Macromolecular Rapid Communications最新文献_第6页

Emissive Hydrazone-Linked Covalent Organic Frameworks as Highly Sensitive and Selective Sensor for the Hydrazine Detection. 发射型肼键共价有机框架作为肼检测的高灵敏度和选择性传感器。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-29 DOI: 10.1002/marc.202400711

Longjin Liu, Dongxue Wei, Hao Liang, Yuwei Zhang, Xueyan Zhang, Yongfeng Zhi

引用次数: 0

Poly(3, 4-Ethylenedioxythiophene) as Promising Energy Storage Materials in Zinc-Ion Batteries. 聚（3，4-乙烯二氧噻吩）作为锌-离子电池中的储能材料前景看好。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-29 DOI: 10.1002/marc.202400476

Tianyun Zhang, Jiaojiao Wu, Fen Ran

{"title":"Poly(3, 4-Ethylenedioxythiophene) as Promising Energy Storage Materials in Zinc-Ion Batteries.","authors":"Tianyun Zhang, Jiaojiao Wu, Fen Ran","doi":"10.1002/marc.202400476","DOIUrl":"https://doi.org/10.1002/marc.202400476","url":null,"abstract":"Benefiting from the advantages of high conductivity and good electrochemical stability, the conjugated conducting polymer poly (3, 4-ethylenedioxythiophene) is a promising energy storage material in zinc-ion batteries. Zinc-ion batteries have the advantages of high safety, environmental friendliness, and low cost, but suffer from unstable cathode material structure, poor electrical conductivity, and uncontrollable dendritic growth of zinc anodes. PEDOT, with its fast electrochemical response and wide potential window, is expected to make up for the shortcomings and enhance capacity and cycle life of zinc-ion batteries. Herein, in this review different polymerization methods of poly (3, 4-ethylenedioxythiophene) as well as their structure and properties are summarized; the progress in doping strategies related to the increasing conductivity and dispersivity of poly (3, 4-ethylenedioxythiophene) materials is discussed; specific applications of poly (3, 4-ethylenedioxythiophene)-based materials in anode, cathode, electrolyte, and binder of zinc-ion batteries are explored; and the representative advancements for improving the electrochemical performance of poly (3, 4-ethylenedioxythiophene) in zinc-ion batteries are emphasized. Finally, the current challenges of poly (3, 4-ethylenedioxythiophene) as promising materials in zinc-ion batteries and an insight into their future research directions are pointed out.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400476"},"PeriodicalIF":4.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142520549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sulfonated Covalent Organic Frameworks Anchoring Cobalt as High-Efficient and Stable Catalysts for Peroxymonosulfate Activation. 磺化共价有机框架锚定钴作为高效稳定的过一硫酸盐活化催化剂。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-28 DOI: 10.1002/marc.202400533

Xinke Zhang, Yutong Li, Fengliang Cao, Xiaohui Sun, Zhihan Jin, Song Xue, Manfred Wagner, Linjie Zhi

{"title":"Sulfonated Covalent Organic Frameworks Anchoring Cobalt as High-Efficient and Stable Catalysts for Peroxymonosulfate Activation.","authors":"Xinke Zhang, Yutong Li, Fengliang Cao, Xiaohui Sun, Zhihan Jin, Song Xue, Manfred Wagner, Linjie Zhi","doi":"10.1002/marc.202400533","DOIUrl":"https://doi.org/10.1002/marc.202400533","url":null,"abstract":"Heterogeneous cobalt-based catalysts are highly effective in activing peroxymonosulfate (PMS) and produce free radicals to deal with recalcitrant organic pollutants in water. However, unfeasible recyclability and gradual performance degradation remain challenging due to the easy agglomeration and leaching of active cobalt species. Herein, a strategy is proposed to construct stably anchored and highly dispersed Co2+ sites on dual functional sulfonated covalent organic frameworks (COF-Co). The sulfonic acid groups are able to realize the targeted binding with cobalt ions through a two-step cation-exchange method, leading to strong combination with active Co2+ sites and utmost utilization efficiencies. Moreover, the super-hydrophility of sulfonic acid groups favors the rapid accessibility of organic molecules to the catalyst and accelerates the degradation. Remarkably, COF-Co exhibits high activity in PMS activation, effective oxidation for tetracycline degradation (92% within 30 min at 30 mg L-1) and other coloring contaminants, and excellent recycle stability. This work can guide the rational design of efficient and environmentally friendly PMS-activated catalyst with great potential for application in wastewater treatment.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400533"},"PeriodicalIF":4.2,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Glaser-Hay-Coupled Random Copolymers Containing Boron Difluoride Formazanate Dyes. 含二氟化硼甲臢染料的 Glaser-Hay-Coupled 无规共聚物。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-27 DOI: 10.1002/marc.202400786

Erin L Cotterill, Yasmeen Jaberi, Jasveer S Dhindsa, Paul D Boyle, Joe B Gilroy

{"title":"Glaser-Hay-Coupled Random Copolymers Containing Boron Difluoride Formazanate Dyes.","authors":"Erin L Cotterill, Yasmeen Jaberi, Jasveer S Dhindsa, Paul D Boyle, Joe B Gilroy","doi":"10.1002/marc.202400786","DOIUrl":"https://doi.org/10.1002/marc.202400786","url":null,"abstract":"𝜋-Conjugated polymers, including those based on acetylenic repeating units, are an exciting class of materials that offer narrow optical band gaps and tunable frontier orbital energies that lead to their use in organic electronics. This work expands the knowledge of structure-property relationships of acetylenic polymers through the synthesis and characterization of a series of Glaser-Hay-coupled model compounds and random copolymers comprised of BF2 formazanate, fluorene, and/or bis(alkoxy)benzene units. The model compounds and copolymers synthesized exhibit redox activity associated with the reversible reduction of the BF2 formazanate units and the irreversible reduction of the fluorene and bis(alkoxy)benzene units. The copolymers exhibit absorption profiles characteristic or intermediate of their respective models and homopolymers, leading to broad absorption of UV-vis light. The alkyne linkages of the model compounds and copolymers are reacted with [Co2(CO)8] to convert the alkyne functional groups into cobalt carbonyl clusters. This transformation leads to blue-shifted absorption profiles due to a decrease in π-conjugation, demonstrating the ability to tune the properties of these materials through post-polymerization functionalization. The redox activity and broad absorption bands of the polymers reported make them excellent candidates for use in photovoltaics and other light-harvesting applications.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400786"},"PeriodicalIF":4.2,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green Advances in Wet Finishing Methods and Nanoparticles for Daily Textiles. 用于日用纺织品的湿整理方法和纳米粒子的绿色进展。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-27 DOI: 10.1002/marc.202400636

Antonella Patti

{"title":"Green Advances in Wet Finishing Methods and Nanoparticles for Daily Textiles.","authors":"Antonella Patti","doi":"10.1002/marc.202400636","DOIUrl":"https://doi.org/10.1002/marc.202400636","url":null,"abstract":"This work presented an overview of greener technologies for realizing everyday fabrics with enhanced antibacterial activity, flame retardancy, water repellency, and UV protection. Traditional methods for improving these qualities in textiles involved dangerous chemicals, energy and water-intensive procedures, harmful emissions. New strategies are presented in response to the current emphasis on process and product sustainability. Nanoparticles (NPs) are suggested as a potential alternative for hazardous components in textile finishing. NPs are found to efficiently decrease virus transmission, limit combustion events, protect against UV radiation, and prevent water from entering, through a variety of mechanisms. Some attempts are made to increase NPs efficiency and promote long-term adherence to textile surfaces. Traditional wet finishing methods are implemented through a combination of advanced green technologies (plasma pre-treatment, ultrasound irradiations, sol-gel, and layer-by-layer self-assembly methods). The fibrous surface is activated by adding functional groups that facilitate NPs grafting on the textile substrate by basic interactions (chemical, physical, or electrostatic), also indirectly via crosslinkers, ligands, or coupling agents. Finally, other green options explore the use of NPs synthesized from bio-based materials or hybrid combinations, as well as inorganic NPs from green synthesis to realize ecofriendly finishing able to provide durable and protective fabrics.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400636"},"PeriodicalIF":4.2,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multi-Responsive Polymer Nanoparticles: A Versatile Platform for Double-Security Anticounterfeiting and Smart Food Packaging. 多反应聚合物纳米粒子：双重安全防伪和智能食品包装的多功能平台。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-26 DOI: 10.1002/marc.202400561

Hossein Alidaei-Sharif, Milad Babazadeh-Mamaqani, Moein Mohammadi-Jorjafki, Hossein Roghani-Mamaqani, Mehdi Salami-Kalajahi

{"title":"Multi-Responsive Polymer Nanoparticles: A Versatile Platform for Double-Security Anticounterfeiting and Smart Food Packaging.","authors":"Hossein Alidaei-Sharif, Milad Babazadeh-Mamaqani, Moein Mohammadi-Jorjafki, Hossein Roghani-Mamaqani, Mehdi Salami-Kalajahi","doi":"10.1002/marc.202400561","DOIUrl":"https://doi.org/10.1002/marc.202400561","url":null,"abstract":"Potential applications of colloidal polymer nanoparticles in the preparation of smart inks are investigated by physical incorporation of the oxazolidine molecules. Precise adjusting the polymer chain flexibility and polarity is achieved by controlling the ratio of methyl methacrylate and butyl acrylate monomers in the polymerization reaction. In addition, nanofibrous indicators of acid-base vapors are prepared from the latex nanoparticles. This can be beneficial for creating materials that sense and respond to environmental changes, such as humidity or moisture and acidity. Thermochromic inks are prepared by microencapsulating crystal violet lactone dye (CVL) in polymer matrices to prevent their release into the aqueous media. Combining two distinct systems with varying triggers, such as light and temperature, provides an effective strategy for double-encryption anticounterfeiting and crack and scratch detection and indication applications. Preparing labels impregnated with double-responsive inks, a novel approach is developed for food spoilage detection and preservation indication. Labels are manufactured using polymer nanoparticles, which contain photoluminescent oxazolidine molecules, as well as a trinary mixture of CVL within core-shell latex particles as the thermochromic dye. The combination of these two responsive elements transforms traditional packaging into a dynamic and interactive sentinel for the food it holds.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400561"},"PeriodicalIF":4.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Facile Method in Fabricating Flexible Conductive Composites with Large-Size Segregated Structures for Electromagnetic Interference Shielding. 制造具有大尺寸分段结构的柔性导电复合材料以屏蔽电磁干扰的简便方法。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-26 DOI: 10.1002/marc.202400585

Liang He, Yang Chen, Xiaoming Shao, Qiyuan Yao, Ding Feng, Lijie Yin, Wencai Wang

{"title":"A Facile Method in Fabricating Flexible Conductive Composites with Large-Size Segregated Structures for Electromagnetic Interference Shielding.","authors":"Liang He, Yang Chen, Xiaoming Shao, Qiyuan Yao, Ding Feng, Lijie Yin, Wencai Wang","doi":"10.1002/marc.202400585","DOIUrl":"https://doi.org/10.1002/marc.202400585","url":null,"abstract":"To resist the plastic deformation of polymer particles during hot press molding, high molecular weights, and moduli are required for composites with segregated structures, thus the prepared composites exhibit poor flexibility. Also, larger particle sizes can bring lower percolation thresholds while the ensuing greater deformation destroys the conductive network. Moreover, segregated composites still face preparation complexities. Herein, a facile method for developing flexible composites with large-size segregated structures is proposed. First, silver-coated polydopamine-modified reduced graphene oxide (Ag@PrGO), as conductive fillers, is prepared by electroless plating. Next, polydimethylsiloxane (PDMS)-coated polyolefin elastomer (POE) beads are put into a bag containing the fillers. After a simple shaking, the fillers are adhered to the POE surface as the cohesive property of cured PDMS. Finally, flexible composites with large-size segregated structures are obtained via hot pressing. Benefiting from the 2D structure of the Ag@PrGO and the ability to slip, the conductive networks possess adaptable deformability. The prepared composites exhibit excellent electrical conductivity (203.55 S cm-1) at filler volume fractions of 3.4 vol%. The EMI shielding effectiveness can reach 70 dB in the X-band at a thickness of 1.9 mm and remains stable after bending and rubbing damage. This work paves the way for constructing large-size segregated structures.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400585"},"PeriodicalIF":4.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polymerization-Induced Self-Assembly for the Synthesis of Polyisoprene-Polystyrene Block and Random Copolymers: Towards High Molecular Weight and Conversion. 聚合诱导自组装合成聚异戊二烯-聚苯乙烯嵌段和无规共聚物：实现高分子量和高转化率。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-26 DOI: 10.1002/marc.202400727

Maryam Moradi, Prokopios Georgopanos

{"title":"Polymerization-Induced Self-Assembly for the Synthesis of Polyisoprene-Polystyrene Block and Random Copolymers: Towards High Molecular Weight and Conversion.","authors":"Maryam Moradi, Prokopios Georgopanos","doi":"10.1002/marc.202400727","DOIUrl":"https://doi.org/10.1002/marc.202400727","url":null,"abstract":"In this study, reversible addition-fragmentation chain- transfer (RAFT) polymerization combined with the polymerization-induced self-assembly (PISA) technique is used to synthesize polyisoprene (PI)-based block and random copolymers with polystyrene (PS), aiming for high molecular weight and monomer conversion. The focus is to optimize the polymerization conditions to overcome the existing challenge of cross-linking and Diels-Alder reactions during the polymerization of isoprene, which typically constrain the reaction conversion and molecular weight of the final polymers. Using a poly(methacrylic acid) (PMAA) macroRAFT agent synthesized in ethanol at 80 °C, random and block copolymers of PS-PI with a target molecular weight of 50 000 g mole-1 and a high monomer conversion of ≈80% are achieved under optimized conditions in water-emulsion at 35 °C. 1H nuclear magnetic resonance (NMR) verified the successful synthesis as well as the high content of 1,4 microstructure in polyisoprene. The thermal analysis via differential scanning calorimetry indicated distinct glass transitions for the microphase-separated PI-PS block copolymer, while a single transition for PI-PS random copolymer, indicating no microphase separation. Furthermore, dynamic light scattering analysis together with transmission electron microscopy provided further insight into the self-assembled emulsion nanoparticles of the polymers indicating a particle size in the range 70 to 130 nm.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400727"},"PeriodicalIF":4.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication of Zinc(II) Mediated Poly(Acrylamide Co Acrylic Acid) Hydrogel with Thixotropic and Tribological Properties. 制备具有触变性和摩擦学特性的锌(II)介导聚丙烯酰胺-丙烯酸水凝胶。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-26 DOI: 10.1002/marc.202400670

Paresh Nageshwar, Suraj W Wajge, Gopal Lal Dhakar, Avinash A Thakre, Swapnil Tripathi, Shiva Singh, Pradip K Maji, Chayan Das

{"title":"Fabrication of Zinc(II) Mediated Poly(Acrylamide Co Acrylic Acid) Hydrogel with Thixotropic and Tribological Properties.","authors":"Paresh Nageshwar, Suraj W Wajge, Gopal Lal Dhakar, Avinash A Thakre, Swapnil Tripathi, Shiva Singh, Pradip K Maji, Chayan Das","doi":"10.1002/marc.202400670","DOIUrl":"https://doi.org/10.1002/marc.202400670","url":null,"abstract":"Hydrogels have emerged as promising candidates for biomedical applications, such as replacing natural articular cartilage, owing to their unique viscoelastic properties. However, sufficient mechanical properties, self-healing ability, and adhesive nature are some issues limiting its application window. Here, a facile one-pot synthesis of dual cross-linked zinc-coordinated copolymer hydrogels is presented. The network structure of the copolymer hydrogels is strategically developed via dynamic and reversible physical cross-linking by Zn2+ ions and simultaneous covalent cross-linking through a covalent cross-linker viz methylene bisacrylamide. Fourier-transform infrared (FTIR), X-ray diffraction (XRD) scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) analysis have thoroughly characterized the structure of the synthesized hydrogels. The introduction of Zn2+ offers dynamic and reversible complexation, leading to excellent mechanical properties and self-healing features. Moreover, the percentage of the equilibrium water content of zinc-coordinated copolymer hydrogel samples is comparable with that of natural articular cartilage. The Shear sliding study shows the dominant adhesive behavior of HGel-Zn(NO3)2 sample compared to the parent HGel sample. This facile dual cross-linked hydrogel, HGel-Zn(NO3)2, with a combination of good mechanical properties, efficient self-recovery, adequate water content, and favorable adhesive nature, seems very promising to mimic the articular cartilage.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400670"},"PeriodicalIF":4.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Uncovering Integrated Dual-State ESIPT-Conductivity, Redox-Capacity, and Opto-Electronic Responses Toward Hg(II)/ Cr(III) of Aliphatic Fluorescent Polymers. 揭示脂肪族荧光聚合物对汞(II)/铬(III)的综合双态 ESIPT-电导率、氧化还原能力和光电响应。

IF 4.2 3区化学

Macromolecular Rapid Communications Pub Date : 2024-10-26 DOI: 10.1002/marc.202400677

Md Hussain Sanfui, Nadira Hassan, Shrestha Roy, Deepak Chowdhury, Preetam Nandy, Mincheol Chang, Mostafizur Rahaman, Narendra Nath Ghosh, Swapan Majumdar, Pijush Kanti Chattopadhyay, Dilip K Maiti, Nayan Ranjan Singha

{"title":"Uncovering Integrated Dual-State ESIPT-Conductivity, Redox-Capacity, and Opto-Electronic Responses Toward Hg(II)/ Cr(III) of Aliphatic Fluorescent Polymers.","authors":"Md Hussain Sanfui, Nadira Hassan, Shrestha Roy, Deepak Chowdhury, Preetam Nandy, Mincheol Chang, Mostafizur Rahaman, Narendra Nath Ghosh, Swapan Majumdar, Pijush Kanti Chattopadhyay, Dilip K Maiti, Nayan Ranjan Singha","doi":"10.1002/marc.202400677","DOIUrl":"https://doi.org/10.1002/marc.202400677","url":null,"abstract":"Excited-state intramolecular proton transfer (ESIPT)-associated dual-state emissive aliphatic dual-light emitting conducting polymers (DLECPs) having oxidation-reduction capacities are prepared polymerizing 2-acrylamido-2-methylpropane-1-sulfonic acid, methacrylic acid, and 2-methyl-3-(N-(2-methyl-1-sulfopropan-2-yl)acrylamido)propanoic acid monomers. Of as-synthesized DLECPs, nuclear magnetic resonance (NMR) and Fourier transform infrared (FTIR) spectroscopies, fluorescent enhancements (I/I0), and computational investigation indicate intriguing photophysical features in DLECP3 (optimum composition). In DLECP3, ─CONH─, ─CON<, and ─COOH subluminophores are recognized by density-functional theory (DFT)/time-dependent-DFT calculations and experimental investigations. ESIPT-associated dual-state emission/conductivity, aggregation-enhanced emissions, selective opto-electronic responses toward Hg(II)/Cr(III) at 437/574 nm, and redox properties of DLECP3 are supported by solid-state/solution spectroscopies, time-correlated single photon counting (TCSPC) measurements, dual-state excitation dependent emissions, microscopic images, electrochemical measurements, and DFT calculations. Here, preferential interaction of Hg(II)/Cr(III) with DLECP3 (amide)/DLECP3 (imidol) and reduction/oxidation of Hg(II)/Cr(III) to Hg(I)/Cr(VI) are substantiated by UV-vis, FTIR, and X-ray photoelectron spectroscopies; TCSPC measurements; NMR-titration; electrochemical studies; alongside computational calculations. The proton-electrical conductivities of DLECP3, Hg(II/I)-DLECP3, and Cr(III/VI)-DLECP3 in solids/solutions are 15.27 × 10-5/6.16 × 10-5, 19.60 × 10-5/25.52 × 10-5, and 26.69 × 10-5/27.60 × 10-5 S cm-1, respectively.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":" ","pages":"e2400677"},"PeriodicalIF":4.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142491739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0