螺旋混合纳米结构
Nanomaterials Pub Date : 2024-07-16 DOI: 10.3390/nano14141208
Thanh Mien Nguyen, Sung-Jo Kim, Daegon Ryu, Jae Hun Chung, S. Lee, Sun-Hwi Hwang, Cheol Woong Choi, Jin‐Woo Oh
{"title":"Helical Hybrid Nanostructure Based on Chiral M13 Bacteriophage via Evaporation-Induced Three-Dimensional Process","authors":"Thanh Mien Nguyen, Sung-Jo Kim, Daegon Ryu, Jae Hun Chung, S. Lee, Sun-Hwi Hwang, Cheol Woong Choi, Jin‐Woo Oh","doi":"10.3390/nano14141208","DOIUrl":"https://doi.org/10.3390/nano14141208","url":null,"abstract":"The use of naturally sourced organic materials with chirality, such as the M13 bacteriophage, holds intriguing implications, especially in the field of nanotechnology. The chirality properties of bacteriophages have been demonstrated through numerous studies, particularly in the analysis of liquid crystal phase transitions, developing specific applications. However, exploring the utilization of the M13 bacteriophage as a template for creating chiral nanostructures for optics and sensor applications comes with significant challenges. In this study, the chirality of the M13 bacteriophage was leveraged as a valuable tool for generating helical hybrid structures by combining it with nanoparticles through an evaporation-induced three-dimensional (3D) printing process. Utilizing on the self-assembly property of the M13 bacteriophage, metal nanoparticles were organized into a helical chain under the influence of the M13 bacteriophage at the meniscus interface. External parameters, including nanoparticle shape, the ratio between the bacteriophage and nanoparticles, and pulling speed, were demonstrated as crucial factors affecting the fabrication of helical nanostructures. This study aimed to explore the potential of chiral nanostructure fabrication by utilizing the chirality of the M13 bacteriophage and manipulating external parameters to control the properties of the resulting hybrid structures.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"1 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141640738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Niu, Y.; Galluzzi, M. Hyaluronic Acid/Collagen Nanofiber Tubular Scaffolds Support Endothelial Cell Proliferation, Phenotypic Shape and Endothelialization. Nanomaterials 2021, 11, 2334 更正:Niu, Y.; Galluzzi, M. Hyaluronic Acid/Collagen Nanofiber Tubular Scaffolds Support Endothelial Cell Proliferation, Phenotypic Shape and Endothelialization.纳米材料,2021,11,2334
Nanomaterials Pub Date : 2024-07-16 DOI: 10.3390/nano14141203
Yuqing Niu, M. Galluzzi
{"title":"Correction: Niu, Y.; Galluzzi, M. Hyaluronic Acid/Collagen Nanofiber Tubular Scaffolds Support Endothelial Cell Proliferation, Phenotypic Shape and Endothelialization. Nanomaterials 2021, 11, 2334","authors":"Yuqing Niu, M. Galluzzi","doi":"10.3390/nano14141203","DOIUrl":"https://doi.org/10.3390/nano14141203","url":null,"abstract":"In the original publication [...]","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"24 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141644017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mo-Doped Ni/C Catalyst for Improved Simultaneous Production of Hydrogen and Carbon Nanotubes through Ethanol Decomposition 通过乙醇分解同时生产氢气和碳纳米管的掺钼镍/碳催化剂
Nanomaterials Pub Date : 2024-07-16 DOI: 10.3390/nano14141205
Jinxiang Diao, Xiaojie Liu, Xianmeng Wang, Yuzhu Zhang, Jingkai Yue, Hui Wang
{"title":"Mo-Doped Ni/C Catalyst for Improved Simultaneous Production of Hydrogen and Carbon Nanotubes through Ethanol Decomposition","authors":"Jinxiang Diao, Xiaojie Liu, Xianmeng Wang, Yuzhu Zhang, Jingkai Yue, Hui Wang","doi":"10.3390/nano14141205","DOIUrl":"https://doi.org/10.3390/nano14141205","url":null,"abstract":"A Mo-Ni/C catalyst was developed and assessed in terms of the decomposition of ethanol to produce multi-wall carbon nanotubes (MWCNTs) and hydrogen. The catalyst utilized different molar ratios of Mo:Ni (1:9, 2:8, and 3:7), with Mo acting as a dopant to enhance the MWCNT yield and Ni acting as the primary active phase for MWCNT formation. Among the tested ratios, the 2:8 Mo:Ni ratio exhibited the optimal performance, yielding 86% hydrogen and high-quality MWCNTs. In addition to hydrogen, the process also generated CO, CH4, and CO2. Gas chromatography (GC) was employed to analyze the influence of the Mo:Ni ratio on gas production and selectivity, while the quality of the resulting MWCNTs was evaluated using SEM, Raman spectroscopy, and TEM analyses.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"15 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141641473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Size-Dependent Thresholds in CuO Nanowires: Investigation of Growth from Microstructured Thin Films for Gas Sensing 氧化铜纳米线的尺寸阈值:用于气体传感的微结构薄膜的生长研究
Nanomaterials Pub Date : 2024-07-16 DOI: 10.3390/nano14141207
Christian Maier, V. Leitgeb, Larissa Egger, Anton Köck
{"title":"Size-Dependent Thresholds in CuO Nanowires: Investigation of Growth from Microstructured Thin Films for Gas Sensing","authors":"Christian Maier, V. Leitgeb, Larissa Egger, Anton Köck","doi":"10.3390/nano14141207","DOIUrl":"https://doi.org/10.3390/nano14141207","url":null,"abstract":"An experimental characterization of cupric oxide nanowire (CuO NW) growth from thermally oxidized, microstructured Cu thin films is performed. We have systematically studied the influence of the thickness and dimension of Cu layers on the synthesis of CuO NW. The objective was to determine the optimum Cu geometries for increased CuO NWs growth to bridge the gap between adjacent Cu structures directly on the chip for gas sensing applications. Thresholds for CuO-NW growth regarding film thickness and lateral dimensions are identified based on SEM images. For a film thickness of 560 nm, NWs with lengths > 500 nm start to grow from the edges of Cu structures with an area ≥ 4 µm2. NWs growing from the upper surface were observed for an area ≥ 16 µm2. NW growth between adjacent thermally oxidized thin films was analyzed. The study provides information on the most relevant parameters of CuO NWs growth, which is mandatory for integrating CuO NWs as gas sensor components directly on microchips. Based on this result, the gap size of the structure was varied to find the optimum value of 3 µm.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"92 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141642756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potentiometric Studies on Ion-Transport Selectivity in Charged Gold Nanotubes 带电金纳米管中离子传输选择性的电位计研究
Nanomaterials Pub Date : 2024-07-16 DOI: 10.3390/nano14141209
Thomas T. Volta, Stevie N. Walters, Charles R. Martin
{"title":"Potentiometric Studies on Ion-Transport Selectivity in Charged Gold Nanotubes","authors":"Thomas T. Volta, Stevie N. Walters, Charles R. Martin","doi":"10.3390/nano14141209","DOIUrl":"https://doi.org/10.3390/nano14141209","url":null,"abstract":"Under ideal conditions, nanotubes with a fixed negative tube-wall charge will reject anions and transport-only cations. Because many proposed nanofluidic devices are optimized in this ideally cation-permselective state, it is important to know the experimental conditions that produce ideal responses. A parameter called Ccrit, the highest salt concentration in a contacting solution that still produces ideal cation permselectivity, is of particular importance. Pioneering potentiometric studies on gold nanotubes were interpreted using an electrostatic model that states that Ccrit should occur when the Debye length in the contacting salt solution becomes equivalent to the tube radius. Since this “double-layer overlap model” (DLOM), treats all same-charge ions as identical point charges, it predicts that all same-charged cations should produce the same Ccrit. However, the effect of cation on Ccrit in gold nanotubes was never investigated. This knowledge gap has become important because recent studies with a polymeric cation-permselective nanopore membrane showed that DLOM failed for every cation studied. To resolve this issue, we conducted potentiometric studies on the effect of salt cation on Ccrit for a 10 nm diameter gold nanotube membrane. Ccrit for all cations studied were, within experimental error, the same and identical, with values predicted by DLOM. The reason DLOM prevailed for the gold nanotubes but failed for the polymeric nanopores stems from the chemical difference between the fixed negative charges of these two membranes.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"5 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141642110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulation and Experimental Investigation of the Effect of Pore Shape on Heat Transfer Behavior of Phase Change Materials in Porous Metal Structures 多孔金属结构中孔隙形状对相变材料传热行为影响的模拟与实验研究
Nanomaterials Pub Date : 2024-07-16 DOI: 10.3390/nano14141206
Chao Chang, Bo Li, Baocai Fu, Xu Yang, Tianyi Lou, Yulong Ji
{"title":"Simulation and Experimental Investigation of the Effect of Pore Shape on Heat Transfer Behavior of Phase Change Materials in Porous Metal Structures","authors":"Chao Chang, Bo Li, Baocai Fu, Xu Yang, Tianyi Lou, Yulong Ji","doi":"10.3390/nano14141206","DOIUrl":"https://doi.org/10.3390/nano14141206","url":null,"abstract":"With the gradual increase in energy demand in global industrialization, the energy crisis has become an urgent problem. Due to high heat storage density, small volume change, and nearly constant transition temperature, phase change materials (PCMs) provide a promising method to store thermal energy. In this work, we designed and fabricated three kinds of porous metal structures with hexagonal, rectangular, and circular pores and explored the phase change process of PCMs within them. A two-dimensional numerical model was established to investigate the heat transfer process of PCMs within different shapes of porous metal structures and analyze the influence of heat source location on the thermal performance of the thermal storage units. Visualization experiments were also carried out to reveal the melting process of PCMs within different porous metal structures by a digital camera. The results show that paraffin in a porous metal structure with hexagonal pores has the fastest melting rate, while that in a porous metal structure with circular pores has the slowest melting rate. Under the bottom heating mode, the melting time of the paraffin in porous metal structures with hexagonal pores is shortened by 18.6% compared to that in porous metal structures with circular pores. Under the left heating mode, the corresponding melting time is shortened by 16.7%. These findings in this work will offer an effective method to design and optimize the structure of porous metal and improve the thermal properties of PCMs.","PeriodicalId":508599,"journal":{"name":"Nanomaterials","volume":"66 21","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141643378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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