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Thermodynamic and Theoretical solvation parameters for 2-amino-4,5-dimethylthiophene-3-carboxamide(ADTC) in Ethanol and Mixed EtOH-H2O solvents 2-氨基-4,5-二甲基噻吩-3-羧酰胺(ADTC)在乙醇和混合乙醇-水溶剂中的热力学和理论溶剂化参数
Progress in Chemical and Biochemical Research Pub Date : 2018-10-01 DOI: 10.29088/SAMI/PCBR.2018.1.1928
E. A. Gomaa, Moged A. Berghout, Mohamed R. Moustafa, Fathy M. El Taweel, Hader M . Farid
{"title":"Thermodynamic and Theoretical solvation parameters for 2-amino-4,5-dimethylthiophene-3-carboxamide(ADTC) in Ethanol and Mixed EtOH-H2O solvents","authors":"E. A. Gomaa, Moged A. Berghout, Mohamed R. Moustafa, Fathy M. El Taweel, Hader M . Farid","doi":"10.29088/SAMI/PCBR.2018.1.1928","DOIUrl":"https://doi.org/10.29088/SAMI/PCBR.2018.1.1928","url":null,"abstract":"The molar solubility for 2-amino-4,5-dimethylthiophene-3-carboxamide  (ADTC) in pure ethanol and mixed ethanol (EtOH)- water solvents were measured at five different temperatures, 293.15, 298.15, 303.15, 308.15, and 313.15 K in the used mixed solvents, the solubility were increase by increase in the mole fraction of ethanol in the mixtures and increase of temperature due to more salvation parameters. All the solvation and thermodynamic parameters for ADTC in mixed EtOH+ H2O solvents were evaluated like solubility products, Gibbs free energies, enthalpies and entropies of solvation and discussed. Theoretical calculations for (ADTC) were done quantum mechanically by using Gaussian on set of calculations in ethanol for evaluating the different thermodynamic parameters.","PeriodicalId":20668,"journal":{"name":"Progress in Chemical and Biochemical Research","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89485321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Cyclic Voltammetric studies of calcium acetate salt with Methylene blue (MB) Using Gold Electrode 用金电极亚甲基蓝(MB)研究醋酸钙盐的循环伏安法
Progress in Chemical and Biochemical Research Pub Date : 2018-10-01 DOI: 10.29088/SAMI/PCBR.2018.1.1118
M. Eldefrawy, E. A. Gomaa, Shereen E. Salem, Fatma Abdel Razik
{"title":"Cyclic Voltammetric studies of calcium acetate salt with Methylene blue (MB) Using Gold Electrode","authors":"M. Eldefrawy, E. A. Gomaa, Shereen E. Salem, Fatma Abdel Razik","doi":"10.29088/SAMI/PCBR.2018.1.1118","DOIUrl":"https://doi.org/10.29088/SAMI/PCBR.2018.1.1118","url":null,"abstract":"Cyclic Voltammetric studies of calcium acetate salt [Ca(CH3COO)2] in absence or presence of Methylene blue (MB) were performed to predict and analyze the behavior of complexation between the ligand and metal ion in aqueous solution. From these studies, the values of solvation and kinetic parameters [Ep (peak potential), Ip(peak current), ΔEP (peak potential difference), E½ (half wave potential), D(Diffusion coefficient), Ks (electron transfer rate constant), Г(surface coverage) and Qa (quantity of electricity)] were evaluated. In addition, the effect of different concentration and a scan rate of above the calculated quantities were studied. In case of presence MB, the stability constants and Gibbs free energies were performed.","PeriodicalId":20668,"journal":{"name":"Progress in Chemical and Biochemical Research","volume":"52 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73556306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
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