Open Ceramics最新文献

High-resolution tomographic analysis of microstructure and porosity in mock-ups of ancient-inspired mosaics 古代镶嵌画模型中微观结构和孔隙度的高分辨率层析分析

IF 2.8

Open Ceramics Pub Date : 2025-09-30 DOI: 10.1016/j.oceram.2025.100859

Neva M.E. Stucchi , Gianluca Iori , Philipp Hans , Andrea Vavasori , Giulia Franceschin , Arianna Traviglia

{"title":"High-resolution tomographic analysis of microstructure and porosity in mock-ups of ancient-inspired mosaics","authors":"Neva M.E. Stucchi , Gianluca Iori , Philipp Hans , Andrea Vavasori , Giulia Franceschin , Arianna Traviglia","doi":"10.1016/j.oceram.2025.100859","DOIUrl":"10.1016/j.oceram.2025.100859","url":null,"abstract":"<div><div>This research investigates the use of Synchrotron X-ray Computed Tomography (SXCT) to study Roman mosaic mock-ups, focusing on the three-dimensional distribution of material density, cracks, and stress-strain interactions across layers. Three samples were analysed: one of stone <em>tesserae</em> and two of glass <em>tesserae</em>. High-resolution SXCT scans, using polychromatic radiation at X-ray energies above 70 keV, enabled non-invasive, microscale examination of cracks and assessment of how composition influences crack development at interfaces. Digital reconstruction and phase contrast analysis distinguished cracks from pores, revealing microstructural features and enabling quantification of pore volumes and porosity variations within <em>strata</em>. The results showed that stone <em>tesserae</em> induced more extensive cracking in the <em>Supra Nucleus stratum</em> than glass <em>tesserae</em>. These findings enhance understanding of internal microstructure and stress behaviour in mosaics, providing a basis for developing appropriate conservation strategies. Quantifying fracture dimensions enables conservators to determine the optimal viscosity and formulation of consolidants for effective penetration and stabilization, while insights on compaction and tesserae surface quality inform the design of re-adhesion and cleaning protocols that enhance cohesion and minimize future detachment. Together, these results show how microscale analysis can guide material selection and treatment strategies, ultimately supporting more durable repairs and the long-term preservation of mosaics.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100859"},"PeriodicalIF":2.8,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145221341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Incorporation of Zn/Sr-Ga based LDH particles into Si-HAp coatings to control the corrosion of Nitinol alloys 在Si-HAp涂层中加入Zn/Sr-Ga基LDH颗粒控制镍钛诺合金的腐蚀

IF 2.8

Open Ceramics Pub Date : 2025-09-24 DOI: 10.1016/j.oceram.2025.100852

Reza Samiee , Alicia Duran , Yolanda Castro , Dusan Galusek , A.R. Boccaccini , Amirhossein Pakseresht

{"title":"Incorporation of Zn/Sr-Ga based LDH particles into Si-HAp coatings to control the corrosion of Nitinol alloys","authors":"Reza Samiee , Alicia Duran , Yolanda Castro , Dusan Galusek , A.R. Boccaccini , Amirhossein Pakseresht","doi":"10.1016/j.oceram.2025.100852","DOIUrl":"10.1016/j.oceram.2025.100852","url":null,"abstract":"<div><div>Metallic implants, especially Nitinol, have numerous biomedical applications; however, they have inherent drawbacks, such as poor corrosion and wear resistance and suffer from nickel ion leaching. To address these challenges, this paper explores the use of silicon-substituted hydroxyapatite (Si-HAp) coatings with incorporated Zn/Sr-Ga based Layered Double Hydroxide (LDH) particles deposited by electrophoretic deposition (EPD). The synthesized Zn/Sr-Ga based LDH particles were investigated as both passive and active fillers in Si-HAp coatings. An anodization pre-treatment of the Nitinol substrates was performed to improve adhesion between the substrate and the coating. The EPD parameters were also optimized to prepare homogeneous and stable Si-HAp coatings loaded with Zn/Sr-Ga LDH particles. The morphology, composition, and electrochemical properties of the Si-HAp composite coatings were characterized using different techniques. Electrochemical impedance spectroscopy (EIS) and polarization studies demonstrated a significant improvement of the corrosion resistance properties of Si-HAp coatings with Zn/Sr-Ga LDH particles, compared to pure Si-HAp coatings and Nitinol substrate. The LDH@Si-HAp-coated sample showed the lowest nickel release, indicating the potential of LDH to reduce toxicity and enhance the strength of Nitinol implants.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100852"},"PeriodicalIF":2.8,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145158914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

CaO/SiC(O) nanocomposites for CO2 capture at higher temperatures: Synthesis, characterization, and initial performance studies 用于高温CO2捕获的CaO/SiC(O)纳米复合材料：合成、表征和初始性能研究

IF 2.8

Open Ceramics Pub Date : 2025-09-18 DOI: 10.1016/j.oceram.2025.100851

Sarabjeet Kaur , Kurosch Rezwan , Michaela Wilhelm

{"title":"CaO/SiC(O) nanocomposites for CO2 capture at higher temperatures: Synthesis, characterization, and initial performance studies","authors":"Sarabjeet Kaur , Kurosch Rezwan , Michaela Wilhelm","doi":"10.1016/j.oceram.2025.100851","DOIUrl":"10.1016/j.oceram.2025.100851","url":null,"abstract":"<div><div>This study presents the synthesis and characterization of CaO/SiC(O) nanocomposites via chemical modification of allylhydridopolycarbosilane (SMP) using two calcium precursors: calcium acetylacetonate (CaAcac) and calcium hydroxide (CaOH). ATR-FTIR analysis showed that CaAcac chemically interacts with SMP, promoting hydrosilylation and extensive cross-linking, while CaOH showed no interaction. Thermogravimetric analysis revealed higher than expected ceramic yields for CaAcac-modified SMP samples, whereas CaOH-modified SMP samples matched theoretical values. XRD and TEM results showed that CaAcac leads to mostly amorphous ceramics, while CaOH facilitated CaO crystallization at 600 °C. The nanocomposites captured 2–5 wt% CO<sub>2</sub> at 500 °C, which is comparable to the uptake of pure CaO derived from CaCO<sub>3</sub> due to their low CaO content (11–15 %). However, only the amorphous CaAcac modified nanocomposite can release the absorbed CO<sub>2</sub> at 500 °C in larger amounts of 66 wt%. CaAcac-modified SMP nanocomposites thus show a higher potential for CO<sub>2</sub> capture and release applications at moderate temperatures of 500 °C compared to CaOH-modified nanocomposites.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100851"},"PeriodicalIF":2.8,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145221361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rheological characterization of clay–refractory waste composites for direct ink writing of ceramic structures 陶瓷结构直接油墨书写用粘土-耐火废料复合材料的流变学表征

IF 2.8

Open Ceramics Pub Date : 2025-09-14 DOI: 10.1016/j.oceram.2025.100850

Jiří Rozbroj , David Žurovec , Jakub Hlosta , Michaela Topinková , Hana Ovčačíková , Jan Diviš , Kamila Pokorná , Jan Nečas , Jiří Zegzulka

{"title":"Rheological characterization of clay–refractory waste composites for direct ink writing of ceramic structures","authors":"Jiří Rozbroj , David Žurovec , Jakub Hlosta , Michaela Topinková , Hana Ovčačíková , Jan Diviš , Kamila Pokorná , Jan Nečas , Jiří Zegzulka","doi":"10.1016/j.oceram.2025.100850","DOIUrl":"10.1016/j.oceram.2025.100850","url":null,"abstract":"<div><div>In the context of the circular economy and raw material sustainability, it is essential to explore alternative raw materials for the development of formulations with optimized physical and mechanical properties. This study focused on the rheological characterization of refractory ceramic waste blended with clay, aiming to optimize compositions for 3D printing. A mixture exhibiting the highest strength and resistance to shear stress was identified, making it a promising candidate for use in complex structural components. Mixtures with lower strength proved suitable for less demanding applications with simpler geometries. The presence of finer particles and lower bulk density of the filler led to increased viscosity and critical shear stress, contributing to higher mechanical stability. In contrast, mixtures with higher bulk density exhibited lower viscosity and reduced resistance to mechanical loading, despite demonstrating higher elasticity within the linear viscoelastic region. These findings represent a significant contribution to the effective selection and design of refractory ceramic formulations for additive manufacturing, tailored to the specific functional requirements of targeted applications. The research also demonstrated the feasibility of using waste-derived materials as feedstock for Direct Ink Writing (DIW) 3D printing of refractory ceramics, supporting both material circularity and sustainable manufacturing practices.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100850"},"PeriodicalIF":2.8,"publicationDate":"2025-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145097524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of crystalline Si3N4 fillers on the mechanical strength and thermal stability of complex SiCN(O) ceramic architectures produced by powder bed fusion and densified via polymer infiltration and pyrolysis 结晶Si3N4填料对粉末床熔合、聚合物渗透和热解致密复合SiCN(O)陶瓷结构机械强度和热稳定性的影响

IF 2.8

Open Ceramics Pub Date : 2025-09-13 DOI: 10.1016/j.oceram.2025.100846

Marco Pelanconi , Samuele Bottacin , Mario Caccia , Alberto Ortona , Yawei Li

{"title":"Effect of crystalline Si3N4 fillers on the mechanical strength and thermal stability of complex SiCN(O) ceramic architectures produced by powder bed fusion and densified via polymer infiltration and pyrolysis","authors":"Marco Pelanconi , Samuele Bottacin , Mario Caccia , Alberto Ortona , Yawei Li","doi":"10.1016/j.oceram.2025.100846","DOIUrl":"10.1016/j.oceram.2025.100846","url":null,"abstract":"<div><div>Silicon nitride is a high-performance ceramic recognized for its mechanical, thermal, and chemical stability at elevated temperatures. In this study, we present a novel method to fabricate macroporous Si₃N₄ ceramics via powder bed fusion of polyamide mixed with 0-40 vol% of crystalline Si₃N₄ powder. The printed preforms were subsequently infiltrated with a polysilazane polymer and pyrolyzed to form SiCN(O) matrices containing β-Si₃N₄ particles. A rotated cube lattice was selected as a benchmark geometry and scaled to compensate for shrinkage. The effects of ceramic filler content on densification, microstructure, strength, and oxidation resistance at 1500 °C were investigated. Increasing β-Si₃N₄ content improved the relative density, compressive strength, and thermal stability of the final ceramics. Particularly, 20–40 vol% Si₃N₄ enhanced oxidation resistance by forming a protective silica-rich surface layer and stabilizing the underlying structure. This study highlights an effective strategy to tailor the high-temperature behaviour of polymer-derived ceramics for advanced structural applications.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100846"},"PeriodicalIF":2.8,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145158913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microstructure and adsorption studies on the simultaneous removal of Cu2+, Ni2+, and Zn2+ from simulated wastewater using magnetically functionalized Philippine natural zeolite composite 磁性功能化菲律宾天然沸石复合材料同时去除模拟废水中Cu2+、Ni2+和Zn2+的微观结构和吸附研究

IF 2.8

Open Ceramics Pub Date : 2025-09-09 DOI: 10.1016/j.oceram.2025.100845

Belinda B. Faustino , Reynaldo M. Vequizo , Rolando T. Candidato Jr.

{"title":"Microstructure and adsorption studies on the simultaneous removal of Cu2+, Ni2+, and Zn2+ from simulated wastewater using magnetically functionalized Philippine natural zeolite composite","authors":"Belinda B. Faustino , Reynaldo M. Vequizo , Rolando T. Candidato Jr.","doi":"10.1016/j.oceram.2025.100845","DOIUrl":"10.1016/j.oceram.2025.100845","url":null,"abstract":"<div><div>This study reports the microstructural characteristics and adsorption properties for heavy metal ions of the surface-modified Philippine natural zeolite (MPNZ) and magnetically functionalized Philippine natural zeolite (PNZM) composite. SEM analysis confirmed the presence of magnetite particles dispersed on PNZM, making its surface rougher and irregular while retaining its porous structure. X-ray diffractogram revealed distinct peaks corresponding to the spinel crystalline structure of magnetite and the aluminosilicate structure of the zeolite framework, suggesting a well-integrated composite material. BET analysis showed an increase in the surface area of MPNZ from 33.876 m<sup>2</sup>/g to 45.052 m<sup>2</sup>/g after adding magnetite. EDS characterization verified the strong presence of Fe<sup>+</sup> ions in the PNZM structure, enhancing its cation-exchange capacity (CEC). The Si/Al ratio of MPNZ decreased from 3.75 to 3.37, indicating a more negative charge, supported by zeta potential results that showed surface charges of (-)12.200 for MPNZ to (-) 20.854 mV for PNZM. In single ion solutions, PNZM obtained a removal uptake of 98.85 %, 99.99 % and 99.48 % for Ni<sup>2+</sup>, Cu<sup>2+</sup>and Zn<sup>2+</sup> respectively, which are higher than MPNZ. In mixed-ion solutions, PNZM also showed improved adsorption with removal rates of 91.17 % for Ni<sup>2+</sup> and 97.90 % for Cu<sup>2+</sup>, although Zn<sup>2+</sup> uptake decreased to 97.98 % compared to the 99.99 % of MPNZ. Overall, incorporating magnetite has functionalized the ability of PNZM for sustainable water treatment by removing heavy metal ions through the synergistic mechanism of ion-exchange and Coulombic electrostatic interactions.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100845"},"PeriodicalIF":2.8,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145061266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The study of natural dolomite as a prospective material for CO2 capture employing a novel approach to the evaluation of breakthrough curves 采用一种新的方法来评估突破曲线，研究天然白云岩作为二氧化碳捕获的有前景的材料

IF 2.8

Open Ceramics Pub Date : 2025-09-09 DOI: 10.1016/j.oceram.2025.100844

Anna Imrichová , Patrik Sokola , Jiří Másilko , Marek Baláš , Vladislav Cába , Kateřina Karásková , Jiří Švec , Petr Ptáček

{"title":"The study of natural dolomite as a prospective material for CO2 capture employing a novel approach to the evaluation of breakthrough curves","authors":"Anna Imrichová , Patrik Sokola , Jiří Másilko , Marek Baláš , Vladislav Cába , Kateřina Karásková , Jiří Švec , Petr Ptáček","doi":"10.1016/j.oceram.2025.100844","DOIUrl":"10.1016/j.oceram.2025.100844","url":null,"abstract":"<div><div>The capture of carbon dioxide (CO<sub>2</sub>) is a critical technology for addressing climate change and sustainability objectives. In this study, the performance of natural dolomite as an effective sorbent for repeated CO<sub>2</sub> capture was evaluated. The results suggested that an optimal calcination temperature of 850 °C was beneficial for minimizing surface sintering of the dolomite, thereby facilitating effective decarbonation. Breakthrough curve analysis was conducted to evaluate the dynamic adsorption performance of dolomite at varying CO<sub>2</sub> concentrations (10 %, 12 %, and 16 %). To assess the progress of gas adsorption onto regenerated dolomite, an innovative method of curve fitting using the modified Avrami equation was employed, which provided three essential parameters for the adsorption process: retention time, rate constant, and Avrami coefficient. A steady decrease in breakthrough time and adsorption efficiency was found to be correlated with sintering and surface area loss. The maximum CO<sub>2</sub> adsorption capacity was achieved during the second or third cycle for all three measured CO<sub>2</sub> concentrations; however, performance gradually deteriorated in subsequent cycles due to surface sintering and a reduction in specific surface area. TPD and BET analyses supported the conclusion that the surface area decreased with repeated regeneration, and the basic active sites were reduced.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100844"},"PeriodicalIF":2.8,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145047584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and characterization of LLZNO & LLZTO: Insights into the impact of different lithium precursors on properties LLZNO和LLZTO的合成与表征：不同锂前驱体对性能的影响

IF 2.8

Open Ceramics Pub Date : 2025-09-03 DOI: 10.1016/j.oceram.2025.100842

Chengjian Li , Frank Kern , Lianmeng Liu , Christopher Parr , Andreas Börger , Chunfeng Liu

{"title":"Synthesis and characterization of LLZNO & LLZTO: Insights into the impact of different lithium precursors on properties","authors":"Chengjian Li , Frank Kern , Lianmeng Liu , Christopher Parr , Andreas Börger , Chunfeng Liu","doi":"10.1016/j.oceram.2025.100842","DOIUrl":"10.1016/j.oceram.2025.100842","url":null,"abstract":"<div><div>Garnet-type Li₇La₃Zr₂O₁₂ (LLZO) is a promising solid electrolyte for all-solid-state batteries due to its high ionic conductivity and excellent thermal stability. However, production of high performance LLZO remains constrained by the reliance on high-purity reagents and complex synthesis routes. This study presents a cost-effective strategy to prepare high-performance Ta- and Nb-doped LLZO using commercially sourced raw materials via conventional solid-state reaction. Two lithium precursors, Li<sub>2</sub>CO<sub>3</sub> and LiOH·H₂O, were systematically compared to evaluate their impacts on formation and performances of LLZO. LiOH-derived powders showed higher phase purity and finer morphology, while Li<sub>2</sub>CO<sub>3</sub>-derived powders offered better processability. While the LLZNO-LOH sample achieved 94.4% relative density and 0.78 × 10⁻<sup>3</sup> S/cm conductivity, LLZTO-LCO also reached 0.75 × 10⁻<sup>3</sup> S/cm with a relative density of 94.1%. All sintered samples exhibited phase-pure cubic garnet structures. These findings demonstrate the industrial feasibility of LLZO production, paving the way for its practical deployment in next-generation solid-state batteries.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"24 ","pages":"Article 100842"},"PeriodicalIF":2.8,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145047583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Temperature effects of defect formation in BeO ceramics during helium blistering 氦泡胀过程中BeO陶瓷缺陷形成的温度效应

IF 2.8

Open Ceramics Pub Date : 2025-09-01 DOI: 10.1016/j.oceram.2025.100843

Azamat E. Ryskulov , Artem L. Kozlovskiy , Igor A. Ivanov , Inesh E. Kenzhina , Marina Konuhova

{"title":"Temperature effects of defect formation in BeO ceramics during helium blistering","authors":"Azamat E. Ryskulov , Artem L. Kozlovskiy , Igor A. Ivanov , Inesh E. Kenzhina , Marina Konuhova","doi":"10.1016/j.oceram.2025.100843","DOIUrl":"10.1016/j.oceram.2025.100843","url":null,"abstract":"<div><div>The work is devoted to the study of the processes of defect accumulation in the near-surface layer of BeO ceramics associated with irradiation with low-energy He<sup>2+</sup> ions, as well as to the establishment of the role of temperature effects on changes in thermal conductivity. Identification of the role of temperature effects in acceleration of the processes of distortion and disordering of the near-surface layers is one of the key tasks, the solution of which will allow more accurate prediction of the behavior of materials under extreme conditions combining the effects of high temperatures and radiation damage. During assessment of changes in structural parameters depending on variations in irradiation conditions, anisotropic distortion of the crystal lattice, the degree of deformation of which has a direct relationship with the temperature effect, was established. It has been determined that an increase in the irradiation temperature leads to an acceleration of the processes of accumulation of deformation distortions, the growth of which in the damaged layer leads to a more pronounced destabilization and broadening of the damaged layer depth. Such changes are associated with the acceleration of the diffusion processes of point and vacancy defects, the migration of which leads not only to an increase in deformation distortions and amorphous inclusions, but also to an increase in the damaged layer thickness. During determination of changes in the concentration of vacancy and structural defects in the damaged layer, relationships between the concentration of oxygen vacancies and the degradation of thermal conductivity, the reduction of which is due to an increase in the effects of phonon scattering and a decrease in the rate of heat transfer, were established.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"23 ","pages":"Article 100843"},"PeriodicalIF":2.8,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145010397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Determination of the prospects for the use of multicomponent composite ceramics as thermal barrier protective coatings 多组分复合陶瓷热障防护涂层应用前景的确定

IF 2.8

Open Ceramics Pub Date : 2025-09-01 DOI: 10.1016/j.oceram.2025.100838

Ye.A. Kenzhin , D.I. Shlimas , A.M. Zikirina , A.L. Kozlovskiy

{"title":"Determination of the prospects for the use of multicomponent composite ceramics as thermal barrier protective coatings","authors":"Ye.A. Kenzhin , D.I. Shlimas , A.M. Zikirina , A.L. Kozlovskiy","doi":"10.1016/j.oceram.2025.100838","DOIUrl":"10.1016/j.oceram.2025.100838","url":null,"abstract":"<div><div>The paper presents the results of experiments aimed at identification of the influence of variations in thermal sintering conditions on the phase transformation processes in multicomponent ceramics based on oxide compounds of cerium, tellurium, bismuth, tungsten and zinc. According to the data obtained, it was established that with the annealing temperature growth above 1000 °C, the observed growth of zinc tungstate inclusions is due to the processes of recrystallization of the ZnTeO<sub>3</sub> and Bi₂WO₆ phases, which lead to the growth of grains of the ZnWO<sub>4</sub> phase and the formation of glass-like inclusions that have a reinforcing effect. During the studies conducted it was determined that the formation of inclusions in the form of zinc tungstate in the composition of multicomponent ceramics, caused by the thermal effect of sintering, leads to an increase in the resistance of ceramics to external influences, and also enhances resistance to high-temperature destruction and hydrogenation processes. An analysis of the thermal insulation characteristics of the studied ceramics showed that the dominance of zinc tungstate inclusions in the composition of the ceramics leads to increased resistance to both the processes of destruction caused by hydrogenation and thermal aging, the long-term impact of which leads to increased destabilization of the strength properties of the ceramics and deterioration of thermal insulation.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"23 ","pages":"Article 100838"},"PeriodicalIF":2.8,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145010402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0