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Two-dimensional carbon-based nanomaterials convoying dendrite-free Zn/Li metal batteries
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-09 DOI: 10.1016/j.ces.2025.121499
Na Jiang , Yuan Shao , Xin Zhao , Yong Zhang, Puda Lu, Lihang Ye, Qi Yang, Jieshan Qiu
{"title":"Two-dimensional carbon-based nanomaterials convoying dendrite-free Zn/Li metal batteries","authors":"Na Jiang ,&nbsp;Yuan Shao ,&nbsp;Xin Zhao ,&nbsp;Yong Zhang,&nbsp;Puda Lu,&nbsp;Lihang Ye,&nbsp;Qi Yang,&nbsp;Jieshan Qiu","doi":"10.1016/j.ces.2025.121499","DOIUrl":"10.1016/j.ces.2025.121499","url":null,"abstract":"<div><div>Zn and Li metal batteries have garnered significant interest due to their energy density advantage, whereas facing lifespan and safety challenges caused by dendrite formation. Two-dimensional carbon-based nanomaterials (2D-CNM) have been extensively utilized to address dendrite, leveraging their dimensional attributes such as lattice compatibility and feasible assembly. Despite the reviews on carbon materials in metal batteries, the correlation between the 2D structure of 2D-CNMs and dendrite suppression has not been reported. This study aims to fill this gap. It begins by introducing the dendrite formation mechanism and 2D-CNM advantages. Subsequent sections discuss how the pore structure engineering, surface chemistry, and assembly of 2D-CNM contribute to dendrite suppression from perspectives of ion mass transfer and electrodeposition electrode reaction. Insights into dendrite suppression based on advanced characterization techniques are also summarized. Finally, the paper identifies the remaining challenges and suggests potential solutions to steer the rapid progress in this burgeoning field.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121499"},"PeriodicalIF":4.1,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mass transfer modeling of absorption and desorption behavior of atmospheric water with an aqueous potassium acetate solution in a packed column
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-09 DOI: 10.1016/j.ces.2025.121503
Julius Potyka , Antoine Dalibard , Günter E.M. Tovar
{"title":"Mass transfer modeling of absorption and desorption behavior of atmospheric water with an aqueous potassium acetate solution in a packed column","authors":"Julius Potyka ,&nbsp;Antoine Dalibard ,&nbsp;Günter E.M. Tovar","doi":"10.1016/j.ces.2025.121503","DOIUrl":"10.1016/j.ces.2025.121503","url":null,"abstract":"<div><div>The potential of absorptive atmospheric water generation using a liquid salt solution offers the advantage of good scalability and specific uptake potential for atmospheric water. To investigate the sorption kinetics of an aqueous potassium acetate solution, a packed column experimental setup was constructed. A total of 99 runs were conducted to determine the sorption kinetics and the impact of varying experimental parameters. A maximum absorption rate of up to 8.6 g/s from the air was achieved with the mass flow rates and the inlet air humidity having the greatest positive impact on the absorption rate. Furthermore, the mass transfer was modeled using three distinct models for the mass transfer coefficients and the effective mass transfer area. The findings indicate that the Billet-Schultes model exhibits the least deviation from the observed results with an average of 15.6 % for absorption. The Onda (22.7 %) and Hanley-Chen model (16.8 %) demonstrate comparatively higher average deviations.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121503"},"PeriodicalIF":4.1,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Differences in organic and inorganic components of poplar, spirulina and pig manure form biochar of very distinct properties
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-09 DOI: 10.1016/j.ces.2025.121512
Dezhi Zhou , Kai Sun , Shu Zhang , Chao Li , Xun Hu
{"title":"Differences in organic and inorganic components of poplar, spirulina and pig manure form biochar of very distinct properties","authors":"Dezhi Zhou ,&nbsp;Kai Sun ,&nbsp;Shu Zhang ,&nbsp;Chao Li ,&nbsp;Xun Hu","doi":"10.1016/j.ces.2025.121512","DOIUrl":"10.1016/j.ces.2025.121512","url":null,"abstract":"<div><div>Poplar, spirulina and pig manure are representatives of woody biomass, algae, and biowastes in poultry breeding. They are all carbonaceous, but their distinct composition in both organic and inorganic fractions could impact properties/compositions of pyrolytic products. The detailed impacts were investigated herein by conducting pyrolysis of poplar, spirulina and pig manure at 500 °C and systematic analysis of resulting products. The results showed that bio-oil yield from poplar or spirulina was roughly 2 times of that from pig manure, due to their abundant organic components. However, the yield of biochar from poplar or spirulina was less than half of that from pig manure, but, on organic basis (excluding ash in biochar), the biochar yield was the highest from pyrolysis of poplar. Abundant inorganic components in pig manure formed ash-rich biochar (73.2 %), which was much higher than the ash content in spirulina-biochar (23.9 %) or poplar-biochar (9.0 %). This led to remarkably lower heating value (5.3 versus 26.3 MJ/kg for poplar-biochar) and much lower overall combustion index. Additionally, more intensive cracking induced by low thermal stability of organics in spirulina and pig manure, together with their abundant inorganics (i.e. SiO<sub>2</sub>, CaCO<sub>3</sub> and KCl), resulted in remarkably lower carbon yields than that from pyrolysis of poplar. This, however, reduced the activation energy in pyrolysis of spirulina. Biological fibrous structures of poplar could be inherited by poplar-biochar, while morphology of pig manure-char was very irregular. Melting/agglomeration of proteins and lipids in spirulina formed spirulina-biochar of densified structures with smooth surface.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121512"},"PeriodicalIF":4.1,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143582551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characteristics of iron phase migration and redox performance of Fe/Al particles blending with iron-rich sludge ash
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-09 DOI: 10.1016/j.ces.2025.121501
Xiaoying Yuan, Jiahui Song, Wanxia Hu, Sheng Yao, Kun Wang, Cuiping Wang
{"title":"Characteristics of iron phase migration and redox performance of Fe/Al particles blending with iron-rich sludge ash","authors":"Xiaoying Yuan,&nbsp;Jiahui Song,&nbsp;Wanxia Hu,&nbsp;Sheng Yao,&nbsp;Kun Wang,&nbsp;Cuiping Wang","doi":"10.1016/j.ces.2025.121501","DOIUrl":"10.1016/j.ces.2025.121501","url":null,"abstract":"<div><div>The problem of iron phase enrichment leading to activity decay to failure is currently a bottleneck in the industrialization of iron-based oxygen carriers (OCs) in chemical looping technology. Owing to the poly iron/poly aluminum coagulants usually used in wastewater disposal and finally into the sludge, sludge ash contains a high proportion of iron oxides. To investigate whether sludge ash has the potential to be an economic OC or an auxiliary iron-based OC, iron-rich sludge ash (IRSA), Fe/Al-OC, and their mixed OC in equal proportions (Fe1Ash1) were tested in 30 redox cycles using a thermogravimetric analyzer (TG) and tubular furnace. The TG analysis combined with BET and SEM results could present the following results. The IRSA shows a high oxygen-carrying capacity only in the first two cycles; Fe/Al-OC has a lower oxygen-transferring capacity, the Fe-phase enrichment and mechanical strength impairment are kept during multi-cycling reactions. As for Fe1Ash1, the oxygen-carrying capacity was higher than the theoretically weighted value, and the sintering of the sludge ash was slowed down. However, fragmentation and the low-melting-point Fe-containing components in the sludge ash were still present, and the released components and fragmented under higher temperature adhered to the surface and increased the surface Fe phase density of the Fe/Al-OC particle, the Fe concentration difference between the surface and section inhibited the migration of section Fe moving to the surface. Consequently, by blending IRSA, the iron phase migration of Fe/Al-OC was inhibited and the oxygen transfer performance was improved.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121501"},"PeriodicalIF":4.1,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of mass, energy, and thermodynamics constrained steady-state and dynamic neural networks for interconnected chemical systems
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-08 DOI: 10.1016/j.ces.2025.121506
Angan Mukherjee, Debangsu Bhattacharyya
{"title":"Development of mass, energy, and thermodynamics constrained steady-state and dynamic neural networks for interconnected chemical systems","authors":"Angan Mukherjee,&nbsp;Debangsu Bhattacharyya","doi":"10.1016/j.ces.2025.121506","DOIUrl":"10.1016/j.ces.2025.121506","url":null,"abstract":"<div><div>This paper discusses the development of steady-state and dynamic modeling algorithms for mass, energy, and thermodynamics constrained neural networks (METCNNs) for interconnected chemical process systems. The METCNN models can ‘exactly’ conserve the overall system mass and energy balances, as well as certain thermodynamics constraints during both training and forward problems. The proposed approaches can accommodate an outer layer integer programming problem for selection of the best thermodynamics model from a family of candidates given a particular transient dataset. The developed algorithms for both steady-state and dynamic METCNNs are tested for an interconnected chemical system in presence of noise and bias in training data. For all case studies considered in this work, it has been observed that the optimal METCNN models ensure exact conservation of system physics and consistently converge close to the system truth, even when trained against complex dynamic noisy measurements that do not necessarily satisfy the system physics.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121506"},"PeriodicalIF":4.1,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic properties of natural gas mixture in the pre-salt layer: A molecular dynamics approach
IF 4.7 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-08 DOI: 10.1016/j.ces.2025.121505
Juliana J.F. Souza-Rêgo, Itamar Borges, Leonardo S. de B. Alves, Luiz O.V. Pereira, Rogério Ramos, Jakler Nichele
{"title":"Thermodynamic properties of natural gas mixture in the pre-salt layer: A molecular dynamics approach","authors":"Juliana J.F. Souza-Rêgo, Itamar Borges, Leonardo S. de B. Alves, Luiz O.V. Pereira, Rogério Ramos, Jakler Nichele","doi":"10.1016/j.ces.2025.121505","DOIUrl":"https://doi.org/10.1016/j.ces.2025.121505","url":null,"abstract":"Accurate determination of thermodynamic properties under extreme conditions, such as those of supercritical fluids, is challenging. Such conditions are typically found in the oil reservoirs in pre-salt layer. In this work, we investigate the behavior of thermodynamic properties of natural gas mixtures, primarily composed of methane (CH<sub>4</sub>), light hydrocarbons, and non-hydrocarbon gases, in pre-salt layer conditions employing molecular dynamics simulations with the TraPPE and OPLS force fields. We computed density, speed of sound, isobaric and isochoric heat capacities, Joule-Thomson coefficient, isothermal compressibility, and thermal expansion coefficient over a temperature range of 323.15 to 413.15 K and a pressure range of 10 to 60 MPa. To enhance the accuracy of our results, we employed the Multistate Bennett Acceptance Ratio (MBAR) estimator. The values obtained for density and speed of sound showed strong agreement with available experimental data. Given the scarcity of experimental data for the other properties, we validated our simulation results against the Soave-Benedict-Webb-Rubin (SBWR) equation of state. Notably, the rigid-molecule force fields provided a more accurate description of the thermodynamic properties of the natural gas mixture studied, underscoring its efficacy in modeling complex fluid behaviors under extreme conditions.","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"8 1","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring two-phase bubble dynamics and convective mass transfer in thermochemical Cu–Cl cycle for hydrogen production
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-07 DOI: 10.1016/j.ces.2025.121476
Amir Mohammadi , Ofelia A. Jianu , Canan Acar
{"title":"Exploring two-phase bubble dynamics and convective mass transfer in thermochemical Cu–Cl cycle for hydrogen production","authors":"Amir Mohammadi ,&nbsp;Ofelia A. Jianu ,&nbsp;Canan Acar","doi":"10.1016/j.ces.2025.121476","DOIUrl":"10.1016/j.ces.2025.121476","url":null,"abstract":"<div><div>In water-splitting processes such as thermochemical cycles for hydrogen production, phase transitions cause bubble flow, vapor transfer, and gas redissolution. Proper bubble formation and distribution can significantly reduce the energy required for gas dispersion and mixing, enhancing operational efficiency. The research examines bubble dynamics across various sparger sizes and develops a mass transfer model. The Re numbers range from approximately 630 to 1660, and the corresponding Bo numbers vary between 0.35 and 4. An empirical correlation for the Sh number is developed using a multi-objective genetic algorithm, demonstrating excellent predictive capability (R<sup>2</sup> ≈ 0.98). A predictive 1D model for a rising bubble in rectangular reactors is formulated, which is directly applicable to water-splitting processes such as the thermochemical Cu–Cl cycle. Results demonstrate that as bubbles grow larger, the increase in mass transfer rate becomes less pronounced due to a relatively smaller interfacial area for mass transfer per unit volume of gas.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121476"},"PeriodicalIF":4.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis of isosorbide-based polycarbonate via dimethyl carbonate by dual imidazolate ionic liquid catalyst
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-07 DOI: 10.1016/j.ces.2025.121491
Zifeng Yang , Junping Zhang , Ming Jiang , Hao Wang , Weilu Ding , Xiangping Zhang , Hongyan He , Fei Xu
{"title":"Green synthesis of isosorbide-based polycarbonate via dimethyl carbonate by dual imidazolate ionic liquid catalyst","authors":"Zifeng Yang ,&nbsp;Junping Zhang ,&nbsp;Ming Jiang ,&nbsp;Hao Wang ,&nbsp;Weilu Ding ,&nbsp;Xiangping Zhang ,&nbsp;Hongyan He ,&nbsp;Fei Xu","doi":"10.1016/j.ces.2025.121491","DOIUrl":"10.1016/j.ces.2025.121491","url":null,"abstract":"<div><div>Addressing the increased demand for the development of bio-based polymers from renewable resources, a pathway for synthesizing poly(isosorbide carbonate) (PIC) <em>via</em> melt polycondensation catalyzed by ionic liquid (IL) was proposed from CO<sub>2</sub>-based dimethyl carbonate (DMC) and bio-based isosorbide (ISB) as reactants. 1-Ethyl-3-methylimidazolium imidazolate ([Emim][Im]) with imidazole acted as both an anion and a cation was designed and the highest activity with an ISB conversion of 98 % and PIC molecular weight of 52600 g·mol<sup>−1</sup> was achieved for the PIC synthesis compared to other catalysts with single imidazole cation or anion. High catalytic activity of [Emim][Im] can be attributed to its exceptionally high cationic electrostatic potential (+53.05 kcal/mol) and remarkably low anionic electrostatic potential (−76.12 kcal/mol), which collectively result in the strongest relative electrophilicity and nucleophilicity. Furthermore, the reduced electrostatic complementarity weakens the ion-pair interactions between the cation and anion, thereby enhancing the accessibility of active sites during the catalytic process. This process will promote the sustainable production of bio-based polymers.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121491"},"PeriodicalIF":4.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on the L80 steel column sample of gas storage reservoir tubing in high-pressure three-phase flow: Erosion mechanism and impact angle effect
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-07 DOI: 10.1016/j.ces.2025.121490
Lei Xie , Yang Tang , Jinzhong Wang , Jie Wang
{"title":"Experimental study on the L80 steel column sample of gas storage reservoir tubing in high-pressure three-phase flow: Erosion mechanism and impact angle effect","authors":"Lei Xie ,&nbsp;Yang Tang ,&nbsp;Jinzhong Wang ,&nbsp;Jie Wang","doi":"10.1016/j.ces.2025.121490","DOIUrl":"10.1016/j.ces.2025.121490","url":null,"abstract":"<div><div>The erosion mechanism of L80 steel under alternating injection-production conditions was studied by experiment and numerical simulation. A self-designed jet gas–liquid-solid erosion test system was used to simulate multiphase flow environment. According to the experimental and numerical simulation results, when the impact Angle is 0–30°, the erosion rate increases with the increase of the Angle, and when the impact Angle is 30–90°, the erosion rate decreases with the increase of the Angle. The erosion mechanism of gas storage pipe column mainly includes micro-cutting, furrow and impact deformation. Sand accumulation, embedded particle fragmentation and cutting “lip” in the gas production stage will be carried by high-speed gas and fall off during the gas injection stage, causing secondary erosion to the string. In this study, the erosion characteristics of L80 steel under different impact angles under alternating injection-production conditions were revealed, and the impact Angle function was established.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"310 ","pages":"Article 121490"},"PeriodicalIF":4.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Asymmetric spreading and rewetting phenomena of droplet impact on curved surfaces: A pseudopotential MRT-LBM simulation
IF 4.1 2区 工程技术
Chemical Engineering Science Pub Date : 2025-03-07 DOI: 10.1016/j.ces.2025.121470
Long Li , Zhuoyi Li , Dengwei Jing
{"title":"Asymmetric spreading and rewetting phenomena of droplet impact on curved surfaces: A pseudopotential MRT-LBM simulation","authors":"Long Li ,&nbsp;Zhuoyi Li ,&nbsp;Dengwei Jing","doi":"10.1016/j.ces.2025.121470","DOIUrl":"10.1016/j.ces.2025.121470","url":null,"abstract":"<div><div>Droplet dynamics research is one of the most significant challenges from micro-nano coatings on surfaces and microfluidic control in biomedicine to industrial spray painting, atomized combustion, and environmental pollution control. In nature and practical applications, the motion of droplets on non-uniform surface structures is often involved, yet the resulting asymmetric spreading and rewetting phenomena have not received sufficient attention. This poses a significant barrier to further refining the control of droplets and broadening their applications. Here we proposed a refined dynamic model and study the behavior of spray droplets on semi-cylindrical curved surfaces using the pseudopotential multi-relaxation-time scheme of lattice Boltzmann method (MRT-LBM). Our results indicate that the peripheral annular flow of the droplet preferentially spreads along the tangential direction. The axial retraction effect further squeezes the liquid to spread laterally, resulting in a maximum spreading length ratio of 1.3 for the tangential to axial directions. This asymmetric behavior is significantly enhanced with the increase of the droplet’s Weber number and the curvature of the structure (<em>R/R</em><sub>0</sub>). We also discussed the effects of asymmetric retraction and initial velocity during the droplet impact process on the reduced contact time of up to ∼ 32 %, as well as the rewetting phenomenon. The proposed model should enable accurate simulation of the droplet dynamics on various non-uniform structural surfaces. It highlights a systematic analysis of the complex interactions between initial conditions, structural parameters, liquid properties, and surface tension that affect droplet dynamics, providing an in-depth understanding of the mesoscale interactions of droplets on non-uniform structural surfaces.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"309 ","pages":"Article 121470"},"PeriodicalIF":4.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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