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Heterogeneous Processes in Detoxification of Metal Ions 金属离子解毒过程中的异质过程
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020161
N. Skorik, O. A. Asochakov, A. A. Seregina
{"title":"Heterogeneous Processes in Detoxification of Metal Ions","authors":"N. Skorik, O. A. Asochakov, A. A. Seregina","doi":"10.31857/s0044460x24020161","DOIUrl":"https://doi.org/10.31857/s0044460x24020161","url":null,"abstract":"The conditions for the synthesis of sparingly soluble salts of lead, cadmium, mercury(II), copper(II) and iron(II, III) with anions of some organic acids HmL were given. Based on their solubility data (ionic strength I = 0.1), the solubility constants KS were calculated; based on the [Mn+]/MPCM ratio, conclusions were drawn about the applicability of low-toxic organic ligands as precipitators (antidotes) of toxic metal ions. It was shown that deactivation is also possible during the redox reaction of mercury(II), copper(II) with ascorbic acid. According to adsorption data on activated carbon, a number of ions were established to reduce sorption (deactivation ability): Pb2+ (96.6%), Fe3+ (95.4%), Hg2+ (80.6%), Cd2+ (42.4%). Adsorption data complemented the results of reagent methods for studying the detoxification of metal ions.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"19 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141809933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Disecondary Aromatic Diols 二元芳香族二元醇的合成
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020022
B. Zaitsev, L. G. Kleptsova, I. D. Shvabskaya
{"title":"Synthesis of Disecondary Aromatic Diols","authors":"B. Zaitsev, L. G. Kleptsova, I. D. Shvabskaya","doi":"10.31857/s0044460x24020022","DOIUrl":"https://doi.org/10.31857/s0044460x24020022","url":null,"abstract":"The synthesis of disecondary aromatic diols (the main precursors for divinyl aromatic monomers) was carried out. The optimal conditions for the preparation of these diols by selective catalytic hydrogenation of aromatic diketones in the presence of Raney nickel and by reduction of these diketones by sodium borohydride were established. It was demonstrated that sodium borohydride reduction afforded the pure diols under mild and relatively safe conditions (in the systems of CHCl3–PEG400–H2O, at room temperature and atmospheric pressure).","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"138 31","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141811022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gibbs Energy of Cryptand[2.2.2] Transfer from Water to Aqueous Dimethyl Sulfoxide Solvent 隐含物[2.2.2] 从水转移到二甲基亚砜水溶液的吉布斯能
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020106
V. A. Isaeva, E. I. Pogodina, A. S. Katolikova, K. V. Grazhdan
{"title":"Gibbs Energy of Cryptand[2.2.2] Transfer from Water to Aqueous Dimethyl Sulfoxide Solvent","authors":"V. A. Isaeva, E. I. Pogodina, A. S. Katolikova, K. V. Grazhdan","doi":"10.31857/s0044460x24020106","DOIUrl":"https://doi.org/10.31857/s0044460x24020106","url":null,"abstract":"We represent the Gibbs energies of cryptand[2.2.2] transfer from water to different composition water–dimethyl sulfoxide solvent. The Gibbs energies were determined by interphase distribution of cryptand[2.2.2] between two immiscible solvents. We conclude, that when the dimethyl sulfoxide concentration increases, the cryptand[2.2.2] solvation is weakening.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"137 49","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141811107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inclusion Complex of Gd(III) with β-Cyclodextrin and L-Tryptophan 钆（III）与β-环糊精和 L-色氨酸的包合物
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020128
S. S. Khasaeva, N. N. Bukov, S. Ivanin, S. L. Kuznetsova, E. L. Isaeva
{"title":"Inclusion Complex of Gd(III) with β-Cyclodextrin and L-Tryptophan","authors":"S. S. Khasaeva, N. N. Bukov, S. Ivanin, S. L. Kuznetsova, E. L. Isaeva","doi":"10.31857/s0044460x24020128","DOIUrl":"https://doi.org/10.31857/s0044460x24020128","url":null,"abstract":"An inclusion complex of gadolinium(III) with L-tryptophan (Trp) and β-cyclodextrin (β-CD) with the composition Gd(Trp)3Cl3∙3β-CD∙nH2O was synthesized. It was established that the complex is formed due to the entry of the aromatic part of the L-Trp molecule into the β-CD cavity, and the Gd3+ ions are located in the outer sphere.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"85 15","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141812627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural Features of d2-Rhenium(V) Monomeric Octahedral Dioxocomplexes with Tridentate-Chelate, Monodentate Ligands [ReO2(Ltri)(Lmono)], and Tetradentate-Chelate Ligands [ReO2(Ltetra)] (A Review) d2-铼(V)单体八面体二氧羰基络合物与三叉螯合物、单价配体[ReO2(Ltri)(Lmono)]和四价螯合物配体[ReO2(Ltetra)]的结构特征（综述）
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020135
V. Sergienko, A. V. Churakov
{"title":"Structural Features of d2-Rhenium(V) Monomeric Octahedral Dioxocomplexes with Tridentate-Chelate, Monodentate Ligands [ReO2(Ltri)(Lmono)], and Tetradentate-Chelate Ligands [ReO2(Ltetra)] (A Review)","authors":"V. Sergienko, A. V. Churakov","doi":"10.31857/s0044460x24020135","DOIUrl":"https://doi.org/10.31857/s0044460x24020135","url":null,"abstract":"Molecular geometry features of 21 structurally characterized mononuclear octahedral dioxocomplexes of d2-rhenium(V) with mono-, tri- and tetradentate ligands [ReO2(Ltri)(Lmono)], [ReO2(Ltetra)] are discussed. In eleven cases, multiple-bonded Ooxo ligands are arranged in trans-positions to each other with OoxoReOoxo angles ranging within 172.9–180°. In ten structures, the ReO2 unit adopts cis-configuration with OoxoReOoxo angles vary within 106.7–124.8°. Re atoms possess either trans-octahedral coordination environment ReOoxo2X4 (X = N, P, As, O) or cis-structure ReOoxo2N2O2. Bonds Re=Ooxo in monomeric octahedral dioxocompounds d2-Re(V) (mean length 1.772 Å) are significantly longer those observed for monooxocomplexes d2-Re(V) (1.676–1.699 Å).","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"13 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141810340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electron Transfer in Reaction of 12H-Quinoxalino[2,3-b]phenoxazines with π-Acceptors 12H-喹喔啉并[2,3-b]苯噁嗪与π受体反应中的电子转移
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020072
E. Ivakhnenko, P. Knyazev, N. Makarova, O. Demidov, A. Starikov, V. Minkin
{"title":"Electron Transfer in Reaction of 12H-Quinoxalino[2,3-b]phenoxazines with π-Acceptors","authors":"E. Ivakhnenko, P. Knyazev, N. Makarova, O. Demidov, A. Starikov, V. Minkin","doi":"10.31857/s0044460x24020072","DOIUrl":"https://doi.org/10.31857/s0044460x24020072","url":null,"abstract":"Using the reaction of 2,4-di-(tert-butyl)-12-(4-methoxyphenyl)-10-methoxy-12H-quinoxalino[2,3-b]phenoxazine with π-electron acceptors such as tetracyanoquinodimethane and 3,6-di-(tert-butyl)-o-quinone) as an example it was shown that derivatives of this N,O-pentaheterocyclic system are effective electron donors that, under mild conditions, carry out electron transfer reactions with the formation of stable cation and anion radical structures.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"116 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141811914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of the Nature of Nitrogen-Containing Organic Base on Destruction of Octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine 含氮有机碱的性质对八(4-叔丁基苯基)四吡嗪卟嗪破坏的影响
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020098
O. Petrov, K. A. Volzhankina
{"title":"Effect of the Nature of Nitrogen-Containing Organic Base on Destruction of Octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine","authors":"O. Petrov, K. A. Volzhankina","doi":"10.31857/s0044460x24020098","DOIUrl":"https://doi.org/10.31857/s0044460x24020098","url":null,"abstract":"The properties of octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine in 2-methylpyridine were studied. During the acid-base interaction of molecules, a kinetically stable complex was formed with proton transfer. The addition of morpholine, piperidine, n-butylamine, and diethylamine to 2-methylpyridine led to the destruction of this complex, unlike the addition of tert-butylamine and triethylamine. The influence of the proton-accepting ability and spatial structure of the nitrogen-containing base, as well as the basicity of the medium, on the process of the tetrapyrazinoporphyrazine macrocycle decomposition was considered, and a destruction scheme was proposed.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"83 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141812938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A New Approach to the Synthesis of [1,2,4]Triazolo[1,5-a]pyrimidines by Reaction of 1,2,4,5-Tetrazines with 2-Aminoxazoles 通过 1,2,4,5-Tetrazines 与 2-Aminoxazoles 反应合成 [1,2,4]Triazolo[1,5-a]pyrimidines 的新方法
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020067
A. Rammohan, E. Ladin, Y. Shtaitz, A. Krinochkin, I. Khalymbadzha, P. Slepukhin, D. Kopchuk, G. Zyryanov, V. Charushin, V. C. Ranu
{"title":"A New Approach to the Synthesis of [1,2,4]Triazolo[1,5-a]pyrimidines by Reaction of 1,2,4,5-Tetrazines with 2-Aminoxazoles","authors":"A. Rammohan, E. Ladin, Y. Shtaitz, A. Krinochkin, I. Khalymbadzha, P. Slepukhin, D. Kopchuk, G. Zyryanov, V. Charushin, V. C. Ranu","doi":"10.31857/s0044460x24020067","DOIUrl":"https://doi.org/10.31857/s0044460x24020067","url":null,"abstract":"A new transformation of 3,6-diphenyl-1,2,4,5-tetrazine was discovered during the solvent-free reaction with 2-amino-4-aryloxazoles, leading to the formation of 2,5,7-triaryl[1,2,4]triazolo[1,5-a]pyrimidines. Stucture of products was also confirmed by single crystal X-ray diffraction data. A possible mechanism for this reaction was proposed.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"118 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141811771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical Composition and Properties of Water-Methanol Solution of Formaldehyde 甲醛水甲醇溶液的化学成分和性质
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020111
N. N. Gibadullina, E. R. Ishmiyarov, A. I. Voloshin, R. F. Gallyamova, A. R. Mukhamedyarova, V. A. Dokichev
{"title":"Chemical Composition and Properties of Water-Methanol Solution of Formaldehyde","authors":"N. N. Gibadullina, E. R. Ishmiyarov, A. I. Voloshin, R. F. Gallyamova, A. R. Mukhamedyarova, V. A. Dokichev","doi":"10.31857/s0044460x24020111","DOIUrl":"https://doi.org/10.31857/s0044460x24020111","url":null,"abstract":"By reacting paraform with methanol and water at concentrations of 10.8, 11.6 and 22.7 mol/l in the presence of catalytic quantities of monoethanolamine, a method was developed for obtaining a bactericide that, at a concentration of 500 mg/l, completely inhibits the formation of hydrogen sulfide in an accumulative culture of planktonic form of sulfate-reducing bacteria with a quantity of 106 cells/ml. The composition of the resulting bactericide, its effectiveness and corrosion properties were studied. Using scanning electron microscopy using a system for energy-dispersive microanalysis, it was shown that the corrosion products formed during the corrosive action of the bactericide on St-20 steel are iron oxides.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"4 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141814087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Catalytic Systems for Condensation of Monoterpene Compounds with Aldehydes (A Review) 单萜烯化合物与醛缩合的新型催化体系（综述）
ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI: 10.31857/s0044460x24020087
A. Sidorenko, V. E. Agabekov
{"title":"Novel Catalytic Systems for Condensation of Monoterpene Compounds with Aldehydes (A Review)","authors":"A. Sidorenko, V. E. Agabekov","doi":"10.31857/s0044460x24020087","DOIUrl":"https://doi.org/10.31857/s0044460x24020087","url":null,"abstract":"New catalysts for the Prins condensation of renewable monoterpene compounds with aldehydes were considered. Effective catalytic systems were functionalized zeolites, oxides, clays, halloysite and carbon nanotubes, organometallic structures and heteropolyacids, which make it possible to obtain target products with high selectivity. A number of compounds synthesized using such systems are used in perfumery, have high pharmaceutical potential and are platform molecules for further synthesis.","PeriodicalId":411386,"journal":{"name":"ЖУРНАЛ ОБЩЕЙ ХИМИИ","volume":"16 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141810136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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