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Progress on Chemistry and Application of Chitin and its Derivatives最新文献

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ADSORPTION OF SILVER IONS ON CHITOSAN HYDROGEL BEADS 壳聚糖水凝胶珠对银离子的吸附
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2023-09-30 DOI: 10.15259/pcacd.28.016
Witold Sujka, Grzegorz Rogacki, Zofia Modrzejewska, Roman Zarzycki
{"title":"ADSORPTION OF SILVER IONS ON CHITOSAN HYDROGEL BEADS","authors":"Witold Sujka, Grzegorz Rogacki, Zofia Modrzejewska, Roman Zarzycki","doi":"10.15259/pcacd.28.016","DOIUrl":"https://doi.org/10.15259/pcacd.28.016","url":null,"abstract":"We investigated the adsorption of silver(I) from silver nitrate (AgNO3) and silver sulphate (Ag2SO4). We compared the adsorption ability of chitosan in the form of hydrogel beads with that of chitosan acetate – an initial solution from which the beads were derived. We developed a model of adsorption kinetics, assuming the simultaneous occurrence of the diffusion process and the chemical reaction. We confirmed and described the chemical nature of adsorption based on the Fourier-transform infrared and X-ray photoelectron spectra.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135031699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
THE EFFECTS OF APPLYING CHITOSAN OF DIFFERENT MOLECULAR WEIGHTS ON THE GROWTH AND QUALITY OF KAMCHATKA BERRIES (LONICERA CAERULEA L.): PART 1 施用不同分子量壳聚糖对堪察加浆果生长和品质的影响:第1部分
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2023-09-30 DOI: 10.15259/pcacd.28.011
Ireneusz Ochmian, Marcelina Krupa-Małkiewicz
{"title":"THE EFFECTS OF APPLYING CHITOSAN OF DIFFERENT MOLECULAR WEIGHTS ON THE GROWTH AND QUALITY OF KAMCHATKA BERRIES (LONICERA CAERULEA L.): PART 1","authors":"Ireneusz Ochmian, Marcelina Krupa-Małkiewicz","doi":"10.15259/pcacd.28.011","DOIUrl":"https://doi.org/10.15259/pcacd.28.011","url":null,"abstract":"Kamchatka berries contain many valuable organic and mineral compounds. However, the ripe berries are not very firm and have low transport resistance. We aimed to study the effect of chitosan solutions of different molecular weights on the growth, yield, and quality of Kamchatka berries. Chitosan with lower molecular weights, 3 and 12 kDa, stimulated plant growth, while those with molecular weights above 50 kDa reduced plant growth compared with control shrubs. Chitosan 125 and 500 kDa increased Kamchatka berry yield. In addition, chitosan 125 kDa increased fruit weight throughout the yield period. Fruit sprayed with chitosan 3, 5, and 50 kDa were dark in colour at harvest. Chitosan 3, 5, 12, and 50 kDa increased fruit/skin resistance to mechanical damage. Finally, chitosan 3, 5, 50, and 950 kDa increased average fruit firmness. Overall, we recommend higher molecular weight chitosan to increase yield and lower molecular weight chitosan to increase firmness and resistance to damage.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135031700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CHITOSAN GELS TO PREVENT REFLUX DISEASE 壳聚糖凝胶预防反流病
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2023-09-30 DOI: 10.15259/pcacd.28.009
Katarzyna Małolepsza-Jarmołowska
{"title":"CHITOSAN GELS TO PREVENT REFLUX DISEASE","authors":"Katarzyna Małolepsza-Jarmołowska","doi":"10.15259/pcacd.28.009","DOIUrl":"https://doi.org/10.15259/pcacd.28.009","url":null,"abstract":"Reflux disease is one of the most frequently diagnosed conditions in developed countries. The problem is both the acidic content of the stomach and the alkaline content of the intestines. In each case, the oesophageal mucosa is destroyed. I analysed hydrogels that prevent irritation of the oesophageal mucosa. Specifically, I investigated the effect of chitosan and sodium alginate on the properties of gels protecting the oesophagus. Gels containing chitosan and 1.0% sodium alginate can be used to treat advanced alkaline reflux. The addition of chitosan to all the tested gels increased their pH and dynamic viscosity, making it possible to neutralise acid reflux. Texture studies showed the influence of chitosan and sodium alginate on the adhesiveness of the tested gels.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135031701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MITIGATION EFFECTS OF WATER-SOLUBLE CHITOSAN ON BORON TOXICITY IN PEPPER PLANTS 水溶性壳聚糖对辣椒硼毒性的缓解作用
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2023-09-30 DOI: 10.15259/pcacd.28.014
Piotr Salachna
{"title":"MITIGATION EFFECTS OF WATER-SOLUBLE CHITOSAN ON BORON TOXICITY IN PEPPER PLANTS","authors":"Piotr Salachna","doi":"10.15259/pcacd.28.014","DOIUrl":"https://doi.org/10.15259/pcacd.28.014","url":null,"abstract":"Excess boron in soil is often found in dry agricultural areas and is one of the factors limiting crop yields. Polysaccharide-based biostimulants can mitigate the harmful effects of environmental stresses on plants. I performed this study under controlled greenhouse conditions to understand the response of pepper plants under boron stress to treatment with water-soluble chitosan (WSC). I watered plants with 50 or 100 mg/l WSC and 1.5 mM boric acid solution. As a result of WSC application at both concentrations, plants were taller and had more leaves and greater leaf length, width, relative chlorophyll content, and fresh aboveground weight compared with the control. Plants exposed to boron stress had fewer leaves, a lower relative chlorophyll content, and leaf blade damage indicative of boron toxicity. At the same time, boron-exposed plants showed a marked increase in the leaf nitrogen, phosphorus, potassium, and boron contents. Applying WSC at both concentrations modulated boron stress in plants by improving plant growth; reducing boron accumulation in leaves; and increasing the available nitrate nitrogen, phosphorus, and potassium contents in the substrate.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135031702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
THE EFFECT OF A COMPOSITE CHITOSAN-SILVER(I) ION COATING ON THE CORROSION RESISTANCE OF THE COBALT-CHROMIUM-MOLYBDENUM ALLOY IN SALINE SOLUTION 壳聚糖-银离子复合涂层对钴铬钼合金耐盐腐蚀性能的影响
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2023-09-30 DOI: 10.15259/pcacd.28.007
Bożena Łosiewicz, Patrycja Osak, Julian Kubisztal
{"title":"THE EFFECT OF A COMPOSITE CHITOSAN-SILVER(I) ION COATING ON THE CORROSION RESISTANCE OF THE COBALT-CHROMIUM-MOLYBDENUM ALLOY IN SALINE SOLUTION","authors":"Bożena Łosiewicz, Patrycja Osak, Julian Kubisztal","doi":"10.15259/pcacd.28.007","DOIUrl":"https://doi.org/10.15259/pcacd.28.007","url":null,"abstract":"We determined the in vitro corrosion resistance of the composite chitosan-silver(I) [Ag(I)] ion coating on the cobalt-chromium-molybdenum (CoCrMo) dental alloy in a 0.9% sodium chloride (NaCl) solution at 37°C. We obtained the novel composite chitosan–Ag(I) ion coating by electrophoretic deposition at 20 V for 30 s at room temperature in a 2% (v/v) aqueous solution of acetic acid with 1 g dm–3 chitosan and 10 g dm–3 silver nitrate. We evaluated the chemical composition with energy dispersive spectroscopy and Fouriertransform infrared spectroscopy. We investigated surface topography and electronic properties with a scanning Kelvin probe. We determined the mechanism and kinetics of the electrochemical corrosion of the obtained coatings by electrochemical impedance spectroscopy. The Ag content in the composite chitosan–Ag(I) ion coating was 1.9 ± 1 wt.%. The cataphoretic co-deposition of chitosan and Ag(I) ions in an aqueous solution can be used to modify the CoCrMo alloy surface to obtain new coatings with antibacterial properties.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135031703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
STUDY OF THE QUANTITATIVE AND QUALITATIVE CHANGES IN CHITIN AT DIFFERENT STAGES OF RIPENING OF MUSHROOM FRUITING BODIES 香菇子实体不同成熟阶段几丁质的定量变化研究
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2023-09-30 DOI: 10.15259/pcacd.28.004
Ivan Korabel, Semen Khomyak, Lidiia Panchak, Volodymyr Antonyuk
{"title":"STUDY OF THE QUANTITATIVE AND QUALITATIVE CHANGES IN CHITIN AT DIFFERENT STAGES OF RIPENING OF MUSHROOM FRUITING BODIES","authors":"Ivan Korabel, Semen Khomyak, Lidiia Panchak, Volodymyr Antonyuk","doi":"10.15259/pcacd.28.004","DOIUrl":"https://doi.org/10.15259/pcacd.28.004","url":null,"abstract":"We investigated the extraction of chitin with various solvents and changes in the amount of chitin and its molecular mass at different stages of maturity in the fruiting bodies of the fungi Laetiporus sulphureus, Tyromyces chioneus, Oudemansiella mucida, Lycoperdon perlatum, and Fomitopsis betulina. We extracted chitin from crushed mushroom fruiting bodies with 25% hydrochloric acid at 0°C. We characterised the molecular weight of reprecipitated purified chitin with a viscosimeter and Fourier-transform infrared spectroscopy. The mass of extracted chitin in all studied mushrooms initially increased from youth to maturity, and then decreased after ripening. At the same time, the molecular weight of chitin tended to increase.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135032912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
THE OUTLOOK FOR CHITOSAN IN TEXTILES: A REVIEW OF THE LITERATURE SINCE THE START OF THE 2020’S 壳聚糖在纺织品中的应用前景:自本世纪初以来的文献综述
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2023-09-30 DOI: 10.15259/pcacd.28.001
Samuel M. Hudson
{"title":"THE OUTLOOK FOR CHITOSAN IN TEXTILES: A REVIEW OF THE LITERATURE SINCE THE START OF THE 2020’S","authors":"Samuel M. Hudson","doi":"10.15259/pcacd.28.001","DOIUrl":"https://doi.org/10.15259/pcacd.28.001","url":null,"abstract":"","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135031923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PREPARATION OF NANOCRYSTALS AND CHITIN MICROFIBRILS 纳米晶体和甲壳素微纤维的制备
IF 0.6
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2022-09-30 DOI: 10.15259/pcacd.27.003
D. Biniaś, W. Biniaś
{"title":"PREPARATION OF NANOCRYSTALS AND CHITIN MICROFIBRILS","authors":"D. Biniaś, W. Biniaś","doi":"10.15259/pcacd.27.003","DOIUrl":"https://doi.org/10.15259/pcacd.27.003","url":null,"abstract":"Chitin nanocrystals and microfibrils were prepared based on the strong acid hydrolysis method. The change in the molecular structure was studied by Fourier-transform infrared and Raman spectroscopy. The surface morphology of chitin materials was observed using scanning electron and optical microscopy. The separation of nano-crystals and microfibril crystalline regions from native chitin may increase the scope of its application for the creation of bioactive composites and scaffolds for tissue culture. As a result of the conducted experimental work, it was possible to loosen the amorphous areas and partially separate nano-crystals and chitin microfibrils. Stable aqueous suspensions of chitin nano-crystals and microfibrils were obtained, which can be used for further experimental work.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.6,"publicationDate":"2022-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46739989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
INFLUENCE OF CARBOXYMETHYLCELLULOSE SODIUM SALT ON THE PROTECTIVE PROPERTIES OF GELS WITH CHITOSAN FOR THE OESOPHAGEAL MUCOSA 羧甲基纤维素钠盐对壳聚糖凝胶对食管黏膜保护性能的影响
IF 0.6
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2022-09-30 DOI: 10.15259/pcacd.27.014
K. Małolepsza-Jarmołowska
{"title":"INFLUENCE OF CARBOXYMETHYLCELLULOSE SODIUM SALT ON THE PROTECTIVE PROPERTIES OF GELS WITH CHITOSAN FOR THE OESOPHAGEAL MUCOSA","authors":"K. Małolepsza-Jarmołowska","doi":"10.15259/pcacd.27.014","DOIUrl":"https://doi.org/10.15259/pcacd.27.014","url":null,"abstract":"Gastro-oesophageal reflux disease is a serious social problem that affects every sphere of life. The quality of life of people with this disease is reduced due to the presence of troublesome symptoms, which translates into reduced work efficiency and vitality. The major problem is acidic gastro-oesophageal reflux. This study was undertaken to examine whether hydrogels prevent irritation of the oesophageal mucosa. The aim was to investigate the influence of chitosan and carboxymethylcellulose sodium salt on the protective properties of prepared gels in the treatment of acid reflux. The addition of chitosan to all tested gels increased their pH and dynamic viscosity. Preparations containing 0.3% carboxymethylcellulose sodium salt showed the highest pH. The texture tests showed the effect of carboxymethylcellulose sodium salt concentration on the adhesion work of the tested gels. These gels could be used in the treatment of advanced acid reflux","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.6,"publicationDate":"2022-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48812517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CHITIN NANOFIBRES AS REINFORCEMENT FOR HYDROXYAPATITE-BASED COMPOSITE PREPARATION 几丁质纳米纤维增强羟基磷灰石基复合材料的制备
IF 0.6
Progress on Chemistry and Application of Chitin and its Derivatives Pub Date : 2022-09-30 DOI: 10.15259/pcacd.27.012
T. Machałowski, M. Kozlowski, Agnieszka Kołodziejczak-Radzimska, J. Jakubowicz, T. Jesionowski
{"title":"CHITIN NANOFIBRES AS REINFORCEMENT FOR HYDROXYAPATITE-BASED COMPOSITE PREPARATION","authors":"T. Machałowski, M. Kozlowski, Agnieszka Kołodziejczak-Radzimska, J. Jakubowicz, T. Jesionowski","doi":"10.15259/pcacd.27.012","DOIUrl":"https://doi.org/10.15259/pcacd.27.012","url":null,"abstract":"The development and improvement of chitin applications have drawn special attention from the global scientific community due to their extraordinary features and abundance. In this study, β-chitin nanofibres were obtained using the ultrasonication treatment method. Then, hydroxyapatite/nanochitin (HAp/NCh) composites were prepared at different maturation times. In this case, mixtures of various amounts of β-chitin nanofibres (1%, 2%, and 5%) were added during the HAp precipitation approach. The prepared HAp/NCh materials were characterised with Fourier-transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, and energy-dispersive X-ray spectroscopy. The surface of prepared specimens was observed using scanning electron microscopy. The presence of nanofibres was confirmed by non-invasive backscattering with dynamic light scattering particle size analysis. Moreover, the synergic effect of chitin nanofibres on the mechanical resistance of HAp-based composite was investigated. The sample with 5% of chitin nanofibres exhibited about 10 times higher compression strength than the pure HAp. All these results essentially indicate that the prepared material can be a potential candidate for bone tissue engineering applications and further development.","PeriodicalId":44461,"journal":{"name":"Progress on Chemistry and Application of Chitin and its Derivatives","volume":null,"pages":null},"PeriodicalIF":0.6,"publicationDate":"2022-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46726765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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