E. Wakelin, Giselle C. Yeo, A. Kondyurin, Michael J. Davies, D. Mckenzie, A. Weiss, M. Bilek
{"title":"Bio-functionalisation of polyether ether ketone using plasma immersion ion implantation","authors":"E. Wakelin, Giselle C. Yeo, A. Kondyurin, Michael J. Davies, D. Mckenzie, A. Weiss, M. Bilek","doi":"10.1117/12.2202506","DOIUrl":"https://doi.org/10.1117/12.2202506","url":null,"abstract":"Plasma immersion ion implantation (PIII) is used here to improve the surface bioactivity of polyether ether ketone (PEEK) by modifying the chemical and mechanical properties and by introducing radicals. Modifications to the chemical and mechanical properties are characterised as a function of ion fluence (proportional to treatment time) to determine the suitability of the treated surfaces for biological applications. Radical generation increases with treatment time, where treatments greater than 400 seconds result in a high concentration of long-lived radicals. Radical reactions are responsible for oxidation of the surface, resulting in a permanent increase in the polar surface energy. The nano-scale reduced modulus was found to increase with treatment time at the surface from 4.4 to 5.2 GPa. The macromolecular Young’s modulus was also found to increase, but by an amount corresponding to the volume fraction of the ion implanted region. The treated surface layer exhibited cracking under cyclical loads, associated with an increased modulus due to dehydrogenation and crosslinking, however it did not show any sign of delamination, indicating that the modified layer is well integrated with the substrate – a critical factor for bioactive surface coatings to be used in-vivo. Protein immobilisation on the PIII treated surfaces was found to saturate after 240 seconds of treatment, indicating that there is room to tune surface mechanical properties for specific applications without affecting the protein coverage. Our findings indicate that the modification of the chemical and mechanical properties by PIII treatments as well as the introduction of radicals render PEEK well suited for use in orthopaedic implantable devices.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"117 35","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131912987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Rehman, K. Rehman, S. Anwar, S. Firdous, M. Nawaz
{"title":"Optical parameter measurement of highly diffusive tissue body phantoms with specifically designed sample holder for photo diagnostic and PDT applications","authors":"A. Rehman, K. Rehman, S. Anwar, S. Firdous, M. Nawaz","doi":"10.1117/12.2202497","DOIUrl":"https://doi.org/10.1117/12.2202497","url":null,"abstract":"Knowledge of optical properties (absorption coefficients, scattering Coefficients, and anisotropy) is necessary for understanding light tissue interactions. Optical parameters define the behavior of light in the tissues. Intralipid and Indian ink are well-established tissue body phantoms. Quantitative characterization of biological tissues in terms of optical properties is achieved with integrating sphere. However, samples having significantly higher scattering and absorption coefficients such as malignant tissues potentially reduce the signal to noise ratio (SNR) and accuracy of integrating sphere. We have measured the diffuse reflection and transmission of these phantoms by placing them in integrating sphere at 632.8 nm and then applied IAD method to determine the optical properties tissue phantoms composed of Indian ink (1.0%) and Intralipid (20%). We have fabricated a special sample holder with thin microscopic cover slips which can be used to measure signal from highly concentrated intralipid and Indian ink solutions. Experiments conducted with various phantoms reveal significant improvement of SNR for a wide range of optical properties. This approach opens up a field for potential applications in measurement of optical properties of highly diffusive biological tissues. For 20% intralipid μa =0.112±0.046 cm-1 and μs =392.299±10.090 cm-1 at 632.8 nm and for 1.0% Indian ink μa =9.808±0.490 cm-1 and μs =1.258±0.063 cm-1 at same wavelength. System shows good repeatability and reproducibility within 4.9% error. Work may have important biomedical applications in photo-diagnosis and Photodynamic therapy.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"329 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117069269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Comparison of sensor structures for the signal amplification of surface plasmon resonance immunoassay using enzyme precipitation","authors":"Chih‐Tsung Yang, B. Thierry","doi":"10.1117/12.2202554","DOIUrl":"https://doi.org/10.1117/12.2202554","url":null,"abstract":"Surface plasmon resonance (SPR) biosensing has been successfully applied for the label-free detection of a broad range of bioanalytes ranging from bacteria, cell, exosome, protein and nucleic acids. When it comes to the detection of small molecules or analytes found at low concentration, amplification schemes are desirable to enhance binding signals and in turn increase sensitivity. A number of SPR signal amplification schemes have been developed and validated; however, little effort has been devoted to understanding the effect of the SPR sensor structures on the amplification of binding signals and therefore on the overall sensing performance. The physical phenomenon of long-range SPR (LRSPR) relies on the propagation of coupled surface plasmonic waves on the opposite sides of a nanoscale-thick noble metal film suspended between two dielectrics with similar refractive indices. Importantly, as compared with commonly used conventional SPR (cSPR), LRSPR is not only characterized by a longer penetration depth of the plasmonic waves in the analyzed medium but also by a greater sensitivity to bulk refractive index changes. In this work, an immunoassay signal amplification platform based on horseradish peroxidase (HRP) catalyzed precipitation was utilized to investigate the sensing performance with regards to cSPR and LRSPR. The enzymatic precipitation of 3, 3’-diaminobenzidine tetrahydrochloride (DAB)/H2O2 was used to amplify SPR signals. The structure-function relationship of cSPR and LRSPR sensors is presented for both standard refractometric measurements and the enzymatic precipitation scheme. Experimental data shows that despite its inherent higher sensitivity to bulk refractive index changes and higher figure of merit, LRSPR was characterized by a lower angular sensitivity in the model enzymatic amplification scheme used here.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124965528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. Balaur, C. Sadatnajafi, D. Langley, Jiao Lin, S. Kou, B. Abbey
{"title":"Electron-beam induced diamond-like-carbon passivation of plasmonic devices","authors":"E. Balaur, C. Sadatnajafi, D. Langley, Jiao Lin, S. Kou, B. Abbey","doi":"10.1117/12.2202567","DOIUrl":"https://doi.org/10.1117/12.2202567","url":null,"abstract":"Engineered materials with feature sizes on the order of a few nanometres offer the potential for producing metamaterials with properties which may differ significantly from their bulk counterpart. Here we describe the production of plasmonic colour filters using periodic arrays of nanoscale cross shaped apertures fabricated in optically opaque silver films. Due to its relatively low loss in the visible and near infrared range, silver is a popular choice for plasmonic devices, however it is also unstable in wet or even ambient conditions. Here we show that ultra-thin layers of Diamond-Like Carbon (DLC) can be used to prevent degradation due to oxidative stress, ageing and corrosion. We demonstrate that DLC effectively protects the sub-micron features which make up the plasmonic colour filter under both atmospheric conditions and accelerated aging using iodine gas. Through a systematic study we confirm that the nanometre thick DLC layers have no effect on the device functionality or performance.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125795704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. R. Kaysir, S. Fleming, Rowan W. MacQueen, T. Schmidt, A. Argyros
{"title":"Luminescent solar concentrator improvement by stimulated emission","authors":"M. R. Kaysir, S. Fleming, Rowan W. MacQueen, T. Schmidt, A. Argyros","doi":"10.1117/12.2202787","DOIUrl":"https://doi.org/10.1117/12.2202787","url":null,"abstract":"Luminescent solar concentrators (LSCs) offer the prospect of reducing the cost of solar energy, and are a promising candidate for building integrated photovoltaic (PV) structures. However, the realization of commercially viable efficiency of LSCs is currently hindered by reabsorption losses. In this work, a method is introduced for reducing reabsorption as well as improving directional emission in LSCs by using stimulated emission. Light from a seed laser (potentially an inexpensive laser diode) passes through the entire length of the LSC panel, modifying the emission spectrum of excited dye molecules such that it is spectrally narrower, at wavelengths that minimize reabsorption, and directed by the seed laser towards a small target PV cell. A mathematical model of such a system is presented which identifies different physical parameters responsible for the power conversion efficiency and gives the net effective output power.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"2023 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127613195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marc Gali, M. Tai, M. Arnold, M. Cortie, A. Gentle, Geoffrey B. Smith
{"title":"Plasmonic response in nanoporous metal: dependence on network topology","authors":"Marc Gali, M. Tai, M. Arnold, M. Cortie, A. Gentle, Geoffrey B. Smith","doi":"10.1117/12.2202278","DOIUrl":"https://doi.org/10.1117/12.2202278","url":null,"abstract":"The optical and electrical responses of open, nanoscale, metal networks are of interest in a variety of technologies including transparent conducting electrodes, charge storage, and surfaces with controlled spectral selectivity. The properties of such nanoporous structures depend on the shape and extent of individual voids and the associated hyper-dimensional connectivity and density of the metal filaments. Unfortunately, a quantitative understanding of this dependence is at present only poorly developed. Here we address this problem using numerical simulations applied to a systematically designed series of prototypical sponges. The sponges are produced by a Monte Carlo simulation of the dealloying of Ag-Al alloys containing from 60% to 85% Al. The result is a series of Ag sponges of realistic morphology. The optical properties of the sponges are then calculated by the discrete dipole approximation and the results used to construct an 'effective medium' model for each sponge. We show how the resulting effective medium can be correlated with the associated morphological characteristics of each target and how the optical properties are primarily controlled by the density of the sponge and its state of percolation.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"37 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122715182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Evstafyev, S. Timoshenkov, Vyacheslav K. Samoilykov, N. Korobova, A. Timoshenkov, Anatolij M. Tereshhenko
{"title":"Calculation of the dynamic characteristics of micro-mirror element based on thermal micro-actuators","authors":"S. Evstafyev, S. Timoshenkov, Vyacheslav K. Samoilykov, N. Korobova, A. Timoshenkov, Anatolij M. Tereshhenko","doi":"10.1117/12.2202444","DOIUrl":"https://doi.org/10.1117/12.2202444","url":null,"abstract":"Paper presents a structure of a micro-mirror element driven by thermal micro-actuators. Micro-mirror dimensions are 100x100 um and it was manufactured by a surface micromachining using microelectronics technologies. Thermal microactuator is a bimorph structure consisting of aluminum and silicon dioxide layers with a polysilicon heater between them. The description of manufacturing process for micro-mirror element is given. The micro-mirror motion is achieved by passing an electric current through the heater. The actuator structure is heated and rotates the mirror. The processes of heating and cooling of thermal micro-actuator structure directly affects the characteristics of manufactured micro-mirror, thus the studying of these processes is essential. The report proposes a method for calculating the heating and cooling time, taking into account the influence of the structure geometry, electrical characteristics of external influence and the environment conditions. Also a method for the experimental determination of the dynamic characteristics is proposed, along with the method of electro-thermal analogy. The results of calculation are in good agreement with the experimental data, which allows one to use it to determine the dynamic characteristics of micro-devices based on thermal microactuators.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126145419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Quantum plasmonics for next-generation optical and sensing technologies","authors":"M. Moaied, K. Ostrikov","doi":"10.1117/12.2220785","DOIUrl":"https://doi.org/10.1117/12.2220785","url":null,"abstract":"Classical plasmonics has mostly focused on structures characterized by large dimension, for which the quantummechanical effects have nearly no impact. However, recent advances in technology, especially on miniaturized plasmonics devices at nanoscale, have made it possible to imagine experimental applications of plasmons where the quantum nature of free charge carriers play an important role. Therefore, it is necessary to use quantum mechanics to model the transport of charge carriers in solid state plasma nanostructures. Here, a non-local quantum model of permittivity is presented by applying the Wigner equation with collision term in the kinetic theory of solid state plasmas where the dominant electron scattering mechanism is the electron-lattice collisions. The surface plasmon resonance of ultra-small nanoparticles is investigated using this non-local quantum permittivity and its dispersion relation is obtained. The successful application of this theory in ultra-small plasmonics structures such as surface plasmon polariton waveguides, doped semiconductors, graphene, the metamaterials composed of alternating layers of metal and dielectric, and the quantum droplets is anticipated.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"118 ","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114002774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Development of functional nano-particle layer for highly efficient OLED","authors":"Jae‐Hyun Lee, Min‐Hoi Kim, Haechul Choi, Y. Choi","doi":"10.1117/12.2202489","DOIUrl":"https://doi.org/10.1117/12.2202489","url":null,"abstract":"Organic light emitting diodes (OLEDs) are now widely commercialized in market due to many advantages such as possibility of making thin or flexible devices. Nevertheless there are still several things to obtain the high quality flexible OLEDs, one of the most important issues is the light extraction of the device. It is known that OLEDs have the typical light loss such as the waveguide loss, plasmon absorption loss and internal total reflection. In this paper, we demonstrate the one-step processed light scattering films with aluminum oxide nano-particles and polystyrene matrix composite to achieve highly efficient OLEDs. Optical characteristics and surface roughness of light scattering film was optimized by changing the mixing concentration of Al2O3 nano-particles and investigated with the atomic force microscopy and hazemeter, respectively.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"144 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116408291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Casas-Bedoya, B. Morrison, M. Pagani, D. Marpaung, B. Eggleton
{"title":"Tunable microwave notch filter created by stimulated Brillouin scattering in a silicon chip","authors":"A. Casas-Bedoya, B. Morrison, M. Pagani, D. Marpaung, B. Eggleton","doi":"10.1117/12.2202488","DOIUrl":"https://doi.org/10.1117/12.2202488","url":null,"abstract":"We show the first functional signal processing device based on forward stimulated Brillouin scattering from a silicon nanowire. We harness 1dB of SBS gain to create a high performance, energy efficient microwave photonic notch filter. The filter possess 48dB of suppression, 98 MHz linewidth, and is tunable within a 6 GHz bandwidth. This demonstration represents a significant advance in integrated microwave photonics with potential applications in on-chip microwave signal processing and establish the foundation towards the first CMOS-compatible high performance RF photonic filter.","PeriodicalId":320411,"journal":{"name":"SPIE Micro + Nano Materials, Devices, and Applications","volume":"121 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2015-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115305765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}