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Eutectic Solvent Gel for Flexible Wearable Sensors 柔性可穿戴传感器用共熔溶剂凝胶
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2025-09-30 DOI: 10.1002/zaac.202500118
Dengke Song, Zhiqing Li, Shihui Qiu, Songmei Ma, Gang Liu, Shaohua Zhang
{"title":"Eutectic Solvent Gel for Flexible Wearable Sensors","authors":"Dengke Song, Zhiqing Li, Shihui Qiu, Songmei Ma, Gang Liu, Shaohua Zhang","doi":"10.1002/zaac.202500118","DOIUrl":"https://doi.org/10.1002/zaac.202500118","url":null,"abstract":"Aiming at the problem of poor stability of traditional hydrogels in flexible sensing applications, in this paper, a ternary eutectic solvent is successfully constructed by using choline chloride, acrylic acid, and ethylene glycol. By introducing α‐methacrylic acid (MAA) monomer and N , N ′‐methylene diacrylamide crosslinking agent, a new type of eutectic solvent gel is prepared by ultraviolet light‐initiated polymerization. The influence of MAA content on the mechanical properties of the gel is systematically studied. When the MAA content is 25 wt%, the comprehensive performance of the gel is the best, the fracture strain reaches 404%, the compressive strength is 1.38 MPa, and the elastic modulus (122 kPa) matched that of human skin. Differential scanning calorimetry confirmes that it still have no crystallization peak from room temperature to −80 °C and have excellent frost resistance. The maximum shear adhesion strength to nine substrates such as metals and plastics reached 343.4 kPa. The sensing test showes that the gel have a significant sensitivity (gauge factor = 1.64–4.06) within the strain range of 0%–320%, and could stably monitor human joint movements. This work provides a new strategy for developing high‐performance flexible wearable sensors suitable for extreme environments.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"651 17","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced Proton Conductivity in Proton Exchange Membranes via Integration of Protic Ionic Liquid–Encapsulated NH2‐MIL‐53(Al) with Sulfonated Poly(Ether Ether Ketone) 质子离子液体包封NH2 - MIL - 53（Al）与磺化聚醚醚酮集成增强质子交换膜中的质子电导率
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2025-05-12 DOI: 10.1002/zaac.202500038
Jun Zhao, Feng-Qi Jiang, Rui Zhang, Dan Ba, Wen‐Wen Dong, Dong‐Sheng Li
{"title":"Enhanced Proton Conductivity in Proton Exchange Membranes via Integration of Protic Ionic Liquid–Encapsulated NH<sub>2</sub>‐MIL‐53(Al) with Sulfonated Poly(Ether Ether Ketone)","authors":"Jun Zhao, Feng-Qi Jiang, Rui Zhang, Dan Ba, Wen‐Wen Dong, Dong‐Sheng Li","doi":"10.1002/zaac.202500038","DOIUrl":"https://doi.org/10.1002/zaac.202500038","url":null,"abstract":"Metal‐organic frameworks (MOFs) exhibit exceptional potential for proton conduction owing to their unique structural characteristics, including tunable porosity and functional surfaces. In this study, a novel proton exchange membrane is developed by incorporating a protic ionic liquid (IL) into NH 2 ‐MIL‐53(Al) materials of institute Lavoisier (MIL)and embedding the resulting composite within a sulfonated poly(ether ether ketone) (SPEEK) matrix. The porous architecture of the MOF facilitates the formation of an extensive hydrogen‐bonding network between the IL cations and water molecules, which is critical for efficient proton transport. Furthermore, the synergistic interaction between the NH 2 groups of NH 2 ‐MIL‐53(Al) and the SO 3 H groups of SPEEK enables dual‐proton‐conduction pathways, resulting in a remarkable proton conductivity of 0.42 S cm −1 for the IL@NH 2 ‐MIL‐53(Al)/SPEEK‐7 composite. Additionally, the IL@NH 2 ‐MIL‐53(Al)/SPEEK‐7 membrane demonstrates exceptional stability in proton conduction under tested conditions. This work provides a strategic approach for designing high‐performance and durable‐proton exchange membranes with significantly enhanced conductivity, offering valuable insights for future research in this field.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"651 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synthesis and Characterization of 18‐Crown‐6 with 3‐Aminocyclobutanone Guest: A Novel Host–Guest Inclusion Compound with Phase Transition 含3 -氨基环丁酮的18 - Crown - 6的合成与表征：一种具有相变的新型主-客体包合物
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2025-01-28 DOI: 10.1002/zaac.202400210
Ziyue Zhang, Zhuoer Cai, Yinan Zhang, Jian Chen, Xiu‐Ni Hua, Bai Wang Sun, Baiwang Sun
{"title":"Synthesis and Characterization of 18‐Crown‐6 with 3‐Aminocyclobutanone Guest: A Novel Host–Guest Inclusion Compound with Phase Transition","authors":"Ziyue Zhang, Zhuoer Cai, Yinan Zhang, Jian Chen, Xiu‐Ni Hua, Bai Wang Sun, Baiwang Sun","doi":"10.1002/zaac.202400210","DOIUrl":"https://doi.org/10.1002/zaac.202400210","url":null,"abstract":"The focus of this study is on the development of novel host–guest inclusion compounds, which is a crucial molecule model for the synthesis of dielectric phase transition materials. In this research, a new host–guest inclusion compound is successfully synthesized by selecting 18‐crown‐6 as the host and 3‐aminocyclobutanone as the guest molecule. The thermal behavior and crystal structure of the compound are analyzed in this article. It is found that the compound exhibits a reversible phase transition near 147 K, accompanied by a dielectric anomaly, exhibiting dielectric switching characteristics. The 18‐crown‐6 molecule and the 3‐aminocyclobutanone molecule are connected via hydrogen bonding. Furthermore, the enthalpy changes of the heating process and cooling process are also calculated. This finding is expected to yield valuable new insights into the design of host–guest inclusions.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"651 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147334161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oxygen redox activity in battery cathodes and the role of underbonded oxygen 电池阴极中的氧氧化还原活性和欠键氧的作用
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-09-18 DOI: 10.1002/zaac.202400067
Anthony West, Yangyang Roy Zhao, Laurence Roy Middlemiss, Xuan Roy Zhi, Peter Roy Gross
{"title":"Oxygen redox activity in battery cathodes and the role of underbonded oxygen","authors":"Anthony West, Yangyang Roy Zhao, Laurence Roy Middlemiss, Xuan Roy Zhi, Peter Roy Gross","doi":"10.1002/zaac.202400067","DOIUrl":"https://doi.org/10.1002/zaac.202400067","url":null,"abstract":"It is widely recognised that oxygen redox makes a significant contribution to the high capacity of some cathode materials in addition to transition metal redox. We attribute this to the presence of underbonded oxide ions, either in bulk structures or at surfaces, which are the initial source of oxygen redox during charging. Underbonded oxide ions experience departures from local electroneutrality; examples include Li4Mn5O12 spinel and Li‐rich layered rock salt structures but not stoichiometric LiCoO2 or Li2MnO3. Underbonded oxide ions ionise more readily than fully‐stabilised lattice oxide ions since, using an ionic bonding description, they are associated with a deficiency of positive charge in the coordination sphere of surrounding cations. Pauling’s electrostatic bond strength criterion gives a simple guide to structures or compositions that show departures from local electroneutrality and provides the starting point for a new way to consider oxygen redox. Li­­4Mn5O12 behaves as an anode due to Mn redox below 3V and as a cathode due to reversible oxygen redox above ~3.8 V. Underbonded oxygens are also identified in other structures, including high capacity Li‐rich layered rock salt structures.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High‐Pressure Synthesis and Crystal Structure of the Inoborate Ni[B2O2(OH)4] 铌酸镍[B2O2(OH)4]的高压合成及其晶体结构
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-09-09 DOI: 10.1002/zaac.202400137
Leonard Conrad Pasqualini, Hubert Huppertz
{"title":"High‐Pressure Synthesis and Crystal Structure of the Inoborate Ni[B2O2(OH)4]","authors":"Leonard Conrad Pasqualini, Hubert Huppertz","doi":"10.1002/zaac.202400137","DOIUrl":"https://doi.org/10.1002/zaac.202400137","url":null,"abstract":"The novel inoborate Ni[B2O2(OH)4] was synthesized under high‐pressure/high‐temperature conditions of 9 GPa and 800 °C. Its structure was determined via single‐crystal X‐ray diffraction analysis. The single‐grain IR‐spectrum of Ni[B2O2(OH)4] supports the existence of O–H bonds. The structural similarities and differences with the mineral vimsite possessing the sum formula Ca[B2O2(OH)4], as well as with the phylloborate HP‐Ni(B2O4) is discussed. The title compound can be described as the structural hydrolysis product of the latter.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3− Sn5Bi3]3- 的合成与单晶 X 射线表征
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-09-09 DOI: 10.1002/zaac.202400086
Ute Friedrich, Franz Schmidt, Nikolaus Korber
{"title":"Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3−","authors":"Ute Friedrich, Franz Schmidt, Nikolaus Korber","doi":"10.1002/zaac.202400086","DOIUrl":"https://doi.org/10.1002/zaac.202400086","url":null,"abstract":"The extraction of the solid state materials <jats:italic>“M</jats:italic>SnBi<jats:sub><jats:italic>x</jats:italic></jats:sub><jats:italic>“</jats:italic> (<jats:italic>M</jats:italic>/<jats:italic>x</jats:italic>=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sup>3−</jats:sup>. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]<jats:sub>3</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 7NH<jats:sub>3</jats:sub>, [K@[18]crown‐6]<jats:sub>1.5</jats:sub>[Cs@[18]crown‐6][Cs@([18]crown‐6)<jats:sub>2</jats:sub>]<jats:sub>0.5</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 3.98NH<jats:sub>3</jats:sub>, [Na@DB[18]crown‐6]<jats:sub>2</jats:sub>[Na(NH<jats:sub>3</jats:sub>)<jats:sub>6</jats:sub>][Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 14NH<jats:sub>3</jats:sub> and [Cs@[2.2.2]crypt]<jats:sub>6</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sub>2</jats:sub> ⋅ 9.53NH<jats:sub>3</jats:sub>. The [Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sup>3−</jats:sup> anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chiral Homodinuclear Dysprosium Macrocyclic Complexes with Single‐molecule Magnetic Behaviours 具有单分子磁性的手性同核大环镝配合物
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-09-07 DOI: 10.1002/zaac.202400139
Zi-Hang Cheng, Ru-Chan Liu, Feng Gao
{"title":"Chiral Homodinuclear Dysprosium Macrocyclic Complexes with Single‐molecule Magnetic Behaviours","authors":"Zi-Hang Cheng, Ru-Chan Liu, Feng Gao","doi":"10.1002/zaac.202400139","DOIUrl":"https://doi.org/10.1002/zaac.202400139","url":null,"abstract":"A pair of enantiomerically chiral dysprosium homodinuclear complexes: [(acac)4Dy2(R,R,R,R‐L)] (R‐Dy) and [(acac)4Dy2(S,S,S,S‐L)] (S‐Dy) (Hacac = acetylacetone) have been synthesized based on macrocyclic chiral ligands (R,R,R,R‐H2L/S,S,S,S‐H2L), derived from the [2+2] template condensation of 4‐tert‐butyl‐2,6‐diformylphenol, dysprosium acetylacetonate and (1R,2R)‐/(1S,2S)‐1,2‐cyclohexanediamine, respectively. Circular dichroism spectra confirms their enantiomeric chirality. Single‐crystal structures show two crystallographic independent dysprosium(III) ions have square antiprismatic coordination with different D4d local symmetry. Furthermore, the selected R‐Dy complex owns the slow magnetic relaxation behaviour with the ferromagnetic Dy3+···Dy3+ coupling.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"24 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supramolecular Interactions as Key in Racemic Resolution: New Insights into the (SSi)‐ and (RSi)‐Diastereomers of (1R,2S,5R)‐Methyl(1‐naphthyl)‐phenylmenthoxy­silane of Sommer 超分子相互作用是外消旋解析的关键：索默(1R,2S,5R)-甲基(1-萘基)-苯基薄荷硅烷的(SSi)-和(RSi)-非对映异构体的新见解
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-09-02 DOI: 10.1002/zaac.202400135
Jan-Lukas Kirchhoff, Carsten Strohmann
{"title":"Supramolecular Interactions as Key in Racemic Resolution: New Insights into the (SSi)‐ and (RSi)‐Diastereomers of (1R,2S,5R)‐Methyl(1‐naphthyl)‐phenylmenthoxy­silane of Sommer","authors":"Jan-Lukas Kirchhoff, Carsten Strohmann","doi":"10.1002/zaac.202400135","DOIUrl":"https://doi.org/10.1002/zaac.202400135","url":null,"abstract":"A highly selective approach with high yields of two diastereomeric silicon‐stereogenic menthoxysilanes, (RSi)‐3 and (SSi)‐3, introduced by Sommer et al., could be established as well as investigated in detail using different analytical tools. Single‐crystal X‐ray diffraction analysis was used to examine the different crystallization rates while Hirshfeld surface analysis was applied to extend supramolecular interactions in the solid state which showed stronger hydrogen bridges for the faster crystallizing diastereomer (SSi)‐3. In addition, similar ground‐state energies have been found for both diastereomers by DFT calculations. Subsequent NMR studies showed stable Si‐configurations wherein epimerization only started after more than 4 hours at 110 °C. Access to both diastereomers with opposite configuration at the stereogenic silicon center is achievable in high yields and high stereochemical purity using only naturally occurring (–)‐menthol as a reagent.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
From tin(II) to tin(IV): Following solid‐liquid reactions by microscopy 从锡(II)到锡(IV)：用显微镜跟踪固液反应
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-09-02 DOI: 10.1002/zaac.202400091
Hans Reuter, Simona Schröder, Natalie Röwekamp-Krugley, Markus Imwalle
{"title":"From tin(II) to tin(IV): Following solid‐liquid reactions by microscopy","authors":"Hans Reuter, Simona Schröder, Natalie Röwekamp-Krugley, Markus Imwalle","doi":"10.1002/zaac.202400091","DOIUrl":"https://doi.org/10.1002/zaac.202400091","url":null,"abstract":"In order to study the formation of complexes independently from stoichiometry we developed a microscale experiment that allows us to monitor the reaction progress by light microscopy In the present study, the complex formation between SnF2 and 1,10‐phenanthroline (phen) with N,N‐dimethylformamide as solvent was investigated over a period of some weeks. By use of this setup, the formation of three different crystals has been observed, whose compositions and structures were determined by single crystal X‐ray diffraction: 3SnF2 · phen, 1, 2SnF2 · SnF4 · phen, 2, SnF4 · phen, 3. While the octahedral fluorine environment of the tin(IV) atoms of 2 and 3 is very regular, the coordinations of the tin(II) atoms in 1 and 2 is irregular. Assuming a non‐bonding 5s electron pair, classical 2c‐2e‐ and symmetrical and asymmetrical, hypervalent 3c‐4e‐bonds ‐ all based on the orthogonal p atomic orbitals of Sn – an approach to analyse and describe these coordinations in a simple comprehensive way is presented.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Syntheses, structures, properties, and calculation of a family of ionic crystals based on 1,3‐bis(5‐tetrazolyl)triazene 基于 1,3-双(5-四唑基)三氮烯的离子晶体家族的合成、结构、特性和计算
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-08-29 DOI: 10.1002/zaac.202400049
Bin Liu, Liang He, Zi-chen Shi, Wen-hui Huang, Qi Xue, Jian-hui Yang
{"title":"Syntheses, structures, properties, and calculation of a family of ionic crystals based on 1,3‐bis(5‐tetrazolyl)triazene","authors":"Bin Liu, Liang He, Zi-chen Shi, Wen-hui Huang, Qi Xue, Jian-hui Yang","doi":"10.1002/zaac.202400049","DOIUrl":"https://doi.org/10.1002/zaac.202400049","url":null,"abstract":"Sodium salt of 1,3‐bis(5‐tetrazolyl)triazene (NaH2BTT‧4H2O) was obtained through diazo‐couple reaction with 5‐aminotetrazole as starting reactants, and a family of energetic ionic crystals of the 1,3‐bis(5‐tetrazolyl)triazene anions HnBTT(3‐n)‐ with different cations were investigated, including protonated amines (ethanediamine, hydrazinium, aminoguanidine, methylhydrazinium) and Y(H2O)83+. The structures and physicochemical properties of these compounds were characterized by IR, Raman, X‐ray diffraction (XRPD) and TG‐DSC. Ethanediamine salt is the best thermal stable, while hydrazinium salt possess a highest nitrogen rich value of 79.76%. Both of them show a rapid collapse of the BTT main frame, and almost all of the dissociation products are released in the form of gas.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"114 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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