IJCA (Indonesian Journal of Chemical Analysis)最新文献

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The Identification of Acetic Acid-Ethanol Mixture Using Gas Sensor Array and Ensemble Regression 利用气体传感器阵列和集合回归识别醋酸-乙醇混合物
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art1
S. Suprapto, Y. Ni'mah, Harmami Harmami, I. Ulfin, Annisa Ardiyanti
{"title":"The Identification of Acetic Acid-Ethanol Mixture Using Gas Sensor Array and Ensemble Regression","authors":"S. Suprapto, Y. Ni'mah, Harmami Harmami, I. Ulfin, Annisa Ardiyanti","doi":"10.20885/ijca.vol7.iss1.art1","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art1","url":null,"abstract":"Identification of acetic acid-ethanol mixtures using a commercial gas sensor array equipped with ensemble regression has been carried out. The gas sensor analysis was simple, rapid, and fast since it did not require any sample preparation. A quantitative analysis of the acetic acid-ethanol mixture was carried out to determine the sensitivity and selectivity of the sensor in distinguishing the concentration of the acetic acid and ethanol mixture. This study focuses on the coefficient of determination of 80% of the calibration data set and recovery of 20% of the testing data set. The models showed excellent performance,specifically, the Bagging and Random Forest r2 for the ethanol calibration data reached 0.91 and 0.94, respectively. The corresponding ethanol test recoveries were 99.95% and 97.84%, indicating the robustness of the model in accurately predicting ethanol concentration. Acetic acid test recoveries were 100.56% and 101.38% with r2 of 0.89 and 0.93 for Bagging and Random Forest regression, respectively. Hence, the commercial gas sensor array equipped with ensemble regression can be applied to the quantification of the acetic acid – ethanol mixture and demonstrate opportunities for the practical use of this gas sensor array in analyzing real samples, i.e. human breath or environmental monitoring samples.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"15 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140359122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Implementing Biodigester Technology for Sustainable Waste Management in Mojokerto City, Indonesia 印度尼西亚 Mojokerto 市采用生物发酵池技术实现可持续废物管理
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art6
Mega Mutiara Sari, A. Afifah, W. K. Suryawan
{"title":"Implementing Biodigester Technology for Sustainable Waste Management in Mojokerto City, Indonesia","authors":"Mega Mutiara Sari, A. Afifah, W. K. Suryawan","doi":"10.20885/ijca.vol7.iss1.art6","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art6","url":null,"abstract":"Mojokerto City, located in East Java, grapples with a steadily rising waste generation trend accentuated by the COVID-19 pandemic. Drawing data from the National Waste Management Information System (SIPSN) and supplemented with an exhaustive literature review, this study scrutinizes the potential of biodigester technology as a solution to this mounting challenge. Mojokerto's waste, consistent in its composition from 2019 to 2022, is dominated by food waste, making it an ideal candidate for biodigester intervention. The study revealed that existing biodigester facilities in Mojokerto vary in their waste reduction efficiencies yet collectively demonstrate the viability of converting food waste to energy. For instance, the TPS 3R Magersari Berseri facility showcased an impressive waste reduction rate of 85.0%, processing 62.05 tons out of 73 tons of waste received annually. Comparative analyses of other facilities like TPS 3R Pulorejo \"Cahaya Berseri\" and TPS 3R Muria Berseri were also conducted, revealing varying degrees of efficiency. These facilities underscore the potential of biodigester technology in managing the rising tide of waste and contributing to sustainable energy generation. The findings of this study also call for increased awareness about food conservation, improved waste segregation at the source, and the promotion of composting and other organic waste processing methods, thereby optimizing the overall efficiency of waste management in the city.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"19 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140358570","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Detection of Microplastics and Heavy Metals in Famous Edible Molluscs in Can Gio Biosphere Reserve of Vietnam 越南 Can Gio 生物圈保护区著名食用软体动物中的微塑料和重金属检测
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art10
Vo Thi Kim Khuyen, O. T. T. Kim
{"title":"Detection of Microplastics and Heavy Metals in Famous Edible Molluscs in Can Gio Biosphere Reserve of Vietnam","authors":"Vo Thi Kim Khuyen, O. T. T. Kim","doi":"10.20885/ijca.vol7.iss1.art10","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art10","url":null,"abstract":"Can Gio, designated in 2000, is the first Biosphere Reserve of Vietnam. In recent years, local agriculture, tourism, households, nearby industrial zones, and maritime transport have released substances into rivers flowing through Can Gio Mangrove to the East Sea and transported into creatures. This study aims to investigate microplastics and heavy metals in the famous seafood of Can Gio. A Raman microscope was used to identify microplastics from the tissue of oysters, grease snails, and clams after enzymatic treatment with trypsin. Heavy metals were quantified with ICP-MS after acidic treatment. As a result, microplastics were found in almost all samples, even up to 10 in a random individual of bivalve. Fibers dominated, especially from 30 to 150 µm long. The metal with the highest content was zinc, followed by copper, especially in oysters. Non-essential metals were also present in the soft tissue in the order As > Pb > Cd. The accumulation of metals in Can Gio’s molluscs was generally lower than in other regions and still in the allowed range for consumption of Vietnamese Standard. Although there have not been any Vietnamese regulations on the permissible level of microplastics for consumption, regular seafood intake will increase the risk of chronic poisoning and unknown disorders caused by the accumulation of microplastics and heavy metals.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"5 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140359424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In Vitro Activity of Ethanol Extract of Rimbang Fruit (Solanum ferox) as an Active Ingredient in Sunscreen Preparations 作为防晒制剂活性成分的 Rimbang 果实(Solanum ferox)乙醇提取物的体外活性
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art8
Septaria Yolan Kalalinggi, Rasidah Rasidah, Y. Yuliana
{"title":"In Vitro Activity of Ethanol Extract of Rimbang Fruit (Solanum ferox) as an Active Ingredient in Sunscreen Preparations","authors":"Septaria Yolan Kalalinggi, Rasidah Rasidah, Y. Yuliana","doi":"10.20885/ijca.vol7.iss1.art8","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art8","url":null,"abstract":"Solanum ferox is a typical Central Kalimantan plant widely used by Dayak’s community as a vegetable. The study aims to determine the ethanol extract of sour eggplant activities by measuring its SPF in vitro and identifying secondary metabolite contents. The sour eggplant is extracted by maceration using 96% ethanol solvent and then bound with an evaporator. The secondary metabolite groups of ethanol extract were identified using phytochemical screening. The identification results indicate the presence of flavonoid, terpenoid, steroid, and phenolic compounds. Then, the ethanol extract was fractionated with a water solvent, and its functional cluster was identified using the IR spectrum. IR spectral identification results indicate the presence of OH, C-O, C=C olefin, C -O ether, and aliphatic CH functional groups. (CH2 and CH3) SPF values were determined by measuring the absorption of ethanol and water extracts in vitro using UV-Vis spectrophotometry at UV-B wavelengths of 290-320 nm. In vitro testing has been conducted as a preliminary test in developing a sunscreen product (active substance). The SPF values of ethanol extract and water from weighted fruit extract in sequence are 40 and 23 at a 10% concentration with ultra-category.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"18 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140359649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Role of Zeolite (Microporous Crystalline Aluminosilicates) In Catalytic Pyrolysis of Waste High- and Low-Density Polyethylene Bags for Production of Fuel and Chemicals: A Review 沸石(微孔结晶铝硅酸盐)在催化热解废弃高密度和低密度聚乙烯袋生产燃料和化学品中的作用:综述
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art9
U. M. Jibreel, Amina Salihi Bayero, usa Ibrahim Mohamaed, Bashir Audu Muzakkari
{"title":"The Role of Zeolite (Microporous Crystalline Aluminosilicates) In Catalytic Pyrolysis of Waste High- and Low-Density Polyethylene Bags for Production of Fuel and Chemicals: A Review","authors":"U. M. Jibreel, Amina Salihi Bayero, usa Ibrahim Mohamaed, Bashir Audu Muzakkari","doi":"10.20885/ijca.vol7.iss1.art9","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art9","url":null,"abstract":"This review provides a state-of-the-art summary of the role which zeolite plays as a catalyst via pyrolysis as a way of recovering fuels and chemicals from waste high and or low density polyethylene bags. It also highlighted the two types of zeolite (natural or synthetic) which are used as a two-stage pyrolysis−catalysis in giving a free waxing product to pure fuel and chemicals which can be subjected to further analyzing and or upgrading. As yield of oil/wax decreased with the addition of a zeolite as catalyst from 44 and 51 wt.%, (depending on the waste high density polyethylene “HDPE” or low density polyethylene bags “LDPE” and other factors). However, the composition of the pyrolysis−catalysis oils significantly increased in aromatic hydrocarbon content accordingly. In addition, the composition of the oils shifted from high molecular weight hydrocarbons (C16+) to fuel range hydrocarbons (C5−C15), with a high content of single-ring aromatic hydrocarbons such as benzene, toluene, ethylbenzene, xylenes, and styrene. This process shows great potential for production of fuels or chemicals, and also addresses the urgent issue of waste HDPE and or LDPE disposal.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"24 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140359883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption of Remazol Blue And Indigosol Yellow Mixed Dyes Using Bidara Arab Leaves (Ziziphus spina-christi) 利用阿拉伯比达拉叶(Ziziphus spina-christi)吸附雷马唑蓝和靛蓝混合染料
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art3
Mega Kurnia, S. Suprapto, atim Lailun Ni'mah
{"title":"Adsorption of Remazol Blue And Indigosol Yellow Mixed Dyes Using Bidara Arab Leaves (Ziziphus spina-christi)","authors":"Mega Kurnia, S. Suprapto, atim Lailun Ni'mah","doi":"10.20885/ijca.vol7.iss1.art3","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art3","url":null,"abstract":"In this study, the adsorption of Remazol Blue and Indigosol Yellow using Bidara Arab leaves (Ziziphus spina-christi) as adsorbents was investigated through batch adsorption. The experimental parameters included contact time, adsorbent mass, initial concentrations, and pH. UV-Vis spectrophotometer was employed to measure the adsorption results at the maximum wavelength of each dye. The research was conducted in triplicate, and a t-test, \"Paired Two Sample for Means\", with a standard deviation <2% was employed for statistical analysis. Optimal adsorption conditions were achieved at a contact time of 45 minutes, an adsorbent mass of 45 mg, an initial concentration of 30 ppm, and a pH of 3. The results indicated that Bidara Arab leaves effectively reduced the concentration of the mixed dyes with %decoloration up to 99,79% on Remazol Blue and 99,50% on Indigosol Yellow.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"17 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140358746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Detection of Adulterants Metanil Yellow in Turmeric Powder Using Fourier Transform Infrared (FTIR) Spectroscopy Combined with Chemometrics OPLS-DA and PLS 利用傅立叶变换红外光谱(FTIR)结合化学计量学 OPLS-DA 和 PLS 检测姜黄粉中的掺假物质 Metanil Yellow
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art7
Syahril Maulid Dia, Anggita Rosiana Putri, Luthfi Ahmad Muchlashi
{"title":"Detection of Adulterants Metanil Yellow in Turmeric Powder Using Fourier Transform Infrared (FTIR) Spectroscopy Combined with Chemometrics OPLS-DA and PLS","authors":"Syahril Maulid Dia, Anggita Rosiana Putri, Luthfi Ahmad Muchlashi","doi":"10.20885/ijca.vol7.iss1.art7","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art7","url":null,"abstract":"Turmeric powder (Curcuma longa L.) is often used for food coloring and flavoring. The high demand for turmeric powder has led to adulteration, one of which is metanil yellow. This study aims to detect metanil yellow dye in turmeric powder using Infrared Spectroscopy (FT-IR) and Chemometrics. The chemometrics model was built by preparing turmeric powder and metanil yellow in the concentration range of 0-50% (w/w). Data was processed using multivariate calibration using OPLS-DA (Orthogonal Partial Least Squares Discriminant Analysis) and PLS (Partial Last Square). The results obtained from OPLS-DA processing of market samples 1 and 2 are estimated to be pure turmeric powder, and samples 3 to 10 are adulterated. From the PLS results, the best calibration model was obtained at wave numbers 1199-539 cm-1 with R2 values for calibration and validation of 0.9967 and 0.9970, respectively, with RMSEC of 2.48 and RMSEP of 6.35. The PLS results showed that in sample 3 containing metanil yellow, in samples 4 to 10, no metanil yellow was detected. The ingredients added were not metanil yellow. It was concluded that FTIR combined with chemometrics could detect the metanil yellow in turmeric powder.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"40 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140357658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Determination of Ethanol in Vinegar and Beverage by Gas Chromatography: A Validated Method for Halal Verification 用气相色谱法测定醋和饮料中的乙醇:用于清真验证的有效方法
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art5
Yulirohyami Yulirohyami, Aprisilia Risky Wijaya, Yorfan Ruwindya
{"title":"Determination of Ethanol in Vinegar and Beverage by Gas Chromatography: A Validated Method for Halal Verification","authors":"Yulirohyami Yulirohyami, Aprisilia Risky Wijaya, Yorfan Ruwindya","doi":"10.20885/ijca.vol7.iss1.art5","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art5","url":null,"abstract":"Validation of the method for determining ethanol in vinegar and beverages has been carried out in the linearity range of 0.05-1% using GC-FID. This research was carried out using an internal standard solution and without an internal standard solution. The research aims to validate the linearity of ethanol determination at low concentration levels. This validation is useful to ensure that the ethanol test method in the sample can be detected at low concentration levels. In the halal authentication process, the maximum limit for ethanol content is 5%. The method validation results confirm that in the concentration range 0.05-1% it has good linearity with a correlation coefficient (R) without the addition of internal standards and with the addition of standard solutions being 0.9972 (R2=0.9943) and 0.9952 (R2=0.9905). The results of the analysis of variance (ANOVA) test with a 95% confidence interval and 9 degrees of freedom F-count (0.0141) < F-critical (0.3146) show that the range 0.05-1% corresponds to the limit of linearity. The results of the ANOVA test with a 95% confidence interval with df=6 show the F-test value (0.0879) < F-critical (0.2334) indicating that the two proposed methods have high precision and no significant differences. Both methods also have high accuracy and no significant differences in accuracy as shown by the results of the ANOVA test with a 95% confidence interval and degrees of freedom = 6 showing the F-test value (1.5204) < F-critical (4.2839). It is recommended that the results of this validation be useful in the halal verification process for vinegar and beverage products.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"13 23","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140358623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green-AgNPs modified membrane for monitoring mercury ions in cosmetic sample using pre-concentration assisted voltammetry technique 利用预浓缩辅助伏安法技术监测化妆品样品中汞离子的绿色-AgNPs 改性膜
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art4
G. Fadillah, Eka Nurdina Inayatussholeha, Rahmat Hidayat
{"title":"Green-AgNPs modified membrane for monitoring mercury ions in cosmetic sample using pre-concentration assisted voltammetry technique","authors":"G. Fadillah, Eka Nurdina Inayatussholeha, Rahmat Hidayat","doi":"10.20885/ijca.vol7.iss1.art4","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art4","url":null,"abstract":"The carcinogenic and teratogenic properties of mercury have driven the necessity for the development of highly sensitive methods capable of detecting even trace amounts of the element. In response to this need, an analysis technique has been established for mercury ions, employing preconcentration methods utilizing filter paper modified by silver nanoparticles (AgNPs) and 3-Amino propyl trimethoxy silane (APTMS). This method allows for the detection of mercury ions through the voltammetry technique, ensuring accurate and reliable results. Upon conducting analyses using this method, it was found that the tested cosmetic samples were free from Hg2+ ions, indicating the absence of mercury contamination in the cosmetics under investigation. The correlation coefficient derived from the graph of the analysis results stands at an impressive value of 0.9976, affirming the strong relationship between the measured concentrations and the actual mercury content. Additionally, the method demonstrates excellent sensitivity, as evidenced by the low limit of detection (LOD) value of 0.0483 mM and the limit of quantification (LOQ) value of 0.1611 mM.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"28 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140359022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption of Cadmium (II) Ions Using Cassava Peel Activated Carbon: Study of Adsorption Kinetics, Isotherms and Thermodynamics 木薯皮活性炭对镉(II)离子的吸附:吸附动力学、等温线和热力学研究
IJCA (Indonesian Journal of Chemical Analysis) Pub Date : 2024-03-31 DOI: 10.20885/ijca.vol7.iss1.art2
Tri Ariyanto Nugroho, C. A. Riyanto, ovember Rianto Aminu
{"title":"Adsorption of Cadmium (II) Ions Using Cassava Peel Activated Carbon: Study of Adsorption Kinetics, Isotherms and Thermodynamics","authors":"Tri Ariyanto Nugroho, C. A. Riyanto, ovember Rianto Aminu","doi":"10.20885/ijca.vol7.iss1.art2","DOIUrl":"https://doi.org/10.20885/ijca.vol7.iss1.art2","url":null,"abstract":"Heavy metals Cd2+ is a dangerous pollutant of water and ecological systems if it is above the quality standard threshold. Cassava peel has a fairly high carbon element content, namely 59,31%, so it can be used as an activated carbon to break down Cd2+ metals ions in water. This research aims to determine kinetic modeling and adsorption isotherms of Cd2+ ions using CPAC activated by H3PO4, determine the optimum pH and temperature conditions for Cd2+ ion adsorption and determine the adsorption capacity of Cd2+ ions using CPAC activated by H3PO4. CPAC is made through a carbonization process at a temperature of 500 °C for 1 hour. Next, it was impregnated with H3PO4 at a concentration of 30 % with a ratio of 1:5 (w/w) for 24 hours and physically activated at a temperature of 600 °C for 1 hour. Based on research, kinetic modeling and adsorption isotherms of Cd2+ ions using CPAC activated by H3PO4 following Pseudo-Second-Order (PSO) kinetic modeling and Freundlich isotherm, the optimum pH and temperature conditions for Cd2+ ion adsorption were obtained at pH 5 and temperature 25 °C. Thermodynamic parameters such as Gibbs energy (∆G°), enthalpy (∆H°), and entropy (∆S°), have been evaluated and indicate physical, spontaneou, and exothermic adsorption processes. The adsorption capacity of Cd2+ ions using CPAC activated by H3PO4 is 5.2219 mg/g.","PeriodicalId":215410,"journal":{"name":"IJCA (Indonesian Journal of Chemical Analysis)","volume":"7 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140359333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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