Supramolecular Chemistry最新文献_第7页

Supramolecular Assembly of a Terpyridyl based Binuclear Cu(II) Complex and its DNA Docking Study 三吡啶基双核Cu(II)配合物的超分子组装及其DNA对接研究

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-09-02 DOI: 10.1080/10610278.2022.2057228

Sanobar Naaz, R. A. Laskar, Sk Khalid Rahaman, S. Wabaidur, M. Siddiqui, M. Islam, Md. Maidul Islam, Mohammad Hedayetullah Mir, S. M. Alam

引用次数: 2

Aqueous compatibility of 15 pharmaceutical antimicrobial preservatives with the macrocycles cucurbit[7]uril and para-sulfonatocalix[4]arene 15种药物抗菌防腐剂与大环葫芦[7]脲和对磺托基[4]芳烃的水相容性

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-09-02 DOI: 10.1080/10610278.2022.2073823

Xenia L. Nastatos, Elissar Mansour, Alice Gu, N. Wheate

{"title":"Aqueous compatibility of 15 pharmaceutical antimicrobial preservatives with the macrocycles cucurbit[7]uril and para-sulfonatocalix[4]arene","authors":"Xenia L. Nastatos, Elissar Mansour, Alice Gu, N. Wheate","doi":"10.1080/10610278.2022.2073823","DOIUrl":"https://doi.org/10.1080/10610278.2022.2073823","url":null,"abstract":"ABSTRACT The compatibility of 15 antimicrobial preservatives used in liquid/semi-solid pharmaceutical dosage formulations with the macrocycles cucurbit[7]uril (CB[7]) and para-sulfonatocalix[4]arene (sCX[4]) was examined by 1H NMR. A preservative was deemed to be compatible with one, or both, of the macrocycles if there was no evidence of host-guest complex formation. Eight preservatives (benzoic acid, ethanol, glycerine, methyl paraben, potassium sorbate, propylene glycol, sodium ethylenediaminetetraacetic acid, and sodium metabisulfite) were determined to be compatible with both CB[7] and sCX[4]. Three preservatives (benzalkonium chloride, cetrimide, and chlorhexidine) were determined to be not compatible with either macrocycle, whereas chlorobutanol and chlorocresol were found to be compatible with sCX[4] but not with CB[7]. Phenoxyethanol was incompatible with sCX[4] but possibly incompatible with CB[7] depending on the concentration of the preservative used with the cucurbituril. Finally, sodium propanoate was compatible with sCX[4] but only possibly compatible with CB[7]. Graphical abstract","PeriodicalId":22084,"journal":{"name":"Supramolecular Chemistry","volume":"23 1","pages":"504 - 512"},"PeriodicalIF":3.3,"publicationDate":"2021-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84594151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

A novel thiosemicarbazide based chemosensor for colorimetric detection of Co2+ in commercial B12 vitamin and Co2+, Ni2+ simultaneously in aqueous media 一种新型硫脲基化学传感器，可同时比色检测商业维生素B12中的Co2+和水介质中的Co2+、Ni2+

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-09-02 DOI: 10.1080/10610278.2022.2085105

Nasibeh Azizi Khereshki, A. Mohammadi, H. Zavvar Mousavi, N. Alizadeh

引用次数: 5

Study on assembling compactness of amphiphilic calixarenes by fluorescence anisotropy 用荧光各向异性研究两亲杯芳烃的组装紧密性

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-09-02 DOI: 10.1080/10610278.2022.2087523

Han‐Wen Tian, Zhe Xu, Hua-Bin Li, Xin-Yue Hu, Dong‐sheng Guo

引用次数: 2

Chromogenic detection of fluoride, dihydrogen phosphate, and arsenite anions based on 2,4-dinitrophenyl hydrazine receptors: spectral and electrochemical study 基于2,4-二硝基苯肼受体的氟化物、磷酸二氢和亚砷酸阴离子的显色检测:光谱和电化学研究

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-09-02 DOI: 10.1080/10610278.2022.2087524

N. K, Ashutosh Kumar Singh, A. N. Shetty, Darshak R. Trivedi

{"title":"Chromogenic detection of fluoride, dihydrogen phosphate, and arsenite anions based on 2,4-dinitrophenyl hydrazine receptors: spectral and electrochemical study","authors":"N. K, Ashutosh Kumar Singh, A. N. Shetty, Darshak R. Trivedi","doi":"10.1080/10610278.2022.2087524","DOIUrl":"https://doi.org/10.1080/10610278.2022.2087524","url":null,"abstract":"ABSTRACT The colorimetric recognition of biologically relevant fluoride (F−), acetate (AcO−), and dihydrogen phosphate (H2PO4 −) ions, and poisonous arsenite (AsO2 −) ions, was devised and new receptors for these anions synthesised via the Schiff base condensation procedure. UV–visible titration, fluorescence titration, 1H-NMR titration, and cyclic voltammetry were used to explore the interactions of receptors R1–R3 with anions and possible detection mechanisms. The synthesised probes could sense inorganic fluoride, acetate, dihydrogen phosphate, and arsenite in the organo–aqueous medium (H2O/ Dimethylsulphoxide, 1: 9, v/v) and displayed a change in colour detectable to the naked eye. Out of the three synthesised receptors, receptor R1 showed better sensing ability of fluoride, acetate, dihydrogen phosphate, and arsenite ions in the organo–aqueous medium with a lower detection limit of 0.1 ppm, 0.171 ppm, 0.194 ppm, and 0.144 ppm, respectively. All three receptors formed complexes with the anions through H-bonding interaction followed by deprotonation of the NH proton. Graphical Abstract","PeriodicalId":22084,"journal":{"name":"Supramolecular Chemistry","volume":"22 1","pages":"534 - 549"},"PeriodicalIF":3.3,"publicationDate":"2021-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88804014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

C. David Gutsche 1921-2018 C. David Gutsche 1921-2018

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-08-03 DOI: 10.1080/10610278.2022.2041237

David N. Reinhoudt

引用次数: 0

Adsorption of calixarene-based supramphiphiles at the solid–liquid interface monitored by QCM-D QCM-D监测杯芳烃类超亲两性试剂在固液界面的吸附

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-08-03 DOI: 10.1080/10610278.2022.2047969

R. Migliore, G. Grasso, Paola Milana, Simona Cusmano, Giuseppina D G Santonoceta, C. Sgarlata

{"title":"Adsorption of calixarene-based supramphiphiles at the solid–liquid interface monitored by QCM-D","authors":"R. Migliore, G. Grasso, Paola Milana, Simona Cusmano, Giuseppina D G Santonoceta, C. Sgarlata","doi":"10.1080/10610278.2022.2047969","DOIUrl":"https://doi.org/10.1080/10610278.2022.2047969","url":null,"abstract":"ABSTRACT Supramolecular amphiphiles are a topic of widespread interest in supramolecular chemistry and the characterisation of their properties at the interfacesis at the basis of industrial and biotechnology applications. This work focuses on the determination of the adsorption features of supramolecular amphiphiles, formed by the host-guest complexation of a p-sulfonatocalix[4]arene with selected cationic surfactants, at the solid–liquid interface monitored by quartz crystal microbalance with dissipation monitoring (QCM-D) experiments. The adsorption process resulted to be favourite and strongly affected by the length of the surfactant alkyl chain and somehow by the nature of the polar head. The adsorption isotherms highlighted the key role played by the calixarene scaffold in the CMC value, the amount of material absorbed and the efficiency of the adsorption process on a gold substrate. Furthermore, the kinetic profiles provided significant insights on the different mechanisms of adsorption undergone by either conventional or supramolecular amphiphilic systems. Graphical abstract","PeriodicalId":22084,"journal":{"name":"Supramolecular Chemistry","volume":"24 1","pages":"475 - 486"},"PeriodicalIF":3.3,"publicationDate":"2021-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77984932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Recent advances in the fluorescent and colorimetric detection of dihydrogen phosphate 磷酸二氢荧光和比色法检测的最新进展

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-08-03 DOI: 10.1080/10610278.2022.2035387

N. K, A. N. Shetty, Darshak R. Trivedi

引用次数: 2

Protonation–deprotonation dynamics of 2-(4’-pyridyl) benzimidazole derivative with cucurbit[6]uril at two different pH 2-(4′-吡啶基)苯并咪唑衍生物与葫芦[6]脲在两种不同pH下的质子-去质子动力学

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-08-03 DOI: 10.1080/10610278.2022.2043550

Vijaykant Khorwal, Riya Kathuria

引用次数: 1

Sulfated-β-cyclodextrin templated aggregation of a metachromatic dye, Basic Orange 21: A photophysical investigation 硫酸盐-β-环糊精模板化的异色染料碱性橙21的聚集:光物理研究

IF 3.3 4区化学

Supramolecular Chemistry Pub Date : 2021-08-03 DOI: 10.1080/10610278.2022.2046277

G. Singh, V. R. Singh, Shrishti P. Pandey, Prabhat K. Singh

{"title":"Sulfated-β-cyclodextrin templated aggregation of a metachromatic dye, Basic Orange 21: A photophysical investigation","authors":"G. Singh, V. R. Singh, Shrishti P. Pandey, Prabhat K. Singh","doi":"10.1080/10610278.2022.2046277","DOIUrl":"https://doi.org/10.1080/10610278.2022.2046277","url":null,"abstract":"ABSTRACT The recently discovered molecular rotor and supravital dye, Basic Orange-21 (BO21), has shown improved differential counting of leukocytes through metachromasia (change in colour), which is believed to be due to the aggregation of chromophores. Thus, investigation on the aggregation behaviour of BO21 holds special importance and may help us to delineate its spectroscopic behaviour. In this contribution, we have investigated the photophysical behaviour of BO21 in presence of a negatively charged supramolecular host, sulfated-β-cyclodextrin (SC), using ground-state absorption, steady-state and time-resolved emission spectroscopy including ultrafast fluorescence spectroscopy, and molecular docking calculations. The spectral characteristics of BO21 display extreme modulations in presence of SCD, with features similar to that observed for BO21 during its metachromatic behaviour. These spectroscopic features have been rationalised in terms of aggregation of BO21 molecules in the vicinity of SCD, which are also extremely sensitive to external stimuli, such as, ionic strength and temperature of the medium. Graphical abstract","PeriodicalId":22084,"journal":{"name":"Supramolecular Chemistry","volume":"15 4","pages":"460 - 474"},"PeriodicalIF":3.3,"publicationDate":"2021-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72404427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3