A. Staubitz, Jonas Hoffmann, Jonas Hoffmann, Philipp J. Gliese
{"title":"Group 13-Group 15 Element Bonds Replacing Carbon-Carbon Bonds in Main Group Polyolefin Analogs","authors":"A. Staubitz, Jonas Hoffmann, Jonas Hoffmann, Philipp J. Gliese","doi":"10.1002/9783527819140.CH2_1","DOIUrl":"https://doi.org/10.1002/9783527819140.CH2_1","url":null,"abstract":"","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128275806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Inorganic Dendrimers","authors":"A. Caminade","doi":"10.1002/9783527819140.CH5","DOIUrl":"https://doi.org/10.1002/9783527819140.CH5","url":null,"abstract":"Summary Dendrimers are a special class of hyperbranched polymers, constituted of branched constitutional repeating units. Contrary to common polymers, dendrimers are not synthesized by polymerization reactions, but by the step-by-step approach around a central core unit. Most dendrimers are organic compounds with nitrogen or quaternary carbon or benzene ring as branching points, but several families of “inorganic” dendrimers have emerged, essentially based on either silicon or phosphorus as branching points. Despite the architectural similarity, organic and inorganic dendrimers differ in terms of methods of synthesis and characterization, and also by types of utilization. Inorganic dendrimers can offer completely new properties, as will be emphasized later in Chapter 10. The present chapter describes the synthesis of dendrimers comprising either silicon or phosphorus branching points with the emphasis on carbosilane and phosphorhydrazone dendrimers, both of which have obtained the largest attention of all inorganic dendrimers to date. Many other types of small dendrimers have been described in literature, but they will not be reported in this chapter, which focuses both on the above most widely used and also on the most original types of inorganic dendrimers. A few miscellaneous examples of dendrimers based on germanium, tin, or bismuth branching points will be given as well, although they are still rare among dendrimers.","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117185258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Other Examples of Inorganic Polymers as Functional Materials","authors":"Irene Weymuth, W. Caseri","doi":"10.1002/9783527819140.CH11","DOIUrl":"https://doi.org/10.1002/9783527819140.CH11","url":null,"abstract":"","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124108999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Group 14 Metal-Containing Polymers","authors":"A. Torvisco, F. Uhlig, D. Scheschkewitz","doi":"10.1002/9783527819140.CH3","DOIUrl":"https://doi.org/10.1002/9783527819140.CH3","url":null,"abstract":"","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129262210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Current Status and Future Perspectives of Functional and Smart Materials in Daily Life","authors":"R. Pietschnig","doi":"10.1002/9783527819140.CH1","DOIUrl":"https://doi.org/10.1002/9783527819140.CH1","url":null,"abstract":"Smart materials in general, are defined as materials with adaptive properties that undergo change upon exposure to an external stimulus. These changing properties can be very diverse including, but not limited to, reversible changes in volume, shape, opacity, or color, which may be triggered by changes in pH, temperature, magnetic/electric fields, or light. Because of their adaptive nature, these properties play a key role in the manufacture of many technical devices used in daily life, and the ability to switch them is the basis for the surging interest in smart materials for emerging technologies and applications. Besides the responsive features outlined above, materials with optoelectronic and thermoelectric properties that allow conversion of light or heat to electricity at different temperature levels are also sometimes termed as smart materials, but will not be covered in this chapter. Self-healing materials that have the intrinsic ability to repair damage have also not been included. On the other hand, shape memory materials are included. In this chapter, a brief outline on the current status and future perspectives of smart materials in daily life will be given, with a special focus on polymeric materials and inorganic polymeric materials in particular.","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132778246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Valente, Rafaella L. M. Precker, E. Hey‐Hawkins
{"title":"Inorganic Polymers for Potential Medicinal Applications","authors":"A. Valente, Rafaella L. M. Precker, E. Hey‐Hawkins","doi":"10.1002/9783527819140.CH9","DOIUrl":"https://doi.org/10.1002/9783527819140.CH9","url":null,"abstract":"","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116794633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Polymers Containing Group 15 Elements","authors":"A. Orthaber, A. P. Soto","doi":"10.1002/9783527819140.CH4","DOIUrl":"https://doi.org/10.1002/9783527819140.CH4","url":null,"abstract":"","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"51 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125109866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}