Progress in Surface Science最新文献

{"title":"Surface physics of semiconducting nanowires","authors":"Michele Amato ,&nbsp;Riccardo Rurali","doi":"10.1016/j.progsurf.2015.11.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.11.001","url":null,"abstract":"<div><p>Semiconducting nanowires<span> (NWs) are firm candidates for novel nanoelectronic devices and a fruitful playground for fundamental physics.</span></p><p>Ultra-thin nanowires, with diameters below 10<!--> <!-->nm, present exotic quantum effects due to the confinement of the wave functions, e.g. widening of the electronic band-gap, deepening of the dopant states. However, although several reports of sub-10<!--> <!-->nm wires exist to date, the most common NWs have diameters that range from 20 to 200<!--> <!-->nm, where these quantum effects are absent or play a very minor role. Yet, the research activity on this field is very intense and these materials still promise to provide an important paradigm shift for the design of emerging electronic devices and different kinds of applications. A legitimate question is then: what makes a nanowire different from bulk systems? The answer is certainly the large surface-to-volume ratio.</p><p>In this article we discuss the most salient features of surface physics and chemistry<span> in group-IV semiconducting nanowires, focusing mostly on Si NWs. First we review the state-of-the-art of NW growth to achieve a smooth and controlled surface morphology. Next we discuss the importance of a proper surface passivation and its role on the NW electronic properties. Finally, stressing the importance of a large surface-to-volume ratio and emphasizing the fact that in a NW the surface is where most of the action takes place, we discuss molecular sensing and molecular doping.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"91 1","pages":"Pages 1-28"},"PeriodicalIF":6.4,"publicationDate":"2016-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.11.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2401963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Oxygen adsorption on surfaces studied by a spin- and alignment-controlled O2 beam","authors":"Mitsunori Kurahashi","doi":"10.1016/j.progsurf.2016.03.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2016.03.001","url":null,"abstract":"<div><p><span>Molecular oxygen (O</span>₂<span>) is a paramagnetic linear molecule, yet the effect of its molecular alignment and electron spin on the dynamics of O</span>₂ adsorption has remained unclear. Recently, it has been however shown that the use of magnetic hexapolar field allows us to prepare a single spin-rotational state [(<span><math><mrow><mi>J</mi><mtext>,</mtext><mi>M</mi></mrow></math></span>)<!--> <!-->=<!--> <!-->(2,<!--> <!-->2)] selected O₂<span> beam for which both the molecular alignment and the spin state of O</span>₂ are well defined. State-resolved studies of O₂ sticking on Si(1<!--> <!-->0<!--> <!-->0), Al(1<!--> <!-->1<!--> <!-->1), Ni(1<!--> <!-->1<!--> <!-->1) surfaces conducted with this beam have clarified that the O₂<span> sticking probability depends strongly on the molecular alignment and the spin orientation of O</span>₂ relative to the surface. The mechanism of O₂ adsorption on Al(1<!--> <!-->1<!--> <span>1) has been disputed in the past few decades, but the observed steric effect has provided a reasonable picture for it. The preparation method of the state-selected O</span>₂ beam and its application to the alignment- and spin-resolved O₂ sticking studies are reviewed.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"91 1","pages":"Pages 29-55"},"PeriodicalIF":6.4,"publicationDate":"2016-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2016.03.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2120071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Growth morphology and properties of metals on graphene","authors":"Xiaojie Liu ,&nbsp;Yong Han ,&nbsp;James W. Evans ,&nbsp;Albert K. Engstfeld ,&nbsp;R. Juergen Behm ,&nbsp;Michael C. Tringides ,&nbsp;Myron Hupalo ,&nbsp;Hai-Qing Lin ,&nbsp;Li Huang ,&nbsp;Kai-Ming Ho ,&nbsp;David Appy ,&nbsp;Patricia A. Thiel ,&nbsp;Cai-Zhuang Wang","doi":"10.1016/j.progsurf.2015.07.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.07.001","url":null,"abstract":"<div><p><span>Graphene, a single atomic layer of graphite, has been the focus of recent intensive studies due to its novel electronic and structural properties. Metals grown on graphene also have been of interest because of their potential use as metal contacts in graphene devices, for spintronics applications, and for catalysis. All of these applications require good understanding and control of the metal growth morphology, which in part reflects the strength of the metal–graphene bond. Also of importance is whether the interaction between graphene and metal is sufficiently strong to modify the electronic structure of graphene. In this review, we will discuss recent experimental and computational studies related to deposition of metals on graphene supported on various substrates (SiC, SiO</span>₂<span>, and hexagonal close-packed metal surfaces). Of specific interest are the metal–graphene interactions (adsorption energies and diffusion<span> barriers of metal adatoms), and the crystal structures and thermal stability of the metal nanoclusters.</span></span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 4","pages":"Pages 397-443"},"PeriodicalIF":6.4,"publicationDate":"2015-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.07.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2401964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polar discontinuities and 1D interfaces in monolayered materials","authors":"Rafael Martinez-Gordillo ,&nbsp;Miguel Pruneda","doi":"10.1016/j.progsurf.2015.08.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.08.001","url":null,"abstract":"<div><p>Interfaces are the birthplace of a multitude of fascinating discoveries in fundamental science, and have enabled modern electronic devices, from transistors, to lasers, capacitors or solar cells. These interfaces between bulk materials are always bi-dimensional (2D) ‘surfaces’. However the advent of graphene and other 2D crystals opened up a world of possibilities, as in this case the interfaces become one-dimensional (1D) lines. Although the properties of 1D nanoribbons have been extensively discussed in the last few years, 1D interfaces within infinite 2D systems had remained mostly unexplored until very recently. These include grain boundaries in polycrystalline samples, or interfaces in hybrid 2D sheets composed by segregated domains of different materials (as for example graphene/BN hybrids, or chemically different transition metal dichalcogenides). As for their 2D counterparts, some of these 1D interfaces exhibit polar characteristics, and can give rise to fascinating new physical properties. Here, recent experimental discoveries and theoretical predictions on the polar discontinuities that arise at these 1D interfaces will be reviewed, and the perspectives of this new research topic, discussed.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 4","pages":"Pages 444-463"},"PeriodicalIF":6.4,"publicationDate":"2015-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.08.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2621777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultrafast dynamics during the photoinduced phase transition in VO2","authors":"Daniel Wegkamp,&nbsp;Julia Stähler","doi":"10.1016/j.progsurf.2015.10.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.10.001","url":null,"abstract":"<div><p>The phase transition of VO₂ from a monoclinic insulator to a rutile metal, which occurs thermally at <span><math><mrow><msub><mrow><mi>T</mi></mrow><mrow><mtext>C</mtext></mrow></msub></mrow></math></span> <!-->=<!--> <!-->340<!--> <!-->K, can also be driven by strong photoexcitation. The ultrafast dynamics during this photoinduced phase transition (PIPT) have attracted great scientific attention for decades, as this approach promises to answer the question of whether the insulator-to-metal (IMT) transition is caused by electronic or crystallographic processes through disentanglement of the different contributions in the time domain. We review our recent results achieved by femtosecond time-resolved photoelectron, optical, and coherent phonon spectroscopy and discuss them within the framework of a selection of latest, complementary studies of the ultrafast PIPT in VO₂. We show that the population change of electrons and holes caused by photoexcitation launches a highly non-equilibrium plasma phase characterized by enhanced screening due to quasi-free carriers and followed by two branches of non-equilibrium dynamics: (i) an instantaneous (within the time resolution) collapse of the insulating gap that precedes charge carrier relaxation and significant ionic motion and (ii) an instantaneous lattice potential symmetry change that represents the onset of the crystallographic phase transition through ionic motion on longer timescales. We discuss the interconnection between these two non-thermal pathways with particular focus on the meaning of the critical fluence of the PIPT in different types of experiments. Based on this, we conclude that the PIPT threshold identified in optical experiments is most probably determined by the excitation density required to drive <em>the lattice potential change rather than the IMT</em>. These considerations suggest that the IMT can be driven by weaker excitation, predicting a transiently metallic, monoclinic state of VO₂ that is not stabilized by the non-thermal structural transition and, thus, decays on ultrafast timescales.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 4","pages":"Pages 464-502"},"PeriodicalIF":6.4,"publicationDate":"2015-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.10.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2401967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Direct observation and control of hydrogen-bond dynamics using low-temperature scanning tunneling microscopy","authors":"Takashi Kumagai","doi":"10.1016/j.progsurf.2015.04.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.04.001","url":null,"abstract":"<div><p><span>Hydrogen(H)-bond dynamics are involved in many elementary processes in chemistry and biology. Because of its fundamental importance, a variety of experimental and theoretical approaches have been employed to study the dynamics in gas, liquid, solid phases, and their interfaces. This review describes the recent progress of direct observation and control of H-bond dynamics in several model systems on a metal surface by using low-temperature scanning tunneling microscopy (STM). General aspects of H-bond dynamics and the experimental methods are briefly described in chapter 1 and 2. In the subsequent four chapters, I present direct observation of an H-bond exchange reaction within a single water dimer (chapter 3), a symmetric H bond (chapter 4) and H-atom relay reactions (chapter 5) within water–hydroxyl complexes, and an intramolecular H-atom transfer reaction (tautomerization) within a single porphycene molecule (chapter 6). These results provide novel microscopic insights into H-bond dynamics </span><em>at the single-molecule level</em>, and highlight significant impact on the process from quantum effects, namely tunneling and zero-point vibration, resulting from the small mass of H atom. Additionally, local environmental effect on H-bond dynamics is also examined by using atom/molecule manipulation with the STM.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 3","pages":"Pages 239-291"},"PeriodicalIF":6.4,"publicationDate":"2015-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.04.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2401965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly charged ion induced nanostructures at surfaces by strong electronic excitations","authors":"Richard A. Wilhelm ,&nbsp;Ayman S. El-Said ,&nbsp;Franciszek Krok ,&nbsp;René Heller ,&nbsp;Elisabeth Gruber ,&nbsp;Friedrich Aumayr ,&nbsp;Stefan Facsko","doi":"10.1016/j.progsurf.2015.06.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.06.001","url":null,"abstract":"<div><p><span><span>Nanostructure<span> formation by single slow highly charged ion impacts<span> can be associated with high density of electronic excitations at the impact points of the ions. Experimental results show that depending on the target material these electronic excitations may lead to very large desorption yields in the order of a few 1000 atoms per ion or the formation of nanohillocks at the impact site. Even in ultra-thin insulating membranes the formation of nanometer sized pores is observed after ion impact. In this paper, we show recent results on nanostructure formation by highly charged ions and compare them to structures and defects observed after intense electron and light </span></span></span>ion irradiation<span><span> of ionic crystals and graphene. Additional data on energy loss, charge exchange and secondary </span>electron emission of highly charged ions clearly show that the </span></span>ion charge dominates the defect formation at the surface.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 3","pages":"Pages 377-395"},"PeriodicalIF":6.4,"publicationDate":"2015-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.06.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2621778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ab initio quantum transport calculations using plane waves","authors":"A. Garcia-Lekue ,&nbsp;M.G. Vergniory ,&nbsp;X.W. Jiang ,&nbsp;L.W. Wang","doi":"10.1016/j.progsurf.2015.05.002","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.05.002","url":null,"abstract":"<div><p>We present an <em>ab initio</em><span><span><span><span> method to calculate elastic quantum transport at the </span>nanoscale. The method is based on a combination of </span>density functional theory using plane wave nonlocal </span>pseudopotentials<span><span> and the use of auxiliary periodic boundary conditions to obtain the scattering states. The method can be applied to any applied bias voltage and the charge density and potential profile can either be calculated self-consistently, or using an approximated self-consistent field (SCF) approach. Based on the scattering states one can straightforwardly calculate the transmission coefficients and the corresponding electronic current. The overall scheme allows us to obtain accurate and numerically stable solutions for the elastic transport, with a computational time similar to that of a ground state calculation. This method is particularly suitable for calculations of tunneling currents through vacuum, that some of the </span>nonequilibrium<span><span><span> Greens function (NEGF) approaches based on atomic basis sets might have difficulty to deal with. Several examples are provided using this method from </span>electron tunneling, to </span>molecular electronics, to electronic devices: (i) On a Au nanojunction, the tunneling current dependence on the electrode–electrode distance is investigated. (ii) The tunneling through field emission resonances (FERs) is studied via an accurate description of the surface vacuum states. (iii) Based on quantum transport calculations, we have designed a molecular conformational switch, which can turn on and off a molecular junction by applying a perpendicular electric field. (iv) Finally, we have used the method to simulate tunnel field-effect transistors (TFETs) based on two-dimensional transition-metal dichalcogenides (TMDCs), where we have studied the performance and scaling limits of such nanodevices and proposed atomic doping to enhance the transistor performance.</span></span></span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 3","pages":"Pages 292-318"},"PeriodicalIF":6.4,"publicationDate":"2015-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.05.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3390755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hot electron lifetimes in metals probed by time-resolved two-photon photoemission","authors":"M. Bauer ,&nbsp;A. Marienfeld ,&nbsp;M. Aeschlimann","doi":"10.1016/j.progsurf.2015.05.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2015.05.001","url":null,"abstract":"<div><p>This review reports on experimental and theoretical results on the inelastic decay of optically excited volume electrons in different types of metals, including simple metals (Al), noble metals<span><span> (Au, Ag, Cu), transition metals (Ta, Mo, Rh, Co, Fe, Ni) and rare earth metals (Gd, Tb, Yb, La). The comparison of the different materials and material classes provides particular insight into the relevance of the localization and delocalization of electronic states for inelastic carrier scattering processes. The discussion of the data illustrates furthermore the capabilities and limitations of the time-resolved two-photon </span>photoemission technique as well as current theoretical approaches in analyzing and determining inelastic lifetimes of excited electrons.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 3","pages":"Pages 319-376"},"PeriodicalIF":6.4,"publicationDate":"2015-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2015.05.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2067678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The influence of electron confinement, quantum size effects, and film morphology on the dispersion and the damping of plasmonic modes in Ag and Au thin films","authors":"Antonio Politano ,&nbsp;Gennaro Chiarello","doi":"10.1016/j.progsurf.2014.12.002","DOIUrl":"https://doi.org/10.1016/j.progsurf.2014.12.002","url":null,"abstract":"<div><p>Plasmons<span> are collective longitudinal modes of charge fluctuation in metal samples excited by an external electric field. Surface plasmons (SPs) are waves that propagate along the surface of a conductor. SPs find applications in magneto-optic data storage, optics, microscopy, and catalysis.</span></p><p><span><span>The investigation of SPs in silver<span> and gold is relevant as these materials are extensively used in plasmonics. The theoretical approach for calculating plasmon modes in noble metals is complicated by the existence of localized d electrons near the </span></span>Fermi level. Nevertheless, recent calculations based on linear response theory and time-dependent </span>local density approximation adequately describe the dispersion and damping of SPs in noble metals.</p><p>Furthermore, in thin films the electronic response is influenced by electron quantum confinement. Confined electrons modify the dynamical screening processes at the film/substrate interface by introducing novel properties with potential applications. The presence of quantum well states in the Ag and Au overlayer affects both the dispersion relation of SP frequency and the damping processes of the SP.</p><p>Recent calculations indicate the emergence of acoustic surface plasmons (ASP) in Ag thin films exhibiting quantum well states. The slope of the dispersion of ASP decreases with film thickness.</p><p><span>High-resolution electron energy loss spectroscopy (HREELS) is the main experimental technique for investigating collective </span>electronic excitations, with adequate resolution in both the energy and momentum domains to investigate surface modes.</p><p>Herein we review on recent progress of research on collective electronic excitations in Ag and Au films deposited on single-crystal substrates.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"90 2","pages":"Pages 144-193"},"PeriodicalIF":6.4,"publicationDate":"2015-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2014.12.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2065095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}