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Comparative Evaluation of a Functions and Volume-Translation Strategies to Predict Densities for Gas(es)-Heavy Oil/Bitumen Systems 预测天然气-重油/沥青系统密度的函数和体积转换策略的比较评估
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/217980-pa
Esther Anyi Atonge, Daoyong Yang
{"title":"Comparative Evaluation of a Functions and Volume-Translation Strategies to Predict Densities for Gas(es)-Heavy Oil/Bitumen Systems","authors":"Esther Anyi Atonge, Daoyong Yang","doi":"10.2118/217980-pa","DOIUrl":"https://doi.org/10.2118/217980-pa","url":null,"abstract":"In this work, a unified, consistent, and efficient framework has been proposed to better predict the density of a gas(es)-heavy oil/bitumen system by using the Peng-Robinson equation of state (PR EOS) and Soave-Redlich-Kwong (SRK) EOS together with α functions and volume-translation (VT) strategies, respectively. With a database comprising 218 experimentally measured densities for gas(es)-heavy oil/bitumen systems, five α functions defined at a reduced temperature (Tr) of 0.70 as well as three new α functions at Tr = 0.60 together with four VT strategies are selected and evaluated. For α Functions 1 to 4 defined at Tr = 0.70, VTs 1 to 4 lead to an overall absolute average relative deviation (AARD) of 7.21%, 9.74%, 7.02%, and 7.16%, respectively, for predicting the mixture densities. For α Function 5 defined at Tr = 0.70, these four VT strategies predict the mixture density with an AARD of 3.13%, 5.01%, 2.92%, and 2.56%, respectively. As for the two new α Functions 7 and 8 defined at Tr = 0.60, these four VT strategies predict the mixture density with an AARD of 1.38%, 2.57%, 1.34%, and 1.67%, respectively, among which VT 3 has a very close prediction compared to an AARD of 1.31% obtained from the ideal mixing rule with effective density (IM-E).","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"50 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139302816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking Continental Shale Oil Potential: Microscopic Insights into Fluid Saturation Mechanisms via Imbibition for Future Development Strategies in the Songliao Basin 解锁陆相页岩油潜力:松辽盆地未来开发战略中流体饱和机制的微观洞察
3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/218004-pa
Ying Yang, Jianguang Wei, Erlong Yang, Fahimeh Hadavimoghaddam, Mehdi Ostadhassan, Shuang Liang, Xiaofeng Zhou
{"title":"Unlocking Continental Shale Oil Potential: Microscopic Insights into Fluid Saturation Mechanisms via Imbibition for Future Development Strategies in the Songliao Basin","authors":"Ying Yang, Jianguang Wei, Erlong Yang, Fahimeh Hadavimoghaddam, Mehdi Ostadhassan, Shuang Liang, Xiaofeng Zhou","doi":"10.2118/218004-pa","DOIUrl":"https://doi.org/10.2118/218004-pa","url":null,"abstract":"Summary Microscopic assessment of oil distribution and imbibition mechanisms within shale formations lays the groundwork for future development strategies. In this regard, the Songliao Basin’s continental shale oil holds immense exploration and development potential. In this study, we focus on shale samples extracted from the first member of the Qingshankou Formation (Q1) within the Songliao Basin. These samples were subjected to a comprehensive analysis, encompassing mercury injection capillary pressure (MICP), porosity, and permeability measurements and detailed monitoring processes. The experimental protocol involved multiple injection cycles, commencing with spontaneous oil imbibition, followed by a series of differential pressurized oil saturation stages (eight pressurization steps ranging from 0.2 MPa to 10 MPa). Subsequently, forced imbibition using slickwater under varying pressures was used, and the process was meticulously monitored via gravimetric and nuclear magnetic resonance (NMR) measurements to deduce relative fractions within distinct pores across the entire experimental process. Notably, the results unveiled that, during oil saturation through spontaneous imbibition, the interbedd-type shale core samples exhibit more efficient oil saturation compared with the organic-rich dark massive type. In the former, clay interlayers predominate in absorbing oil, while the latter showcases preferential saturation of mesopores and macropores. Following the differential pressurized oil saturation phase, clay interlayers continued to play a significant role in both sample types, accounting for 54.2% and 57.0% of the interbed-type and massive shale’s oil intake, respectively. Furthermore, a quantification of the slickwater imbibition recovery originating from pores of varying sizes under distinct pressures revealed that clay interlayers and micropores are the primary contributors to imbibition recovery in both sample types. Collectively, the experimental findings corroborate that shale oil can be displaced from nanopores to larger matrix pores and bedding fractures through imbibition, offering valuable insights for enhancing oil recovery operations in practical field scenarios.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"66 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135566926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Individualized Design and Field Application of Annular-Groove Polycrystalline Diamond Composite Bit 环槽聚晶金刚石复合钻头的个性化设计和现场应用
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/218379-pa
Kuilin Huang, Cheng Fu, Yong Li, Jian Zhou, Yingxin Yang, Yueqiang Feng
{"title":"Individualized Design and Field Application of Annular-Groove Polycrystalline Diamond Composite Bit","authors":"Kuilin Huang, Cheng Fu, Yong Li, Jian Zhou, Yingxin Yang, Yueqiang Feng","doi":"10.2118/218379-pa","DOIUrl":"https://doi.org/10.2118/218379-pa","url":null,"abstract":"Aiming at the problems of slow drilling speed, low service life, and poor stability of conventional polycrystalline diamond compact (PDC) bits in deep formations that are difficult to drill, a new annular-grooved PDC bit is proposed. The bit adopts discontinuous tooth arrangement to set cutters, and a circumferential annular groove around the center of the bit is set on the bit body to form a fragile convex annular ridge at the bottom of the well, improving the bit’s ability to invade the formation and its rock-breaking efficiency. Combined with the formation characteristics of Shapai 11 well and Shixi 102 well in Xinjiang Oil Field, the PDC bit crown shape, annular-groove design, cutter selection, and other aspects are designed individually, and the dynamic rock-breaking and hydraulic characteristics of the annular-groove PDC bit are simulated and analyzed. Finally, two PDC bits with different diameters are developed—a Φ215.9-mm annular-groove PDC bit and the field application bit. The field application bit results show that compared with the bit in the same layer of adjacent wells, the mechanical penetration rate of the annular-groove PDC bit is increased by 29.8–176.7%, and the footage is increased by 142.5–273.1%. It is concluded that the annular-groove PDC bit can significantly reduce the rock-breaking energy consumption of the bit and improve the mechanical rate of penetration (ROP) of the bit. At the same time, the raised annular ridge can reduce the lateral vibration of the bit and extend the service life of the bit, which will accelerate the exploration and development of deep difficult-to-drill formations. It is of positive significance to reduce drilling costs.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"24 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139297541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Approach to Define and Quantify Porosity System in Heterogeneous Carbonate Reservoirs through Textural Analysis using High-Resolution Resistivity Image in the Bassein Formation of Mumbai Offshore Basin, India 利用印度孟买近海盆地 Bassein 地层的高分辨率电阻率图像进行纹理分析,从而确定和量化异质碳酸盐岩储层中的孔隙度系统的方法
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/218375-pa
Suraj Kumar, Soumya Chandan Panda
{"title":"An Approach to Define and Quantify Porosity System in Heterogeneous Carbonate Reservoirs through Textural Analysis using High-Resolution Resistivity Image in the Bassein Formation of Mumbai Offshore Basin, India","authors":"Suraj Kumar, Soumya Chandan Panda","doi":"10.2118/218375-pa","DOIUrl":"https://doi.org/10.2118/218375-pa","url":null,"abstract":"In evaluating the porosity system of the Bassein formation, high-resolution resistivity image (FMI) data have been used. Major features observed from the FMI data are the presence of low-angle fractures and solution channels of varying length and thickness. Against the layers with very-low-density neutron porosity, solution channels are seen as conductive features. These mud-filled solution channels can actively participate in production. Being very small-scale features, these types of porosities are not identifiable from conventional log data. To define and quantify porosity types such as vugs, solution channel, and matrix porosity, the resistivity image data are processed and image-based porosity is calculated. A core thin-section study is carried out and is used for calibration of the image-derived porosity system. Using resistivity image data, we have computed porosity types, for example, vugs, connected matrix and resistive, and their contribution to total porosity. Identification of hydrocarbons in reservoir layers with their porosity contribution (porosity partitioning) gives better insight into hydrocarbon production in these low-porosity layers which are producing after acid job.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"2015 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139299117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Structural Aspects of Heavy-Crude-Derived Asphaltene Molecules for Investigating the Crude Mix Processability in Refinery Operation 重质原油衍生沥青质分子的新结构特征用于研究炼油操作中原油混合可加工性
3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/218002-pa
Raj K. Das, Ravi K. Voolapalli, Sreedevi Upadhyayula, Rajeev Kumar
{"title":"Novel Structural Aspects of Heavy-Crude-Derived Asphaltene Molecules for Investigating the Crude Mix Processability in Refinery Operation","authors":"Raj K. Das, Ravi K. Voolapalli, Sreedevi Upadhyayula, Rajeev Kumar","doi":"10.2118/218002-pa","DOIUrl":"https://doi.org/10.2118/218002-pa","url":null,"abstract":"Summary In this paper, we investigate the role of asphaltenes derived from heavy crudes, which dictates the behavior of crude mix properties for hassle-free downstream refinery operation. Combined characterization techniques such as proton nuclear magnetic resonance (1H-NMR), cross-polarization magic-angle-spinning carbon-13 (CP/MAS 13C)-NMR, heteronuclear single-quantum coherence (HSQC), Fourier transform infrared (FTIR), thermogravimetric analysis (TGA), and X-ray diffraction (XRD) are used for the detailted study of Ratwai and Ras Gharib (RG)-derived asphaltenes to validate their structural role in selecting the optimal crude mix. As per our investigation, when the polyaromatic core of asphaltene structures are less substituted, the availability of aromatic hydrogen is more; it exhibits a stable crude mix as compared to heavy crudes that have more aromatic core substitution, despite the crudes possessing similar asphaltene content and physicochemical properties. This finding is further extended to West Canadian (WC) and Belayim (BL) heavy crudes for operational suitability. In this study, the key feature is to develop a CP/MAS 13C-NMR-based robust and quick characterization technique that could potentially become a prescreening method to assess crude oil compatibility and its various blend processability in the refinery system. Other characterization techniques, such as 1H-NMR, HSQC, FTIR, TGA, and XRD, would corroborate and confirm the reliability of the data obtained by CP/MAS 13C-NMR.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"56 3-4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135715086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reservoir Drilling and Openhole Gravel Packing with High-Density Cesium Formate Fluids in a High-Pressure, Marginal Mud Window Environment at Martin Linge 在马丁林格的高压边缘泥浆窗环境中使用高密度甲酸铯流体进行储层钻探和裸眼砾石封隔
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/212487-pa
Simen Jøsang Nilsen, Hanne Undheim Obrestad, H. Kaarigstad, Nadia Mansurova, Tom Are Solvoll, Johan Løchen, Siv Howard, Ben Abrahams, Christian Busengdal
{"title":"Reservoir Drilling and Openhole Gravel Packing with High-Density Cesium Formate Fluids in a High-Pressure, Marginal Mud Window Environment at Martin Linge","authors":"Simen Jøsang Nilsen, Hanne Undheim Obrestad, H. Kaarigstad, Nadia Mansurova, Tom Are Solvoll, Johan Løchen, Siv Howard, Ben Abrahams, Christian Busengdal","doi":"10.2118/212487-pa","DOIUrl":"https://doi.org/10.2118/212487-pa","url":null,"abstract":"High-density cesium/potassium (Cs/K) formate fluids were successfully utilized from reservoir drilling to upper completion installation in five productive Martin Linge high-rate gas wells. Four wells were completed with openhole gravel pack (OHGP) and one with standalone sand screens. The gravel packing operation marks what is considered to be the highest density carrier fluid OHGP successfully completed worldwide, with a specific gravity (SG) of 2.06. A complex operation under pressure and temperature conditions (745–780 bar and 135–140°C) that almost qualify as high pressure/high temperature (HP/HT), including managed pressure drilling (MPD), overbalanced screen running, and openhole gravel packing, was simplified by using the same base brine throughout the operation. Cs/K formate reservoir drilling fluid (RDF) and screen-running fluid were designed with biopolymeric additives and minimal calcium carbonate bridging particles. Clear Cs/K formate brine was chosen as gravel pack (GP) carrier fluid. The use of Cs/K formate fluids for all stages of the operation reduced the complexity of transitioning between the operational stages. In addition, the reservoir was only exposed to one filtrate without application of damaging weighting solids. The drilling fluid contributed to successful MPD and delivered wells with very good hole quality in the reservoir, which consisted of interbedded sandstone, coal stringers, and shale. The shale-stabilizing properties of concentrated formate brine–based fluids provided acceptable conditions for extended openhole time and allowed additional logging runs, including pore pressure measurements, under near-HP/HT conditions, before running the screens. One bottom-up cleanout was conducted before the screen-running fluid was circulated in and the screens installed. The spurt and seepage losses were low throughout the drilling and screen-running phases. No breaker treatment was required in any of the wells. All wells have proved to have good initial productivity and high well productivity index. The successful OHGP operations performed with the high fluid densities required in Equinor’s Martin Linge field have set a new standard for well completions in challenging high-pressure environments.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"1 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139301347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulation of Hydrate Particles Aggregation and Deposition in Gas-Dominated Flow 模拟气体主导流中水合物颗粒的聚集和沉积
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/218384-pa
Zhiyuan Wang, Zeqin Li, Jihao Pei, Nan Ma, Jianbo Zhang, Baojiang Sun
{"title":"Simulation of Hydrate Particles Aggregation and Deposition in Gas-Dominated Flow","authors":"Zhiyuan Wang, Zeqin Li, Jihao Pei, Nan Ma, Jianbo Zhang, Baojiang Sun","doi":"10.2118/218384-pa","DOIUrl":"https://doi.org/10.2118/218384-pa","url":null,"abstract":"Owing to low-temperature and high-pressure production environments, hydrate generation, accumulation, and deposition are prone to occur in deepwater oil and gas production wells and transportation pipelines, leading to pipeline blockage and threatening the safety of oil and gas production. To explore the aggregation mechanism and deposition law of hydrate particles in the main gas diversion pipeline, this study considered the adhesion effect of hydrate particles and established a hydrate particle aggregation and deposition model based on theory and experiments. The coupled computational fluid dynamics-discrete element method (CFD-DEM) is used in the simulation calculation. The simulation results were compared with the relevant experimental results, and maximum and average errors of 9.48% and 4.56% were observed, respectively. It was found that the main factor affecting the aggregation of hydrates is the adhesion between particles. As the subcooling temperature increased, the aggregation and adhesion of the hydrate particles increased to varying degrees. The tangential adhesion force between the hydrate aggregate particles was significantly greater than the normal adhesion force, and the adhesion force between the particles gradually increased from the surface to the interior of the aggregates. The coordination number of the hydrate particles can quantitatively characterize the degree of aggregation and is affected by many factors, such as adhesion. By studying the particle coordination number, the evolution of hydrate accumulation and deposition under different conditions can be summarized. Based on the simulation results, the mathematical relationship between different dimensionless numbers and hydrate deposition ratio (HDR) was calculated, and an expression that can predict the HDR was obtained, with an average relative error of 10.155%. This study provides a theoretical basis for predicting the aggregation and deposition of hydrate particles in gas-dominated systems and a reference for the development of hydrate prevention and control plans.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"15 2 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139298913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Real-Time Gamma Ray Log Generation from Drilling Parameters of Offset Wells Using Physics-Informed Machine Learning 利用物理信息机器学习从偏置井钻井参数生成实时伽马射线测井曲线
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/212445-pa
Prasham Sheth, Sailaja Sistla, Indranil Roychoudhury, Mengdi Gao, Crispin Chatar, Jose Celaya, Priya Mishra
{"title":"Real-Time Gamma Ray Log Generation from Drilling Parameters of Offset Wells Using Physics-Informed Machine Learning","authors":"Prasham Sheth, Sailaja Sistla, Indranil Roychoudhury, Mengdi Gao, Crispin Chatar, Jose Celaya, Priya Mishra","doi":"10.2118/212445-pa","DOIUrl":"https://doi.org/10.2118/212445-pa","url":null,"abstract":"By 2026, USD 5.05 billion will be spent per year on logging while drilling (LWD) according to the market report from Fortune Business Insights (2020). Logging tools and wireline tools are costly services for operators to pay for, and the companies providing the services also have a high cost of service delivery. They are, however, an essential service for drilling wells efficiently. The ability to computationally generate logs in real time using known relationships between the rock formations and drilling parameters, namely, rate of penetration (ROP), rotations per minute (RPM), surface weight on bit (SWOB), surface torque (TQX), standpipe pressure (SPPA), and hookload (HKLD), provides an alternative method to generate formation evaluation information (analysis of the subsurface formation characteristics such as lithology, porosity, permeability, and saturation). This paper describes an approach to creating a digital formation evaluation log generator using a novel physics-informed machine learning (PIML) approach that combines physics-based approaches with machine learning (ML) algorithms. The designed approach consists of blocks that calculate mechanical specific energy (MSE), physical estimates of gamma ray (GR) using physical and empirical models, and formation information. All this information and the drilling parameters are used to build a classification model to predict the formations, followed by formation-based regression models to get the final estimate of GR log. The designed PIML approach learns the relationships between drilling parameters and the GR logs using the data from the offset wells. The decomposition of the model into multiple stages enables the model to learn the relationship between drilling parameters data and formation evaluation data. It makes it easier for the model to generate GR measurements consistent with the rock formations of the subject well being drilled. Because the computationally generated GR by the model is not just dependent on the relationships between drilling parameters and GR logs, this model is also generalizable and capable of being deployed into the application with only retraining on the offset wells and no change in the model structure or complexity. For this paper, the drilling of the horizontal section will not be discussed, as this was done as a separate body of work. Historically collected data from the US Land Permian Basin wells are used as the primary data set for this work. Results from the experiments based on the data collected from five different wells have been presented. Leave-one-out validation for each of the wells was performed. In the leave-one-out validation process, four of the wells represent the set of offset wells and the remaining one becomes the subject well. The same process is repeated for each of the wells as they are in turn defined as a subject well. Results show that the framework can infer and generate logs such as GR logs in real time. The average root-mean-squar","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"113 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139305994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Molecular Structure of Thio-Chemicals on Corrosion Inhibition in CO2 Corrosive Environments 硫代化学品分子结构对二氧化碳腐蚀环境中缓蚀作用的影响
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/213848-pa
Jiang Yang, Xintong Wang, Yefei Wang, Zhen Yang
{"title":"Effect of Molecular Structure of Thio-Chemicals on Corrosion Inhibition in CO2 Corrosive Environments","authors":"Jiang Yang, Xintong Wang, Yefei Wang, Zhen Yang","doi":"10.2118/213848-pa","DOIUrl":"https://doi.org/10.2118/213848-pa","url":null,"abstract":"Carbon dioxide (CO2) is frequently present in oil and gas fields, and its use in CO2 flooding for enhanced oil recovery is growing. However, CO2 is highly corrosive to steel in oilfield fluid. The effective and economical method for controlling corrosion is the addition of corrosion inhibitors for carbon steel materials. Thio-compounds of small size have shown potential as corrosion inhibitors to enhance the performance of imidazoline inhibitors. In this study, several small thio-derivatives inhibitors including mercaptoethanol (ME), thiourea (TU), mercaptoacetic acid (TGA), and 2-mercaptobenzimidazole (MBI) were compared to inhibit the CO2 corrosion. They were used as synergists to enhance corrosion inhibition of oleic imidazoline (OIM) on carbon steel in CO2-saturated brine at 60°C. The corrosion inhibition was evaluated using weight loss and electrochemical techniques, while the surface was characterized using atomic force microscopy (AFM). Additionally, quantum chemical calculations were conducted to investigate the mechanism of corrosion inhibition. The results demonstrate that the MBI, with its aromatic group, exhibited superior corrosion inhibition performance compared with ME, TGA, and TU. The surface characterization revealed no pitting and localized corrosion at 10 ppm of inhibitor. A proposed interaction model suggests that OIM becomes protonated and forms a coadsorption layer with MBI on the carbon steel surface through electrostatic attraction. MBI adsorbs onto iron through a bidentate binding-N-S-bridge connection, effectively preventing carbon steel corrosion in the CO2 environments. This research contributes to establishing a structure-properties relationship for thio-chemicals, aiding in the development of more efficient corrosion inhibitors.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"8 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139301366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion Inhibition of Benzyl Quinoline Chloride Derivative-Based Formulation for Acidizing Process 基于苄基氯化喹啉衍生物的酸化工艺配方的缓蚀作用
IF 3.6 3区 工程技术
SPE Journal Pub Date : 2023-11-01 DOI: 10.2118/218374-pa
Zhen Yang, Yefei Wang, Jiang Yang, Jing Wang, M. Finšgar
{"title":"Corrosion Inhibition of Benzyl Quinoline Chloride Derivative-Based Formulation for Acidizing Process","authors":"Zhen Yang, Yefei Wang, Jiang Yang, Jing Wang, M. Finšgar","doi":"10.2118/218374-pa","DOIUrl":"https://doi.org/10.2118/218374-pa","url":null,"abstract":"Due to the severe and rapid corrosion of metallic equipment by strong acids at high temperatures, a high concentration of acidizing corrosion inhibitors (ACIs) is required during acidizing processes. There is always a need to develop more effective and environmentally friendly ACIs than current products. In this work, a highly effective ACI obtained from a novel main component and its synergistic effect with paraformaldehyde (PFA) and potassium iodide (KI) is presented. The ACI was prepared from the crude product of benzyl quinolinium chloride derivative (BQD) synthesized from benzyl chloride and quinoline in a simple way. The new ACI formulation, named “synergistic indolizine derivative mixture” (SIDM), which consists of BQD, PFA, and KI, showed superior corrosion inhibition effectiveness (IE) and temperature stability compared with commercially available ACI. More importantly, the SIDM formulation eliminates the need for commonly used highly toxic synergists (e.g., propargyl alcohol and As2O3). In a 20 wt% hydrochloric acid (HCl) solution, the addition of 0.5 wt% SIDM mitigates the corrosion rate of N80 steel down to less than 0.00564 lbm·ft−2 at 194°F, while the corrosion rate at 320 °F is 0.0546 lbm·ft−2·when 4.0 wt% SIDM is added.","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"8 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139301418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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