隐含物[2.2.2] 从水转移到二甲基亚砜水溶液的吉布斯能

ЖУРНАЛ ОБЩЕЙ ХИМИИ Pub Date : 2024-07-23 DOI:10.31857/s0044460x24020106

V. A. Isaeva, E. I. Pogodina, A. S. Katolikova, K. V. Grazhdan

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摘要

我们表示了隐色体[2.2.2]从水转移到不同成分的水-二甲亚砜溶剂中的吉布斯能。吉布斯能是通过隐色体[2.2.2]在两种不相溶溶剂之间的相间分布确定的。我们得出结论，当二甲亚砜浓度增加时，隐糖[2.2.2]的溶解作用会减弱。

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Gibbs Energy of Cryptand[2.2.2] Transfer from Water to Aqueous Dimethyl Sulfoxide Solvent

We represent the Gibbs energies of cryptand[2.2.2] transfer from water to different composition water–dimethyl sulfoxide solvent. The Gibbs energies were determined by interphase distribution of cryptand[2.2.2] between two immiscible solvents. We conclude, that when the dimethyl sulfoxide concentration increases, the cryptand[2.2.2] solvation is weakening.

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