ECS Advances最新文献_第2页

Comparative Analysis of Loss Mechanism Localization in a Semi-2D SOEC Single Cell Modell: Non-Equilibrium Thermodynamics versus Monocausal-Based Approach 半二维 SOEC 单细胞模型中损耗机制定位的比较分析：非平衡热力学与基于单因果关系的方法

ECS Advances Pub Date : 2024-01-03 DOI: 10.1149/2754-2734/ad1a73

Aydan Gedik, Jonas Wachtel, Stephan Kabelac

{"title":"Comparative Analysis of Loss Mechanism Localization in a Semi-2D SOEC Single Cell Modell: Non-Equilibrium Thermodynamics versus Monocausal-Based Approach","authors":"Aydan Gedik, Jonas Wachtel, Stephan Kabelac","doi":"10.1149/2754-2734/ad1a73","DOIUrl":"https://doi.org/10.1149/2754-2734/ad1a73","url":null,"abstract":"This study aims to theoretically analyze the local entropy production rate in a SOEC single cell at T = 1123.15 K and p = 1 bar. Local entropy rates signify loss mechanisms, crucial for cell design and optimization. A semi-2D SOEC model based on non-equilibrium thermodynamics is developed, supplemented by monocausal correlations for direct comparison. The model is validated using KeraCell III data and grid independence analysis. Simulations of electric current density, temperature, heat flow, and local entropy production for various SOEC operating modes are presented. Coupled transport mechanisms significance is discussed, highlighting the pronounced impact of the Peltier effect on heat flux and temperature. The importance of the Peltier effect in SOECs compared to SOFCs is emphasised. The effects of the Seebeck effect on the potential distribution are superimposed by the dominant ohmic losses in the electrolyte. The localization of entropy production rates shows for exothermic operation that 66.6% of the total losses are due to the predominantly dominant irreversible ion transport in the electrolyte, while the entanglements in the reaction layers contribute 33% and GDLs less than 1%.","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":"59 20","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139451373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Annealing Strategies for Spray Deposited Precursor Films of p-Type CuCr1-xMgxO2 对型 CuCr1-xMgxO2 喷镀前驱体薄膜的退火策略

ECS Advances Pub Date : 2024-01-03 DOI: 10.1149/2754-2734/ad1a74

M. Boshta, Mohammed. M Gomaa, Mohamed H. Sayed, Hagar Mohamed, Alexander Shengelaya, E. Chikoidze, Yves Dumont, Michael Neumann-Spallart

引用次数: 0

Crystallinity-Controlled Atomic Layer Deposition of Ti-Doped ZrO2 Thin Films 结晶度受控的掺钛 ZrO2 薄膜原子层沉积

ECS Advances Pub Date : 2024-01-03 DOI: 10.1149/2754-2734/ad1a75

Hyeongtag Jeon, S. Song, Eungju Kim, Kyunghoo Kim, Jangho Bae, Jinho Lee, Chang Hwa Jung, Hanjin Lim

引用次数: 0

Evaluation of Fire Spread and Suppression Techniques in Micro-Mobility Battery Packs 评估微型移动电池组的火势蔓延和抑制技术

ECS Advances Pub Date : 2024-01-03 DOI: 10.1149/2754-2734/ad1a72

Daniel Torelli, Nicholas Faenza, Phil Johns, Sam Lawton, James Frake

{"title":"Evaluation of Fire Spread and Suppression Techniques in Micro-Mobility Battery Packs","authors":"Daniel Torelli, Nicholas Faenza, Phil Johns, Sam Lawton, James Frake","doi":"10.1149/2754-2734/ad1a72","DOIUrl":"https://doi.org/10.1149/2754-2734/ad1a72","url":null,"abstract":"\u0000 Lithium-ion battery packs used in micro-mobility devices, such as e-bikes and e-scooters can lead to substantial safety hazards should a single cell go into thermal runaway. Here we explore the extent and severity of e-mobility battery fires resulting from a single cell thermal runaway failure and evaluate various suppression techniques a user may attempt to implement if they experience a battery fire at home. We tested a household water hose as well as different fire blankets deployed both before the forced thermal runaway event and after initiation. The water hose was unable to supply a sufficient amount of water to extinguish the thermal event, however, the average pack temperature was decreased and the cell-to-cell propagation rate was slowed. Neither fire blanket tested was able to contain the flames or debris ejected from the battery packs and both acted to hold in the heat from the event, increasing the temperature, rather than allow it to dissipate. In addition, we also demonstrated how various design approaches, such as added thermal insulation between cells, can help prevent cell-to-cell propagation and reduce the severity of a battery pack failure.","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":"29 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139389227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrochemical Performance of Activated Graphene-Based Materials for Electrodes of Double-Layer Supercapacitors 用于双层超级电容器电极的活化石墨烯基材料的电化学性能

ECS Advances Pub Date : 2023-12-18 DOI: 10.1149/2754-2734/ad16ba

Yeixon Quintero Martínez, Sara Herrera, Z. Zapata-Benabithe, Alejandro Manzano Ramírez, Luis Javier Cruz Riaño

引用次数: 0

Performance of Low-Pressure-Plasma-Processed RuCo Electrocatalysts for Hydrogen Evolution Reaction 低压等离子体处理的钴钌电催化剂在氢气进化反应中的性能

ECS Advances Pub Date : 2023-11-29 DOI: 10.1149/2754-2734/ad10fa

Chia-Yun Tseng, Yu-Lun Su, I‐Chih Ni, Chih-I Wu, I. Cheng, Jian-Zhang Chen

引用次数: 0

Comparative Study of Indium as a Filler or as a Substitute in Yb-Filled Ni-Doped CoSb3 在掺镱掺镍 CoSb3 中将铟作为填充物或替代物的比较研究

ECS Advances Pub Date : 2023-11-29 DOI: 10.1149/2754-2734/ad10e2

K. Dabral, Kalpna Rajput, Krishna Dabral, Ajay singh Verma

{"title":"Comparative Study of Indium as a Filler or as a Substitute in Yb-Filled Ni-Doped CoSb3","authors":"K. Dabral, Kalpna Rajput, Krishna Dabral, Ajay singh Verma","doi":"10.1149/2754-2734/ad10e2","DOIUrl":"https://doi.org/10.1149/2754-2734/ad10e2","url":null,"abstract":"CoSb3 with an open structure that can accommodate several fillers has been extensively studied due to its PGEC character. It is known that partial substitution of Ni with Co generates more free electron and alter the CoSb3 into a stable n-type skutterudite. In this work, we used In as a filler with Yb and as a partial substitution of Sb in Co3.85Ni0.15Sb12. All alloys have been synthesized by solid-state reaction method and hot press processes. The Seebeck coefficient varies from 160 μVK−1 to 200 μVK−1 in Yb0.3Co3.85Ni0.15Sb11.5In0.5; however, it exhibits the highest charge carrier concentration. Yb0.3Co3.85Ni0.15Sb11.5In0.5 exhibits the highest power factor of 3.9 mW−1K−2 at 723 K, which is 20% and 15% larger than a single-filled and double-filled Ni-doped system respectively. The suitable amount of In doped with Sb in a Ni-doped single-filled skutterudite system resulted is not only an improvement of the thermopower but also a decrease of the thermal conductivity due to enhanced point-defect scattering and increased electron-phonon interaction. Hence Yb0.3Co3.85Ni0.15Sb11.5In0.5 exhibits a maximum zT of 1.25 which is 25% higher than Yb0.2In0.2, Co3.85Ni0.5Sb12. Therefore, indium is also a good option to use as a substitution, n-type skutterudite compared to use as a filler.","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":"32 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139212870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Asymmetrical Optical Response of Opal Photonic Crystals with Graded Thickness 厚度渐变的乳白光子晶体的非对称光学响应

ECS Advances Pub Date : 2023-11-16 DOI: 10.1149/2754-2734/ad0cd4

A. Grant, C. O’Dwyer

引用次数: 0

Erratum: Electrochemical-Thermal Modeling of Large-Format, Thin-Film, Lithium-Ion Batteries with Cocurrent and Countercurrent Tab Connections Using a Reduced-Order Model ( ECS Adv. 2, 040505 (2023)) 勘误：使用降序模型对具有同流和逆流接片连接的大型薄膜锂离子电池进行电化学-热建模 ( ECS Adv. 2, 040505 (2023))

ECS Advances Pub Date : 2023-11-15 DOI: 10.1149/2754-2734/ad0889

Mark W. Verbrugge, Daniel R. Baker

引用次数: 0

Immunoelectrochemical Detection of Prostate-Specific Antigen on PEDOT/Cerium Phosphate Nanotubes Modified ITO Electrode PEDOT/磷酸铈纳米管修饰ITO电极上前列腺特异性抗原的免疫电化学检测

ECS Advances Pub Date : 2023-11-08 DOI: 10.1149/2754-2734/ad0a9c

Hua-ju Zhang, Ping Xia, Cheng Chen, Yuchun Fu, Hai-Zhu Shi, Cenxuan Wang, Guo-Wei Zhang, Shun Feng

{"title":"Immunoelectrochemical Detection of Prostate-Specific Antigen on PEDOT/Cerium Phosphate Nanotubes Modified ITO Electrode","authors":"Hua-ju Zhang, Ping Xia, Cheng Chen, Yuchun Fu, Hai-Zhu Shi, Cenxuan Wang, Guo-Wei Zhang, Shun Feng","doi":"10.1149/2754-2734/ad0a9c","DOIUrl":"https://doi.org/10.1149/2754-2734/ad0a9c","url":null,"abstract":"Abstract Herein, a label-free electrochemical immunosensor was developed to detect prostate-specific antigen (PSA), a biomarker for prostate cancer. The immunosensor was fabricated by modifying one-dimensional nanomaterial CePO4 nanotubes, electrodepositing poly-3,4-ethylenedioxythiophene layer, anchoring monoclonal antibodies to PSA, and blocking with bovine serum albumin on the surface of the indium tin oxide sheet. The morphologies and electrochemical performance of the electrochemical sensor were characterized by Fourier transform infrared spectrophotometry, field-emission scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction microscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. For PSA, it exhibits a wide dynamic range from 0.1 ng mL-1 to 100 ng mL-1 and a detection limit of 0.012 ng mL-1 (at a signal-to-noise ratio of 3) with differential pulse voltammetry. Average recoveries from rat serum (a simulated human serum) are between 97.00% – 103.17% with relative standard derivations less than 4.25% (n = 3) at three spiked levels. Moreover, it shows high reproducibility, well selectivity, and good stability. The immunosensor provides an effective tool in the clinical diagnosis of prostate cancer.","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":" 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135340953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0