{"title":"In Situ Synthesis of Polyaniline Nanohybrid and Formulation of Polyaniline/ Carboxymethyl cellulose/Ethylene Glycol Nanocomposite: Study of its Conducting and Antibacterial Properties","authors":"","doi":"10.47485/2832-9384.1041","DOIUrl":"https://doi.org/10.47485/2832-9384.1041","url":null,"abstract":"Polyaniline (PANI) has received great attention as a conducting polymer from researchers in the field of organic synthesis and development of conducting nanocomposite polymer technology for superconductors. Different methods of PANI synthesis are being sought for the obtainment of electrically robust PANI composites for electronic and other useful applications. Different inorganic matrices have been considered for this purpose. This study attempts to prepare PANI In situ on arginine-modified nanoclay template by chemical oxidation polymerization. Further, the PANI/Arginine-modified nanoclay was used to prepare PANI/Arginine-Nanoclay/Carboxymethyl cellulose/Ethylene glycol conducting film with robust electric conductivity (EC). Electrical conductivities, anti-bacterial evaluation, Fourier-transform infrared spectroscopy (FT-IR), thermogravimetry analysis (TGA), differential thermogravimetry analysis (DTG) and Scanning Electron Microscopy (SEM) were used for the characterization studies and property evaluation. The electrical conductivities of PANI/Arginine-Nanoclay/Carboxymethyl cellulose/Ethylene glycol nanocomposite film reached 1900 S/Cm. FT-IR data, 3304–3196, 2926–2828, 2200–2022, 1733, 1620 and 1052 cm-1 respectively, confirmed the presence of organic intercalates, CMC, quinoid and benzenoid rings of PANI, and the inorganic nanoclay matter in the nanocomposite film. SEM revealed the presence of spine-like nanoflowers with elongated and expanded particle agglomerations. Thermal stability of the prepared nanocomposite thin film reached 700oC. The zone of inhibition ranged from 24-36 mm against S. typhi, E. coli and S. aureus. In conclusion, PANI nanocomposite thin conducting films had robust EC and antibacterial properties. In addition, the In-situ synthesis of PANI on Arginine-modified nanoclay platform aided the electric conductivity of the nanocomposite system.","PeriodicalId":372397,"journal":{"name":"Journal of Materials and Polymer Science","volume":"136 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139259632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Plane Strain State of Composite Material Reinforced by Two Rows of Crystalline Fibres in Dynamic Elastic-Plastic Formulation","authors":"Vladislav Bogdanov","doi":"10.47485/2832-9384.1034","DOIUrl":"https://doi.org/10.47485/2832-9384.1034","url":null,"abstract":"A generalized approach was developed for solving contact problems in a dynamic elastic-plastic formulation. For the design of composite and reinforced materials, a technique for solving dynamic contact problems in more adequate an elastic-plastic mathematical formulation is used. To consider the physical nonlinearity of the deformation process, the method of successive approximations is used, which makes it possible to reduce the nonlinear problem to a solution of the sequences of linear problems. In contrast to the traditional plane strain, when one normal stress is equal to a certain constant value, for a more accurate description of the deformation of the sample, taking into ac-count the possible increase in longitudinal elongation, we present this normal stress as a function that depends on the parameters that describe the bending of a prismatic body that is in a plain strain state. The problem of a plane strain state of a beam made from the composite reinforced one-layer material is being solved. The reinforced or armed composite material consists of two materials: the main material of glass and two rows of the reinforcing crystalline fourteen fibres of basalt. Glass has high strength and is not affected by the processes of aging of the material, corrosion, and creep. In addition, this material is cheap and widely available. The reinforced composite beam is rigidly linked to an absolutely solid base and on which an absolutely solid impactor acts from above in the centre on a different size of the area of initial contact.","PeriodicalId":372397,"journal":{"name":"Journal of Materials and Polymer Science","volume":"20 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139360388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Plane Strain State of Four-Layers Composite Reinforced Body in Dynamic Elastic-Plastic Formulation\u0000Authors: Vladislav Bogdanov","authors":"Vladislav Bogdanov","doi":"10.47485/2832-9384.1032","DOIUrl":"https://doi.org/10.47485/2832-9384.1032","url":null,"abstract":"The design of composite and reinforced or armed materials is a requirement of the modern level of production and life. In previous works (Bogdanov, 2022; Bogdanov, 2022; Bogdanov, 2022; Bogdanov, 2022), the plane problems of non-stationary interaction of a bullet-type impactor with the upper surface of a composite reinforced two-layers base, which consists of an upper thin layer of steel and a lower main layer of glass, was investigated. It is of interest to study the question of how a composite material composed of several two-layers composite bases laid on top of each other and rigidly bonded to each other will behave. In this work, we study the non-stationary interaction of a striker and a four-layers composite material reinforced with two thin steel layers. The four-layers base is obtained from two identical two-layers bases rigidly linked to each other. Such a four-layer material along its lower surface is rigidly linked to an absolutely hard half-space. The main layers of the material consist of glass. The use of glass in composites is promising due to the fact that glass is a durable, cheap, widespread material that does not corrode, and its strength properties do not degrade as a result of aging, creep like other materials, especially metals. The problem of glass brittleness is overcome by hard contact between the layers. In this case, the tops of micro cracks, micro pores on the surfaces of glass and steel are immobilized and do not propagate into the layers. An absolutely solid impactor acts from above in the centre on a small area of initial contact. The problem of a plane strain state of a beam made from the composite reinforced four layers material is being solved. A technique for solving dynamic contact problems in a dynamic elastic-plastic mathematical formulation is used. To consider the physical nonlinearity of the deformation process, the method of successive approximations is used, which makes it possible to reduce the nonlinear problem to a solution of the sequences of linear problems.","PeriodicalId":372397,"journal":{"name":"Journal of Materials and Polymer Science","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115807729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}