{"title":"Responsive materials based on coordination bonds","authors":"Shi‐Yi Chen, Zi‐Han Zhao, Cheng‐Hui Li, Quan Li","doi":"10.1002/rpm.20230011","DOIUrl":"https://doi.org/10.1002/rpm.20230011","url":null,"abstract":"Responsive materials can respond to different external stimuli by changing their chemical or/and physical properties, thus being useful for various applications such as drug delivery, bioimaging, actuators, and sensors. A common strategy for constructing responsive materials is to introduce dynamic covalent bonds or noncovalent interactions into polymer systems. Compared with noncovalent interactions and other covalent bonds, coordination bonds have the peculiarity that their bond strength and dissociation rate can be tuned to a greater extent. Such tunability makes coordination bonds uniquely advantageous in constructing stimuli‐responsive materials. Herein, we summarize the recent progress of responsive materials based on coordination bonds that are classified into seven categories, that is, thermo‐responsive, photo‐responsive, electro‐responsive, mechano‐responsive, chemo‐responsive, pH‐responsive, and other responsive materials, according to the type of external stimuli. The corresponding mechanism, design strategy, and research status of each category are comprehensively summarized. Finally, the prospects and challenges for the development of stimuli‐responsive materials based on coordination bonds are discussed.","PeriodicalId":313882,"journal":{"name":"Responsive Materials","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124825701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xuejia Hu, Bing Lei, Sen-Sen Li, Lu-Jian Chen, Quan Li
{"title":"Living cell‐laden hydrogels: Unleashing the future of responsive biohybrid systems","authors":"Xuejia Hu, Bing Lei, Sen-Sen Li, Lu-Jian Chen, Quan Li","doi":"10.1002/rpm.20230009","DOIUrl":"https://doi.org/10.1002/rpm.20230009","url":null,"abstract":"Responsive biohybrid systems have the potential to overcome limitations of both natural and artificial machines in terms of efficiency, accuracy, and functionality. As functional units, living cells act as bricks for building biohybrid machines, where the extracellular matrix mimics hydrogels to act as ideal biological concrete. Combining living cells with hydrogels offers unique advantages in simulating human tissues or organs, which unleashes the future of biohybrid systems, and thus has attracted extensive attention. Herein, recent progress in cell‐laden hydrogel‐based responsive biohybrid systems is summarized to provide a basic understanding of how these systems are built from the bottom up and how to achieve the complex functions. This review focuses on advanced manufacturing technologies for responsive biohybrid systems, including laden cells in hydrogel matrices, three‐dimensional bioprinting, and microfluidic manufacturing. Subsequently, the innovative applications of these works, including actuators, sensors, and engineered functional materials, are presented, along with different triggering mechanisms that are highlighted. Finally, the current challenges and future opportunities in the field are addressed. This review provides a unique perspective and is hoped to inspire fields such as biohybrid technologies, soft robots, and tissue engineering.","PeriodicalId":313882,"journal":{"name":"Responsive Materials","volume":"4 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121146182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jingjing Gao, Yuqi Tang, D. Martella, Jinbao Guo, D. Wiersma, Quan Li
{"title":"Stimuli‐responsive photonic actuators for integrated biomimetic and intelligent systems","authors":"Jingjing Gao, Yuqi Tang, D. Martella, Jinbao Guo, D. Wiersma, Quan Li","doi":"10.1002/rpm.20230008","DOIUrl":"https://doi.org/10.1002/rpm.20230008","url":null,"abstract":"","PeriodicalId":313882,"journal":{"name":"Responsive Materials","volume":"223 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132391258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Sentjens, Augustinus J. J. Kragt, A. Schenning, M. Debije
{"title":"Recent advances in solar infrared light regulating smart windows based on organic materials","authors":"H. Sentjens, Augustinus J. J. Kragt, A. Schenning, M. Debije","doi":"10.1002/rpm.20230006","DOIUrl":"https://doi.org/10.1002/rpm.20230006","url":null,"abstract":"","PeriodicalId":313882,"journal":{"name":"Responsive Materials","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116856079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Responsive Materials: Leading the development of materials science","authors":"Quan Li","doi":"10.1002/rpm.20230010","DOIUrl":"https://doi.org/10.1002/rpm.20230010","url":null,"abstract":"","PeriodicalId":313882,"journal":{"name":"Responsive Materials","volume":"73 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132326711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}