Matthew P. Duffy, Pierre‐Antoine Bouit, M. Hissler
{"title":"Applications of Heteroatom-Based Oligomers and Polymers in Optoelectronics","authors":"Matthew P. Duffy, Pierre‐Antoine Bouit, M. Hissler","doi":"10.1002/9783527819140.CH7","DOIUrl":"https://doi.org/10.1002/9783527819140.CH7","url":null,"abstract":"_______________________________________________________________ This book chapter highlights the different kinds of heteroatom based materials that have been used in electronic devices, such as organic light-emitting diodes (OLEDs), organic photovoltaic cells (OPV cells), dye-sensitized solar cells (DSSCs), organic field-effect transistors (OFETs), and electrochromic cells. Nowadays, new materials with specific properties are still needed for the development of efficient and easily processable organic devices. The control of their properties can be achieved by varying the chemical composition of the conjugated systems and a fruitful approach involves the incorporation of heteroatoms into the backbone of conjugated frameworks. _______________________________________________________________","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"14 9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128309130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Inorganic Dendrimers and Their Applications","authors":"A. Caminade","doi":"10.1002/9783527819140.CH10","DOIUrl":"https://doi.org/10.1002/9783527819140.CH10","url":null,"abstract":"Summary Dendrimers are a special class of hyperbranched polymers, constituted of branched constitutional repeating units. Contrary to common polymers, dendrimers are not synthesized by polymerization reactions, but by the step-by-step approach around a central core unit. Most dendrimers are organic compounds with nitrogen or quaternary carbon or benzene ring as branching points, but several families of “inorganic” dendrimers have emerged, essentially based on either silicon or phosphorus as branching points. Despite the architectural similarity, organic and inorganic dendrimers differ in terms of methods of synthesis and characterization, and also by types of utilization. Inorganic dendrimers can offer completely new properties, as will be emphasized later in Chapter 10. The present chapter describes the synthesis of dendrimers comprising either silicon or phosphorus branching points with the emphasis on carbosilane and phosphorhydrazone dendrimers, both of which have obtained the largest attention of all inorganic dendrimers to date. Many other types of small dendrimers have been described in literature, but they will not be reported in this chapter, which focuses both on the above most widely used and also on the most original types of inorganic dendrimers. A few miscellaneous examples of dendrimers based on germanium, tin, or bismuth branching points will be given as well, although they are still rare among dendrimers.","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"59 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129725022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Highlighting the Binding Behavior of Icosahedral Boron Clusters Incorporated into Polymers: Synthons, Polymers Preparation, and Relevant Properties","authors":"C. Viňas, R. Núñez, I. Romero, F. Teixidor","doi":"10.1002/9783527819140.ch2_2","DOIUrl":"https://doi.org/10.1002/9783527819140.ch2_2","url":null,"abstract":"","PeriodicalId":294632,"journal":{"name":"Smart Inorganic Polymers","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128784834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}