{"title":"Influence of Particle Size, Additive Ratio and Chemical Structure of Zinc Borate on Thermal and Mechanical Properties of Polyvinyl Chloride","authors":"Y. İpek","doi":"10.30728/boron.961843","DOIUrl":"https://doi.org/10.30728/boron.961843","url":null,"abstract":"","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"10 39 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124732894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Genipin ile çapraz bağlı bor katkılı polisakkarit kompleks sentezi ve karakterizasyonu","authors":"Elif ANT BURSALI","doi":"10.30728/boron.944413","DOIUrl":"https://doi.org/10.30728/boron.944413","url":null,"abstract":"","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122990642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation of the effects of using detergent with boron and softener on repetitive washing of towel and loincloths","authors":"Alper Cengiz, Buket Arik, S. Palamutçu","doi":"10.30728/boron.917338","DOIUrl":"https://doi.org/10.30728/boron.917338","url":null,"abstract":"","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"70 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134139188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Lubricants having zinc borate by homogeneous precipitation and Span 60 in spindle oil","authors":"S. Savrık, F. Alp, M. Gönen, D. Balköse","doi":"10.30728/boron.951463","DOIUrl":"https://doi.org/10.30728/boron.951463","url":null,"abstract":"Nano particles of zinc borate were obtained by homogeneous precipitation method which is based on dissolving zinc borate in ammonia and precipitating it as nano particles by slow evaporation of ammonia. The synthesized zinc borates were characterized by advanced analytical techniques. Zinc borate nano particles were used as a lubricant additive to spindle oil having Span 60 dispersant. The particles were well dispersed in spindle oil as shown by optical microscopy of the oils. Four ball tests of the lubricants indicated zinc borate lowered (61.8%) the wear scar diameter significantly. The hardness of wear surfaces of test balls was reduced from 688 HV to 618 HV and presence of zinc borate particles embedded on the surface indicated a flexible skin was formed. Therefore the pressure was decreased due to increase of the contact area of the balls. The surface roughness was also decreased from 35.63 nm to 27.60 nm by the addition of zinc borate to spindle oil having Span 60. Zinc borate prepared by homogeneous precipitation technique lowered the wear of the surfaces that rub to each other.","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"316 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115024690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Çeliklerin Korozyonuna Boraksın Etkisi","authors":"Gülden Asan, Abdurrahman Asan","doi":"10.30728/boron.889110","DOIUrl":"https://doi.org/10.30728/boron.889110","url":null,"abstract":"In this study, the effect of borax (Na 2 B 4 O 7 ) on the corrosion of Ç 1010, Ç 304 and Ç 316 steels was investigated. For this purpose, solutions with borax at different concentrations (0.0125 M, 0.025 M, 0.050 M and 0.100 M) were prepared. Cycling Voltammetry (CV) technique was used to determine the electrochemical behavior of steels in this environment, and Tafel Polarization Method was used to measure corrosion rates. As a result of the experiments, it was determined that the corrosion rate decreased and the corrosion potential increased in all three steels with increasing borax concentrations. Lowest corrosion rate at higest borax concentration was obtained from Ç 316. Corrosion rates of Ç 1010, Ç 304 and Ç 316 steels at 0,100 M borax concentration have been measured respectively as 0.251, 0.132 and 0.071 mm/ year. Borax protected steels from corrosion by showing anodic inhibitory behaviour. It is concluded that the steels can be used safely in borax solutions.","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127314885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Metin Gürü, Gülden Güngör, D. Y. Aydin, Çetin Çakanyıldırım
{"title":"Kalsiyum floroborat sentezi, kinetik ve alev geciktirici özelliklerinin belirlenmesi","authors":"Metin Gürü, Gülden Güngör, D. Y. Aydin, Çetin Çakanyıldırım","doi":"10.30728/boron.880116","DOIUrl":"https://doi.org/10.30728/boron.880116","url":null,"abstract":"In this study, the synthesis parameters of calcium fluoroborate, one of the special boron compounds, were determined and its flame retardant properties in cotton fabric were investigated. In addition, kinetic studies were carried out to calculate the reaction order and activation energy. Calcium fluoroborate was synthesized by wet method using calcium oxide and fluoroboric acid as reactants. The parameters examined were reactant mole ratio (nCaO/nHBF 4 ), temperature and reaction time. FT-IR, XRD and BF 4 - ion selective electrode were used for characterization studies. Thermogravimetric-differential thermal analysis (TG-DTA) was used to characterize the thermal behavior. Calcium fluoroborate was synthesized with 97% yield when molar ratio of reactants, temperature and reaction time are set as 1:4, 90°C and 100 minutes, respectively. In addition, kinetic experiments reveal that the reaction order obeys to first order kinetics and the activation energy was found as 19.14 kJ/mol. LOI tests were used to determine the flame retardant properties of synthesized calcium fluoroborate. Tests proved that the calcium fluoroborate has very good flame retardant properties.","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130962663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of feed water composition and pretreatment on the irrigation water for boron-sensitive crops","authors":"Enver Güler","doi":"10.30728/boron.843259","DOIUrl":"https://doi.org/10.30728/boron.843259","url":null,"abstract":"","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126817176","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Berk Uslu, Şükran Melda Eskitoros Toğay, N. Dilsiz
{"title":"Improvement on flame retarding performance: preparation and characterization of water-based indoor paints with addition of boric acid","authors":"Berk Uslu, Şükran Melda Eskitoros Toğay, N. Dilsiz","doi":"10.30728/boron.865316","DOIUrl":"https://doi.org/10.30728/boron.865316","url":null,"abstract":"With the increasing population, a fire-protection of buildings has become necessary. Therefore, water-based indoor paints, which reduce the rate of the fire and offer the chance to intervene before the flames spread, have received attention; however, the performance and flame retardant property of these paints need to be improved. In this study, boric acid (H 3 BO 3 ), which is the product of boron (B), was used as an additive for a flame retardant in the prepared water-based indoor paints. In order to investigate the effect of different weight ratios of H 3 BO 3 , the paints have been prepared with the addition of 5%, 10%, and 20% (w/w) of H 3 BO 3 . In addition, the synergistic effect of H 3 BO 3 and melamine (C 3 H 6 N 6 ) on the flame retarding performance of the prepared paints was also investigated. The physicochemical properties, flammability characteristics and thermal properties were analyzed by Fourier transform infrared spectroscopy (FTIR), limiting oxygen index (LOI), and thermogravimetric analysis (TGA), respectively. The results demonstrated that the characteristic peaks of H 3 BO 3 were observed in the prepared paints. When the flammability behavior of the paint samples were compared, the sample (P6) containing 20% (w/w) of H 3 BO 3 showed the highest fire resistance property. Moreover, the results of the thermogravimetric analysis demonstrated that the prepared paints containing H 3 BO 3 decomposes into B 2 O 3 and water, which suppresses the fire. It can be concluded that the prepared paint (P6) can be used as a suitable alternative for the water-based indoor paints.","PeriodicalId":431027,"journal":{"name":"Journal of Boron","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115042640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}