Polyphosphorus compounds derived from P4 conversion with sterically demanding cobalt complexes

Fabian Dielmann, Mehdi Elsayed-Mousa, Christoph Riesinger, Manfred Scheer
{"title":"Polyphosphorus compounds derived from P4 conversion with sterically demanding cobalt complexes","authors":"Fabian Dielmann, Mehdi Elsayed-Mousa, Christoph Riesinger, Manfred Scheer","doi":"10.1002/zaac.202400022","DOIUrl":null,"url":null,"abstract":"The conversion of P4 with [CpBnCo(CO)2] (CpBn = C5(CH2C6H5)5) under thermal conditions gives almost exclusively the P10 complex [(CpBnCo)4(μ4‐η4:η4:η2:η2:η1:η1‐P10)]. However, its reaction with [CpBnCo]n, under mild conditions afforded a mixture of products including the P8 species [(CpBnCo)3(μ3‐η4:η2:η2:η1:η1‐P8)] and a rare Co3 cluster [(CpBnCo)2Co(μ3‐η5:η2:η1:η1‐C40H33)(μ‐H)(μ3‐H)]. The products were studied in solution by multinuclear NMR spectroscopy and mass spectrometry and, for some compounds in the solid state, by single crystal X‐ray diffraction.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"48 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400022","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

The conversion of P4 with [CpBnCo(CO)2] (CpBn = C5(CH2C6H5)5) under thermal conditions gives almost exclusively the P10 complex [(CpBnCo)4(μ4‐η4:η4:η2:η2:η1:η1‐P10)]. However, its reaction with [CpBnCo]n, under mild conditions afforded a mixture of products including the P8 species [(CpBnCo)3(μ3‐η4:η2:η2:η1:η1‐P8)] and a rare Co3 cluster [(CpBnCo)2Co(μ3‐η5:η2:η1:η1‐C40H33)(μ‐H)(μ3‐H)]. The products were studied in solution by multinuclear NMR spectroscopy and mass spectrometry and, for some compounds in the solid state, by single crystal X‐ray diffraction.
由 P4 与立体要求极高的钴络合物转化而来的多磷化合物
在热条件下,P4 与 [CpBnCo(CO)2](CpBn = C5(CH2C6H5)5)的转化几乎只得到 P10 复合物[(CpBnCo)4(μ4-η4:η4:η2:η2:η1:η1-P10)]。然而,在温和的条件下,它与[CpBnCo]n 的反应产生了一种混合产物,其中包括 P8 物种[(CpBnCo)3(μ3-η4:η2:η2:η1:η1-P8)]和一种罕见的 Co3 团簇[(CpBnCo)2Co(μ3-η5:η2:η1:η1-C40H33)(μ-H)(μ3-H)]。通过多核核磁共振谱和质谱对溶液中的产物进行了研究,并通过单晶 X 射线衍射对固态中的某些化合物进行了研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信