ECS Advances最新文献_第10页

Hard Carbon Derived from Avocado Peels as a High-Capacity, Fast Na+ Diffusion Anode Material for Sodium-Ion Batteries 从鳄梨皮中提取的硬碳作为钠离子电池的高容量、快速Na+扩散负极材料

ECS Advances Pub Date : 2022-08-18 DOI: 10.1149/2754-2734/ac8aaf

F. Genier, Shreyas Pathreeker, Robson L. Schuarca, Mohammad Islam, I. Hosein

{"title":"Hard Carbon Derived from Avocado Peels as a High-Capacity, Fast Na+ Diffusion Anode Material for Sodium-Ion Batteries","authors":"F. Genier, Shreyas Pathreeker, Robson L. Schuarca, Mohammad Islam, I. Hosein","doi":"10.1149/2754-2734/ac8aaf","DOIUrl":"https://doi.org/10.1149/2754-2734/ac8aaf","url":null,"abstract":"Deriving battery grade materials from natural sources is a key element to establishing sustainable energy storage technologies. In this work, we present the use of avocado peels as a sustainable source for conversion into hard carbon-based anodes for sodium ion batteries. The avocado peels are simply washed and dried then proceeded to a high temperature conversion step. Materials characterization reveals conversion of the avocado peels in high purity, highly porous hard carbon powders. When prepared as anode materials they show to the capability to reversibly store and release sodium ions. The hard carbon-based electrodes exhibit excellent cycling performance, namely, a reversible capacity of 352.55 mAh g−1 at 0.05 A g−1, rate capability up to 86 mAh g−1 at 3500 mA g−1, capacity retention of >90%, and 99.9% coulombic efficiencies after 500 cycles. Cyclic voltammetry studies indicated that the storage process was diffusion-limited, with diffusion coefficient of 8.62 × 10−8 cm2 s−1. This study demonstrates avocado derived hard carbon as a sustainable source that can provide excellent electrochemical and battery performance as anodes in sodium ion batteries.","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":"121 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125405706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Review—Combining Experimental and Engineering Aspects of Catalyst Design for Photoelectrochemical Water Splitting 光电化学水分解催化剂设计的实验与工程结合综述

ECS Advances Pub Date : 2022-08-01 DOI: 10.1149/2754-2734/ac85cd

Chhavi Sharma, Dr.P. Renuka Devi, Anupma Thakur, Y. S. Negi

引用次数: 1

Proof Before Submission 提交前证明

ECS Advances Pub Date : 2022-08-01 DOI: 10.1149/2754-2734/ac8655

P. Cooper

引用次数: 0

Ag-rGO Nanocomposite as an Efficient Electrochemical Sensor for Thiourea Ag-rGO纳米复合材料作为硫脲的高效电化学传感器

ECS Advances Pub Date : 2022-07-20 DOI: 10.1149/2754-2734/ac82be

Murtaza Shafi, Ali Bahader, Fazal Suhrab Gul, Alamgir Khan, Habibullah, M. I. Khan, Kamran Farooqi

{"title":"Ag-rGO Nanocomposite as an Efficient Electrochemical Sensor for Thiourea","authors":"Murtaza Shafi, Ali Bahader, Fazal Suhrab Gul, Alamgir Khan, Habibullah, M. I. Khan, Kamran Farooqi","doi":"10.1149/2754-2734/ac82be","DOIUrl":"https://doi.org/10.1149/2754-2734/ac82be","url":null,"abstract":"The nanofabrication of composites-based sensor can be routinely seen in the research literature, but high price restricts its use on a wider scale in the developing world for establishing sustainable society. Iraj Jodan Synthesized Ag-nanoparticles and alizarin yellow polymer based electrochemical sensor for thiourea detection. Alizarin yellow polymer provide stability, chemical attachment on the electrode surface but it is toxic to lungs, mucous membranes, and can cause organs damage by continuously disclosure to it.1 For solving this problem, r-GO has pasted on electrode surface that provided excellent conduction as well as large surface area and had excellent sensitivity and low detection limit toward TU. Herein, this theme is materialized for the detection of thiourea (TU). Briefly, reduced graphene (r-GO) sheets with silver (Ag) nanoparticles impregnated were prepared via hydrothermal and chemical reduction method. The synthesized nano-composite material was characterized by various physiochemical techniques like FTIR, XRD, SEM and Cyclic Voltammetry (CV) and applied as synthesized for the detection and sensing of TU, a well-known carcinogen. The Ag-rGO changed electrode enhanced approximately three times greater anodic current as compared to rGO and five times greater anodic current as compare to GCE. Electrically and catalytically oxidation TU was achieved by GCE, GO, rGO and Ag-rGO at 0.2 V to 0.25 V applying cyclic voltammetry (CV). The concentrations were used 10 μM to 50 μM, while the current at anode increased as the concentration increased. The rGO and Ag-rGO also planned at various concentrations. The anodic current is increased by increasing scan rate of 20, 40, 60, 80 and 100 mV s−1. So it could be used for recognition of TU in real time sample with good sensitivity, stability and reproducibility.","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125558141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Superhydrophobic, Oleophobic, Self-Cleaning Flexible Wearable Temperature Sensing Device 超疏水，疏油，自清洁柔性可穿戴温度传感装置

ECS Advances Pub Date : 2022-07-20 DOI: 10.1149/2754-2734/ac82bf

Chen-Han Chen, T. Tsai, I. Cheng, Jian-Zhang Chen

引用次数: 0

Review—New Approaches for the Detection of Lithium Carbonate: The First Line Treatment for Bipolar Disorder 综述-碳酸锂检测的新方法:双相情感障碍的一线治疗

ECS Advances Pub Date : 2022-07-12 DOI: 10.1149/2754-2734/ac8065

Lynn Mouawad

{"title":"Review—New Approaches for the Detection of Lithium Carbonate: The First Line Treatment for Bipolar Disorder","authors":"Lynn Mouawad","doi":"10.1149/2754-2734/ac8065","DOIUrl":"https://doi.org/10.1149/2754-2734/ac8065","url":null,"abstract":"Bipolar disorder is known to be a group of affective disorders depicted by depressive manic or hypomanic disorders. Indeed, considered as an oldie as its pharmaceutical usage started in the 19th -century lithium is also a goodie used as the first-line treatment for bipolar disorder, also it is considered to be the only treatment with anti-suicidal effects. During treatment, lithium levels should be monitored as its therapeutic levels (0.5–0.8 mM) in the blood are close to intoxication levels (>1.5 mM) and to severe intoxication levels >2.5 mM that might induce coma. That is why it is necessary for patients diagnosed with bipolar disorder to monitor lithium levels frequently. In fact, there are many traditional analytical techniques for lithium detection. Still, these are associated with limitations as they are very expensive, time-consuming, and not found in all laboratories. So, the need to develop a cost-effective, sensitive, and easy-to-handle devices has grown. Affinity sensors constituted a promising potential for the sensitive detection of lithium. This review, to my knowledge, is the first review highlighting the different types of biosensors developed for lithium-ion detection while explaining the mode of action of each biosensor, and talking about all possible biological fluids that can be used for the detection of this drug.","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":"116 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127783056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced Ga2O3-Based RRAM via Stacked Bilayer ZnO/Ga2O3 ZnO/Ga2O3双层叠加增强基于Ga2O3的RRAM

ECS Advances Pub Date : 2022-06-17 DOI: 10.1149/2754-2734/ac79bf

Chih-Yung Wang, Sheng-Po Chang, Wei-Lun Huang

引用次数: 0

Review—The Thermistor-Electrode as a Temperature Sensor to Obtain Thermodynamic Data of Electrochemical Systems 综述-热敏电阻电极作为获取电化学系统热力学数据的温度传感器

ECS Advances Pub Date : 2022-06-10 DOI: 10.1149/2754-2734/ac77a1

M. Sánchez-Amaya, F. Scholz, M. Bárcena-Soto, R. Antaño-López, A. Rodríguez-López, A. Gutiérrez-Becerra, N. Casillas, E. R. Larios-Durán

引用次数: 1

Photoluminescence Properties and Energy Transfers in the Novel LiYMgWO6: Dy3+, Tm3+ 新型LiYMgWO6: Dy3+， Tm3+的光致发光特性和能量转移

ECS Advances Pub Date : 2022-05-25 DOI: 10.1149/2754-2734/ac7340

Lina Wu, Yelong Wu, Yufan Fan, Bei Sun, Qiangxiang Li, Jinying Yu

引用次数: 2

Environmentally Benign Synthesis of Copper Benzenetricarboxylic Acid MOF as an Electrocatalyst for Overall Water Splitting and CO2 Reduction 环境友好型苯三羧酸铜MOF电催化剂的合成及其对水整体分解和CO2还原的作用

ECS Advances Pub Date : 2022-04-27 DOI: 10.1149/2754-2734/ac6ad5

Eshagh Irandoost, H. Farsi, A. Farrokhi, Neda Sadat Barekati, Zhihai Li

{"title":"Environmentally Benign Synthesis of Copper Benzenetricarboxylic Acid MOF as an Electrocatalyst for Overall Water Splitting and CO2 Reduction","authors":"Eshagh Irandoost, H. Farsi, A. Farrokhi, Neda Sadat Barekati, Zhihai Li","doi":"10.1149/2754-2734/ac6ad5","DOIUrl":"https://doi.org/10.1149/2754-2734/ac6ad5","url":null,"abstract":"As a class of porous coordination polymers, metal organic frameworks (MOFs) have potential applications in many fields. In this work, a novel synthetic method, without using toxic solvents, has been developed to prepare HKUST-1 MOF nanoparticles from coprecipitation reaction of copper (II) chloride and 1,3,5-benzenetricarboxylic acid (trimesic acid) in distilled water. The synthesized nanoparticles were first characterized by X–ray diffraction (XRD), Fourier–transform infrared spectroscopy (FT–IR), and scanning electron microscopy (SEM). The flat–band potential, conduction band, and valence band edges of HKUST-1 nanoparticles were experimentally determined in alkaline solution, and UV–Vis diffuse reflectance spectra (DRS) analysis showed the band gap energy to be 2.5 eV. Electrochemical working electrodes were prepared by electrophoretic deposition of HKUST-1 on the surface of a stainless steel electrode for electrochemical voltammetry and impedance measurements. For the first time the prepared HKUST-1 nanoparticles were investigated as multifunctional electrocatalysts for both overall water splitting and CO2 reduction in alkaline solution. The Tafel plot was used to show the relationship between the over–potential (η) and the logarithmic current density, revealing the kinetic parameters of the electrochemical reactions. Furthermore, the Tafel slope was determined to be 190 mVdec−1, indicating that the Volmer mechanism with electrochemical desorption of hydrogen acts as the rate–determining step (RDS).","PeriodicalId":338397,"journal":{"name":"ECS Advances","volume":"17 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115133142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2