Progress in Surface Science最新文献

{"title":"Photon upconversion towards applications in energy conversion and bioimaging","authors":"Qi-C. Sun ,&nbsp;Yuchen C. Ding ,&nbsp;Dodderi M. Sagar ,&nbsp;Prashant Nagpal","doi":"10.1016/j.progsurf.2017.09.003","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.09.003","url":null,"abstract":"<div><p>The field of plasmonics can play an important role in developing novel devices for application in energy and healthcare. In this review article, we consider the progress made in design and fabrication of upconverting nanoparticles<span><span><span> and metal nanostructures for precisely manipulating light photons, with a wavelength of several hundred nanometers, at nanometer length scales, and describe how to tailor their interactions with molecules and surfaces so that two or more lower energy photons can be used to generate a single higher energy photon in a process called photon upconversion. This review begins by introducing the current state-of-the-art in upconverting </span>nanoparticle synthesis<span><span> and achievements in color tuning and upconversion enhancement. Through understanding and tailoring physical processes, color tuning and strong upconversion enhancement have been demonstrated by coupling with surface plasmon </span>polariton waves, especially for low intensity or diffuse infrared radiation. Since more than 30% of incident sunlight is not utilized in most </span></span>photovoltaic cells, this photon upconversion is one of the promising approaches to break the so-called Shockley-Queisser thermodynamic limit for a single junction solar cell. Furthermore, since the low energy photons typically cover the biological window of optical transparency, this approach can also be particularly beneficial for novel biosensing and bioimaging techniques. Taken together, the recent research boosts the applications of photon upconversion using designed metal nanostructures and nanoparticles for green energy, bioimaging, and therapy.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 4","pages":"Pages 281-316"},"PeriodicalIF":6.4,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.09.003","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3390900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Two-dimensional silica opens new perspectives","authors":"Christin Büchner,&nbsp;Markus Heyde","doi":"10.1016/j.progsurf.2017.09.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.09.001","url":null,"abstract":"<div><p>In recent years, silica films have emerged as<!--> <!-->a novel class of two-dimensional (2D) materials. Several groups succeeded in epitaxial growth of ultrathin SiO₂ layers using different growth methods and various substrates. The structures consist of tetrahedral [SiO₄] building blocks in two mirror symmetrical planes, connected via oxygen bridges. This arrangement is called a silica bilayer as it is the thinnest 2D arrangement with the stoichiometry SiO₂ known today. With all bonds saturated within the nano-sheet, the interaction with the substrate is based on van der Waals forces. Complex ring networks are observed, including hexagonal honeycomb lattices, point defects and domain boundaries, as well as amorphous domains. The network structures are highly tuneable through variation of the substrate, deposition parameters, cooling procedure, introducing dopants or intercalating small species.</p><p>The amorphous networks and structural defects were resolved with atomic resolution microscopy and modeled with density functional theory and molecular dynamics. Such data contribute to our understanding of the formation and characteristic motifs of glassy systems. Growth studies and doping with other chemical elements reveal ways to tune ring sizes and defects as well as chemical reactivities. The pristine films have been utilized as molecular sieves and for confining molecules in nanocatalysis. Post growth hydroxylation can be used to tweak the reactivity as well.</p><p>The electronic properties of silica bilayers are favourable for using silica as insulators in 2D material stacks. Due to the fully saturated atomic structure, the bilayer interacts weakly with the substrate and can be described as quasi-freestanding. Recently, a<!--> <!-->mm-scale film transfer under structure retention has been demonstrated. The chemical and mechanical stability of silica bilayers is very promising for technological applications in 2D heterostacks.</p><p>Due to the impact of this bilayer system for glass science, catalysis and the field of 2D materials, a large number of theoretical and experimental studies on silica bilayers have been reported in the last years. This review aims to provide an overview on the insights gained on this material and to point out opportunities for further discovery in various fields.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 4","pages":"Pages 341-374"},"PeriodicalIF":6.4,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.09.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2621771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface and interface sciences of Li-ion batteries","authors":"Taketoshi Minato ,&nbsp;Takeshi Abe","doi":"10.1016/j.progsurf.2017.10.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.10.001","url":null,"abstract":"<div><p>The application potential of Li-ion batteries is growing as demand increases in different fields at various stages in energy systems, in addition to their conventional role as power sources for portable devices. In particular, applications in electric vehicles and renewable energy storage are increasing for Li-ion batteries. For these applications, improvements in battery performance are necessary. The Li-ion battery produces and stores electric power from the electrochemical redox reactions<span> between the electrode materials. The interface between the electrodes and electrolyte strongly affects the battery performance because the charge transfer causing the electrode redox reaction begins at this interface. Understanding of the surface structure, electronic structure, and chemical reactions at the electrode–electrolyte interface is necessary to improve battery performance. However, the interface is located between the electrode and electrolyte materials, hindering the experimental analysis of the interface; thus, the physical properties and chemical processes have remained poorly understood until recently. Investigations of the physical properties and chemical processes at the interface have been performed using advanced surface science techniques. In this review, current knowledge and future research prospects regarding the electrode–electrolyte interface are described for the further development of Li-ion batteries.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 4","pages":"Pages 240-280"},"PeriodicalIF":6.4,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.10.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2120190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Doped and codoped silicon nanocrystals: The role of surfaces and interfaces","authors":"Ivan Marri,&nbsp;Elena Degoli,&nbsp;Stefano Ossicini","doi":"10.1016/j.progsurf.2017.07.003","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.07.003","url":null,"abstract":"<div><p><span><span>Si nanocrystals have been extensively studied because of their novel properties and their potential applications in electronic, optoelectronic, photovoltaic, </span>thermoelectric and biological devices. These new properties are achieved through the combination of the quantum confinement of carriers and the strong influence of surface chemistry. As in the case of bulk Si the tuning of the electronic, optical and transport properties is related to the possibility of doping, in a controlled way, the nanocrystals. This is a big challenge since several studies have revealed that doping in Si nanocrystals differs from the one of the bulk. Theory and experiments have underlined that doping and codoping are influenced by a large number of parameters such as size, shape, </span>passivation<span> and chemical environment of the silicon nanocrystals. However, the connection between these parameters and dopant localization as well as the occurrence of self-purification effects are still not clear. In this review we summarize the latest progress in this fascinating research field considering free-standing and matrix-embedded Si nanocrystals both from the theoretical and experimental point of view, with special attention given to the results obtained by ab-initio calculations and to size-, surface- and interface-induced effects.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 4","pages":"Pages 375-408"},"PeriodicalIF":6.4,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.07.003","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2415679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface chemistry and microscopy of food powders","authors":"Jennifer Burgain ,&nbsp;Jeremy Petit ,&nbsp;Joël Scher ,&nbsp;Ron Rasch ,&nbsp;Bhesh Bhandari ,&nbsp;Claire Gaiani","doi":"10.1016/j.progsurf.2017.07.002","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.07.002","url":null,"abstract":"<div><p>Despite high industrial and scientific interest, a comprehensive review of the surface science of food powders is still lacking. There is a real gap between scientific concerns of the field and accessible reviews on the subject. The global description of the surface of food powders by multi-scale microscopy approaches seems to be essential in order to investigate their complexity and take advantage of their high innovation potential.</p><p>Links between these techniques and the interest to develop a multi-analytical approach to investigate scientific questions dealing with powder functionality are discussed in the second part of the review. Finally, some techniques used in others fields and showing promising possibilities in the food powder domain will be highlighted.<span><figure><span><img><ol><li><span>Download : <span>Download high-res image (202KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 4","pages":"Pages 409-429"},"PeriodicalIF":6.4,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.07.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2621772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Atomic-scale investigation of nuclear quantum effects of surface water: Experiments and theory","authors":"Jing Guo ,&nbsp;Xin-Zheng Li ,&nbsp;Jinbo Peng ,&nbsp;En-Ge Wang ,&nbsp;Ying Jiang","doi":"10.1016/j.progsurf.2017.11.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.11.001","url":null,"abstract":"<div><p><span>Quantum behaviors of protons in terms of tunneling and zero-point motion have significant effects on the macroscopic properties<span>, structure, and dynamics of water even at room temperature<span> or higher. In spite of tremendous theoretical and experimental efforts, accurate and quantitative description of the nuclear quantum effects (NQEs) is still challenging. The main difficulty lies in that the NQEs are extremely susceptible to the structural inhomogeneity and local environments, especially when interfacial systems are concerned. In this review article, we will highlight the recent advances of scanning tunneling microscopy and spectroscopy (STM/S), which allows the access to the quantum degree of freedom of protons both in real and energy space. In addition, we will also introduce recent development of </span></span></span><em>ab initio</em> path-integral molecular dynamics (PIMD) simulations at surfaces/interfaces, in which both the electrons and nuclei are treated as quantum particles in contrast to traditional <em>ab initio</em><span> molecular dynamics (MD). Then we will discuss how the combination of STM/S and PIMD are used to directly visualize the concerted quantum tunneling of protons within the water clusters and quantify the impact of zero-point motion on the strength of a single hydrogen bond (H bond) at a water/solid interface. Those results may open up the new possibility of exploring the exotic quantum states of light nuclei at surfaces, as well as the quantum coupling between the electrons and nuclei.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 4","pages":"Pages 203-239"},"PeriodicalIF":6.4,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.11.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2621769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Non-adiabatic effects in elementary reaction processes at metal surfaces","authors":"M. Alducin ,&nbsp;R. Díez Muiño ,&nbsp;J.I. Juaristi","doi":"10.1016/j.progsurf.2017.09.002","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.09.002","url":null,"abstract":"<div><p>Great success has been achieved in the modeling of gas-surface elementary processes by the use of the Born-Oppenheimer approximation. However, in metal surfaces low energy electronic excitations are generated even by thermal and hyperthermal molecules due to the absence of band gaps in the electronic structure. This shows the importance of performing dynamical simulations that incorporate non-adiabatic effects to analyze in which way they affect most common gas-surface reactions. Here we review recent theoretical developments in this problem and their application to the study of the effect of electronic excitations in the adsorption and relaxation of atoms and molecules in metal surfaces, in scattering processes, and also in recombinative processes between impinging atoms and adsorbates at the surface. All these studies serve us to establish what properties of the gas-surface interaction favor the excitation of low-energy electron-hole pairs. A general observation is that the nature of these excitations usually requires long lasting interactions at the surface in order to observe deviations from the adiabatic behaviour. We also provide the basis of the local density friction approximation (LDFA) that have been used in all these studies, and show how it has been employed to perform ab initio molecular dynamics with electronic friction (AIMDEF). As a final remark, we will shortly review on recent applications of the LDFA to successfully simulate desorption processes induced by intense femtosecond laser pulses.</p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 4","pages":"Pages 317-340"},"PeriodicalIF":6.4,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.09.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2621770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Spatially-resolved studies on the role of defects and boundaries in electronic behavior of 2D materials","authors":"Saban M. Hus,&nbsp;An-Ping Li","doi":"10.1016/j.progsurf.2017.07.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.07.001","url":null,"abstract":"<div><p><span>Two-dimensional (2D) materials are intrinsically heterogeneous. Both localized defects, such as vacancies and dopants, and mesoscopic boundaries, such as surfaces and interfaces, give rise to compositional or structural heterogeneities. The presence of defects and boundaries can break lattice symmetry, modify the energy landscape, and create quantum confinement, leading to fascinating electronic properties different from the “ideal” 2D sheets. This review summarizes recent progress in understanding the roles of defects and boundaries in electronic, magnetic, thermoelectric, and transport properties of 2D layered materials. The focus is on the understanding of correlation of atomic-scale structural information with electronic functions by interrogating heterogeneities individually. The materials concerned are graphene, transition metal dichalcogenides<span><span> (TMDs), hexagonal boron nitride (hBN), and </span>topological insulators (TIs). The experimental investigations benefit from new methodologies and techniques in scanning tunneling </span></span>microscopy<span> (STM), including spin-polarized STM, scanning tunneling potentiometry (STP), scanning tunneling thermopower microscopy, and multi-probe STM. The experimental effort is complemented by the computational and theoretical approaches, capable of discriminating between closely competing states and achieving the length scales necessary to bridge across features such as local defects and complex heterostructures. The goal is to provide a general view of current understanding and challenges in studying the heterogeneities in 2D materials and to evaluate the potential of controlling and exploiting these heterogeneities for novel functionalities and electron devices.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 3","pages":"Pages 176-201"},"PeriodicalIF":6.4,"publicationDate":"2017-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.07.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2401961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The role of contact resistance in graphene field-effect devices","authors":"Filippo Giubileo ,&nbsp;Antonio Di Bartolomeo","doi":"10.1016/j.progsurf.2017.05.002","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.05.002","url":null,"abstract":"<div><p>The extremely high carrier mobility<span><span> and the unique band structure, make graphene very useful for field-effect transistor applications. According to several works, the primary limitation to graphene based transistor performance is not related to the material quality, but to extrinsic factors that affect the electronic transport properties. One of the most important parasitic element is the contact resistance appearing between graphene and the metal electrodes functioning as the source and the drain. Ohmic contacts to graphene, with low contact resistances, are necessary for injection and extraction of majority charge carriers to prevent transistor parameter fluctuations caused by variations of the contact resistance. The International Technology Roadmap for Semiconductors, toward integration and down-scaling of graphene electronic devices, identifies as a challenge the development of a CMOS compatible process that enables reproducible formation of low contact resistance. However, the contact resistance is still not well understood despite it is a crucial barrier towards further improvements. In this paper, we review the experimental and theoretical activity that in the last decade has been focusing on the reduction of the contact resistance in graphene transistors. We will summarize the specific properties of graphene-metal contacts with particular attention to the nature of metals, impact of fabrication process, </span>Fermi level pinning, interface modifications induced through surface processes, charge transport mechanism, and edge contact formation.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 3","pages":"Pages 143-175"},"PeriodicalIF":6.4,"publicationDate":"2017-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.05.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2621773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Atomically flat single terminated oxide substrate surfaces","authors":"Abhijit Biswas ,&nbsp;Chan-Ho Yang ,&nbsp;Ramamoorthy Ramesh ,&nbsp;Yoon H. Jeong","doi":"10.1016/j.progsurf.2017.05.001","DOIUrl":"https://doi.org/10.1016/j.progsurf.2017.05.001","url":null,"abstract":"<div><p><span><span><span>Scientific interest in atomically controlled layer-by-layer fabrication of transition metal oxide<span> thin films and heterostructures has increased intensely in recent decades for basic physics reasons as well as for technological applications. This trend has to do, in part, with the coming post-Moore era, and functional oxide electronics could be regarded as a viable alternative for the current semiconductor electronics. Furthermore, the interface of transition metal oxides is exposing many new emergent phenomena and is increasingly becoming a playground for testing new ideas in </span></span>condensed matter physics. To achieve high quality epitaxial thin films and heterostructures of transition metal oxides with atomically controlled interfaces, one critical requirement is the use of atomically flat single terminated oxide substrates since the atomic arrangements and the reaction </span>chemistry<span> of the topmost surface layer of substrates determine the growth and consequent properties of the overlying films. Achieving the atomically flat and chemically single terminated surface state of commercially available substrates, however, requires judicious efforts because the surface of as-received substrates is of chemically mixed nature and also often polar. In this review, we summarize the surface treatment procedures to accomplish atomically flat surfaces with single terminating layer for various metal oxide substrates. We particularly focus on the substrates with lattice constant ranging from 4.00</span></span> <!-->Å to 3.70<!--> <span>Å, as the lattice constant of most perovskite materials falls into this range. For materials outside the range, one can utilize the substrates to induce compressive or tensile strain on the films and explore new states not available in bulk. The substrates covered in this review, which have been chosen with commercial availability and, most importantly, experimental practicality as a criterion, are KTaO</span>₃, <span><em>RE</em></span>ScO₃ (<em>RE</em> <!-->=<!--> <!-->Rare-earth elements), SrTiO₃, La_0.18Sr_0.82Al_0.59Ta_0.41O₃ (LSAT), NdGaO₃, LaAlO₃, SrLaAlO₄, and YAlO₃<span>. Analyzing all the established procedures, we conclude that atomically flat surfaces with selective A- or B-site single termination would be obtained for most commercially available oxide substrates. We further note that this topmost surface layer selectivity would provide an additional degree of freedom in searching for unforeseen emergent phenomena and functional applications in epitaxial oxide thin films and heterostructures with atomically controlled interfaces.</span></p></div>","PeriodicalId":416,"journal":{"name":"Progress in Surface Science","volume":"92 2","pages":"Pages 117-141"},"PeriodicalIF":6.4,"publicationDate":"2017-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsurf.2017.05.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2067676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}