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“Sowing in Science Brings a Rich Harvest for the People.” Life and Work of S. A. Fokin "科学播种，人民丰收"。斯-阿-福金的生活和工作
IF 0.7
Catalysis in Industry Pub Date : 2024-05-27 DOI: 10.1134/S2070050424700107
R. M. Mironenko, A. V. Lavrenov
{"title":"“Sowing in Science Brings a Rich Harvest for the People.” Life and Work of S. A. Fokin","authors":"R. M. Mironenko,&nbsp;A. V. Lavrenov","doi":"10.1134/S2070050424700107","DOIUrl":"10.1134/S2070050424700107","url":null,"abstract":"<p>An essay on the scientific activities of the Russian organic chemist and chemical engineer Sergei Alekseevich Fokin (1865–1917) is presented. The name of the scientist is not widely known although he has made the main contribution to the development of oleochemistry and creation of the industrial process of fat hydrogenation in Russia, and his merits have been appreciated by domestic and foreign researchers.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 2","pages":"196 - 215"},"PeriodicalIF":0.7,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141168007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-Loaded Copper-Containing Catalysts for Furfural Hydroconversion 用于糠醛加氢转化的高负载含铜催化剂
IF 0.7
Catalysis in Industry Pub Date : 2024-05-27 DOI: 10.1134/S2070050424700028
S. A. Selishcheva, A. A. Sumina, O. A. Bulavchenko, V. A. Yakovlev
{"title":"High-Loaded Copper-Containing Catalysts for Furfural Hydroconversion","authors":"S. A. Selishcheva,&nbsp;A. A. Sumina,&nbsp;O. A. Bulavchenko,&nbsp;V. A. Yakovlev","doi":"10.1134/S2070050424700028","DOIUrl":"10.1134/S2070050424700028","url":null,"abstract":"<p>In this paper, high-loaded copper-containing catalysts synthesized by the different methods (sol–gel, fusion, coprecipitation) have been studied in furfural hydroconversion in a batch reactor at a hydrogen pressure of 5.0 MPa and a temperature of 100°C. The reduction temperatures and phase composition of the catalysts have been determined by physicochemical methods. It has been shown that the highest activity in the studied process is exhibited by a coprecipitated copper–alumina catalyst, which provides the production of furfuryl alcohol with a selectivity of 100% at 100–130°C; in addition, in the presence of this catalyst, 2-methylfuran can be synthesized with a yield of 65% at 200°C. The phase composition of the catalyst reduced at a selected temperature and the catalyst after reaction has been determined.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 2","pages":"123 - 132"},"PeriodicalIF":0.7,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141168010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation of Epoxycyclooctane during the Co-Oxidation of Cyclooctene and Alkylbenzenes 环辛烯和烷基苯的共氧化作用生成环氧环辛烷
IF 0.7
Catalysis in Industry Pub Date : 2024-05-27 DOI: 10.1134/S2070050424700041
N. I. Kuznetsova, V. N. Zudin
{"title":"Formation of Epoxycyclooctane during the Co-Oxidation of Cyclooctene and Alkylbenzenes","authors":"N. I. Kuznetsova,&nbsp;V. N. Zudin","doi":"10.1134/S2070050424700041","DOIUrl":"10.1134/S2070050424700041","url":null,"abstract":"<p>Cyclooctene and alkylbenzenes are subjected to co-oxidation in oxygen and a system of two catalysts. Radical catalyst Fe(acac)<sub>3</sub>/NHPI mediates the formation of alkylbenzene hydroperoxides, which are consumed in situ during the MoO<sub>3</sub>/SiO<sub>2</sub>-catalyzed epoxidation of cyclooctene. The chain oxidation rate is limited in cyclooctene and MoO<sub>3</sub>/SiO<sub>2</sub>, but radical catalyst Fe(acac)<sub>3</sub>/NHPI retains fairly high activity in the oxidation of alkylbenzene in hydroperoxide. It is found that isopropylbenzene is a better co-reducing agent than ethylbenzene because it ensures more vigorous and selective formation of epoxycyclooctane. At optimized amounts of components and a temperature of 80°C, selectivity toward epoxycyclooctane reaches 92 and 96% in ethylbenzene or isopropylbenzene, respectively, with more than 70% conversion of cyclooctene.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 2","pages":"141 - 151"},"PeriodicalIF":0.7,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141168074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of Microalgae Biomass to Synthesize Marketable Products: 3. Production of Motor Fuels from Microalgae Biomass Using Catalytic Approaches 利用微藻生物质合成适销产品：3.使用催化方法利用微藻生物质生产汽车燃料
IF 0.7
Catalysis in Industry Pub Date : 2024-05-13 DOI: 10.1134/S2070050424010082
K. N. Sorokina, Yu. V. Samoylova, V. N. Parmon
{"title":"Use of Microalgae Biomass to Synthesize Marketable Products: 3. Production of Motor Fuels from Microalgae Biomass Using Catalytic Approaches","authors":"K. N. Sorokina,&nbsp;Yu. V. Samoylova,&nbsp;V. N. Parmon","doi":"10.1134/S2070050424010082","DOIUrl":"10.1134/S2070050424010082","url":null,"abstract":"<p>The review addresses the main approaches used in the thermochemical and catalytic conversion of microalgae biomass (hydrothermal liquefaction, gasification, transesterification, pyrolysis) to produce biofuels. The key conditions that determine the reaction product yield using bio-oil production catalysts and approaches to bio-oil refining are discussed. It is shown that the use of bifunctional acid–base catalysts is most relevant for transesterification processes. The gasification and pyrolysis processes are used less frequently, because the former is accompanied by the formation of CO<sub>2</sub>, and the latter is characterized by the formation of a large amount of oxidized compounds that deteriorate the quality of bio-oil.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 1","pages":"77 - 88"},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of Microalgae Biomass to Synthesize Marketable Products: 2. Modern Approaches to Integrated Biorefinery of Microalgae Biomass 利用微藻生物质合成适销产品：2.微藻生物质综合生物炼制的现代方法
IF 0.7
Catalysis in Industry Pub Date : 2024-05-13 DOI: 10.1134/S2070050424010057
Yu. V. Samoylova, K. N. Sorokina, V. N. Parmon
{"title":"Use of Microalgae Biomass to Synthesize Marketable Products: 2. Modern Approaches to Integrated Biorefinery of Microalgae Biomass","authors":"Yu. V. Samoylova,&nbsp;K. N. Sorokina,&nbsp;V. N. Parmon","doi":"10.1134/S2070050424010057","DOIUrl":"10.1134/S2070050424010057","url":null,"abstract":"<p>The paper provides a review of reports in the field of microalgae biomass conversion to various types of biofuels (fatty acid methyl esters, ethanol, butanol, hydrogen) and marketable chemicals, in particular, polyunsaturated fatty acids, pigments, and proteins, using modern chemical and biotechnological approaches. This review addresses the synthesis of products using various strategies applied to develop modern approaches to the integrated biorefinery of microalgae biomass.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 1","pages":"69 - 76"},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biocatalytic Conversion of Semi-Finished Hardwood into Sugars: Enzymatic Hydrolysis at High Concentrations of the Substrate 生物催化将半成品硬木转化为糖：高浓度底物的酶水解作用
IF 0.7
Catalysis in Industry Pub Date : 2024-05-13 DOI: 10.1134/S2070050424010070
M. V. Semenova, V. D. Telitsin, A. M. Rozhkova, E. G. Kondratyeva, I. A. Shashkov, A. D. Satrutdinov, Ya. A. Gareeva, V. G. Moseev, A. M. Kryazhev, A. P. Sinitsyn
{"title":"Biocatalytic Conversion of Semi-Finished Hardwood into Sugars: Enzymatic Hydrolysis at High Concentrations of the Substrate","authors":"M. V. Semenova,&nbsp;V. D. Telitsin,&nbsp;A. M. Rozhkova,&nbsp;E. G. Kondratyeva,&nbsp;I. A. Shashkov,&nbsp;A. D. Satrutdinov,&nbsp;Ya. A. Gareeva,&nbsp;V. G. Moseev,&nbsp;A. M. Kryazhev,&nbsp;A. P. Sinitsyn","doi":"10.1134/S2070050424010070","DOIUrl":"10.1134/S2070050424010070","url":null,"abstract":"<p>Exhaustive enzymatic hydrolysis is performed for semi-bleached sulfate hardwood cellulose (a semi-finished pulp and paper product) at ultra-high concentrations of it in a reaction mixture (up to 300 g/L per dry compound). Russian commercial enzyme preparations are used for hydrolysis. The best seems to be Agroxil Plus, which has high cellulase and endoxylanase activities. A total of 290 g/L of sugars (including 210 g/L of glucose and 30 g/L of xylose) is obtained using Agroxil Plus (20 mg protein/1 g substrate) in combination with an auxiliary β-glucosidase enzyme preparation (2 mg protein/1 g substrate) at an initial semi-bleached cellulose concentration of 300 g/L. The dosage of Agroxil Plus can be halved (10 mg of protein/1 g of substrate with a total concentration of semi-bleached cellulose of 300 g/L) with a high yield of hydrolysis product (270 g/L of sugars, including 200 g/L of glucose and 30 g/L of xylose), due to the fractional addition of a substrate.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 1","pages":"102 - 109"},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catalytic Conversion of Ethanol to Aromatic Hydrocarbons in the Presence of Zeolite Catalysts 在沸石催化剂存在下催化乙醇转化为芳香烃
IF 0.7
Catalysis in Industry Pub Date : 2024-05-13 DOI: 10.1134/S2070050424010033
V. A. Koveza, O. V. Potapenko, A. V. Lavrenov
{"title":"Catalytic Conversion of Ethanol to Aromatic Hydrocarbons in the Presence of Zeolite Catalysts","authors":"V. A. Koveza,&nbsp;O. V. Potapenko,&nbsp;A. V. Lavrenov","doi":"10.1134/S2070050424010033","DOIUrl":"10.1134/S2070050424010033","url":null,"abstract":"<p>Results of studying ethanol conversion to aromatic hydrocarbons (benzene, toluene, xylenes) that are currently available in the scientific literature are discussed and systematized. The features of ethanol conversion in the presence of zeolite catalysts and the mechanism of each individual stage of ethanol conversion to aromatic hydrocarbons are discussed. The effect of the zeolite catalyst composition, the feedstock composition, and ethanol conversion process conditions is demonstrated. The effect of the modifier of a zeolite catalyst on the aromatic hydrocarbon selectivity is shown. This review can be of interest and of use to researchers of zeolite catalyst systems and alcohol conversion processes.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 1","pages":"39 - 57"},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deactivation of Mg/HZSM-5 Catalysts for the Synthesis of Lower Olefins from Dimethyl Ether in a Slurry Reactor 淤浆反应器中以二甲醚为原料合成低级烯烃的 Mg/HZSM-5 催化剂失活研究
IF 0.7
Catalysis in Industry Pub Date : 2024-05-13 DOI: 10.1134/S2070050424010094
A. N. Stashenko, T. I. Batova, T. K. Obukhova, N. V. Kolesnichenko
{"title":"Deactivation of Mg/HZSM-5 Catalysts for the Synthesis of Lower Olefins from Dimethyl Ether in a Slurry Reactor","authors":"A. N. Stashenko,&nbsp;T. I. Batova,&nbsp;T. K. Obukhova,&nbsp;N. V. Kolesnichenko","doi":"10.1134/S2070050424010094","DOIUrl":"10.1134/S2070050424010094","url":null,"abstract":"<p>Under slurry reactor conditions, the products of condensation are generrally formed on strong Mg/HZSM-5 acid sites independently of the SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> molar ratio in the zeolite. The composition of condensation products remains virtually unchanged as the molar ratio grows and basically consists of trimethyl and tetramethyl benzenes, but their content falls as the volume of mesopores grows with increasing SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub>. This lowers the hindrances to diffusion and the contribution from secondary reactions to improve the removal of coke precursors from the zeolite’s surface and favorably affect the catalyst’s activity (DME conversion doubles). The composition of reaction products changes slightly with an increase in the SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> molar ratio, and the total selectivity toward lower olefins is ~70 wt %. A rapid loss in Mg/HZSM-5 activity upon extending the period of operation under slurry reactor conditions is not due to coking, but to the catalyst being clogged by dispersion medium (polydimethylsiloxane) decomposition products.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 1","pages":"7 - 13"},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Estimating the Efficiency of Commercial Domestic Catalysts in the Reaction of Ammonia Decomposition 估算商用家用催化剂在氨分解反应中的效率
IF 0.7
Catalysis in Industry Pub Date : 2024-05-13 DOI: 10.1134/S2070050424010100
R. E. Yakovenko, T. V. Krasnyakova, A. V. Dul’nev, A. N. Saliev, M. A. Shilov, A. V. Volik, A. P. Savost’yanov, S. A. Mitchenko
{"title":"Estimating the Efficiency of Commercial Domestic Catalysts in the Reaction of Ammonia Decomposition","authors":"R. E. Yakovenko,&nbsp;T. V. Krasnyakova,&nbsp;A. V. Dul’nev,&nbsp;A. N. Saliev,&nbsp;M. A. Shilov,&nbsp;A. V. Volik,&nbsp;A. P. Savost’yanov,&nbsp;S. A. Mitchenko","doi":"10.1134/S2070050424010100","DOIUrl":"10.1134/S2070050424010100","url":null,"abstract":"<p>Adapting domestic commercial catalysts for use in such important technological processes as the environmentally friendly production of hydrogen accompanied by СО<sub><i>х</i></sub> and NО<sub><i>х</i></sub> emissions is in demand under import substitution conditions. Ammonia seems to be the most promising Н<sub>2</sub> accumulator, due to its high hydrogen density and simple storage and transportation. This work considers the possibility of using the domestic NIAP-03-01, NIAP-07-01, NIAP-06-06 catalysts and Со-Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> developed by the authors in the ammonia dissociation reaction. The conversion and hydrogen production capacity grow in the order NIAP-06-06&lt;NIAP-03-01&lt;NIAP-07-01&lt;Со-Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub>. The conversion of ammonia on Со-Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> is close to 100% at 550°C and a gas hourly space velocity (GHSV) of 3000 h<sup>−1</sup>. The effective activation energies of all the catalysts are comparable to the available literature data for the ammonia decomposition reaction to potentially enable their application at moderate temperatures.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 1","pages":"58 - 68"},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of Microalgae Biomass to Synthesize Marketable Products: 4. Production of Biofuels from Microalgae Using Bioengineering Approaches 利用微藻生物质合成适销产品：4.利用生物工程方法从微藻中生产生物燃料
IF 0.7
Catalysis in Industry Pub Date : 2024-05-13 DOI: 10.1134/S2070050424010069
Yu. V. Samoylova, K. N. Sorokina, V. N. Parmon
{"title":"Use of Microalgae Biomass to Synthesize Marketable Products: 4. Production of Biofuels from Microalgae Using Bioengineering Approaches","authors":"Yu. V. Samoylova,&nbsp;K. N. Sorokina,&nbsp;V. N. Parmon","doi":"10.1134/S2070050424010069","DOIUrl":"10.1134/S2070050424010069","url":null,"abstract":"<p>The paper provides a review of reports on the results of studies in the field of microalgae biomass cultivation and conversion to marketable chemicals using modern bioengineering approaches. The review discusses approaches to producing biofuels (biodiesel, ethanol, hydrogen) from microalgae. Data on biomass pretreatment methods and various procedures for isolating metabolites and converting them to biofuels are provided.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"16 1","pages":"89 - 101"},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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