阻燃性能的提高:添加硼酸的水性室内涂料的制备与表征

Berk Uslu, Şükran Melda Eskitoros Toğay, N. Dilsiz
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引用次数: 0

摘要

随着人口的增加,建筑物的防火变得必要。因此,水性室内涂料受到了人们的关注,因为它可以降低火灾的发生率,并在火焰蔓延之前提供干预的机会;然而,这些涂料的性能和阻燃性能有待提高。本研究将硼(B)的产物硼酸(h3bo3)作为阻燃剂添加到所制备的水性室内涂料中。为了考察不同重量比的氢氧化硼对涂料性能的影响,分别以氢氧化硼的添加量为5%、10%和20% (w/w)制备了涂料。此外,还考察了三聚氰胺(c3h6n6)和三聚氰胺(h3h6n6)对涂料阻燃性能的增效作用。采用傅里叶变换红外光谱(FTIR)、极限氧指数(LOI)和热重分析(TGA)分别分析了其理化性质、可燃性和热性能。结果表明,制备的涂料中存在h3bo3的特征峰。对比两种涂料样品的可燃性,含20% (w/w) h3bo3的P6样品的耐火性能最高。此外,热重分析结果表明,制备的含有h3bo - 3的涂料分解成b2o3和水,具有抑制火灾的作用。由此可见,所制备的涂料(P6)可作为水性室内涂料的合适替代品。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improvement on flame retarding performance: preparation and characterization of water-based indoor paints with addition of boric acid
With the increasing population, a fire-protection of buildings has become necessary. Therefore, water-based indoor paints, which reduce the rate of the fire and offer the chance to intervene before the flames spread, have received attention; however, the performance and flame retardant property of these paints need to be improved. In this study, boric acid (H 3 BO 3 ), which is the product of boron (B), was used as an additive for a flame retardant in the prepared water-based indoor paints. In order to investigate the effect of different weight ratios of H 3 BO 3 , the paints have been prepared with the addition of 5%, 10%, and 20% (w/w) of H 3 BO 3 . In addition, the synergistic effect of H 3 BO 3 and melamine (C 3 H 6 N 6 ) on the flame retarding performance of the prepared paints was also investigated. The physicochemical properties, flammability characteristics and thermal properties were analyzed by Fourier transform infrared spectroscopy (FTIR), limiting oxygen index (LOI), and thermogravimetric analysis (TGA), respectively. The results demonstrated that the characteristic peaks of H 3 BO 3 were observed in the prepared paints. When the flammability behavior of the paint samples were compared, the sample (P6) containing 20% (w/w) of H 3 BO 3 showed the highest fire resistance property. Moreover, the results of the thermogravimetric analysis demonstrated that the prepared paints containing H 3 BO 3 decomposes into B 2 O 3 and water, which suppresses the fire. It can be concluded that the prepared paint (P6) can be used as a suitable alternative for the water-based indoor paints.
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