Progress in Organic Coatings最新文献

{"title":"High performing biocompatible solvent-free pressure-sensitive adhesives derived from acrylated epoxidized linseed oil","authors":"Manjinder Singh ,&nbsp;Siddhartha D. Pramanik ,&nbsp;Aparna S ,&nbsp;Sushanta K. Sahoo ,&nbsp;Partha Roy ,&nbsp;Gaurav Manik","doi":"10.1016/j.porgcoat.2025.109383","DOIUrl":"10.1016/j.porgcoat.2025.109383","url":null,"abstract":"<div><div>A solvent-free method for developing green pressure-sensitive adhesives offers biocompatibility, non-toxicity, cost reduction, and sustainability, positioning it as a superior alternative to conventional PSAs. Herein, epoxy groups were introduced into the linseed oil backbone by epoxidation and further functionalized by acrylic acid mediated ring opening to form acrylated epoxidized linseed oil (AELO) with ∼62.3 % biomass and ∼84 % renewable content. Thereafter, synthesized low <em>T</em>_<em>g</em> monomer was copolymerized with methyl methacrylate (MMA) in different molar ratio via solvent-free approach to obtain bio-based PSAs. The chemical analysis confirms the successful polymerization of PSAs, which are thermally stable and exhibit single glass transition temperatures ranging from – 44 to – 23 °C, desired for a commercially performing PSA. The storage modulus values met the Dahlquist criterion and viscoelastic window lies in removable PSAs category. The maximum peel strength of 3.58 N/in. and tackiness of 5.05 N were obtained by PSA 1/1 (AELO: MMA = 1:1 M ratio), whereas static shear strength of 711 min by PSA 1/3, which were found superior to commercially available medical tapes and food labels. The developed PSA 1/1 exhibits 58.1 % biomass content, &gt;90 % HaCaT cell viability at 100 mg/ml, superior biodegradability (41 % weight loss in 15 days), and enhanced antimicrobial activity with a 7 mm inhibition zone against <em>E. coli</em> ATCC 25922. The reported synthesis strategy and developed AELO-based PSAs pave the way for sustainable framework and motivating a paradigm shift towards green PSAs in multiple industry sectors spanning food packaging and pharmaceuticals.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109383"},"PeriodicalIF":6.5,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144166287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly efficient photothermal self-healing wear-resistant and anti-corrosion coating reinforced by CF@PDA@Cu2O nanocomposite","authors":"Xin Wang ,&nbsp;Xinwei Zhang ,&nbsp;Yunfei Ma ,&nbsp;Wen Li ,&nbsp;Wei Wang ,&nbsp;Jie Zhu ,&nbsp;Shougang Chen","doi":"10.1016/j.porgcoat.2025.109393","DOIUrl":"10.1016/j.porgcoat.2025.109393","url":null,"abstract":"<div><div>Corrosion in the marine splash zone is severe, with coating protection serving as the most commonly used method for corrosion prevention. Polyurethane (PU) coatings have garnered significant attention due to their strong corrosion resistance and controllable properties. However, during research and application, these coatings have exposed drawbacks such as susceptibility to damage and high maintenance costs upon damage, thereby limiting their scope of use. Carbon fibers exhibit excellent mechanical properties but suffer from low surface energy, necessitating modification with polydopamine (PDA), which also exhibits photothermal effects. Cuprous oxide (Cu₂O) possesses outstanding photothermal performance. Therefore, carbon fiber-based photothermal fillers compounded with PDA and Cu₂O were constructed to enhance the mechanical and photothermal properties of PU coatings. Compared to pure PU coatings, PU coatings with the addition of these carbon fiber-based photothermal fillers can self-repair damaged areas within 120 s. In friction and wear tests, the coefficient of friction for pure PU coatings was 0.212, whereas the coefficient for the filler-added coatings was 0.125. The corrosion resistance of the filler-added coatings reached 10⁹ Ω·cm² and remained at this level even after immersion for 90 days. Molecular dynamics studies were performed to clarify the reason why PDA enhances the dispersion of CF inside PU and enhances the coating performance.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109393"},"PeriodicalIF":6.5,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144139776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Amphiphilic materials for advanced antifouling and anticorrosion coatings","authors":"Mintra Muadtrap ,&nbsp;Raweewan Thiramanas ,&nbsp;Daniel Crespy","doi":"10.1016/j.porgcoat.2025.109391","DOIUrl":"10.1016/j.porgcoat.2025.109391","url":null,"abstract":"<div><div>Biofouling, the accumulation of microorganisms on submerged surfaces, poses significant challenges to the environment and human activities. The widespread use of toxic antifouling coatings, such as those containing tributyltin, has led to their progressive ban worldwide due to environmental concerns. As a promising alternative, polymer-based antifouling coatings have gained attention due to their affordability, non-toxicity, biocompatibility, and ease of production. We focus here on the research progress in environmentally friendly amphiphilic antifouling coatings, focusing on silicone-based coatings, fluoropolymer-based coatings, PEG-based coatings, and zwitterionic coatings. Emphasis is placed on synthetic strategies, structural design principles, and functional properties that enhance antifouling performance. Consolidating current advancements and addressing challenges are serving researchers and industry professionals striving to develop innovative, sustainable antifouling solutions for diverse applications.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109391"},"PeriodicalIF":6.5,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144147920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dynamically omniphobic and highly transparent polyurethane coating towards efficient self-cleaning on photovoltaic modules","authors":"Jianwen Peng ,&nbsp;Peng Ye ,&nbsp;Xinyu Bu ,&nbsp;Yue Zhang ,&nbsp;Yanji Zhu ,&nbsp;Ruitao Wang ,&nbsp;Di Bao ,&nbsp;Huaiyuan Wang","doi":"10.1016/j.porgcoat.2025.109394","DOIUrl":"10.1016/j.porgcoat.2025.109394","url":null,"abstract":"<div><div>Photovoltaic (PV) modules have become a powerful contributor to global CO₂ emissions mitigation, but have suffered a significant loss in power generation efficiency caused by the deposition of surface contamination. Conventional self-cleaning coatings typically require laborious fabrication processes, elaborate texturing, and fluorinated materials, which are difficult to integrate with transparency, environmental compatibility, and adaptability. Herein, we show a highly transparent, fluorine-free, and dynamically omniphobic liquid-like polyurethane coating (LLPuC) prepared by well cross-linking between polydimethylsiloxane (PDMS)-grafted hydroxyacrylate (P_xHA_y) copolymer and polyisocyanate at elevated or room temperature. The LLPuC could be applied to various substrates by spraying or blading methods and has demonstrated good transparency (91.79 % at 550 nm) of the coated glass. The liquid-like flexible chains of PDMS were enriched on the LLPuC and moved spontaneously, resulting in a smooth surface with dynamic omniphobicity (WSA = 11.5 ± 0.6°, OSA ≤ 15°), anti-smudge, and self-cleaning capability, as evidenced by the LLPuC coated PV module achieving a 92.83 % efficiency recovery ratio after the self-cleaning process. Moreover, the obtained coating also exhibited good adhesion strength, flexibility, anti-abrasion, and stability. Thus, the approaches and findings in this work have opened up a new avenue for self-cleaning coatings of PV modules and various outdoor transparent devices.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109394"},"PeriodicalIF":6.5,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144116763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced barrier properties of bagasse paperboard for food packaging applications using shellac coating – Effect of concentration and number of layers","authors":"Purva Khule ,&nbsp;Guanqi Lu ,&nbsp;Qiang Yang ,&nbsp;Randolph Beaudry ,&nbsp;Eva Almenar","doi":"10.1016/j.porgcoat.2025.109395","DOIUrl":"10.1016/j.porgcoat.2025.109395","url":null,"abstract":"<div><div>Fiber-based packaging is a sustainable approach for food packaging. To maintain biodegradability and economic viability, coatings used for improving barrier properties of fiber-based materials should be environmentally friendly, biodegradable and inexpensive. Shellac, a natural and biodegradable polyacid resin with good film-forming properties and hydrophobicity, has been widely studied as a film, however, information on shellac as coating for fiber-based materials is limited to its blend with additives or biopolymers and its application as a single layer. This study investigated the effects of shellac layer number and concentration on shellac-coated bagasse paperboard (BP) properties pertinent to food packaging applications. Shellac solution at different concentrations (24, 40, 60 %) was applied on BP in differing numbers of layers (1–4) using the bar coating technique. The different shellac-coated BPs were characterized for water vapor permeability (WVP), oxygen permeability (OP), water absorbency (Cobb60), thickness, coating weight, chemical structure, morphology, and mechanical and thermal properties. The results showed that the BP coated with two 40 % shellac-layers (0.03 mm and 9.6 % in dry weigh) had the lowest WVP (1.3 × 10⁻¹² kg m m⁻² s⁻¹ Pa⁻¹), OP (3.8 × 10⁻¹⁴ kg m m⁻² s⁻¹ Pa⁻¹), and Cobb60 (0.004 g m⁻²) resulting in an 82.2 %, 99.5 %, and 97.5 % improvement in water barrier, oxygen barrier, and resistance to absorb water over the uncoated BP. This shellac coating also improved the thermal resistance of BP and did not affect its mechanical properties. Therefore, the interplay between shellac layer number and concentration can improve the properties of shellac-coated BP and thus, the performance of BP for food packaging as demonstrated by food shelf-life simulation.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109395"},"PeriodicalIF":6.5,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144116764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Harnessing metal-free click chemistry: phosphorus and triazole synergy for improved flame retardant epoxy thermosets","authors":"Irem Gunderen ,&nbsp;Oguzhan Aslanturk ,&nbsp;Gokhan Sagdic ,&nbsp;Emrah Çakmakçı ,&nbsp;Tugce Demirel ,&nbsp;Mustafa E. Üreyen ,&nbsp;Ufuk Saim Gunay ,&nbsp;Hakan Durmaz ,&nbsp;Volkan Kumbaraci","doi":"10.1016/j.porgcoat.2025.109396","DOIUrl":"10.1016/j.porgcoat.2025.109396","url":null,"abstract":"<div><div>The synthesis of novel and effective flame retardants for epoxy resins is an attractive area of research. The use of modern chemical tools for this purpose is highly intriguing. In this work, three novel flame retardants (FRs) containing phosphorus and triazole units were synthesized using metal-free azide-alkyne click chemistry. The FRs were designed to have different N/P ratios. The synthesized FRs were characterized using conventional spectroscopic methods. The FRs were added at various ratios to an epoxy resin, and the obtained resins were thermally cured. The thermosets' thermal and flame retardancy properties were characterized. The thermal degradation temperatures of the FR-containing epoxy thermosets were reduced to lower temperatures, but the char yields increased compared to the neat resin. Combining the triazole units and the phosphorus-containing groups led to superior flame retardancy. The limiting oxygen index (LOI) value of the thermosets was found to be as high as 42.0 ± 0.3 %. Micro combustion calorimeter (MCC) test results of the FR-containing samples showed significant reductions in the peak heat release rate values (pHRR) compared to that of the neat epoxy resin. All the FR-containing thermosets were rated as V-0 according to the UL-94 test. Furthermore, owing to the presence of N and P, intumescent behavior was observed. The significant flame retardant action of the synthesized FRs is attributed to the formation of dense intumescent chars upon combustion and to the synergistic effect of the P- and N-containing species in the gas phase, which capture free radicals and dilute the gas phase.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109396"},"PeriodicalIF":6.5,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144106393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrosion protection of mild steel by protonated and sodiated nafion in epoxy coatings","authors":"Mohammad Redza Hussin ,&nbsp;Ukashat Mamudu ,&nbsp;Muhammad Raziq Rahimi Kooh ,&nbsp;Jose Hernandez Santos ,&nbsp;Ren Chong Lim","doi":"10.1016/j.porgcoat.2025.109347","DOIUrl":"10.1016/j.porgcoat.2025.109347","url":null,"abstract":"<div><div>We explored the anti-corrosion performance of epoxy coatings with Nafion in protonated form (HNE) and sodiated form (NaNE) and compared their characteristics with epoxy-only coating. The successful conversion of the H-Nafion to Na-Nafion was observed by fourier transform infrared (FTIR) spectroscopy, where the shift at the peak 1060 cm⁻¹ and disappearance of the peak at 969 cm⁻¹ were observed after the sodiating process. Mild steel substrates were coated with HNE and NaNE by spray gun and were immersed in 3.5 wt% NaCl solution for 2, 15, and 20 days. X-ray diffraction spectroscopy showed corrosion products due to uniform corrosion were observed in one of the HNE samples, but not in any of the NaNE samples. However, the lack of corrosion products arising from chloride attacks on the HNE and NaNE samples indicated their ability to repel chloride ions. The electrochemical impedance spectroscopy analyses showed that the NaNE and HNE samples with 2 wt% of Na-Nafion and H-Nafion, respectively, produced the highest coating protection efficiency of 99.9 %. Finally, we proposed a mechanism for the corrosion protection of the HNE and NaNE coatings against uniform corrosion and chloride ion penetration.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109347"},"PeriodicalIF":6.5,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144105913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A review on multi-functional polyurethane (PU) coatings for fabric applications: Materials, processes and recent developments","authors":"Amar Srivastava ,&nbsp;Subhankar Maity ,&nbsp;Biswa Ranjan Das","doi":"10.1016/j.porgcoat.2025.109377","DOIUrl":"10.1016/j.porgcoat.2025.109377","url":null,"abstract":"<div><div>In the textile sector, polyurethane (PU) has become a crucial polymeric material for functional coatings, allowing for multipurpose improvements including germicidal, flame retardant, water repellent, ballistic and UV protection. These multifunctional PU coatings are typically applied onto various textile substrates using methods such as dip coating, knife coating, transfer coating, etc., ensuring uniform add-on and controlled thickness. Recently, waterborne PU (WPU) offers a sustainable alternative due to their low volatile organic compound (VOC) emissions and superior performance characteristics. The incorporation of various additives like TiO₂ nanoparticles, flame-retardant chain extenders, nanometals, fluorocarbon, silicone and UV absorbers develops and enhances multifunctional properties like antibacterial effect (&gt;90 % efficiency even after 30 washes), UV protection (UPF &gt; 50+), water repellency (exhibiting contact angles exceeding 140°), fire resistance (limiting oxygen index (LOI) &gt; 29.4 %), thermal stability, ballistic protection etc. This article summarizes chemistry of all these kinds of PUs, latest advancements in these coating technologies, achieved multi-functional properties, performances, and potential applications.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109377"},"PeriodicalIF":6.5,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144116765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of mechanically robust, self-healing superhydrophobic coatings based on novel fluorinated polyurethane via a “two-step” polycondensation process for applications in self-cleaning and anti-icing","authors":"Zhanbo Wang,&nbsp;Jiahui Mei,&nbsp;Minghua Liu,&nbsp;Chaocan Zhang","doi":"10.1016/j.porgcoat.2025.109385","DOIUrl":"10.1016/j.porgcoat.2025.109385","url":null,"abstract":"<div><div>The demand for superhydrophobic coatings has been rapidly increasing, extending from applications in surface antifouling to surface anti-icing and self-cleaning, driving active exploration into mechanically robust superhydrophobic coatings. Fluorinated polyurethane (FPU) is considered a promising candidate for superhydrophobic coatings. However, most FPU-based superhydrophobic coatings exhibit limited adhesion to substrates and rely on nano-SiO₂ or nanoparticles to construct micro-nano hierarchical rough surfaces. However, it has been demonstrated that the rough surfaces created by nanoparticles reduce the effective contact area between the coating and the substrate, leading to accelerated wear of the coatings. Furthermore, to ensure the durability of superhydrophobic coatings, self-healing properties must also be considered. However, most self-healing superhydrophobic coatings developed so far require prolonged high-temperature conditions or external stimuli to restore their superhydrophobicity. Therefore, developing mechanically robust superhydrophobic coatings with self-healing capabilities remains a significant challenge. In this study, we synthesized a novel fully waterborne and self-healing FPU coating using a “two-step” polycondensation method. Even on the smoothest and hardest glass substrates, the coating retained its superhydrophobicity after 200 cycles of sandpaper abrasion, 200 cycles of tape peeling, a 6-hour water droplet test and acid-base resistance tests, outperforming most previously developed superhydrophobic coatings. Additionally, the coating exhibits excellent self-healing functionality. This allowed the coating to self-heal a 100 μm scratch and restore its superhydrophobicity within 56 min at room temperature without any external stimuli. The coating also exhibited excellent self-cleaning and delayed ice formation properties. This novel design and fabrication strategy provides a new perspective for surface protection.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109385"},"PeriodicalIF":6.5,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144098853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optimized sprayable marine creature inspired surface for effectual drag reduction under harsh condition","authors":"Muhammad Nobi Hossain ,&nbsp;Hae Nyeok Kim ,&nbsp;Gyu Do Park ,&nbsp;Younghyeon Kim ,&nbsp;Sang Joon Lee","doi":"10.1016/j.porgcoat.2025.109384","DOIUrl":"10.1016/j.porgcoat.2025.109384","url":null,"abstract":"<div><div>Nature-inspired slippery liquid-infused porous surface (SLIPS) has gained significant attention due to its wide range of applications, including antifouling, self-cleaning, and drag reduction. Drag reduction is particularly crucial in marine environments, as it helps reduce fuel consumption, leading to both economic and environmental benefits. However, SLIPS often lose its slippery features due to the easy depletion of the impregnated lubricant oil, primarily owing to external forces such as flow-induced shear stress. In this study, a sprayable marine creature inspired surface (sMIS) was fabricated to investigate the shear-induced depletion of the infused lubricant from cavities when it was exposed to highly turbulent flows in a water channel. The porosity of the sMIS surfaces is formed to play a key role in maintaining slipperiness by effectively retaining the infused lubricant inside the cavities. The porosity of the sMIS coating was optimized by varying polystyrene concentration and relative humidity by adopting the Taguchi method. The optimized sMIS coating surface (OMIS) retained its excellent slippery properties even after exposing to harsh conditions, including high-speed centrifugal forces. It demonstrated superior slippery performance compared to the non-optimized MIS and bare polydimethylsiloxane (PDMS) surfaces. OMIS surface also exhibited lower pressure drop and friction factor compared to bare surface. Conclusively, the developed OMIS coating surface has great potential in sustainable drag reduction applications.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"207 ","pages":"Article 109384"},"PeriodicalIF":6.5,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144090553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}