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Cation‐Dependent Nuclearity of New HomolepticAzidocuprates(II), From Discrete Ions toAnionic Strands and Sheets 从离散离子到阴离子链和阴离子片，新均质叠氮（II）的阳离子依赖性核性
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-04-23 DOI: 10.1002/zaac.202400025
M. Köckerling, Alexander Hinz
{"title":"Cation‐Dependent Nuclearity of New HomolepticAzidocuprates(II), From Discrete Ions toAnionic Strands and Sheets","authors":"M. Köckerling, Alexander Hinz","doi":"10.1002/zaac.202400025","DOIUrl":"https://doi.org/10.1002/zaac.202400025","url":null,"abstract":"In chemical reactions of copper(II) acetate dihydrate with\u0000imidazolium azide salts in ethanol solution several new homoleptic\u0000azidocuprates(II) were obtained. In dependency of the used counter\u0000cation various different azidocuprate moieties were crystalized. The\u0000doubly charged DMMDIm2+ cation facilitates the formation of\u0000mononuclear [Cu(N3)4]2– complex anions, while the utilisation of the\u0000(PeMIm)+ ion enables the isolation of a di‐nuclear [Cu2(N3)6]2– salt. By\u0000using the unsymmetrical imidazolium ions (BMIm)+ or (EMIm)+ salts\u0000with the tri‐nuclear [Cu3(N3)8]2– complex anion are obtained. With the\u0000(DML)+ cation an azidocuprate(II) crystallizes , which contains both\u0000[Cu(N3)4]2– and the [Cu2(N3)6]2– anion. The anions in the salt with the\u0000(PeMIm)+ cation are interconnected through further Cu−N bonds and\u0000form layers with a 2D‐honecomb structure. The tri‐nuclear units in the\u0000(BMIm)+ and the (EMIm)+salts form coordination strands of different\u0000structures.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"45 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140668108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: (Z. Anorg. Allg. Chem. 8/2024) 封面：（Z. Anorg. Allg. Chem. 8/2024）
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-04-18 DOI: 10.1002/zaac.202470081
{"title":"Front Cover: (Z. Anorg. Allg. Chem. 8/2024)","authors":"","doi":"10.1002/zaac.202470081","DOIUrl":"https://doi.org/10.1002/zaac.202470081","url":null,"abstract":"","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"77 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140627156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, structure, and reactivity of a superbulky low‐valentbeta‑diketiminate Ga(I) complex 超强低价β-二偏二亚基镓（I）络合物的合成、结构和反应活性
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-04-17 DOI: 10.1002/zaac.202400044
Tim Richter, Stefan Thum, Oliver Townrow, Michael Wiesinger, Jens Langer, Sjoerd Harder
{"title":"Synthesis, structure, and reactivity of a superbulky low‐valentbeta‑diketiminate Ga(I) complex","authors":"Tim Richter, Stefan Thum, Oliver Townrow, Michael Wiesinger, Jens Langer, Sjoerd Harder","doi":"10.1002/zaac.202400044","DOIUrl":"https://doi.org/10.1002/zaac.202400044","url":null,"abstract":"A low‐valent GaI complex with the superbulky b‐diketiminate ligand DIPePBDI (HC[C(Me)N‐DIPeP]2, DIPeP = 2,6‐C(H)Et2‐phenyl)) was obtained by reduction of (DIPePBDI)GaI2 (1) with KC8 in toluene. Considering that (BDI)GaI and analogue (BDI)AlI complexes are prone to decomposition and can generally only be obtained in low yields (20‐40%), the quantitative formation of (DIPePBDI)GaI (2) is remarkable and no doubt related to its excellent thermal stability even in refluxing toluene. Although the low‐valent metal center in 2 is sterically protected by the superbulky DIPePBDI ligand, it is readily oxidized by N2O to give intermediate (DIPePBDI)Ga=O which readily decomposed by abstracting a proton from the backbone Me‐substituent. Reaction with trimethylsilyl azide gave an intermediate imido complex (DIPePBDI)Ga=N(SiMe3)2 which reacted with a second equivalent of Me3SiN3 to a mixture of an azide/amido complex (DIPePBDI)GaN3[N(SiMe3)2] (4) and a tetrazagallole complex (DIPePBDI)Ga[N4(SiMe3)2] (5) in a 1:2 ratio. Whereas the azide/amido complex 4 could be structurally characterised, the tetraazagallole complex 5 was identified by NMR spectroscopy. DFT calculations on (DIPePBDI)GaI (2) and its reaction products complement this study.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"49 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140616848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyphosphorus compounds derived from P4 conversion with sterically demanding cobalt complexes 由 P4 与立体要求极高的钴络合物转化而来的多磷化合物
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-04-09 DOI: 10.1002/zaac.202400022
Fabian Dielmann, Mehdi Elsayed-Mousa, Christoph Riesinger, Manfred Scheer
{"title":"Polyphosphorus compounds derived from P4 conversion with sterically demanding cobalt complexes","authors":"Fabian Dielmann, Mehdi Elsayed-Mousa, Christoph Riesinger, Manfred Scheer","doi":"10.1002/zaac.202400022","DOIUrl":"https://doi.org/10.1002/zaac.202400022","url":null,"abstract":"The conversion of P4 with [CpBnCo(CO)2] (CpBn = C5(CH2C6H5)5) under thermal conditions gives almost exclusively the P10 complex [(CpBnCo)4(μ4‐η4:η4:η2:η2:η1:η1‐P10)]. However, its reaction with [CpBnCo]n, under mild conditions afforded a mixture of products including the P8 species [(CpBnCo)3(μ3‐η4:η2:η2:η1:η1‐P8)] and a rare Co3 cluster [(CpBnCo)2Co(μ3‐η5:η2:η1:η1‐C40H33)(μ‐H)(μ3‐H)]. The products were studied in solution by multinuclear NMR spectroscopy and mass spectrometry and, for some compounds in the solid state, by single crystal X‐ray diffraction.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"48 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140561440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2‐Pyridylmetallocenes, Part VII. Synthesis and Reactivity of cycloaurated Pyridylmetallocenes. Spectroscopic and Crystallographic Characterization 2-Pyridylmetallocenes, Part VII.环状吡啶基茂金属的合成与反应活性。光谱和晶体表征
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-04-05 DOI: 10.1002/zaac.202300258
Stefan Weigand, Karlheinz Sünkel
{"title":"2‐Pyridylmetallocenes, Part VII. Synthesis and Reactivity of cycloaurated Pyridylmetallocenes. Spectroscopic and Crystallographic Characterization","authors":"Stefan Weigand, Karlheinz Sünkel","doi":"10.1002/zaac.202300258","DOIUrl":"https://doi.org/10.1002/zaac.202300258","url":null,"abstract":"Treatment of the 2‐pyridylferrocenes [CpFe(C5H3R{C5H4N})] (R= H, Me) with HAuCl4 or NaAuCl4 in aqueous acetonitrile yields the cycloaurated complexes [CpFe(C5H2R{C5H4N}AuCl2)] (R= H, 2a; Me, 2b). Reaction of 2a,b with phenylacetylene in the presence of CuI and NEt3 produces the monoalkynyl complexes [CpFe(C5H2R{C5H4N}AuI{CCPh})] (R= H, 3a; Me, 3b), while the reaction of 2a with NaCN/ LiCl yields.the bis‐cyanide [CpFe(C5H3{C5H4N}Au{CN}2)] 4a. The molecular structures of 2a, 3a, 3b and 4a were determined by X‐ray diffraction.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"147 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140561552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: (Z. Anorg. Allg. Chem. 7/2024) 封面：（Z. Anorg. Allg. Chem. 7/2024）
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-04-04 DOI: 10.1002/zaac.202470071
{"title":"Front Cover: (Z. Anorg. Allg. Chem. 7/2024)","authors":"","doi":"10.1002/zaac.202470071","DOIUrl":"https://doi.org/10.1002/zaac.202470071","url":null,"abstract":"<i>ZAAC</i> is an international scientific journal which publishes original papers on new relevant research results from all areas of inorganic chemistry, solid state chemistry, and co-ordination chemistry.The contributions reflect the latest findings in these research areas and serve the development of new materials, such as super-hard materials, electrical superconductors, or intermetallic compounds. Up-to-date physical methods for the characterization of new chemical compounds and materials are also described.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"55 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140561603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterization of Novel Transition Metal Pnictogenide Compounds 新型过渡金属苷元化合物的合成与表征
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-04-03 DOI: 10.1002/zaac.202400023
Carsten von Hänisch, Kevin Dollberg, Jan Moritz, Katalin Mészáros, Celina Jakobi, Roman-Malte Richter, Florian Weigend
{"title":"Synthesis and Characterization of Novel Transition Metal Pnictogenide Compounds","authors":"Carsten von Hänisch, Kevin Dollberg, Jan Moritz, Katalin Mészáros, Celina Jakobi, Roman-Malte Richter, Florian Weigend","doi":"10.1002/zaac.202400023","DOIUrl":"https://doi.org/10.1002/zaac.202400023","url":null,"abstract":"A series of transition metal‐pnictogenide compounds were prepared starting from [(Dipp2NacNac)MCl] (M = Cr, Mn, Fe, Zn) (Dipp2NacNac = HC{C(Me)N(Dipp)}2) and [M´E(SiMe3)2] (M´= Li, K; E = P, As, Sb) as well as [Li(Et2O)nPH2] and [Li(tmeda)AsH2]. In the course of these investigations we were able to characterize all permutations for compounds of the composition [(Dipp2NacNac)ZnE(SiMe3)2] (E = P, As, Sb) and [(Dipp2NacNac)ZnEH2] (E = P, As). Moreover, the synthesis of selected compounds of type [(Dipp2NacNac)ME(SiMe3)2] for M = Cr, Mn, Fe and E = P‐Sb are described. As part of our efforts, we established a number of bonding motifs that are underexplored in the literature to date. All isolated compounds, were examined by NMR spectroscopy, IR spectroscopy, Elemental analysis and X‐Ray structure analysis. DFT calculations on the chromium compounds were performed to investigate the binding situation between chromium and the group 15 element in more detail.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"47 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140561595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2D Z n (II) Metal‐Organic Framework as a Highly Sensitive Luminescent Sensor for detection of the Cr2O72 ‐ and Fe3+ 二维 Z n (II) 金属有机框架作为用于检测 Cr2O72 - 和 Fe3+ 的高灵敏度发光传感器
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-03-19 DOI: 10.1002/zaac.202400008
Yi-Xuan Shi, Teng Li, Qing-Yun Yang, Qiang Guo, Yan-Lan Wang, Jing Ru
{"title":"2D Z n (II) Metal‐Organic Framework as a Highly Sensitive Luminescent Sensor for detection of the Cr2O72 ‐ and Fe3+","authors":"Yi-Xuan Shi, Teng Li, Qing-Yun Yang, Qiang Guo, Yan-Lan Wang, Jing Ru","doi":"10.1002/zaac.202400008","DOIUrl":"https://doi.org/10.1002/zaac.202400008","url":null,"abstract":"In this work, NH2‐containing organic ligand 5‐Aminoisophthalic acid (AIPA), and trans‐1,2‐bis(4‐pyridyl)ethene (bpe) were selected as organic ligands to construct a new two‐dimensional luminescent Zn(II) metal‐organic framework [Zn(AIPA)(bpe)1/2]·named MOF‐1. It is worth noting that MOF‐1 exhibited excellent thermal stability and chemical stability in common solvents and different pH aqueous solution. As we expected, the luminescence sensing investigations demonstrated that MOF‐1 could be deemed as a multifunctional fluorescence sensor toward Cr2O72‐ and Fe3+ via a “turn‐off” effect.Notably, MOF‐1 had high selectivity and sensitivity for Fe3+ and Cr2O72‐ with low detection limits of 9.72× 10‐5 M and 1.95× 10‐5 M, respectively. Furthermore, the possible quenching mechanisms were also explored in detail.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"2014 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140169523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: (Z. Anorg. Allg. Chem. 5‐6/2024) 封面： (Z. Anorg. Allg. Chem. 5-6/2024)
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-03-13 DOI: 10.1002/zaac.202470061
{"title":"Front Cover: (Z. Anorg. Allg. Chem. 5‐6/2024)","authors":"","doi":"10.1002/zaac.202470061","DOIUrl":"https://doi.org/10.1002/zaac.202470061","url":null,"abstract":"<i>ZAAC</i> is an international scientific journal which publishes original papers on new relevant research results from all areas of inorganic chemistry, solid state chemistry, and co-ordination chemistry.The contributions reflect the latest findings in these research areas and serve the development of new materials, such as super-hard materials, electrical superconductors, or intermetallic compounds. Up-to-date physical methods for the characterization of new chemical compounds and materials are also described.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"44 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140125787","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review on binary alkaline‐earth trielides: an overview of compositions and structures, of their stabilities and energetics and of criteria for the validity of the Zintl‐concept. 二元碱土三硒化物综述：成分和结构、其稳定性和能量学以及 Zintl 概念有效性标准综述。
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-03-12 DOI: 10.1002/zaac.202400011
Horst Philipp Beck
{"title":"A review on binary alkaline‐earth trielides: an overview of compositions and structures, of their stabilities and energetics and of criteria for the validity of the Zintl‐concept.","authors":"Horst Philipp Beck","doi":"10.1002/zaac.202400011","DOIUrl":"https://doi.org/10.1002/zaac.202400011","url":null,"abstract":"Omitting alloys with a compositional range we present a compilation of binary alkaline earth trielides AExTRy together with results of DFT calculations to estimate total energies and energies of formation in comparison and to analyse the distribution of charges at the atomic positions in a Bader analysis of the electron density. In a comparison of many structures, we furthermore analyse the effect of bonding on this charge distribution and reflect on the real bonding patterns in comparison with our expectations according to the Zintl concept, and we find mechanisms blocking an electron transfer as favoured by the electronegativity differences. We have subjected a variety of structural parameters together with the DFT results to a Principal Component Analysis to explore their relationship which we describe in the form of correlation matrices and biplots. The Zintl rules turn out to be a very slack guideline in rationalizing the structures of these compounds.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"120 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140125611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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