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BINDING AFFINITIES OF SANGGENON DERIVATIVES AS PTP1B INHIBITORS; USING MOLECULAR DYNAMICS AND FREE ENERGY CALCULATIONS sanggenon衍生物作为ptp1b抑制剂的结合亲和力利用分子动力学和自由能计算
Azerbajčan himiâ žurnaly Pub Date : 2023-11-14 DOI: 10.32737/0005-2531-2023-4-71-83
S.Ozhan Kocakaya
{"title":"BINDING AFFINITIES OF SANGGENON DERIVATIVES AS PTP1B INHIBITORS; USING MOLECULAR DYNAMICS AND FREE ENERGY CALCULATIONS","authors":"S.Ozhan Kocakaya","doi":"10.32737/0005-2531-2023-4-71-83","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-4-71-83","url":null,"abstract":"Recently, protein tyrosine phosphatase 1B (PTP1B) inhibitors have become the frontier as possible targeting for anti-cancer and antidiabetic drugs. The contemporary observe represents a pc assisted version to investigate the importance of precise residues within the binding web site of PTP1B with numerous Sanggenon derivatives remoted from nature. Molecular dynamics (MD) simulations were performed to estimate the dynamics of the complexes, and absolute binding unfastened energies have been calculated with exclusive additives, and carried out through the usage of the Molecular Mechanics-Poisson-Boltzmann floor region (MM-PB/SA) and Generalized Born surface vicinity (MM-GB/SA) strategies. The effects show that the expected free energies of the complexes are normally constant with the available experimental statistics. MM/GBSA free energy decomposition analysis shows that the residues Asp29, Arg24, Met258, and , Arg254 in the second active site in PTP1B are crucial for the excessive selectivity of the inhibitors","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"37 21","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134954440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ELECTROCHEMICAL SYNTESIS OF A CATHODE MATERIAL BASED ON Co-Se ALLOY 钴硒合金阴极材料的电化学合成
Azerbajčan himiâ žurnaly Pub Date : 2023-11-14 DOI: 10.32737/0005-2531-2023-4-120-127
K.I. Hajiyeva, Y.E. Alizade, A.G. Aliyeva, S.P. Javadova
{"title":"ELECTROCHEMICAL SYNTESIS OF A CATHODE MATERIAL BASED ON Co-Se ALLOY","authors":"K.I. Hajiyeva, Y.E. Alizade, A.G. Aliyeva, S.P. Javadova","doi":"10.32737/0005-2531-2023-4-120-127","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-4-120-127","url":null,"abstract":"The present work is devoted to the electrochemical deposition of thin CoSe films and study of the influence of various factors on the composition of the resulting film. It was established that during the deposition of both individual components and in their joint presence, the electroreduction potentials (Se, Co and CoSe) are respectively equal to 0.35, -0.2, 0.23 V. Anodic dissolution of CoSe is observed at a potential of 0.75 V. The electrochemical reduction of selenium and cobalt occurs in 2 stages. The results demonstrated that both the temperature and the electrode material have a significant effect on the kinetics of CoSe electrodeposition. At temperatures above 600C, the quality of the resulting films deteriorates. High-quality crystalline films with high adhesion surface are obtained in the temperature range of 25–600 C. Pt, Ni were taken as a cathode material and Pt served as the anode. The optimal electrolyte composition and electrolysis mode for obtaining thin CoSe films close to the stoichiometric composition were also determined. 0.01 M H2SeO3, 0.1 М CoCl2, 100 ml H2O, i=0.2-0.4 mА/sm2, Т=25–600С, Cathode - Pt, Ni. anode Pt","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"37 41","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134954611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
AMINOMETHOXY DERIVATIVES OF 1-BENZYLTHIOOCTANE AS A BIOCORROSION INHIBITOR 1-苄基硫辛烷的氨基甲氧基衍生物作为生物缓蚀剂
Azerbajčan himiâ žurnaly Pub Date : 2023-11-14 DOI: 10.32737/0005-2531-2023-4-31-39
I.A. Jafarov, E.H. Mammadbayli, A.Z. Zalov, K.O. Iskenderova, A.G. Habibova
{"title":"AMINOMETHOXY DERIVATIVES OF 1-BENZYLTHIOOCTANE AS A BIOCORROSION INHIBITOR","authors":"I.A. Jafarov, E.H. Mammadbayli, A.Z. Zalov, K.O. Iskenderova, A.G. Habibova","doi":"10.32737/0005-2531-2023-4-31-39","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-4-31-39","url":null,"abstract":"Based on benzylthioctane-2-ol, heterocyclic amines (piperidine, morpholine, hexamethyleneimine), and formaldehyde, new Mannich bases were synthesized. The reaction was carried out at a temperature of 45–500C for 3–4 h. in an equimolar ratio of starting compounds. The yield of target products was 70–74%. The physicochemical data of the synthesized compounds were determined. The composition and structure of the target products were confirmed by elemental analysis, IR and 1H NMR spectroscopy. Their influence on the vital activity of sulfate-reducing bacteria of the Desulfovibrio desulfiricans type at three con¬centrations (25, 50, 100 mg/l) was studied. The obtained compounds showed high bactericidal pro¬perties, since 1% solutions of these compounds in isopropyl alcohol at a concentration of 100 mg/l showed a 100% bactericidal effect. Given that the aminomethoxy derivatives of 1-benzylthiooctane affect bacteria at very low concentrations, they can be proposed as effective inhibitors of sulfate reducing bacteria (SRB).","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"36 42","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134954262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ELECTROCHEMICAL BEHAVIOR OF BISMUTH IONS IN CITRATE SOLUTIONS 铋离子在柠檬酸盐溶液中的电化学行为
Azerbajčan himiâ žurnaly Pub Date : 2023-11-14 DOI: 10.32737/0005-2531-2023-4-5-12
S.P. Javadova, V.A. Majidzade, S.F. Jafarova, T.A. Aliyev, A.Sh. Aliyev, D.B. Tagiyev
{"title":"ELECTROCHEMICAL BEHAVIOR OF BISMUTH IONS IN CITRATE SOLUTIONS","authors":"S.P. Javadova, V.A. Majidzade, S.F. Jafarova, T.A. Aliyev, A.Sh. Aliyev, D.B. Tagiyev","doi":"10.32737/0005-2531-2023-4-5-12","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-4-5-12","url":null,"abstract":"The scientific paper is devoted to the electrochemical reduction of bismuth ions from citrate electrolytes. The kinetics and mechanism of the process and the influence of various factors on the electroreduction process of bismuth ions were studied by recording cyclic and linear polarization curves on Pt, Ni and Ni/Bi electrodes. The effective activation energy and diffusion coefficient were calculated according to the obtained data. The results of the calculation show that the electroreduction process of the bismuth ions from citrate solutions is accompanied by diffusion polarization","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"37 13","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134954448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SYNTHESIS OF S,P,N-CONTAINING ORGANIC COMPOUNDS AND THEIR THERMOSTABILITY WITH RESPECT TO METALS 含硫、磷、氮有机化合物的合成及其对金属的热稳定性
Azerbajčan himiâ žurnaly Pub Date : 2023-11-14 DOI: 10.32737/0005-2531-2023-4-97-103
E.Sh. Mamedov, T.N. Kulibekova, D.S. Veliyeva, Z.S. Safaraliyeva, I.R. Rushinaz
{"title":"SYNTHESIS OF S,P,N-CONTAINING ORGANIC COMPOUNDS AND THEIR THERMOSTABILITY WITH RESPECT TO METALS","authors":"E.Sh. Mamedov, T.N. Kulibekova, D.S. Veliyeva, Z.S. Safaraliyeva, I.R. Rushinaz","doi":"10.32737/0005-2531-2023-4-97-103","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-4-97-103","url":null,"abstract":"The results of thermal studies of some derivatives of dithiophosphoric, xanthogenic, dithiocarbamic acids are presented. The thermal parameters of the compounds were determined both in pure form and in the presence of iron and copper powders. Their chemical activity with respect to iron and copper was studied. It has been found that the temperature at which the thermal stability of the studied compounds is maintained exceeds 1700С, and they are chemically active with respect to iron and copper: the lower the interaction temperature within the same row with iron and copper and the lower its mass loss corresponding to this temperature, the more effective it is like an extreme pressure (EP) additive. It has been found that compounds of the same series, reacting with metal by the type of synchronous and exchange reactions, have better indicators of extreme pressure properties than compounds interacting with metal by the type of asynchronous reaction","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"37 30","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134954620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Au@Fe3O4 NANOPARTICLES: PREPARATION, CHARACTERIZATION AND CYTOTOXIC EVALUATION Au@Fe3O4纳米颗粒:制备，表征和细胞毒性评价
Azerbajčan himiâ žurnaly Pub Date : 2023-09-19 DOI: 10.32737/0005-2531-2023-3-98-104
Z. Kelgenbaeva
{"title":"Au@Fe3O4 NANOPARTICLES: PREPARATION, CHARACTERIZATION AND CYTOTOXIC EVALUATION","authors":"Z. Kelgenbaeva","doi":"10.32737/0005-2531-2023-3-98-104","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-3-98-104","url":null,"abstract":"Gold-coated iron oxide nanoparticles are a class of potential theranostic nanoparticles that have been studied for their multitude of magnetic and optical properties with possible medical applications. In this work, spherical Au@Fe3O4 nanoparticles were successfully synthesized from Fe electrodes immersed in HAuCl4 solution using a very simple method - pulsed plasma in liquid, without any dopants or special conditions for stabilization. Vibrating sample magnetometer indicated ferromagnetic behavior of the particles at room temperature with coercivity and saturation magnetization of Hc=175 and Ms= 3.56 emu/g, respectively. Face-centered cubic Au and spinel inverse structure of FCC- Fe3O4 were determined by X-Ray diffraction analysis. High-resolution transmission electron microscopic analysis revealed that Fe3O4 particles with 14 nm in size are connected to 18 nm Au particles. The cytotoxicity of the nanoparticles was evaluated using a XTT assay on Hela cells, revealing very low (cell viability: 98-89% with Fe3O4 and 99-91% for Au@Fe3O4 NPs). This indicates that Au improves biocompatibility of magnetic nanoparticles, enabling their application in biomedicine","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135107294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
EVOLUTION OF THE DISTRIBUTION FUNCTION OF DROPS IN AN OIL EMULSION 油乳液中液滴分布函数的演化
Azerbajčan himiâ žurnaly Pub Date : 2023-09-19 DOI: 10.32737/0005-2531-2023-3-61-69
M.R. Manafov, S.R. Rasulov, F.R. Shikhieva, V.I. Kerimli
{"title":"EVOLUTION OF THE DISTRIBUTION FUNCTION OF DROPS IN AN OIL EMULSION","authors":"M.R. Manafov, S.R. Rasulov, F.R. Shikhieva, V.I. Kerimli","doi":"10.32737/0005-2531-2023-3-61-69","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-3-61-69","url":null,"abstract":"Oil emulsions are polydisperse media and have a droplet size in the macro and micro range. Macro and microemulsions can be found in both water-in-oil emulsion types and oil-in-water emulsion types. Taking into account the size distribution of water-oil emulsion droplets has a great influence on the accuracy of calculations when modeling the process of oil dehydration. Droplet size and droplet size distribution are important for the stability and viscosity properties of the emulsion. In the article, based on the rate of coalescence and fragmentation of particles, an expression is proposed for the rate of change in the number and size of particles per unit volume. On the basis of the Fokker-Planck equation, an expression for the distribution function of water droplets in an oil emulsion is found and, on its basis, an estimate of the distribution is investigated","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"100 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135063627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CHEMICAL CONSTITUENTS, ANTIBACTERIAL AND ANTIFUNGAL ACTIVITIES OF THE AERIAL PART OF SILENE TOMENTELLA 毛毛蓟地上部的化学成分及抑菌抑菌活性
Azerbajčan himiâ žurnaly Pub Date : 2023-09-19 DOI: 10.32737/0005-2531-2023-3-134-141
U. Yusupova, A. Khurramov, Kh. Bobakulov, S. Sasmakov, Kh. Dolimov, A. Beyatli, D. Usmanov, N. Ramazonov
{"title":"CHEMICAL CONSTITUENTS, ANTIBACTERIAL AND ANTIFUNGAL ACTIVITIES OF THE AERIAL PART OF SILENE TOMENTELLA","authors":"U. Yusupova, A. Khurramov, Kh. Bobakulov, S. Sasmakov, Kh. Dolimov, A. Beyatli, D. Usmanov, N. Ramazonov","doi":"10.32737/0005-2531-2023-3-134-141","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-3-134-141","url":null,"abstract":"This study reports the isolation of steroid glycosides and cycloartane glycosides from the aerial parts of Silene tomentella. Two cycloartans group of triterpenoids astrasieversianin II (1) and cycloastragenol (4), including two compounds belonging to steroid glycosides lokundjoside (2) and lineolon (3) are known, were isolated from the aerial part of S. tomentella by chromatographic techniques (CC, TLC, HPTLC). Their structures were established based on extensive spectroscopic analyses and chemical methods, including NMR (1D and 2D) and HR-ESI-MS data. All of these compounds were obtained for the first time for this plant. In addition, the antimicrobial activities of triterpene and steroid glycosides were evaluated against Pseudomonas aeruginosa, Escherichia coli, Staphylococcus aureus, Bacillus subtilis as well as fungi Candida albicans. There was no evidence of antimicrobial action in the isolated triterpene glycosides and steroid glycosides against used microorganisms","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135063632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SURFACES OF CRYSTALLIZATION AND PHASE RELATIONS IN THE 6Ag2Se+Ag8SiTe66Ag2Te+Ag8SiSe6 RECIPROCAL SYSTEM 6Ag2Se+Ag8SiTe6的结晶表面及相关系6Ag2Te+Ag8SiSe6互易体系
Azerbajčan himiâ žurnaly Pub Date : 2023-09-19 DOI: 10.32737/0005-2531-2023-3-6-17
A.J. Amiraslanova, K.N. Babanly, S.Z. Imamaliyeva, E.I. Akhmedov, Yu.A. Yusibov, M.B. Babanly
{"title":"SURFACES OF CRYSTALLIZATION AND PHASE RELATIONS IN THE 6Ag2Se+Ag8SiTe66Ag2Te+Ag8SiSe6 RECIPROCAL SYSTEM","authors":"A.J. Amiraslanova, K.N. Babanly, S.Z. Imamaliyeva, E.I. Akhmedov, Yu.A. Yusibov, M.B. Babanly","doi":"10.32737/0005-2531-2023-3-6-17","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-3-6-17","url":null,"abstract":"The paper presents the results of a study of phase equilibria in the 6Ag2Se+Ag8SiTe6 6Ag2Te+Ag8SiSe6 reciprocal system by DTA and XRD methods. The projection of the liquidus surface, isothermal sections at 300, 500, 1150 K, and some polythermal sections of the phase diagram are constructed. It is shown that the system is reversible-reciprocal. It is characterized by the formation of continuous high-temperature solid solutions along the Ag8SiSe6-Ag8SiTe6 () and Ag2Se-Ag2Te () boundary systems. It has been established that the liquidus surface of the reciprocal system consists of two fields of primary crystallization - and -phases. These surfaces are delimited by a eutectic curve with monovariant equilibrium L+. In the subsolidus part of the system, a complex interaction is observed associated with the polymorphism of the initial compounds and phases based on them","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135063633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SYNTHESIS AND MESOGENIC PROPERTIES OF NEW AROMATIC SCHIFF BASE’S ESTERS 新型芳香族席夫碱酯的合成及其介生性质
Azerbajčan himiâ žurnaly Pub Date : 2023-09-19 DOI: 10.32737/0005-2531-2023-3-112-125
Teck-Leong Lee, Mei-Ing Quek Chelsea, Sie-Tiong Ha, Guan-Yeow Yeap
{"title":"SYNTHESIS AND MESOGENIC PROPERTIES OF NEW AROMATIC SCHIFF BASE’S ESTERS","authors":"Teck-Leong Lee, Mei-Ing Quek Chelsea, Sie-Tiong Ha, Guan-Yeow Yeap","doi":"10.32737/0005-2531-2023-3-112-125","DOIUrl":"https://doi.org/10.32737/0005-2531-2023-3-112-125","url":null,"abstract":"A homologous series of new Schiff base’s esters, 4-bromobenzylidene-4’-alkanoyloxyanilines were syn-thesized. The structure of the synthesized compounds was elucidated using IR and NMR spectroscopic techniques along with mass spectrometric method. Nine homologous members were prepared whereby the length of alkanoyloxy chain, Cn-1H2n-1COO is varied from n = 2, 4, 6, 8, 10, 12, 14, 16 and 18. Their thermotropic properties were analyzed using differential scanning calorimetry and polarized optical mi-croscopy techniques. Whilst short chain members (number of carbons, n = 2, 4) are non-mesogens, member with n = 6 exhibited monotropic smectic A (SmA) phase. As the n increased to 8, this com-pound becomes the only member that exhibited SmA and SmB as enantiotropic phase. Varying from n = 10 to n = 16, these members displayed enantiotropic SmA and monotropic SmB phases. Longest chain member, n-octadecanoyloxy derivatives exhibited only single mesophase (monotropic SmA). The ester linkage and polar terminal (bromo) group in the present series are essential for the smectic polymorphism in Schiff bases","PeriodicalId":480979,"journal":{"name":"Azerbajčan himiâ žurnaly","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135063796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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