Journal of Industrial and Engineering Chemistry最新文献_第5页

Polypyrrole@Pd solar-thermal catalyst for eco-friendly and scalable multiphasic Suzuki coupling reactions 用于生态友好型可扩展多相铃木偶联反应的聚吡咯@钯太阳能热催化剂

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.06.035

Seungbeom Park , Dongchan Lee , Kangjoo Lee, Sun-Joon Min, Kwang-Suk Jang

引用次数: 0

Green synthesis of graphene-based derivatives from Ulva lactuca extract: Characterization and biomedical applications 从莼菜提取物中绿色合成石墨烯基衍生物：表征与生物医学应用

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.07.016

Mohammed Ali Alshehri , Chellasamy Panneerselvam

{"title":"Green synthesis of graphene-based derivatives from Ulva lactuca extract: Characterization and biomedical applications","authors":"Mohammed Ali Alshehri , Chellasamy Panneerselvam","doi":"10.1016/j.jiec.2024.07.016","DOIUrl":"10.1016/j.jiec.2024.07.016","url":null,"abstract":"<div><div>Graphene-based materials have been extensively researched due to its biocompatibility, unique conjugated structure, and relatively low cost in the realm of biology. Graphene is increasingly being explored for many medical uses, including as DNA-hybridization devices, cancer treatment, and medicine administration. Furthermore, it exhibits substantial potential in several fields of biological applications, such as antibacterial interventions, therapy, and biosensing. The synthesis of GO and rGO was achieved in this work for the first-time using macroalgae, Ulva lactuca as a reducing agent. The antibacterial activity of graphene-based derivatives was evaluated against two different human pathogenic bacteria. Bacterial growth inhibition increased in proportion to the higher concentration. Higher concentration of nanosheets could enhance the cellular enzyme activity. Different scavenging assays are adapted to assess the antioxidant activity of GO and rGO. Significant in-vitro antioxidant activity was observed in a concentration-dependent manner. Furthermore, the antitumor activity of synthesized nanosheets was tested against human breast cancer cells (MCF-7) at various concentrations. The test results show that the graphene derivatives in the MCF-7 cell line exhibit an increase in apoptotic behaviour as sample concentration rises. This study could offer novel insights into the antibacterial, antioxidant, and anticancer activities of the green synthesized graphene-based derivatives.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 554-567"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141695390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced the electrochemical performance of Ni-doped α-MnO2 prepared with one-pot process for supercapacitors 提高一锅法制备的掺镍 α-MnO2 在超级电容器中的电化学性能

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.06.041

Bengang Tan , Nali Chen , Lizhi Huang , Xin Gao , Lin Tan , Huixia Feng

{"title":"Enhanced the electrochemical performance of Ni-doped α-MnO2 prepared with one-pot process for supercapacitors","authors":"Bengang Tan , Nali Chen , Lizhi Huang , Xin Gao , Lin Tan , Huixia Feng","doi":"10.1016/j.jiec.2024.06.041","DOIUrl":"10.1016/j.jiec.2024.06.041","url":null,"abstract":"<div><div>Poor capacitive behavior caused by low electronic conductivity and slow reaction kinetics is the main obstacle faced by the MnO2 electrode materials in current supercapacitors. Herein, the influence of Ni doping on the capacitive behavior of α-MnO2 synthesized by a low-cost and one-pot chemical coprecipitation method was investigated. During the doping process, the amount of Ni was increased from 0.05 mmol to 0.45 mmol in steps of 0.1 mmol. The structure and chemical composition of Ni-doped MnO2 (MnO2-Ni) were characterized by XRD, FTIR, SEM, EDS, and XPS. Comprehensive studies show that no change in the crystal phase structure of MnO2, while the decrease in the nanoparticle size and the increase in electronic conductivity by Ni doping, which improve the capacitive behavior of α-MnO2. With specific capacitance values increasing with increasing amounts of Ni up to a certain limit 0.25 mmol, the specific capacitance of 325.8 F/g was given by MnO2-Ni electrode at a current density of 0.5 A/g, which was nearly 1.72 times that of MnO2 electrode of 189.47 F/g. Moreover, the MnO2-Ni electrode showed excellent capacitance retention (112%) than the MnO2 electrode (109.5%) after 3000 cycles.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 319-327"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In vivo self-assembly of an intact functional cage protein: Intracellular generation of chimeric ferritins without disassembly-involved damage 在体内自组装完整的功能笼蛋白：在细胞内生成嵌合铁蛋白而不会造成分解损伤

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.06.040

Koung Hee Kim , Mi-Ran Ki , Thi Khoa My Nguyen , Ki Ha Min , Seung Pil Pack

{"title":"In vivo self-assembly of an intact functional cage protein: Intracellular generation of chimeric ferritins without disassembly-involved damage","authors":"Koung Hee Kim , Mi-Ran Ki , Thi Khoa My Nguyen , Ki Ha Min , Seung Pil Pack","doi":"10.1016/j.jiec.2024.06.040","DOIUrl":"10.1016/j.jiec.2024.06.040","url":null,"abstract":"<div><div>Ferritin (Fn) is an attractive nano-biomaterial with a hollow structure. Functional chimeric cage-protein Fns (chimera-Fn) can be designed by combining two different monomer subunits. However, unavoidable damage is induced by the severe disassembly conditions required for preparing the Fn monomer. Here, a biocompatible method using a designed dual-expression vector to obtain chimera-Fns without a damage-inducing process is described. Fn monomer and silica-forming peptide (Kpt)-fused Fn monomer are expressed simultaneously and assembled within host-cells to form chimera-Fn of Kpt. Characteristic analysis showed that the chimera-Fns obtained intracellularly were composed of the two monomers in a ratio of 1:1. Morphological and functional analyses determined that the intracellularly-generated chimera-Fns had more intact forms and bioactive functions compared with those produced by chemical-involved disassembly and reassembly. This is the first report about the in vivo self-assembly of chimera-Fn with intact function and hold promise in designing functional templates for various nanomaterial preparations.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 67-71"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unveiling the swelling behavior of κ-carrageenan hydrogels: Influence of composition and physiological environment on drug delivery potential 揭示κ-卡拉胶水凝胶的溶胀行为：成分和生理环境对药物输送潜力的影响

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.06.032

Emad Mozaffari , Bahareh Tanhaei , Maryam Khajenoori , Saeedeh Movaghar Khoshkho

{"title":"Unveiling the swelling behavior of κ-carrageenan hydrogels: Influence of composition and physiological environment on drug delivery potential","authors":"Emad Mozaffari , Bahareh Tanhaei , Maryam Khajenoori , Saeedeh Movaghar Khoshkho","doi":"10.1016/j.jiec.2024.06.032","DOIUrl":"10.1016/j.jiec.2024.06.032","url":null,"abstract":"<div><div>This study aims to develop a biodegradable hydrogel wound dressing film based on carrageenan and agar loaded with tetracycline (TC), which exhibits high antibacterial properties and accelerates wound healing. The swelling behavior of κ-carrageenan/agar and tetracycline-loaded hydrogel films was examined, with a focus on the hydrogel’s efficacy in various physiological fluids, as well as the effects of polysaccharide ratio, cross-linker concentration, and surfactant concentration. The results revealed that the polysaccharide ratio significantly influenced the hydrogel swelling capacity of hydrogel, and a 1:1 ratio of agar to κ-carrageenan achieved the highest swelling degree of 1386 %. Addition of KCl, as a cross-linker, increased swelling capacity to 1713 %. Furthermore, surfactant concentration also influenced swelling behavior, and higher concentrations resulted in an increase in hydrophilicity and swelling. Hydrogel swelling performance varied across physiological fluids, with the highest and lowest swellings observed in deionized water (DIW) and simulated wound fluid (SWF), respectively. The swelling process in DIW and phosphate buffered saline (PBS) exhibited second-order kinetics, whereas non-Fickian diffusion mechanisms were observed in SWF. The drug release of the κC/AG/TC hydrogel film was controlled by its swelling capacity and the pH of medium. The hydrogels’ mechanical properties, antibacterial activity, and water vapor permeability were also investigated.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 217-227"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigating the catalytic performance of polyoxometalate immobilized on magnetic chitosan in the oxidative desulfurization process 研究固定在磁性壳聚糖上的聚氧化金属在氧化脱硫过程中的催化性能

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.07.009

Somayeh Gooneh-Farahani, Mansoor Anbia

引用次数: 0

Bi-doped g-C3N4/Bi2WO6 ternary composites for superior photocatalytic degradation of reactive orange 16 under visible light irradiation 双掺杂 g-C3N4/Bi2WO6 三元复合材料在可见光照射下对活性橙 16 的光催化降解效果更佳

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.07.007

Priti Rohilla , Bonamali Pal , Raj Kumar Das

{"title":"Bi-doped g-C3N4/Bi2WO6 ternary composites for superior photocatalytic degradation of reactive orange 16 under visible light irradiation","authors":"Priti Rohilla , Bonamali Pal , Raj Kumar Das","doi":"10.1016/j.jiec.2024.07.007","DOIUrl":"10.1016/j.jiec.2024.07.007","url":null,"abstract":"<div><div>Because of unrestricted disposal, the concentration of reactive dyes in wastewater is gradually increasing. Owing to their eco-toxicity their removal becomes so crucial. In this regard, Bi(0)-doped g-C3N4/Bi2WO6 (g-C3N4/Bi@Bi2WO6) nanocomposites were prepared by wet impregnation followed by calcination. Remarkably, the Bi(0) doping occurs concertedly during the preparation of Bi2WO6 without the addition of any extra reducing agent. The efficacy of the photocatalyst for eliminating reactive orange 16 was evaluated under visible light irradiation. XRD, FESEM, HRTEM, DRS, XPS, BET, etc., were employed to characterize these hybrids. The presence of Bi(0) was confirmed by HRTEM and XPS. Increasing the g-C3N4 content enhances the specific surface and reduces the charge transfer resistance. Among the various photocatalysts, the 20 wt% g-C3N4/Bi@Bi2WO6 hybrid owned the highest degradation efficiency of 89 % after 300 min of reaction time. The controlled experiments confirm the participation of holes and superoxide anions during the reactions. The various reaction intermediates were detected by HRMS providing the necessary evidence about the mechanism. The heterostructure possesses excellent reusability and stability. Due to enhanced catalytic activity, high stability, and ease of synthesis, the reported composite can be considered as a promising catalyst for the degradation of pollutants.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 456-467"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141696972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Numerical analysis of production of C2 olefins from methane in Partially Decoupled process 部分解耦工艺中甲烷生产 C2 烯烃的数值分析

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.07.002

Maliheh Saravani Ghayour, Seyed Reza Shabanian

{"title":"Numerical analysis of production of C2 olefins from methane in Partially Decoupled process","authors":"Maliheh Saravani Ghayour, Seyed Reza Shabanian","doi":"10.1016/j.jiec.2024.07.002","DOIUrl":"10.1016/j.jiec.2024.07.002","url":null,"abstract":"<div><div>Ethylene (C2H4) and acetylene (C2H2) are crucial materials in the petrochemical industry, obtained through various processes utilizing natural gas and other hydrocarbon fuels. In this research, the Partially Decoupled Process (PDP) has been investigated through Computational Fluid Dynamics (CFD) simulation to analyze the effects of different parameters on the production of acetylene and ethylene. The evaluated parameters included the mass flow rate ratio, fuel preheating temperature, the addition of ethane and propane to the fuel, the addition of H2, CO2, and H2O to the inlet feed and, reducing the jet inlet diameter. The results showed that an increase in the mass flow rate leads to an increase in the mole fraction of C2 (C2H2 + C2H4) in the reactor outlet. Furthermore, the substitution of 30 % methane with a combination of 20 % ethane and 10 % propane has resulted in a 6 % increase in the mole fraction of C2H2, a 43 % reduction in the mole fraction of C2H4, and a 5.6 % increase in the mole fraction of H2 at the outlet of the reactor. It was also observed that by decreasing the diameter of the side tubes from 43.3 mm to 20 mm, methane conversion decreases by 1.14 %, and C2 yield decreases by 46.8 %.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 394-410"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Basil seed hydrogel incorporated activated carbon as a Capable, Bio-Based, and Cost-Effective interfacial solar steam generator 含有活性炭的罗勒种子水凝胶是一种具有能力、生物基础和成本效益的界面太阳能蒸汽发生器

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.06.037

Mahtab Farahpour, Saeid Azizian

{"title":"Basil seed hydrogel incorporated activated carbon as a Capable, Bio-Based, and Cost-Effective interfacial solar steam generator","authors":"Mahtab Farahpour, Saeid Azizian","doi":"10.1016/j.jiec.2024.06.037","DOIUrl":"10.1016/j.jiec.2024.06.037","url":null,"abstract":"<div><div>Utilization of solar energy for desalination and purification of seawater opens up a state-of-the-art way to meet the water needs all around the world specially in coastal cities. Herein, the eco-friendly, low cost and bio-based basil seed (BS) hydrogel is combined with activated carbon (AC) to synthesize activated carbon merged with basil seed hydrogel (AC-BS) composite material. Due to the photothermal property of the AC, the AC-BS composite was used to design an interfacial solar steam generator (ISSG) for water purification. The AC absorbs the sunlight and converts it to the required heat needed for water evaporation and the superhydrophilic BS hydrogel supplies water to the surface causing the high salt rejection ability of the system, in addition, it decreases the required energy for evaporation. The AC-BS is characterized using characterization methods such as EDX and FESEM. The two-dimensional (2D) AC-BS system containing a cotton fiber used to transfer water from the bulk to the surface, a layer of styrofoam as a heat insulator and AC-BS on the surface shows evaporation rate of 1.93 kg m−2h−1. The three-dimensional (3D) AC-BS, designed to solve the solar irradiation angle fluctuation problem during a day and seasons, shows an evaporation rate of 2.70 kg m−2h−1 and an efficiency of about 91 % under 1 sun illumination. The ability of the AC-BS system for saline water desalination and waste water-contaminated dyes as a pollutant treatment is highly acceptable. The AC-BS ISSG can be studied and used on large scales to provide fresh water from saline water.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 285-296"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancement of tetracycline photocatalytic degradation under visible light: Unleashing the synergy of Z-scheme Ag3PO4/GCN/FeNi-BTC photocatalyst with carbon quantum dots 增强可见光下的四环素光催化降解：释放 Z 型 Ag3PO4/GCN/FeNi-BTC 光催化剂与碳量子点的协同作用

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2025-01-25 DOI: 10.1016/j.jiec.2024.07.001

Manh B. Nguyen , Huan V. Doan , Doan Le Hoang Tan , Tran Dai Lam

{"title":"Enhancement of tetracycline photocatalytic degradation under visible light: Unleashing the synergy of Z-scheme Ag3PO4/GCN/FeNi-BTC photocatalyst with carbon quantum dots","authors":"Manh B. Nguyen , Huan V. Doan , Doan Le Hoang Tan , Tran Dai Lam","doi":"10.1016/j.jiec.2024.07.001","DOIUrl":"10.1016/j.jiec.2024.07.001","url":null,"abstract":"<div><div>This study presents a novel photocatalytic composite, Ag3PO4/GCN/FeNi-BTC/CQD (AGF-CQD), synthesized via a green microwave-assisted hydrothermal method, integrating carbon quantum dots (CQDs) derived from aquaculture by-products. The AGF-CQD composite demonstrates superior photocatalytic activity, attributed to enhanced visible light absorption, efficient charge transfer, and improved electron-hole separation. Analytical techniques such as photoluminescence (PL), UV–Vis diffuse reflectance spectroscopy (DRS), and transmission electron microscopy (TEM) validate the composite’s structural and optical properties. In tetracycline degradation tests, AGF-CQD outperforms Ag3PO4, GCN, FeNi-BTC, and 20 % AGF samples by 5.5, 3.6, 4.4, and 2.3 times, respectively, achieving a remarkable 98.4 % removal rate after 60 min under visible light. Factors affecting degradation, including dosage, concentration, pH, and water source, are investigated. Furthermore, an operating mechanism based on electrochemical properties and the involvement of radicals is proposed. This research offers a sustainable approach to synthesizing efficient photocatalysts for environmental remediation.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 380-393"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0