Sum frequency generation vibrational spectroscopy (SFG-VS) for complex molecular surfaces and interfaces: Spectral lineshape measurement and analysis plus some controversial issues

IF 8.7 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science Pub Date : 2016-12-01 DOI:10.1016/j.progsurf.2016.10.001

Hong-Fei Wang

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引用次数: 84

Abstract

Sum-frequency generation vibrational spectroscopy (SFG-VS) was first developed in the 1980s and it has been proven a uniquely sensitive and surface/interface selective spectroscopic probe for characterization of the structure, conformation and dynamics of molecular surfaces and interfaces. In recent years, there have been many progresses in the development of methodology and instrumentation in the SFG-VS toolbox that have significantly broadened the application to complex molecular surfaces and interfaces. In this review, after presenting a unified view on the theory and methodology focusing on the SFG-VS spectral lineshape, as well as the new opportunities in SFG-VS applications with such developments, some of the controversial issues that have been puzzling the community are discussed. The aim of this review is to present to the researchers and students interested in molecular surfaces and interfacial sciences up-to-date perspectives complementary to the existing textbooks and reviews on SFG-VS.

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复杂分子表面和界面的和频产生振动光谱(SFG-VS):谱线测量和分析以及一些有争议的问题

和频产生振动光谱(SFG-VS)在20世纪80年代首次发展起来，它已被证明是一种独特的敏感和表面/界面选择性光谱探针，用于表征分子表面和界面的结构，构象和动力学。近年来，SFG-VS工具箱在方法和仪器的开发方面取得了许多进展，大大拓宽了其在复杂分子表面和界面上的应用。在本文中，在对SFG-VS谱线形态的理论和方法进行了统一的阐述之后，以及随着这一发展在SFG-VS应用中的新机遇，讨论了一些一直困扰业界的有争议的问题。这篇综述的目的是向对分子表面和界面科学感兴趣的研究人员和学生提供最新的观点，补充现有的SFG-VS教科书和综述。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Progress in Surface Science 工程技术-物理：凝聚态物理

CiteScore

11.30

自引率

0.00%

发文量

审稿时长

3 months

期刊介绍： Progress in Surface Science publishes progress reports and review articles by invited authors of international stature. The papers are aimed at surface scientists and cover various aspects of surface science. Papers in the new section Progress Highlights, are more concise and general at the same time, and are aimed at all scientists. Because of the transdisciplinary nature of surface science, topics are chosen for their timeliness from across the wide spectrum of scientific and engineering subjects. The journal strives to promote the exchange of ideas between surface scientists in the various areas. Authors are encouraged to write articles that are of relevance and interest to both established surface scientists and newcomers in the field.