E. A. Gomaa, Moged A. Berghout, Mohamed R. Moustafa, Fathy M. El Taweel, Hader M . Farid
{"title":"2-氨基-4,5-二甲基噻吩-3-羧酰胺(ADTC)在乙醇和混合乙醇-水溶剂中的热力学和理论溶剂化参数","authors":"E. A. Gomaa, Moged A. Berghout, Mohamed R. Moustafa, Fathy M. El Taweel, Hader M . Farid","doi":"10.29088/SAMI/PCBR.2018.1.1928","DOIUrl":null,"url":null,"abstract":"The molar solubility for 2-amino-4,5-dimethylthiophene-3-carboxamide (ADTC) in pure ethanol and mixed ethanol (EtOH)- water solvents were measured at five different temperatures, 293.15, 298.15, 303.15, 308.15, and 313.15 K in the used mixed solvents, the solubility were increase by increase in the mole fraction of ethanol in the mixtures and increase of temperature due to more salvation parameters. All the solvation and thermodynamic parameters for ADTC in mixed EtOH+ H2O solvents were evaluated like solubility products, Gibbs free energies, enthalpies and entropies of solvation and discussed. Theoretical calculations for (ADTC) were done quantum mechanically by using Gaussian on set of calculations in ethanol for evaluating the different thermodynamic parameters.","PeriodicalId":20668,"journal":{"name":"Progress in Chemical and Biochemical Research","volume":"8 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":"{\"title\":\"Thermodynamic and Theoretical solvation parameters for 2-amino-4,5-dimethylthiophene-3-carboxamide(ADTC) in Ethanol and Mixed EtOH-H2O solvents\",\"authors\":\"E. A. Gomaa, Moged A. Berghout, Mohamed R. Moustafa, Fathy M. El Taweel, Hader M . Farid\",\"doi\":\"10.29088/SAMI/PCBR.2018.1.1928\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The molar solubility for 2-amino-4,5-dimethylthiophene-3-carboxamide (ADTC) in pure ethanol and mixed ethanol (EtOH)- water solvents were measured at five different temperatures, 293.15, 298.15, 303.15, 308.15, and 313.15 K in the used mixed solvents, the solubility were increase by increase in the mole fraction of ethanol in the mixtures and increase of temperature due to more salvation parameters. All the solvation and thermodynamic parameters for ADTC in mixed EtOH+ H2O solvents were evaluated like solubility products, Gibbs free energies, enthalpies and entropies of solvation and discussed. Theoretical calculations for (ADTC) were done quantum mechanically by using Gaussian on set of calculations in ethanol for evaluating the different thermodynamic parameters.\",\"PeriodicalId\":20668,\"journal\":{\"name\":\"Progress in Chemical and Biochemical Research\",\"volume\":\"8 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Chemical and Biochemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.29088/SAMI/PCBR.2018.1.1928\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Chemical and Biochemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.29088/SAMI/PCBR.2018.1.1928","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Thermodynamic and Theoretical solvation parameters for 2-amino-4,5-dimethylthiophene-3-carboxamide(ADTC) in Ethanol and Mixed EtOH-H2O solvents
The molar solubility for 2-amino-4,5-dimethylthiophene-3-carboxamide (ADTC) in pure ethanol and mixed ethanol (EtOH)- water solvents were measured at five different temperatures, 293.15, 298.15, 303.15, 308.15, and 313.15 K in the used mixed solvents, the solubility were increase by increase in the mole fraction of ethanol in the mixtures and increase of temperature due to more salvation parameters. All the solvation and thermodynamic parameters for ADTC in mixed EtOH+ H2O solvents were evaluated like solubility products, Gibbs free energies, enthalpies and entropies of solvation and discussed. Theoretical calculations for (ADTC) were done quantum mechanically by using Gaussian on set of calculations in ethanol for evaluating the different thermodynamic parameters.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
