Hui Gu*, Chaoyi Gu, Andre Du Toit, Wen Yu, Michael W. Chen, Heather L. Struckman, Jonathan R. Silva, Yifan Dai* and Andrew G. Ewing*,
{"title":"","authors":"Hui Gu*, Chaoyi Gu, Andre Du Toit, Wen Yu, Michael W. Chen, Heather L. Struckman, Jonathan R. Silva, Yifan Dai* and Andrew G. Ewing*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c09338","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"","authors":"Aniket Mishra, Xiaobin Lin, Kakoli Maji, Masayoshi Nishiura, Xuefeng Cong* and Zhaomin Hou*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c08707","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cody J. Perry, Sebastian A. Ramos, Maria C. Phelps, Leonard J. Mueller and Gregory J. O. Beran*,
{"title":"","authors":"Cody J. Perry, Sebastian A. Ramos, Maria C. Phelps, Leonard J. Mueller and Gregory J. O. Beran*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c08442","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hao Wang,Huihui Zhang,Marta Martínez-Belmonte,Jordi Benet-Buchholz,Ruben Martin
{"title":"Regiodivergent Interrupted Ni-Catalyzed Chain-Walking of Unsaturated Alcohol Side-Chains via Traceless Activating Groups.","authors":"Hao Wang,Huihui Zhang,Marta Martínez-Belmonte,Jordi Benet-Buchholz,Ruben Martin","doi":"10.1021/jacs.5c09426","DOIUrl":"https://doi.org/10.1021/jacs.5c09426","url":null,"abstract":"Herein, we describe a regiodivergent interrupted chain-walking of unsaturated aliphatic alcohols. The method leverages the potential of traceless groups to forge C(sp3)-C(sp3) and C(sp3)-nitrogen bonds at distal methylene sp3 C-H sites, with site selectivity dictated by a judicious choice of the ligand. The protocol is distinguished by its broad applicability, offering unconventional disconnections to access β/γ-substituted aliphatic alcohols that are difficult to reach otherwise.","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"13 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144737296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leon Gomm,Hui Zhu,Gregor Schnakenburg,Senada Nozinovic,Stefan Grimme,Connie C Lu
{"title":"Reversible C-H Bond Activation of Unactivated Arenes by a Nickel-Silylene Complex.","authors":"Leon Gomm,Hui Zhu,Gregor Schnakenburg,Senada Nozinovic,Stefan Grimme,Connie C Lu","doi":"10.1021/jacs.5c10922","DOIUrl":"https://doi.org/10.1021/jacs.5c10922","url":null,"abstract":"A nickel-silylene complex is shown to reversibly activate benzene via C-H bond activation at ambient temperature. The benzene C-H bond formally adds across the Ni-Si core to form a nickel-silyl complex with an H-Si-Ni-Ph linkage bearing a highly covalent Ni-Si bond (2.2363(6) Å). Dissolution of this product in neat arene solvent, e.g., toluene, trifluorotoluene, or anisole, resulted in the complete conversion to the aryl C-H activated product of the solvent and, thereby, demonstrates the facile reversibility of C-H bond activation across the Ni-Si core. The various arene C-H bond activations by the reactive Ni(0)-silylene species were investigated using density functional theory calculations. In all cases, the arene initially forms an η2-adduct to Ni(0), and then C-H activation proceeds via a concerted oxidative addition at only the Ni center. The Si center assists C-H bond activation by sharing the redox burden with Ni while stabilizing the resultant hydride.","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"25 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144737323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"","authors":"Yawen Yang, Pei Liu, Xi-Yang Cui, Junjie Wu, Wenfeng Cai, Jie Cheng, Chuanjie Lu, Xiaowei Fan, Youming Zhang, Zhibo Liu* and Yizhen Yin*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c10625","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pan Ran, Mingzi Sun, Aoqian Qiu, Xiao Han, Bailin Tian, Beiyao Xiang, Fangyuan Wang, Xinrui Xu, Luhan Dai, Haowen Zhang, Yang Lv, Yue Lin*, Bolong Huang* and Mengning Ding*,
{"title":"","authors":"Pan Ran, Mingzi Sun, Aoqian Qiu, Xiao Han, Bailin Tian, Beiyao Xiang, Fangyuan Wang, Xinrui Xu, Luhan Dai, Haowen Zhang, Yang Lv, Yue Lin*, Bolong Huang* and Mengning Ding*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c04028","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"","authors":"Qiao-Fei Xu, Xin-Yang Liu, Ruo-Tong Wu, Ming-Yang Fu, Man-Ting Chen, Jun-Sen Xiang, Yin-Shan Meng, Tao Liu*, Pei-Jie Sun*, La-Sheng Long* and Lan-Sun Zheng, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c10483","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaofeng Zhang, Shiguo Fu, Lei Jia, Bang Hou, Yong Cui* and Yan Liu*,
{"title":"","authors":"Xiaofeng Zhang, Shiguo Fu, Lei Jia, Bang Hou, Yong Cui* and Yan Liu*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c06460","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Joshua M. Lawrence, Rachel M. Egan, Laura T. Wey, Karan Bali, Xiaolong Chen, Darius Kosmützky, Mairi Eyres, Lan Nan, Mary H. Wood, Marc M. Nowaczyk, Christopher J. Howe* and Jenny Z. Zhang*,
{"title":"","authors":"Joshua M. Lawrence, Rachel M. Egan, Laura T. Wey, Karan Bali, Xiaolong Chen, Darius Kosmützky, Mairi Eyres, Lan Nan, Mary H. Wood, Marc M. Nowaczyk, Christopher J. Howe* and Jenny Z. Zhang*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"147 30","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5c08519","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144720440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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