Chao Zhang , Bowen Wu , Haoyuan Dang , Yinxiao Zhang , Jun Xing , Zhenqiang Zhao , Yulong Li
{"title":"Theoretical-numerical integrated multi-scale model for fast prediction of progressive failure in textile composites","authors":"Chao Zhang , Bowen Wu , Haoyuan Dang , Yinxiao Zhang , Jun Xing , Zhenqiang Zhao , Yulong Li","doi":"10.1016/j.compscitech.2025.111341","DOIUrl":"10.1016/j.compscitech.2025.111341","url":null,"abstract":"<div><div>Fast and accurate prediction of mechanical properties and failure behavior are essential for the design and optimization of textile composites. In this paper, a novel synergistic multi-scale modeling approach is proposed to predict the progressive failure of two-dimensional triaxially braided composites. A theoretical-based multi-scale model is integrated with finite element calculation in the user subroutine, <em>VUMAT</em>. The developed multi-scale model enables real-time two-way coupled interactions for mechanical response and damage behavior at meso- and macro-scales, and it shows great computational efficiency and generality because of the theoretical nature of the multi-scale computational framework. The proposed framework is utilized to predict the mechanical responses and failure behaviors of different types of specimens: straight-sided, tube, and notched specimens. The predictions show good agreement with both the meso-scale finite element simulations and the experimental results, while reducing the computational time by more than 10 times as compared to the meso-scale model. The theoretical-numerical integrated multi-scale model provides a fast and reliable solution for modeling the progressive failure behavior of textile composite structures under various loading conditions.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111341"},"PeriodicalIF":9.8,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144879891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mansingh Yadav , Nitesh P. Yelve , Thomas Gries , Asim Tewari
{"title":"Multiscale investigation of winding tension on porosity, misalignment, and mechanical performance of filament-wound CFRP composites","authors":"Mansingh Yadav , Nitesh P. Yelve , Thomas Gries , Asim Tewari","doi":"10.1016/j.compscitech.2025.111340","DOIUrl":"10.1016/j.compscitech.2025.111340","url":null,"abstract":"<div><div>The quality and performance of filament-wound composite structures are significantly influenced by winding parameters, particularly the applied winding tension. Winding tension affects resin flow, porosity formation, fiber alignment, and ultimately the mechanical performance of the composite product. This study investigates the effects of winding tension on the structural integrity of carbon fiber-reinforced polymer composites and identifies the root causes of performance variations. A multiscale approach combining analytical, numerical, and experimental methods is employed. Analytical models describe the relationships between winding tension, resin flow, void growth, residual stress, and fiber bed compaction. Numerical simulations using representative volume element capture the microstructural effects of tension on fiber misalignment (with even a 7.12° fiber misalignment can reduce tensile strength by up to 20 %) and porosity, as well as their influence on stress distribution and overall mechanical behavior. Experimental investigations, including quasi-static tensile testing, X-ray tomography, optical microscopy, and fractography, are conducted to validate the models and examine damage mechanisms. The results reveal that increasing winding tension up to 25 N improves fiber alignment and reduces porosity, thereby enhancing the strength of composite. However, tensions beyond this level lead to higher residual stresses and lower mechanical performance due to fiber damage and incomplete resin infiltration. The study identifies 25 N as the optimal additional winding tension, achieving a porosity of 5.54 % with improved structural performance. These findings contribute to better understanding of process–structure relationships and provide guidance for optimizing the manufacturing of high-performance filament-wound composite structures, such as composite pressure vessels.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111340"},"PeriodicalIF":9.8,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144860477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Experimental and numerical evaluation of the interfacial adhesion properties of additively manufactured carbon-fiber-reinforced thermoplastic/64 titanium hybrids","authors":"Keiichi Shirasu , Takeru Mizuno , Yamato Hoshikawa , Kosuke Ogawa , Yuki Takayama , Hironori Tohmyoh","doi":"10.1016/j.compscitech.2025.111338","DOIUrl":"10.1016/j.compscitech.2025.111338","url":null,"abstract":"<div><div>This study presents an integrated numerical–experimental approach to analyze the interfacial fracture behavior of carbon fiber-reinforced thermoplastic (CFRTP)/metal hybrid joints. A two-scale damage analysis framework is proposed, combining finite element analysis (FEA) for macroscopic stress evaluation with a micromechanics model incorporating Christensen's failure criterion. This methodology enables visualization of the fracture process zone (FPZ) and quantitative assessment of interfacial damage evolution. To validate the approach, hybrid joints consisting of short-fiber CFRTP (sCFRTP), continuous-fiber CFRTP (cCFRTP), and 64Ti substrates were fabricated using a modified fused filament fabrication process. A polyimide film was inserted between the sCFRTP and 64Ti substrate to introduce an artificial precrack, which promoted stress localization during lap-shear testing. The joints demonstrated a maximum shear strength of 22.3 ± 0.3 MPa, with fractographic analysis revealing cohesive failure within the sCFRTP layer. These results suggest that the primary bonding mechanism is mechanical interlocking due to melt infiltration into the sandblasted titanium surface. The two-scale simulation revealed an FPZ extending approximately 27 μm along the interface, in agreement with the observed fracture morphology near the precrack tip. This framework offers a predictive tool for understanding damage propagation in dissimilar-material joints and holds promise for the design of lightweight, high-strength CFRTP–metal hybrid structures in advanced manufacturing applications.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111338"},"PeriodicalIF":9.8,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144860539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ruochen Wang , Guocai Yu , Shubin Tian , Longchao Li , Yang Jin , Lijia Feng , Linzhi Wu
{"title":"Mechanical properties of carbon fiber pyramid-honeycomb with shear strengthening design","authors":"Ruochen Wang , Guocai Yu , Shubin Tian , Longchao Li , Yang Jin , Lijia Feng , Linzhi Wu","doi":"10.1016/j.compscitech.2025.111337","DOIUrl":"10.1016/j.compscitech.2025.111337","url":null,"abstract":"<div><div>This study designed a novel carbon fiber pyramid-honeycomb structure to enhance shear performance. Using honeycomb stretching technology, a pyramid-honeycomb preparation method combining topological deformation design was proposed. A theoretical model was established to reveal the failure mechanism and predict the strength, stiffness, and failure mode of the honeycomb. The reliability of the theoretical model was verified through results that were highly similar to those obtained from corresponding simulations and experiments. The results indicated that the shear performance of honeycomb was significantly improved while maintaining a certain level of compression performance. The extremely thin wall thickness resulted in an extremely low honeycomb density and the failure mode of the honeycomb in all experiments was buckling failure of the sidewalls. The study provides a novel idea for designing and manufacturing composite honeycomb materials in the aerospace field.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111337"},"PeriodicalIF":9.8,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144863309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mechanistic insights into mechanical behavior of MOF-polymer membranes","authors":"Phuong Vo, Maciej Haranczyk","doi":"10.1016/j.compscitech.2025.111287","DOIUrl":"10.1016/j.compscitech.2025.111287","url":null,"abstract":"<div><div>Efforts to optimize the performance of MOF-polymer mixed matrix membranes (MMMs) are often hindered by a lack of comprehensive understanding of interfacial interaction mechanisms. This study investigates the interfacial structure, dynamics, and mechanical properties of MMMs using molecular dynamics (MD) simulations. Models were developed by incorporating polyethylene glycol (PEG), polyvinylidene fluoride (PVDF), poly(methyl methacrylate) (PMMA), and polystyrene (PS) into optimized slabs of UiO-66, ZIF-8, and ZIF-90. While PEG and PVDF are known for their high compatibility with MOFs due to strong surface coverage, the rigid PS typically exhibits poor surface coverage. However, our findings reveal an intriguing exception: PS enhances the mechanical stability of ZIF-8 membranes through geometry interlocking at the interface, driven by interfacial dynamics. This behavior contrasts with PVDF, where mechanical stability is not significantly improved. These results emphasize that beyond surface coverage, the geometrical fit and interfacial dynamics are critical factors influencing membranes performance. We further evaluated the impact of polymer content by doubling the polymer layer thickness, which maintained stable Young’s modulus and tensile strength while enhancing failure strain. By highlighting the interplay between surface interactions and interfacial dynamics, this work provides valuable insights for optimizing the design and durability of MMMs for advanced applications.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111287"},"PeriodicalIF":9.8,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144863310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Dual dynamic crosslinked epoxy exhibiting repairability, recyclability and excellent insulation performance","authors":"Ming-Xiao Zhu, Zhi-Yong Song, Zhao-Xin Teng, Jie-Rui Ren, Xue-Kai Xu, Yi-Fei Li","doi":"10.1016/j.compscitech.2025.111331","DOIUrl":"10.1016/j.compscitech.2025.111331","url":null,"abstract":"<div><div>Reversible bonds were incorporated to create insulating polymers with self-healing ability, but their low bond energy leads to reduced mechanical, thermal, and dielectric performance. In this study, two types of reversible crosslinkers with complementary characteristics, namely tetrahedral boronic ester crosslinker and 4,4′-diaminodiphenyl disulfide (4-AFD) are incorporated into epoxy resin to address the self-healing and intrinsic performance issues. The tetrahedral boronic ester crosslinker with high rate of dynamic exchange facilitates the rapid healing process, while the 4-AFD with higher crosslinking density and incorporated nanofillers ensure the outstanding mechanical strength and insulating properties. The resultant epoxy exhibits a breaking strength of ≈50.4 MPa, Young's modulus of ≈6.7 GPa, and breakdown strength higher than commonly used anhydride-cured counterparts. The dynamically crosslinked epoxy with physical and electrical-trees damages can be healed and to restore their original insulating properties under mild conditions of heating at 105 °C for 10 h. The breakdown strength exhibited a recovery efficiency of 90.2 % after aging–healing process. Moreover, the material can be degraded and recycled in ethylene glycol solution. This work provides a reference method for designing epoxy with repairability, recyclability and excellent insulating performances.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111331"},"PeriodicalIF":9.8,"publicationDate":"2025-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144809714","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Heterojunction engineering of large-sized Ti3C2Tx MXene with ZnO for enhanced high-frequency microwave absorption and thermal conductivity","authors":"Rui Zhang , Peng Zu , Yonggang Yan , Gang Zhang","doi":"10.1016/j.compscitech.2025.111321","DOIUrl":"10.1016/j.compscitech.2025.111321","url":null,"abstract":"<div><div>Polymer composites with superior electromagnetic wave (EMW) absorption properties, such as strong attenuation and broadband absorption, as well as excellent thermal conductivity, are ideal for the preparation of high-frequency, high-power electronic devices. Hence, we designed ZnO/Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene heterostructured nanofillers by loading surface-modified ZnO nanoparticles onto large-sized Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene nanolayers using electrostatic interactions. Subsequently, PVDF/ZnO/Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene (PZM) composites were prepared by blending and hot-press molding process with polyvinylidene difluoride (PVDF) resin. By optimizing the doping ratio of ZnO to Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene in heterogeneous interface engineering, the high-frequency microwave absorption and thermal conductivity of the composites were precisely tuned. When the mass ratio of ZnO to Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene is 3:2 (PZM-3), PZM shows the best attenuation of electromagnetic waves, with a minimum reflection loss of −47.2 dB at a thickness of only 2.5 mm, and an effective absorption bandwidth of 4.2 GHz (11.12–15.32 GHz). This bandwidth covers almost all operating band of high-frequency microwave communication equipment up to 18 GHz. Meanwhile, its thermal conductivity increases by 120 % compared to pristine PVDF resin. Most surprisingly, when the mass ratio of ZnO to Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene is 2:3 (PZM-4), the PZM composites exhibit the best thermal conductivity, which increases by 555 %. Furthermore, radar cross section (RCS) was used to simulate the EMW absorption characteristics of PZM composites in practical application scenarios, confirming that PZM composites have a strong EMW loss capability. This work provides a new path for practical application and deep expansion in the field of efficient microwave absorption and thermal management in complex frequency bands, especially in the high-frequency domain.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111321"},"PeriodicalIF":9.8,"publicationDate":"2025-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144810017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Rapid thermal degradation of polyamide 6 microdroplets and its effect on interfacial shear strength to simulate thermal welding conditions of CFRTP","authors":"Shota Kawasaki, Kimiyoshi Naito, Jonathon Tanks","doi":"10.1016/j.compscitech.2025.111318","DOIUrl":"10.1016/j.compscitech.2025.111318","url":null,"abstract":"<div><div>The objective of this study is to investigate the effect of rapid thermal processes on the interfacial strength of carbon fiber-reinforced polyamide 6 (PA6) and to elucidate the influence of such processes. To this end, high-speed thermal degradation tests were performed on microdroplet specimens. Initially, the thermal stability of PA6 in a simulated air environment was examined using isothermal gravimetric analysis to determine suitable thermal degradation test conditions. Then, the oxidation of the microdroplets after thermal degradation was assessed by measuring the total color difference between untreated and thermally treated specimens. Additionally, the effects of temperature and the test duration on the interfacial shear strength (IFSS) of the microdroplet specimens were investigated. Even short-term degradation tests decreased the IFSS of relatively small microdroplets, and the size of the microdroplets significantly influenced the IFSS of the resin–fiber interface. Additionally, thermal degradation at the contact area between the microdroplet and the knife edge influenced the test results. At 300 °C, the decrease in the IFSS resulting from thermal degradation was relatively small. However, at 325 °C, a longer duration of thermal exposure significantly decreased the IFSS. For specimens with an embedment length of at least 60 μm, differences in the IFSS were small when the total color difference was small, regardless of the test temperature.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"270 ","pages":"Article 111318"},"PeriodicalIF":9.8,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144770650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhongyu Wang, Tao Zheng, Li Zhang, Zhanguang Chen, Jindi Zhou, Licheng Guo
{"title":"A combined high and low cycle fatigue progressive damage model for composite laminates considering the effect of loading interaction","authors":"Zhongyu Wang, Tao Zheng, Li Zhang, Zhanguang Chen, Jindi Zhou, Licheng Guo","doi":"10.1016/j.compscitech.2025.111316","DOIUrl":"10.1016/j.compscitech.2025.111316","url":null,"abstract":"<div><div>A fatigue progressive damage model considering the loading interaction is introduced to predict the combined high and low cycle fatigue (CCF) life and residual fatigue properties of composite laminates. This model incorporates fatigue failure criteria, fatigue damage evolution, residual property degradation and a normalized fatigue life model. By considering the interaction between low cycle fatigue (LCF) and high cycle fatigue (HCF), the cumulative fatigue damage under the CCF loading is calculated, and the models for residual stiffness and strength are improved accordingly. A comprehensive fatigue simulation procedure is established to perform equivalent treatment on the combined fatigue loads and calculate the fatigue life. Experimental tests on LCF and CCF are carried out to validate the accuracy of the proposed model, and the simulated results demonstrate good consistency with the experimental results. Moreover, the key parameters in CCF, such as the stress amplitude ratio of CCF, frequency ratio of CCF and stress ratio of LCF, are discussed in terms of their effects on fatigue life and residual stiffness.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"270 ","pages":"Article 111316"},"PeriodicalIF":9.8,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144770649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Single and repeated low-velocity impact response of CFRP laminates with bioinspired double-helicoidal Bouligand structures","authors":"Fan Yang , Songhe Meng","doi":"10.1016/j.compscitech.2025.111320","DOIUrl":"10.1016/j.compscitech.2025.111320","url":null,"abstract":"<div><div>It is challenging to improve the impact resistance of carbon fiber-reinforced polymer (CFRP), especially in the situation of repeated impacts. This paper reports on the improvement of energy-absorption characteristic and impact resistance of CFRP laminates by using Bouligand-type biomimetic architecture. Three types of specimens, quasi-isotropic (QI), single-twisted (SB) and double-twisted (DB) Bouligand-type laminates, were fabricated and tested with single and 5-time repeated low velocity impact (LVI) experiments under impact energy ranging from 20J to 40J. Meanwhile, a validated finite element (FE) model and ultrasonic C-scan technique were utilized to study the interlaminar damage and energy absorption capacity associated with the impact response. Experimental results indicated that DB outperform QI and SB in terms of specific energy absorption (SEA) and peak impact load. After 5-time repeated impacts the DB with 10° pitch angle enable to retain about 97 % in energy absorption capacity, whereas those with 20° pitch angle exhibited the energy absorption capacity reduction of about 14 % and local structural failure. Furthermore, the effects of pitch angle and impactor mass on the impact resistance of DB was numerically examined. A pitch angle of 5° results in an improvement of up to 10 % in resistance compared to those with 10° and 22.5° pitch angles, and at 40J impact energy a lighter high-speed impactor contributes to obtain a more dispersed damage distribution that presents petal-shaped, resulting improved impact resistance.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"270 ","pages":"Article 111320"},"PeriodicalIF":9.8,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144779620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}