I. Rosyadi, S. Suyitno, Albert Xaverio Ilyas, Afif Faishal, Andres Budiono, Mirza Yusuf
{"title":"Producing hydrogen-rich syngas via microwave heating and co-gasification: a systematic review","authors":"I. Rosyadi, S. Suyitno, Albert Xaverio Ilyas, Afif Faishal, Andres Budiono, Mirza Yusuf","doi":"10.18331/brj2022.9.1.4","DOIUrl":"https://doi.org/10.18331/brj2022.9.1.4","url":null,"abstract":"Co-gasification contributes significantly to the generation of hydrogen-rich syngas since it not only addresses the issue of feedstock variation but also has synergistic benefits. In this article, recent research on hydrogen concentration and yield, tar content, gasification efficiency, and carbon conversion efficiency is explored systematically. In feedstocks with high water content, steam gasification and supercritical hydrothermal gasification technologies are ideal for producing hydrogen at a concentration of 57%, which can be increased to 82.9% using purification technology. Carbonized coals, chars, and cokes have high microwave absorption when used as feedstocks. Moreover, coconut activated carbon contains elements that provide a high tan δ value and are worthy of further development as feedstocks, adsorbents or catalysts. Meanwhile, the FeSO4 catalyst has the greatest capacity for storing microwave energy and producing dielectric losses; therefore, it can serve as both a catalyst and microwave absorber. Although microwave heating is preferable to conventional heating, the amount of hydrogen it generates remains modest, at 60% and 32.75% in single-feeding and co-feeding modes, respectively. The heating value of syngas produced using microwaves is 17.44 MJ/m³, much more than that produced via conventional heating. Thus, despite a lack of research on hydrogen-rich syngas generation based on co-gasification and microwave heating, such techniques have the potential to be developed at both laboratory and industrial scales. In addition, the dielectric characteristics of feedstocks, beds, adsorbents, and catalysts must be further investigated to optimize the performance of microwave heating processes.","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46410040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Patrícia Carvalho, Carlos E. Costa, Sara L. Baptista, L. Domingues
{"title":"Yeast cell factories for sustainable whey-to-ethanol valorisation towards a circular economy","authors":"Patrícia Carvalho, Carlos E. Costa, Sara L. Baptista, L. Domingues","doi":"10.18331/brj2021.8.4.4","DOIUrl":"https://doi.org/10.18331/brj2021.8.4.4","url":null,"abstract":"Cheese whey is the major by-product of the dairy industry, and its disposal constitutes an environmental concern. The production of cheese whey has been increasing, with 190 million tonnes per year being produced nowadays. Therefore, it is emergent to consider different routes for cheese whey utilization. The great nutritional value of cheese whey turns it into an attractive substrate for biotechnological applications. Currently, cheese whey processing includes a protein fractionating step that originates the permeate, a lactose-reach stream further used for valorisation. In the last decades, yeast fermentation has brought several advances to the search for biorefinery alternatives. From the plethora of value-added products that can be obtained from cheese whey, ethanol is the most extensively explored since it is the alternative biofuel most used worldwide. Thus, this review focuses on the different strategies for ethanol production from cheese whey using yeasts as promising biological systems, including its integration in lignocellulosic biorefineries. These valorisation routes encompass the improvement of the fermentation process as well as metabolic engineering techniques for the introduction of heterologous pathways, resorting mainly to Kluyveromyces sp. and Saccharomyces cerevisiae strains. The solutions and challenges of the several strategies will be unveiled and explored in this review.","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2021-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41923536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review on the effects of ethanol/gasoline fuel blends on NOX emissions in spark-ignition engines","authors":"P. Iodice, A. Amoresano, Giuseppe Langella","doi":"10.18331/brj2021.8.4.2","DOIUrl":"https://doi.org/10.18331/brj2021.8.4.2","url":null,"abstract":"Ethanol can be used as an alternative fuel for spark-ignition (SI) engines to increase the octane number and oxygen content of ethanol/gasoline blends, thereby reducing dependence on fossil fuels and the exhaust emissions of incomplete combustion products. Although it is widely agreed that ethanol can reduce CO and HC exhaust emissions, the literature on ethanol and NOX emissions is far from conclusive; hence there is a need for an in-depth, updated review of ethanol/gasoline blends in SI engines and the relative production of NOX emissions. In light of that, the present work aims to provide a comprehensive literature review on the current state of ethanol combustion in SI engines to shed definitive light on the potential changes in NOX emissions under various operating conditions. The first part of this paper discusses the feasibility of ethanol as an alternative transportation fuel, including world production and ethanol production processes. The physicochemical properties of ethanol and gasoline are then compared to analyze their effects on combustion efficiency and exhaust emissions. Then, the pathways of NOX formation inside the cylinder of SI engines are discussed in depth. Finally, we review and critically discuss the effects of ethanol concentration in blends and different engine parameters on NOX formation.","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2021-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43061814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sinhara M. H. D. Perera, Chathuranga Wickramasinghe, B.K.T. Samarasiri, M. Narayana
{"title":"Modeling of thermochemical conversion of waste biomass – a comprehensive review","authors":"Sinhara M. H. D. Perera, Chathuranga Wickramasinghe, B.K.T. Samarasiri, M. Narayana","doi":"10.18331/brj2021.8.4.3","DOIUrl":"https://doi.org/10.18331/brj2021.8.4.3","url":null,"abstract":"Thermochemical processes, which include pyrolysis, torrefaction, gasification, combustion, and hydrothermal conversions, are perceived to be more efficient in converting waste biomass to energy and value-added products than biochemical processes. From the chemical point of view, thermochemical processes are highly complex and sensitive to numerous physicochemical properties, thus making reactor and process modeling more challenging. Nevertheless, the successful commercialization of these processes is contingent upon optimized reactor and process designs, which can be effectively achieved via modeling and simulation. Models of various scales with numerous simplifying assumptions have been developed for specific applications of thermochemical conversion of waste biomass. However, there is a research gap that needs to be explored to elaborate the scale of applicability, limitations, accuracy, validity, and special features of each model. This review study investigates all above mentioned important aspects and features of the existing models for all established industrial thermochemical conversion processes with emphasis on waste biomass, thus addressing the research gap mentioned above and presenting commercial-scale applicability in terms of reactor designing, process control and optimization, and potential ways to upgrade existing models for higher accuracy.","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2021-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45450925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Mashkour, M. Rahimnejad, F. Raouf, N. Navidjouy
{"title":"A review on the application of nanomaterials in improving microbial fuel cells","authors":"M. Mashkour, M. Rahimnejad, F. Raouf, N. Navidjouy","doi":"10.18331/BRJ2021.8.2.5","DOIUrl":"https://doi.org/10.18331/BRJ2021.8.2.5","url":null,"abstract":"Materials at the nanoscale show exciting and different properties. In this review, the applications of nanomaterials for modifying the main components of microbial fuel cell (MFC) systems (i.e., electrodes and membranes) and their effect on cell performance are reviewed and critically discussed. Carbon and metal-based nanoparticles and conductive polymers could contribute to the growth of thick anodic and cathodic microbial biofilms, leading to enhanced electron transfer between the electrodes and the biofilm. Extending active surface area, increasing conductivity, and biocompatibility are among the significant attributes of promising nanomaterials used in MFC modifications. The application of nanomaterials in fabricating cathode catalysts (catalyzing oxygen reduction reaction) is also reviewed herein. Among the various nanocatalysts used on the cathode side, metal-based nanocatalysts such as metal oxides and metal-organic frameworks (MOFs) are regarded as inexpensive and high-performance alternatives to the conventionally used high-cost Pt. In addition, polymeric membranes modified with hydrophilic and antibacterial nanoparticles could lead to higher proton conductivity and mitigated biofouling compared to the conventionally used and expensive Nafion. These improvements could lead to more promising cell performance in power generation, wastewater treatment, and nanobiosensing. Future research efforts should also take into account decreasing the production cost of the nanomaterials and the environmental safety aspects of these compounds.","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43486157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Estefanny Carmona-Garcia, P. Marín-Valencia, J. Solarte-Toro, K. Moustakas, C. A. Cardona-Alzate
{"title":"Comparison of acetone–butanol–ethanol fermentation and ethanol catalytic upgrading as pathways for butanol production: A techno-economic and environmental assessment","authors":"Estefanny Carmona-Garcia, P. Marín-Valencia, J. Solarte-Toro, K. Moustakas, C. A. Cardona-Alzate","doi":"10.18331/BRJ2021.8.2.4","DOIUrl":"https://doi.org/10.18331/BRJ2021.8.2.4","url":null,"abstract":"Butanol is an important compound used as a building block for producing value-added products and an energy carrier. The main butanol production pathways are conventional acetone–butanol–ethanol (ABE) fermentation and catalytic upgrading of ethanol. On the other hand, the application of biomass as a promising substrate for biofuel production has been widely considered recently. However, few studies have compared different butanol production pathways using biomass as raw material. In light of that, the present work aims (i) to provide a short review of the catalytic ethanol upgrading and (ii) to compare conventional ABE fermentation and catalytic ethanol upgrading processes from the economic and environmental perspectives. Aspen Plus v9.0 was used to simulate both processes. The economic and environmental assessments were carried out considering the Colombian economic context, a gate-to-gate approach, and single impact categories. Considering a processing scale of 1000 ton/d, the conventional ABE fermentation process presented a more favorable technical, economic, and environmental performance for butanol production from biomass. It also offered lower net energy consumption (i.e., 57.9 GJ/ton of butanol) and higher butanol production (i.e., 2.59 ton/h). Nevertheless, the proposed processing scale was insufficient to reach economic feasibility for both processes. To overcome this challenge, the minimum processing scale had to be higher than 1584 ton/d and 1920 ton/d for conventional ABE fermentation and catalytic ethanol upgrading, respectively. Another critical factor in enhancing the economic feasibility of both butanol production pathways was the minimum selling price of butanol. More specifically, prices higher than 1.56 USD/kg and 1.80 USD/kg would be required for conventional ABE fermentation and catalytic ethanol upgrading, respectively. From the environmental impact point of view, the conventional ABE fermentation process led to a lower potential environmental impact than catalytic ethanol upgrading (0.12 PEI/kg vs. 0.18 PEI/kg, respectively).","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48094405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effects of particle size of cerium oxide nanoparticles on the combustion behavior and exhaust emissions of a diesel engine powered by biodiesel/diesel blend","authors":"P. Dinesha, Shiva Kumar, M. Rosen","doi":"10.18331/BRJ2021.8.2.3","DOIUrl":"https://doi.org/10.18331/BRJ2021.8.2.3","url":null,"abstract":"Meeting the emission norms specified by governing bodies is one of the major challenges faced by engine manufacturers, especially without sacrificing engine performance and fuel economy. Several methods and techniques are being used globally to reduce engine emissions. Even though emissions can be reduced, doing so usually entails a deterioration in performance. To address this problem, nanoadditives such as cerium oxide (CeO2) nanoparticles are used to reduce engine emissions while improving engine performance. However, some aspects of the application of these nanoadditives are still unknown. In light of that, three sizes of CeO2 nanoparticles (i.e., 10, 30, and 80 nm) and at a constant volume fraction of 80 ppm were added to a 20% blend of waste cooking oil biodiesel and diesel (B20). A single-cylinder diesel engine operating at a 1500 rpm speed and 180 bar fuel injection pressure was used to compare the performance and emission characteristics of the investigated fuel formulations. The results showed that the addition of CeO2 nanoparticles led to performance improvements by reducing brake specific fuel consumption. Moreover, the catalytic action of CeO2 nanoparticles on the hydrocarbons helped achieve effective combustion and reduce the emission of carbon monoxide, unburnt hydrocarbon, oxides of nitrogen, and soot. Interestingly, the size of the nanoadditive played an instrumental role in the improvements achieved, and the use of 30 nm-sized nanoparticles led to the most favorable performance and the lowest engine emissions. More specifically, the fuel formulation harboring 30 nm nanoceria reduced brake specific fuel consumption by 2.5%, NOx emission by 15.7%, and smoke opacity by 34.7%, compared to the additive-free B20. These findings could shed light on the action mechanism of fuel nanoadditives and are expected to pave the way for future research to develop more promising fuel nanoadditives for commercial applications.","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47004451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A comparative evaluation of design factors on bubble column operation in photosynthetic biogas upgrading","authors":"A. Bose, R. O’Shea, Richen Lin, J. Murphy","doi":"10.18331/BRJ2021.8.2.2","DOIUrl":"https://doi.org/10.18331/BRJ2021.8.2.2","url":null,"abstract":"Studies attempting to optimise photosynthetic biogas upgrading by simultaneous investigation of the bubble column-photobioreactor setup have experienced considerable variability in results and conclusions. To identify the sources of such variation, this work quantitatively compared seven design factors (superficial gas velocity; liquid to gas flow rate (L/G) ratio; empty bed residence time; liquid inlet pH; liquid inlet alkalinity; temperature; and algal concentration) using the L16 Taguchi orthogonal array as a screening design of experiment. Assessments were performed using the signal to noise (S/N) ratio on the performance of CO2 removal (CO2 removal efficiency, CO2 absorption rate, and overall CO2 mass transfer coefficient) and O2 stripping (O2 concentration in biomethane and O2 flow rate in biomethane). Results showed that pH and L/G ratio were the most critical design factors. Temperature and gas residence times had minimal impact on the biomethane composition. The interactive effect between pH and L/G ratio was the most impactful, followed by the interactive effects between superficial gas velocity and L/G ratio and pH on CO2 removal efficiency. The impact of L/G ratio, algal concentration, and pH (in that order of impact) caused up to a 90% variation in oxygen content in biomethane. However, algal concentration had a diminishing role as the L/G ratio increased. Using only the statistically significant main effects and interactions, the biomethane composition (CO2% and O2%) was predicted with over 95% confidence through regression equations for superficial gas velocity up to 0.2 cm/s.","PeriodicalId":46938,"journal":{"name":"Biofuel Research Journal-BRJ","volume":" ","pages":""},"PeriodicalIF":13.0,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47979748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}