ProcessesPub Date : 2024-07-19DOI: 10.3390/pr12071517
Maria Tarapoulouzi, J. Entrenas, Dolores Pérez-Marín, Ioannis Pashalidis, C. Theocharis
{"title":"A Preliminary Study on Determining Seasonal Variations in Halloumi Cheese Using Near-Infrared Spectroscopy and Chemometrics","authors":"Maria Tarapoulouzi, J. Entrenas, Dolores Pérez-Marín, Ioannis Pashalidis, C. Theocharis","doi":"10.3390/pr12071517","DOIUrl":"https://doi.org/10.3390/pr12071517","url":null,"abstract":"Cheese quality is affected by seasonal variations. These variations can influence several aspects of cheese, including its flavor, texture, nutritional content, and overall sensory qualities. The aim of this study was to assess the performance of near-infrared (NIR) instrumentation in terms of its ability to detect seasonal variations in Halloumi cheese samples when applying limited sample preparation compared to traditional protocols. Therefore, the use of NIR spectroscopy was examined for the determination of seasonal variations in Halloumi cheese samples from Cyprus in combination with chemometrics. Partial Least Squares Discriminant Analysis (PLS-DA) was applied. We found that NIR and chemometrics successfully discriminated the Halloumi cheese samples based on different climate conditions, the four seasons in the year when the milk collection took place. To externally validate the model, the dataset was divided into training and test sets. The innovation of this study is that Halloumi cheese was studied regarding seasonal variations by applying NIR for the first time. The outcome of this preliminary study is positive in terms of the capability of NIR to distinguish seasonal variations in Halloumi cheese, especially those due to differences in fatty acid molecules throughout the year. Future studies will include more samples to increase the current database.","PeriodicalId":506892,"journal":{"name":"Processes","volume":"117 34","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141822174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ProcessesPub Date : 2024-07-19DOI: 10.3390/pr12071520
Jie-Ming Huang, Jingning Guo, Chengmiao Xu, An Su, Ke-Jun Wu, Chao‐Hong He
{"title":"Direct Epoxidation of Hexafluoropropene Using Molecular Oxygen over Cu-Impregnated HZSM-5 Zeolites","authors":"Jie-Ming Huang, Jingning Guo, Chengmiao Xu, An Su, Ke-Jun Wu, Chao‐Hong He","doi":"10.3390/pr12071520","DOIUrl":"https://doi.org/10.3390/pr12071520","url":null,"abstract":"This study explores a novel method of directly epoxidizing hexafluoropropene with molecular oxygen under gaseous conditions using a Cu/HZSM-5 catalytic system (Cu/HZ). An in-depth investigation was conducted on the catalytic performance of Cu-based catalysts on various supports and Cu/HZ catalysts prepared under different conditions. Cu/HZ catalysts exhibited better catalytic performance than other porous medium-supported Cu catalysts for the epoxidation of hexafluoropropene by molecular oxygen. The highest propylene oxide yield of 35.6% was achieved over the Cu/HZ catalyst prepared under conditions of 350 °C with a Cu loading of 1 wt%. By applying characterization techniques including XRD, BET, NH3-TPD, and XPS to different catalyst samples, the relationship between the interaction of Cu2+ and HZSM-5 and the reactivity of the catalyst was studied, thereby elucidating the influence of calcination temperature and loading on the reactivity. Finally, we further proposed the possible mechanism of how isolated Cu2+ and acid sites improve catalytic performance.","PeriodicalId":506892,"journal":{"name":"Processes","volume":"7 16","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141822457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Micropore Characteristics and Geological Significance of a Tuffaceous Tight Reservoir Formed by Burial Dissolution: A Case Study of the Carboniferous Tuff in the Santanghu Basin, NW China","authors":"Jian Ma, Yongshuai Pan, Zhongzheng Tong, Guoqiang Zhang","doi":"10.3390/pr12071514","DOIUrl":"https://doi.org/10.3390/pr12071514","url":null,"abstract":"As a distinct type of reservoir, tuffaceous tight reservoirs have attracted much attention. However, previous studies on tuffaceous tight reservoirs formed in the burial diagenetic stage are few, particularly regarding the genesis of micropores, which restricts the in-depth exploration of tuffaceous tight oil. According to thin section observation, scanning electron microscopy (SEM) identification, X-ray diffraction (XRD) experiments, elemental analyses, porosity and permeability tests, and pore structure analyses, the micropore characteristics of the Carboniferous tuffaceous tight reservoir formed by burial dissolution in the Santanghu Basin, NW China, are studied. In addition, the cause of the tuff micropore formation and its geological significance are also researched in this paper. The results are as follows: (1) The tuffaceous tight reservoir formed by burial dissolution mainly consists of quartz, feldspar, dolomite, and clay minerals. The reservoir space mainly consists of intergranular pores between minerals, intragranular dissolution pores within feldspars, calcite, dolomite, clay minerals, and locally developed organic matter pores. (2) The formation of micropores in tuff reservoirs formed by burial dissolution is mainly related to the original composition of the tuff. (3) Tuffaceous reservoirs with good physical properties are usually formed at the bottom or top of a large set of source rock. The results of this investigation can provide innovative theoretical evidence for the accumulation mechanism of tuffaceous tight oil formed by burial dissolution. Meanwhile, it can be considered a reference regarding the distribution of and predictions for tuffaceous reservoirs formed by burial dissolution in similar situations in other parts of the world.","PeriodicalId":506892,"journal":{"name":"Processes","volume":" 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141826240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Seismic Identification of Small Strike-Slip Faults in the Deep Sichuan Basin (SW China)","authors":"Hai Li, Jiawei Liu, Majia Zheng, Siyao Li, Hui Long, Chenghai Li, Xuri Huang","doi":"10.3390/pr12071508","DOIUrl":"https://doi.org/10.3390/pr12071508","url":null,"abstract":"Recently, the “sweet spot” of a fractured reservoir, controlled by a strike-slip fault, has been found and become the favorable target for economic exploitation of deep (>4500 m) tight gas reservoirs in the Sichuan Basin, Southwestern China. However, hidden faults of small vertical displacements (<20 m) are generally difficult to identify using low signal–noise rate seismic data for deep subsurfaces. In this study, we propose a seismic processing method to improve imaging of the hidden strike-slip fault in the central Sichuan Basin. On the basis of the multidirectional and multiscale decomposition and reconstruction processes, seismic information on the strike-slip fault can be automatically enhanced to improve images of it. Through seismic processing, the seismic resolution increased to a large extent enhancing the fault information and presenting a distinct fault plane rather than an ambiguous deflection of the seismic wave, as well as a clearer image of the sectional seismic attributes. Subsequently, many more small strike-slip faults, III–IV order faults with a vertical displacement, in the range of 5–20 m, were identified with the reprocessing data for the central Sichuan Basin. The pre-Mesozoic intracratonic strike-slip fault system was also characterized using segmentation and paralleled dispersive distribution in the Sichuan Basin, suggesting that this seismic process method is applicable for the identification of deep, small strike-slip faults, and there is great potential for the fractured reservoirs along small strike-slip fault zones in deep tight matrix reservoirs.","PeriodicalId":506892,"journal":{"name":"Processes","volume":" 89","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141824507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study on the Damage Evolution and Failure Mechanism of Floor Strata under Coupled Static-Dynamic Loading Disturbance","authors":"Hailong Li, Haibo Bai, Wenjie Xu, Bing Li, Peitao Qiu, Ruixue Liu","doi":"10.3390/pr12071513","DOIUrl":"https://doi.org/10.3390/pr12071513","url":null,"abstract":"In the field test, we found that the failure depth of the goaf floor strata tends to be further because the periodic breaking and caving of the immediate roof, upper roof, and roof key stratum has dynamic stress disturbance effects on the floor. To further analyze its formation mechanism, this paper studies the damage evolution and fracture mechanism of goaf floor rock under the coupled static-dynamic loading disturbance caused by roof caving, based on the stress distribution state, the damage evolution equation of coal measure rock, the damage constitutive model, and the fracture criterion of floor rock. The main conclusions are listed as follows: 1. Based on the mining floor stress distribution, the floor beam model establishes the response mechanism of floor rock stress distribution. Also, the equation of stress distribution at any position in floor strata under mining dynamic load is given. 2. Combining the advantages of Bingham and the Generalized-Boydin model, the B-G damage constitutive model is established, which can describe the constitutive characteristics of coal measure rock under the coupled static-dynamic loading disturbance well. Furthermore, the variation law of parameters changing with strain rate is analyzed. 3. According to the twin-shear unified strength yield theory and the B-G damage constitutive model, coal measure rock’s twin-shear unified strength damage fracture criterion is established. Finally, the stress distribution expression of floor strata under concentrated and uniform dynamic loads is introduced, and the fracture criterion of goaf floor strata under a coupled static-dynamic loading disturbance is proposed.","PeriodicalId":506892,"journal":{"name":"Processes","volume":" 41","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141827007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ProcessesPub Date : 2024-07-18DOI: 10.3390/pr12071511
Yanjiao Feng, Lifen Huang, Yue Zeng, Yiyuan Zhang, Wei Liu, Gang He
{"title":"Cloning, Expression and Enzymatic Characterization of Pectin Methyl Esterase from Populus trichocarpa and Its Application","authors":"Yanjiao Feng, Lifen Huang, Yue Zeng, Yiyuan Zhang, Wei Liu, Gang He","doi":"10.3390/pr12071511","DOIUrl":"https://doi.org/10.3390/pr12071511","url":null,"abstract":"The pectin methyl esterase gene from Populus trichocarpa (PtPME) was successfully cloned through PCR amplification and subsequently inserted into the expressing vector pMAL-c5e for successful expression in Escherichia coli BL21 (DE3). Initially, we determined the primary enzymatic properties of PtPME, a pectin methyl esterase derived from Populus trichocarpa. Notably, this enzyme exhibits a higher affinity towards citrus pectin, with an esterification degree exceeding 60%. Furthermore, this enzyme’s optimal reaction temperature and pH were found to be 30 °C and 8, respectively. Importantly, its exceptional stability under neutral conditions highlights its potential application in the industrial production of low-ester pectin.","PeriodicalId":506892,"journal":{"name":"Processes","volume":" 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141824038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ProcessesPub Date : 2024-07-18DOI: 10.3390/pr12071510
Jiaxiong He, Hui Cai, Yuanyuan Wang, Junyan Yan, Caixia Fan
{"title":"Matrix-Metalloproteinase-Responsive Brain-Derived Neurotrophic Factor for Spinal Cord Injury Repair","authors":"Jiaxiong He, Hui Cai, Yuanyuan Wang, Junyan Yan, Caixia Fan","doi":"10.3390/pr12071510","DOIUrl":"https://doi.org/10.3390/pr12071510","url":null,"abstract":"Brain-derived neurotrophic factor (BDNF) plays a vital role in supporting neuronal survival, differentiation, and promoting synaptogenesis, thereby facilitating synaptic plasticity in the central nervous system. Administration of exogenous BDNF is a crucial approach for treating central nervous system injuries. However, the inability of sustained drug release to match disease activity often leads to insufficient drug accumulation in the injured area (ineffectiveness) and severe side effects induced by the drug (toxicity). Matrix metalloproteinases (MMPs), especially MMP-2 and MMP-9, are typically upregulated after tissue damage, and their upregulated expression levels represent the degree of disease activity. In this study, we utilized bioengineering techniques to prepare a BDNF that can specifically bind to collagen and be released in response to MMP substrate cleavage (collagen binding domain tissue inhibitor of matrix metalloproteinases brain-derived neurotrophic factor, CBD-TIMP-BDNF). We verified the ability of CBD-BDNF and CBD-TIMP-BDNF to specifically bind to collagen through collagen binding experiments, examined the characteristics of CBD-TIMP-BDNF in response to MMP-2 to release BDNF, and detected the biological activities of both recombinant proteins. The results demonstrated that the established microenvironment-controlled BDNF release system can respond to MMP-2 to release BDNF. The recombinant proteins CBD-BDNF and CBD-TIMP-BDNF exhibited similar biological activities to the BDNF standard. Targeting the upregulated expression of MMPs after spinal cord injury as a trigger for drug release, it is expected to achieve on-demand release of BDNF in response to the severity of the disease.","PeriodicalId":506892,"journal":{"name":"Processes","volume":" 23","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141826308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ProcessesPub Date : 2024-07-18DOI: 10.3390/pr12071512
Jakub Demčák, K. Židek, T. Krenický
{"title":"Digital Twin for Monitoring the Experimental Assembly Process Using RFID Technology","authors":"Jakub Demčák, K. Židek, T. Krenický","doi":"10.3390/pr12071512","DOIUrl":"https://doi.org/10.3390/pr12071512","url":null,"abstract":"Despite the considerable advances that industrial manufacturing has undergone as a result of digitalization, the real-time monitoring of assembly processes continues to present a significant technical challenge. This article presents a solution to this problem by integrating digital twin technology with radio frequency identification (RFID) in order to improve the monitoring and optimization of assembly processes. The objective of this research is to develop a methodology that ensures synchronized data exchange between physical components and their digital counterparts using RFID for improved visibility and accuracy. The methodology entails the configuration of radio frequency identification systems to track the positions of products on conveyor belts, thereby facilitating real-time monitoring and the prompt detection of any deviations. This integration enhances remote monitoring capabilities and markedly optimizes assembly processes in comparison to traditional methods. The research findings suggest that this approach offers real-time data and monitoring capabilities, which can contribute to improved operational efficiency. This study presents an introduction to digital twins and RFID technology, a review of related research, a detailed methodology, an implementation plan, results and analysis, a discussion of the findings, and conclusions with future recommendations. This article presents a comprehensive discussion of the configuration of an RFID-based digital twin for an assembly line, highlighting the benefits and challenges of integrating these technologies into industrial processes.","PeriodicalId":506892,"journal":{"name":"Processes","volume":" 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141824540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ProcessesPub Date : 2024-06-14DOI: 10.3390/pr12061221
Ferid A. Yonis, Chun-Qing Li, Saman De Saliva
{"title":"Investigating the Reliability of an Existing Top Angle and Seat Pad Semi-Rigid Connection System Using Advanced Modelling Techniques","authors":"Ferid A. Yonis, Chun-Qing Li, Saman De Saliva","doi":"10.3390/pr12061221","DOIUrl":"https://doi.org/10.3390/pr12061221","url":null,"abstract":"The investigation introduces an advanced model procedure for evaluating the structural reliability of semi-rigid frame connections in existing aged buildings. Specifically, the focus is on the top angle and seat pad (TA–SP) semi-rigid connection, which was not initially considered in the current design standards. The approach employs a plastic hinge model to predict the ultimate strength of the connection and its beam-to-column behaviour. In order to increase computational efficiency, the investigation leverages the nonlinear behaviour of the finite element (FE) model to validate critical parameters. The statistical properties of the existing connection were obtained based on past experimental data, highlighting the weakest elements in the system. The first-order and second-order reliability methods and Monte Carlo simulations were employed to estimate the reliability index. Percentile errors were assessed to understand their impact on higher-order interactions. This new technique of identification quantifies the probability of the system failure interactions. Notably, a 45% lesser error aligns with the target reliability index, while a 114.5% larger error indicates a significant deviation from actual failure probability values. Each methodology introduced adheres to the current standard, and the system reliability analysis provides a vigorous conclusions scheme framework for assessing the existing TA–SP semi-rigid connection.","PeriodicalId":506892,"journal":{"name":"Processes","volume":"54 17","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141339512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Machine Learning in Reservoir Engineering: A Review","authors":"Wensheng Zhou, Chen Liu, Yuandong Liu, Zenghua Zhang, Peng Chen, Lei Jiang","doi":"10.3390/pr12061219","DOIUrl":"https://doi.org/10.3390/pr12061219","url":null,"abstract":"With the rapid progress of big data and artificial intelligence, machine learning technologies such as learning and adaptive control have emerged as a research focus in petroleum engineering. They have various applications in oilfield development, such as parameter prediction, optimization scheme deployment, and performance evaluation. This paper provides a comprehensive review of these applications in three key scenarios of petroleum engineering, namely hydraulic fracturing and acidizing, chemical flooding and gas flooding, and water injection. This article first introduces the steps and methods of machine learning processing in these scenarios, then discusses the advantages, disadvantages, existing challenges, and future prospects of these machine learning methods. Furthermore, this article compares and contrasts the strengths and weaknesses of these machine learning methods, aiming to help researchers select and improve their methods. Finally, this paper identifies some potential development trends and research directions of machine learning in petroleum engineering based on the current issues.","PeriodicalId":506892,"journal":{"name":"Processes","volume":"15 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141341097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}