Procedia Chemistry最新文献

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Sustainable of Laminated Rubber-Metal Spring in Transverse Vibration 橡胶-金属层合弹簧在横向振动中的可持续性
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.03.094
M.A. Salim, A. Putra, M.R. Mansor, M.T. Musthafah, M.Z. Akop, M.A. Abdullah, M.N. Abdul Rahman, M.N. Sudin, M.A. Shaharuzaman
{"title":"Sustainable of Laminated Rubber-Metal Spring in Transverse Vibration","authors":"M.A. Salim,&nbsp;A. Putra,&nbsp;M.R. Mansor,&nbsp;M.T. Musthafah,&nbsp;M.Z. Akop,&nbsp;M.A. Abdullah,&nbsp;M.N. Abdul Rahman,&nbsp;M.N. Sudin,&nbsp;M.A. Shaharuzaman","doi":"10.1016/j.proche.2016.03.094","DOIUrl":"10.1016/j.proche.2016.03.094","url":null,"abstract":"<div><p>This paper presents the sustainable of laminated rubber-metal spring (LR-MS) in transverse vibration. The free-fixed boundary condition, longitudinal and rotational force are chosen to represents the transverse behavior of the LR-MS model. The mathematical model is developed and finally the dynamic stiffness matrix for all elements inside the LR-MS are obtained. By using the dynamic stiffness matrix for each element in LR-MS model, the prediction of stiffness level during transverse vibration are determined. Furthermore, it was pointed the comparison of stiffness level between all elements when the forces apply. Finally, the mathematical model developed in this study is accomplished to represent the stiffness level of LR-MS model in actual value when transverse vibration occurred.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"19 ","pages":"Pages 203-210"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.03.094","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79315413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Investigation and Characterization of ZnO Nanostructures Synthesized by Electrochemical Deposition 电化学沉积法制备ZnO纳米结构的研究与表征
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.03.119
C.F. Mah, F.K. Yam, Z. Hassan
{"title":"Investigation and Characterization of ZnO Nanostructures Synthesized by Electrochemical Deposition","authors":"C.F. Mah,&nbsp;F.K. Yam,&nbsp;Z. Hassan","doi":"10.1016/j.proche.2016.03.119","DOIUrl":"10.1016/j.proche.2016.03.119","url":null,"abstract":"<div><p>ZnO with cube-like nanostructures have been fabricated on tin-doped indium oxide (ITO) coated glass substrates via electrochemical deposition method. The electrolytes used containing equimolar of zinc chloride (ZnCl<sub>2</sub>) and potassium chloride (KCl) ranging from 0.05<!--> <!-->M to 0.2<!--> <!-->M. The samples produced subsequently were examined by field emission scanning electron microscope (FESEM), x-ray diffractometer (XRD), energy dispersive X-ray (EDX) spectroscopy and current transient profile. The average size of the cube-like nano ZnO materials, as observed from FESEM images is decreased from 207<!--> <!-->nm to 102<!--> <!-->nm with increasing of electrolytes concentration. The XRD measurement indicated that the as-deposited nanostructures are converted from amorphous to hexagonal wurtzite ZnO phase after heat treatment at 600<!--> <!-->°C for 3<!--> <!-->hours. Photoresponse measurement revealed that the grown sample is sensitive to the 372<!--> <!-->nm ultraviolet (UV) light.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"19 ","pages":"Pages 83-90"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.03.119","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85527858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
Cyclic Voltammetry on CeCl3 in LiCl-KCl Eutectic Using W and Bi Coated Electrode 用W和Bi包覆电极对LiCl-KCl共晶中CeCl3的循环伏安法研究
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.10.056
Sungjune Sohn , Jaeyeong Park , Pyeong-Hwa Kim , Il Soon Hwang
{"title":"Cyclic Voltammetry on CeCl3 in LiCl-KCl Eutectic Using W and Bi Coated Electrode","authors":"Sungjune Sohn ,&nbsp;Jaeyeong Park ,&nbsp;Pyeong-Hwa Kim ,&nbsp;Il Soon Hwang","doi":"10.1016/j.proche.2016.10.056","DOIUrl":"10.1016/j.proche.2016.10.056","url":null,"abstract":"<div><p>This paper presents experimental results of cyclic voltammetry on CeCl<sub>3</sub> in LiCl-KCl using tungsten electrode and Bi coated electrode respectively at 703K. Using tungsten electrode at low concentration of CeCl<sub>3</sub>, the redox reaction has been shown to be reversible. Diffusion coefficient and apparent standard potential of Ce(III) in LiCl-KCl were 0.42×10<sup>-5</sup> (cm<sup>2</sup>/s) and -3.153 (V vs. Cl<sub>2</sub>/Cl<sup>−</sup>) under 50mV/s. In order to obtain Bi coated electrode, cyclic voltammetry was carried out on eutectic salt including BiCl<sub>3</sub>. The redox reaction of Ce on Bi coated electrode has been shown to be reversible and apparent standard potential on Bi coated electrode moved 782mV compared with tungsten cathode.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"21 ","pages":"Pages 401-408"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.10.056","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85722158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Effect of Acrylic Acid Content on Modified NypaFruticans Regenerated Cellulose Biocomposite Films 丙烯酸含量对改性NypaFruticans再生纤维素生物复合膜的影响
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.03.021
G. Vaniespree, H. Salmah, P.L. Teh, M. Marliza
{"title":"Effect of Acrylic Acid Content on Modified NypaFruticans Regenerated Cellulose Biocomposite Films","authors":"G. Vaniespree,&nbsp;H. Salmah,&nbsp;P.L. Teh,&nbsp;M. Marliza","doi":"10.1016/j.proche.2016.03.021","DOIUrl":"10.1016/j.proche.2016.03.021","url":null,"abstract":"<div><p>Nypafruticans (NF) is one of the agriculture crops, which grows abundantly in Malaysia. It can be used as asubstitute for commercial cellulose in order to utilize biomass waste. Regenerated cellulose (RC) biocomposite films from NF and microcrystalline cellulose (MCC) were prepared by dissolving cellulose in lithium chloride (LiCl) and N, N-dimethylacetamide (DMAc). Acrylic acid (AA) was used as surface modifier of NF. The results indicated that the addition of NF in RC biocomposite films increases the tensile strength and Young's modulus of RC biocomposite film up to 3 wt%. The elongation at break of RC biocomposite films decreased with increases of NF content. The modified NF with AA improved the tensile strength and Young's modulus but reduced the elongation at break of RC biocomposite films. The highest tensile strength and Young's modulus of RC biocomposite films was exhibited by 3% AA content.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"19 ","pages":"Pages 340-345"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.03.021","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87132529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling Closed Nuclear Fuel Cycle Processes 封闭核燃料循环过程建模
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.10.070
O.V. Shmidt , I.R. Makeeva , S.N. Liventsov
{"title":"Modeling Closed Nuclear Fuel Cycle Processes","authors":"O.V. Shmidt ,&nbsp;I.R. Makeeva ,&nbsp;S.N. Liventsov","doi":"10.1016/j.proche.2016.10.070","DOIUrl":"10.1016/j.proche.2016.10.070","url":null,"abstract":"<div><p>Determination of optimal operating conditions for closed nuclear fuel cycle processes requires computer models that are used to evaluate and modify the design solution at earlier stages of technology development and the engineering and project documentation as more data from experimental research are obtained. The computational models being developed will significantly accelerate the design process, project commissioning as well as improve quality, performance and safety characteristics of the product.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"21 ","pages":"Pages 503-508"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.10.070","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86859942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Production of High Purity Amorphous Silica from Rice Husk 稻壳制备高纯非晶态二氧化硅
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.03.092
Rohani Abu Bakar , Rosiyah Yahya , Seng Neon Gan
{"title":"Production of High Purity Amorphous Silica from Rice Husk","authors":"Rohani Abu Bakar ,&nbsp;Rosiyah Yahya ,&nbsp;Seng Neon Gan","doi":"10.1016/j.proche.2016.03.092","DOIUrl":"10.1016/j.proche.2016.03.092","url":null,"abstract":"<div><p>Combustion of the rice husk produces rice husk ash, which consists of mainly silica. High purity silica can be produced by controlled combustion after acid treatment. In this study, leaching of rice husk with hydrochloric acid and sulfuric acid were carried out prior to combustion to obtain purer silica. It was found that pre-treatment of the rice husk with sulfuric acid had accelerated the hydrolysis and decomposition of organic components as revealed by thermogravimetry (TG) and Scanning Electron Microscopy (SEM) analyses. In a systematic study, the combustion of un-leached, hydrochloric acid-leached and sulfuric acid-leached rice husks were performed in a muffle furnace at 500, 600, 700, 800 and 900<sup>o</sup>C for 2<!--> <!-->h. Results demonstrated that all the samples produced amorphous silica (SiO<sub>2</sub>) and the average particle size were in the range of 0.50 to 0.70<!--> <!-->μm. The effect of combustion at different temperatures between 500<sup>o</sup>C and 900<sup>o</sup>C on the silica production is very small, particularly at temperature above 600<sup>o</sup>C. Thus, amorphous silica with purity above 99% as confirmed by X-Ray Fluorescence (XRF) analysis can be produced by hydrochloric and sulfuric acids leaching of the rice husk, followed by controlled combustion at 600<sup>o</sup>C for 2<!--> <!-->h. The BET surface area of the silica produced after leaching the rice husk with hydrochloric acid was higher (218 m<sup>2</sup>/g) than with sulfuric acid (209 m<sup>2</sup>/g). The silica obtained has potential application as filler in plastics and rubber compounding.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"19 ","pages":"Pages 189-195"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.03.092","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75306036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 348
Tensile Behavior of SiCNP and MWCNTs Filled Toughened Epoxy Nanocomposites: A Comparative Study SiCNP和MWCNTs填充增韧环氧纳米复合材料拉伸性能的比较研究
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.03.098
S. Ratim , S. Ahmad , N.N. Bonnia , E.S. Ali , J.A. Razak
{"title":"Tensile Behavior of SiCNP and MWCNTs Filled Toughened Epoxy Nanocomposites: A Comparative Study","authors":"S. Ratim ,&nbsp;S. Ahmad ,&nbsp;N.N. Bonnia ,&nbsp;E.S. Ali ,&nbsp;J.A. Razak","doi":"10.1016/j.proche.2016.03.098","DOIUrl":"10.1016/j.proche.2016.03.098","url":null,"abstract":"<div><p>This study is conducted to evaluate the tensile properties of silicon carbide nanoparticles (SiCNP) and multiwalled carbon nanotubes (MWCNTs) filled toughened epoxy composites as a function of filler loading. The nanocomposites with different weight percentage of SiCNP and MWCNTs loading were fabricated by mechanical blending operation assisted with an ultrasonic cavitation technique. The loadings utilized were 0, 2, 4, and 6% of total composites weight. The result shows that the optimum filler loading of both systems were obtainable at 4% of SiCNP and MWCNTs of loadings. Composite with SiCNP filler achieved the highest value of tensile strength and Young's modulus at about 11% and 4%, respectively as compared to unfilled system. The enhancement pattern in MWCNTs nanocomposite systems were not significant as compared than SiCNP composite. The tensile strength and Young's modulus of MWCNTs composite were increased at only about 7% and 2%, respectively compared than unfilled system. The strain at break attribute for both filler system had shown reduction pattern at higher loading started from 2% loading and onwards. The variation in tensile properties were further supported by the tensile fracture morphologies and clearly shown that the filler-matrix plated an important role in affecting the tensile behavior of nanocomposite produced.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"19 ","pages":"Pages 228-233"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.03.098","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72775350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Refractive Index Measurement in Sucrose Solution and Beverage Using Surface Plasmon Resonance Sensor Based on Hetero-core Structured Fiber Optic 基于异芯结构光纤的表面等离子体共振传感器测量蔗糖溶液和饮料中的折射率
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.07.020
Atsushi Seki, Kohei Narita, Kazuhiro Watanabe
{"title":"Refractive Index Measurement in Sucrose Solution and Beverage Using Surface Plasmon Resonance Sensor Based on Hetero-core Structured Fiber Optic","authors":"Atsushi Seki,&nbsp;Kohei Narita,&nbsp;Kazuhiro Watanabe","doi":"10.1016/j.proche.2016.07.020","DOIUrl":"10.1016/j.proche.2016.07.020","url":null,"abstract":"<div><p>The surface plasmon resonance (SPR) sensor was fabricated by depositing silver thin film on the surface of hetero-core structured fiber optic. The SPR sensor based on hetero-core structured fiber optic was applied to measure refractive index of sucrose solution and fruit juices. The sensor part was immersed in sucrose solution and/or juice and the propagating light spectra were measured. It was shown that the fiber optic SPR sensor showed a good agreement with that measured by conventional refractometer.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"20 ","pages":"Pages 115-117"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.07.020","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91094248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Effect of Different Preparation Methods on Crosslink density and Mechanical Properties of Carrageenan filled Natural Rubber (NR) Latex Films 不同制备方法对卡拉胶填充天然橡胶胶乳膜交联密度和力学性能的影响
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/J.PROCHE.2016.03.146
S. Norhazariah, A. Azura, R. Sivakumar, B. Azahari
{"title":"Effect of Different Preparation Methods on Crosslink density and Mechanical Properties of Carrageenan filled Natural Rubber (NR) Latex Films","authors":"S. Norhazariah, A. Azura, R. Sivakumar, B. Azahari","doi":"10.1016/J.PROCHE.2016.03.146","DOIUrl":"https://doi.org/10.1016/J.PROCHE.2016.03.146","url":null,"abstract":"","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"2 1","pages":"986-992"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88380581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 21
In vitro Evaluation of Mesoporous Carbonated Hydroxyapatite in MC3T3-E1 Osteoblast Cells MC3T3-E1成骨细胞中介孔碳化羟基磷灰石的体外研究
Procedia Chemistry Pub Date : 2016-01-01 DOI: 10.1016/j.proche.2016.03.103
Nur Farahiyah Mohammad , Radzali Othman , Nurul Asma Abdullah , Fei Yee Yeoh
{"title":"In vitro Evaluation of Mesoporous Carbonated Hydroxyapatite in MC3T3-E1 Osteoblast Cells","authors":"Nur Farahiyah Mohammad ,&nbsp;Radzali Othman ,&nbsp;Nurul Asma Abdullah ,&nbsp;Fei Yee Yeoh","doi":"10.1016/j.proche.2016.03.103","DOIUrl":"10.1016/j.proche.2016.03.103","url":null,"abstract":"<div><p>Nanoporous bioceramic recently has gained attention as a drug storage and release host in the therapeutic application. Mesoporous carbonated hydroxyapatite (MCHA) is a nanoporous bioceramic with pore sized ranged between 2-50<!--> <!-->nm. In order to use in drug delivery application, this material should demonstrate acceptable cytotoxic activity and osteoinductive response. Therefore, this study aimed to evaluate the effect of mesoporous carbonated hydroxyapatite on viability and alkaline phosphatase (ALP) activity of MC3T3-E1 osteoblasts cell line. These parameters represent cytotoxicity level and osteinductivity capability of the materials. MC3T3-E1 cells were cultured in 25<!--> <!-->mg/ml extraction of mesoporous carbonated hydroxyapatite (meso-CHA) and non-porous CHA (np-CHA) for up to 7 days for viability and 14 days for ALP test. Results indicate that meso-CHA shows better cytotoxicity properties compare to np-CHA. Intracellular ALP of cells treated with meso-CHA was higher than np-CHA.</p></div>","PeriodicalId":20431,"journal":{"name":"Procedia Chemistry","volume":"19 ","pages":"Pages 259-266"},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.proche.2016.03.103","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82053178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 21
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