{"title":"Degradation of levofloxacin by dielectric barrier discharge plasma/chlorine process: Roles of reactive species and control of chlorination disinfection byproducts.","authors":"Jing Lou, Hao Han, Jiutao An, Xiangyou Wang","doi":"10.1016/j.jenvman.2024.123727","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123727","url":null,"abstract":"<p><p>In this study, a novel process of dielectric barrier discharge (DBD)/chlorine for levofloxacin (LEV) degradation was investigated. The combined system boosted the degradation efficiency of LEV from 77.8% to 97.5%, improved the reaction rate constant by 2.3 times, and reduced energy consumption by 64.5%. DBD/chlorine process was highly efficient for LEV degradation across a pH range of 3.3-10.8, with removal rates varying from 90.3% to 97.5%. The electron paramagnetic resonance and scavenging experiments demonstrated the generation of reactive oxygen species (ROS, including HO•, <sup>1</sup>O<sub>2</sub>, and O<sub>2</sub><sup>•-</sup>) and reactive chlorine species (RCS) in the DBD/chlorine system, with <sup>1</sup>O<sub>2</sub> in the nonradical pathway being crucial for LEV removal. Crucially, effective activation of chlorine not only encouraged the production of reactive species but also prevented the formation of disinfection by-products (DBPs), successfully controlling the ecotoxicity of the reaction system. DBD could activate chlorine to form chlorate and HO•, which in turn triggered the production of RCS. The comparison of the LEV degradation pathway was proposed with or without chlorine in the DBD process. Finally, the effects of different water quality and water bodies demonstrated the application prospects of the DBD/chlorine process. This work provided an efficient technique for the elimination of antibiotics by non-thermal plasma/chlorine.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123727"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigations on the saline groundwater pumping method and its impact on active saltwater intrusion on a layered aquifer system.","authors":"Dhanya Narayanan, T I Eldho","doi":"10.1016/j.jenvman.2024.123747","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123747","url":null,"abstract":"<p><p>Active saltwater intrusion (ASWI) accelerates and intensifies salinization due to buoyancy force-induced density differences and concurrent inland fresh groundwater flow. This study investigates saline groundwater (SGW) pumping as a remediation technique for ASWI through experimental and field-scale analyses in a layered aquifer system characterised by diminishing permeability with depth. Experiments demonstrated that higher permeability layers reduced length of intrusion (Ltoe) whereas lower permeability layers restricted vertical displacement. The SGW pumping would be effective for gentler gradient and could be achieved by positioning the SGW wells at a distance of approximately one-third distance between the freshwater well and the coastal boundary. This hypothesis was tested by applying it to a layered case study with real aquifer settings with comparable conductivity anisotropy. Field study results confirmed the hypothesis, but cumulative impact of pumping rates and SGW well positioning showed smaller wedge penetration than experimentation due to higher field scale dispersion, resulting in optimal location within one-fourth of the distance. Diverging saddle points explain this phenomenon, which is necessary to provide a pulling force greater than freshwater abstraction. In contrast, an aquifer with passive saltwater intrusion location of wells should be near the shoreline to direct the hydraulic gradient towards the seawater boundary. Simulation results suggested that SGW pumping rates should be three to four times freshwater pumping rates to maximise Ltoe reduction. The findings from this study will aid in determining the optimal locations for placing subsurface intake wells for desalination operations in an aquifer that is impacted by ASWI.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123747"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jianan Du, Weiwei Ma, Guang Li, Jianghua Wu, Wenhua Chang
{"title":"Vegetation degradation and its progressive impact on soil nitrogen mineralization in the Qinghai-Tibet Plateau's alpine wetlands: Insights from a three-year study.","authors":"Jianan Du, Weiwei Ma, Guang Li, Jianghua Wu, Wenhua Chang","doi":"10.1016/j.jenvman.2024.123668","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123668","url":null,"abstract":"<p><p>The soil nitrogen (N) cycle in the alpine wetland of the Qinghai-Tibet Plateau (QTP) has been strongly affected by vegetation degradation caused by climate change and human activities, subsequently impacting ecosystem functions. However, previous studies have rarely addressed how varying degrees of vegetation degradation affect soil net nitrogen mineralization rates and their temporal dynamics in these sensitive ecosystems. Therefore, we conducted a three-year field-based soil core in situ incubation mineralization experiment on the northeastern margin of the Tibetan Plateau from 2019 to 2021 to assess the variations in soil net ammonification, nitrification, and mineralization rates during the growing season (June to October). The main aim was to determine the dynamic effects of different degrees of vegetation degradation (non-degraded, lightly degraded, moderately degraded, and severely degraded) on soil net nitrogen transformation processes, as well as the impact of seasonal fluctuations in soil temperature and moisture on net nitrogen mineralization. Results indicated that vegetation degradation significantly reduced the net ammonification rate by 22.09%-97.10%, significantly increased the net nitrification rate by 45.38%, and significantly decreased the net mineralization rate by 9.49%-16.25%. Redundancy analysis (RDA) and random forest models revealed the supportive role of soil water content in the soil nitrogen transformation processes, particularly in promoting nitrification, while soil temperature was identified as a positive regulator of N cycling enzyme activity, indirectly affecting net nitrogen mineralization rates.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123668"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A multi-objective optimization approach for interprovincial carbon emission reduction in China: Considering industrial structure and ownership attributes.","authors":"Xiaoguang Zhou, Jiaxi Ji","doi":"10.1016/j.jenvman.2024.123646","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123646","url":null,"abstract":"<p><p>Balancing economic growth with carbon emission control requires the coordination of policy preferences for economic and carbon reduction goals, as well as the low-carbon transformation of industrial and ownership structures. This study employs a multi-objective input-output optimization model to investigate the trade-offs among maximizing GDP growth, minimizing carbon emissions, and minimizing energy consumption within the planning period of 2017-2035 in China. The model accounts for the heterogeneity of industrial structures and ownership attributes, examining both national aggregates and the adjustment paths and ownership trends across different provinces. The findings reveal: (1) Sectors with high output and low energy consumption are growing, while high pollution and high energy-consuming sectors are declining, driven primarily by technological levels, followed by policy and development preferences. (2) Domestic capital expanding into high technology and capital-intensive sectors, HMT capital favoring the economically developed high technology regions, and foreign investment declining. (3) Regional adjustment in high-value or high-energy-consumption sectors are more pronounced in central and western provinces and less economically developed regions, while industries that are neither high-energy-consumption nor high-value show greater increases in resource-rich provinces with better infrastructure.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123646"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Efficient and low resistance multi-functional UV resistant polyphenylene sulfide non-woven hollow membrane.","authors":"Mengen Zhang, Qiyang Xi, Linlin Wang, Qinxing Xie, Zhenhuan Li, Maliang Zhang","doi":"10.1016/j.jenvman.2024.123717","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123717","url":null,"abstract":"<p><p>The heat and corrosion resistance of traditional membranes is inadequate, thus making them inadequate for the separation/filtration needs of harsh environments. Polyphenylene sulfide(PPS) can be used to develop new-generation membrane materials, but PPS has problems such as hydrophobicity and UV resistance. This article proposes a PPS membrane for efficient separation/filtration under extreme conditions, which uses melt-blown PPS non-woven fabric and undergoes oxidation and nitrification modification. Combining the advantages of metal-organic framework material (ZIF-67), a hollow ZIF-67/PPS non-woven fabric membrane has been successfully prepared, solving PPS's hydrophobic and UV-resistant problems. It is ideal for wastewater treatment and air filtration in harsh environments yet retains hydrophilicity even in intense alkaline and high-temperature conditions. The hollow ZIF-67/PPS membrane exhibits a very high pure water flux (34,261 L m<sup>-2</sup> h<sup>-1</sup>). Surprisingly, the ZIF-67/PPS membrane exhibits strong chemical/thermal performance, maintaining good separation/filtration performance even after multiple cyclic tests in extreme conditions. The ZIF-67/PPS membrane with large-scale production capacity has reasonable prospects of dealing with environmental problems under extreme conditions.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123717"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuan Zou, Wei Chen, Siliang Li, Tiejun Wang, Le Yu, Xiao Zhang, Min Xu, Bohan Jiang, Chunying Wu, Ramesh P Singh, Alfredo Huete, Cong-Qiang Liu
{"title":"Assessing vegetation dynamics and human impacts in natural and urban areas of China: Insights from remote sensing data.","authors":"Yuan Zou, Wei Chen, Siliang Li, Tiejun Wang, Le Yu, Xiao Zhang, Min Xu, Bohan Jiang, Chunying Wu, Ramesh P Singh, Alfredo Huete, Cong-Qiang Liu","doi":"10.1016/j.jenvman.2024.123632","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123632","url":null,"abstract":"<p><p>Vegetation changes and human activities in both natural and urban environments have played a crucial role in carbon cycling and sustainable development globally. However, there is an insufficient comparison in national vegetation changes across regions with varying intensities of human activities to those natural areas. Based on urban boundary and night-time light datasets, we have identified and extracted rural, urban-low activity, and urban-high activity areas within China. Geodetector model was applied and conducted to assess the vegetation impacts of seven distinct natural and human factors on vegetation. Results show that overall vegetation change trend was characterized by Significant greening from 2000 to 2020. Areas with less than 1% Significant degradation are predominantly located in the southeastern China. Despite the dominance of forest growth, cropland in urban areas exhibits more stability under human control. Human involvement has significant restraint on vegetation growth from rural to urban, while there was little difference in vegetation growth between areas with strong human activity and areas with weak human activity. Moreover, human factors and land use/land cover have gradually become the dominant impact combinations in the eastern China over the past 20 years. The influence of temperature is increasing annually in southern China but decreasing in northern China. Meanwhile, factors related to water (e. g. precipitation and soil moisture) had more pronounced influences on western China. Our results provide a comprehensive insight in vegetation dynamic change in areas under different degrees of human activities, as well as the alterations in main driving factors on spatial heterogeneity of vegetation.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123632"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845450","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Global distribution pattern and conservation of the cosmopolitan cold-water coral species Desmophyllum dianthus under climate change.","authors":"Wenhao Huang, Zongling Wang, Fangyuan Qu, Chang Zhao, Miaozhuang Zheng, Zhaohui Zhang, Shenghao Liu, Qinzeng Xu, Xuelei Zhang, Linlin Zhao","doi":"10.1016/j.jenvman.2024.123674","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123674","url":null,"abstract":"<p><p>Global climate change impacts marine ecosystems differently across oceanic regions and depths. Thus, understanding how widespread key species adapt globally and locally to multidimensional climate change is crucial for targeted conservation. This study focuses on the cosmopolitan cold-water coral (CWC) Desmophyllum dianthus using ecological niche models (ENMs) to explore climate adaptation and conservation strategies. The findings indicated that D. dianthus occupied a broad ecological niche but had low ecological niche overlap across populations, suggesting local adaptations and supporting population-level ENMs. The models predicted that over 80% of D. dianthus suitable habitats would persist under SSP1-2.6 and SSP5-8.5 climate scenarios by the 2100s, potentially increasing to 95% as new habitats emerge, demonstrating its robust adaptability. However, localized environmental shifts could precipitate habitat losses in areas like the Reykjanes Ridge, Rockall Plateau, Mediterranean Sea, and Patagonian Shelf. We also applied Linkage Mapper to identify potential ecological corridors that intertwined nearshore macrohabitat patches with deep-sea stepping-stone habitats such as escarpments, seamounts, and ridges, maintaining population connectivity. Despite this, the habitats and ecological corridors of D. dianthus remained largely unprotected, with vulnerable portions lying outside of marine protected areas (MPAs), thus underscoring the urgent need for more MPA. These spatial-temporal predictions provide essential insights for the conservation and management of cosmopolitan CWC D. dianthus and serve as a benchmark for the adaptive survival of similar taxa.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123674"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Deciphering the mechanism of microbial metabolic function shift and dissolved organic matter variation in acidogenic fermentation of waste activated sludge induced by antiviral drugs.","authors":"Ruming Wang, Zhuoqin Wang, Chunxing Li, Jiamiao Chen, Nanwen Zhu","doi":"10.1016/j.jenvman.2024.123711","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123711","url":null,"abstract":"<p><p>Antiviral drugs (ATVs), as emerging contaminants enriched in wastewater activated sludge (WAS) in wastewater treatment plants, affect subsequent treatment. ATVs have been shown to have negative influences on anaerobic digestion of WAS, but it is unclear how ATVs affect functional microbial metabolic activity and changes in intermediates. Thus, the effect of the anti-HIV drug ritonavir (RIT) on the period of anaerobic fermentation (AF) and the response of microbial community structure were examined in this study. Results indicated that the production of total volatile fatty acids (VFAs) decreased from 2010.21 mg/L to 372.03 mg/L under 125-1000 μg RIT/kg TSS treatment. Characterization of organic matters revealed that dissolved organic matter in the high-dose RIT groups was less biodegradable, with lower protein content and higher humus content. Mechanistic analyses indicated that RIT exposure reduced the abundance of hydrolyzers and inhibited carbohydrate metabolism, resulting in an increased humification index in the RIT groups. In addition, the expression of genes associated with the synthesis of VFAs was also significantly reduced in the RIT groups, leading to a decrease in both the amount and type of VFAs. This study provides a novel perspective on the effects of emerging contaminants on WAS treatment processes and pollution prevention.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123711"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synergistic and efficient photocatalytic degradation of rhodamine B and tetracycline in wastewater based on novel S-scheme heterojunction phosphotungstic Acid@MIL-101(Cr).","authors":"Keren Shi, Xiaoyu Li, Zhiqiang Tian, Yuren Luo, Runmei Ding, Yanshu Zhu, Huiqin Yao","doi":"10.1016/j.jenvman.2024.123716","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123716","url":null,"abstract":"<p><p>To efficiently treat rhodamine B (RhB) and tetracycline (TC) in wastewater, MIL-101(Cr) was prepared by hydrothermal method and encapsulated with phosphotungstic acid (H<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>, abbreviated as PTA) to form an S-scheme heterojunction PTA@MIL-101(Cr)-x (P@M-x, x = 50, 100, 150, 200). The experimental results showed that after 180 min under visible light at pH 7, the degradation rates of RhB and TC were 97.81% and 99.9%, respectively. Meanwhile, the cycling experiments have showed that the P@M-100 S-scheme heterojunction exhibits good stability. Density Functional Theory (DFT) calculations theoretically verified the experimental results and elucidated the electrons migrate to MIL-101(Cr) and hole enrichment on the PTA surface. It was also revealed that the P@M-x photocatalyst belongs to the S-scheme heterojunction. Moreover, •O<sub>2</sub><sup>-</sup> and h<sup>+</sup> had been identified as the main active constituents during the photocatalytic degradation process. The synergistic effect of MIL-101(Cr) and PTA enhances the visible light absorption of P@M-x S-scheme heterojunction, resulting in more efficient electron transfer ability and faster photoreaction rate, thereby improved its photocatalytic performance. This study provides a potential solution for addressing aromatic pollutants in water.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123716"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Olivier Joseph Abban, Gulasekaran Rajaguru, Alex O Acheampong
{"title":"The spillover effect of economic institutions on the environment: A global evidence from spatial econometric analysis.","authors":"Olivier Joseph Abban, Gulasekaran Rajaguru, Alex O Acheampong","doi":"10.1016/j.jenvman.2024.123645","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.123645","url":null,"abstract":"<p><p>This study examines the impact of economic institutions on ecological footprint and their spatial spillover effects globally, covering the period from 2000 to 2021. We focus on economic institutions because institutions that espouse economic freedom are essential for safeguarding environmental quality. We hypothesize that the spatial influence of these institutions varies both globally and regionally. The Moran's I test reveals significant spatial associations among countries, while the Wald and likelihood tests identify the spatial Durbin model as the most appropriate approach. Furthermore, the Hausman test indicates that a fixed effects model best captures the coefficients. Globally, economic institutions demonstrate a direct reduction effect of 16.4% and a spillover reduction effect of 4.4% on ecological footprint. However, these effects show considerable regional variation. In North America, East Asia and the Pacific, the Middle East, North Africa, Europe, and Central Asia, economic institutions effectively reduce ecological footprint, while their impact is negligible in other regions. These regional differences underscore the importance of addressing institutional deficiencies, encouraging policymakers in regions with limited effects to learn from best practices to enhance institutional effectiveness. These insights collectively advance the literature on economic institutions and environmental economics, emphasizing regional policy adaptation and the transboundary effects of institutional quality. The findings further reveal that economic institutions moderate GDP per capita to curb ecological footprint significantly. These conclusions hold even after addressing endogeneity using the generalized spatial two-stage least squares method. The study recommends that policies promoting economic freedom are essential to mitigate global environmental degradation.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"373 ","pages":"123645"},"PeriodicalIF":8.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142845476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}