Juan Du, Jinfeng Shi, Lei Zhang, Xianghong Ren, Jing Dong, Shuai Yang, Jiapeng Liu
{"title":"An Innovative Geopolymer CompositeInsulation Material Based on PhytoremediationBiowaste: Solidification/Stabilizationof Potentially Toxic Metals","authors":"Juan Du, Jinfeng Shi, Lei Zhang, Xianghong Ren, Jing Dong, Shuai Yang, Jiapeng Liu","doi":"10.15244/pjoes/213560","DOIUrl":"https://doi.org/10.15244/pjoes/213560","url":null,"abstract":"Phytoremediation biowaste without proper disposal might release potentially toxic metals (PTMs) back into the environment and pose a serious threat to environmental safety and human health.A composite geopolymer based on phytoremediation biowastes (PBWs) was used to effectively solidify/stabilize toxic heavy metals and served as an insulation material in the present study.For the solidification/stabilization of PTMs, the optimum proportion of biowastes in the geopolymer insulation material was 3%, at which the compressive strength of the geopolymer reached a maximum of 32.6 MPa and the thermal conductivity of the geopolymer was 0.11 W/(mK), meeting the requirements of insulation materials.The leaching results indicated that the solidification efficiency of PTMs in the geopolymer materials was over 98%.The leaching concentration of all samples was within the standard limits and decreased with the extension of curing time.The XRD and FT-IR spectra of the biowaste-geopolymer confirmed the effective solidification/stabilization of PTMs in the geopolymer composite, where Zn was immobilized as carbonate and silicate.The geopolymer technique can stabilize the PTMs and prepare insulation materials simultaneously.Hence, this research provided a helpful insight and theoretical support for the post-treatment and the reutilization of plant waste accumulated with heavy metals.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.pjoes.com/pdf-213560-134117?filename=An-Innovative-Geopolymer-.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147919356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effects of Combined Supplementationof Germanium and Selenium on the AntioxidantFunction of Przewalski’s Gazelles","authors":"Mei Jiang, Peng He, Xiaoyun Shen","doi":"10.15244/pjoes/208930","DOIUrl":"https://doi.org/10.15244/pjoes/208930","url":null,"abstract":"The Przewalski's gazelle (P.przewalskii) is a rare and endangered species endemic to China, primarily distributed in the Qinghai-Tibet Plateau region.Due to the unique characteristics of the plateau environment, P. przewalskii often faces issues such as nutritional deficiencies and oxidative stress.This study focused on the differences between P. przewalskii in different areas of Qinghai Lake, revealing that P. przewalskii in the Hudong region exhibited symptoms of emaciation, sluggish movement, and lethargy, with distinct differences in body size and shape compared to those in the Bird Island region.Serum parameter analysis showed that the antioxidant function of P. przewalskii in the Bird Island region was significantly higher than that in the Hudong region (p < 0.05).The levels of germanium (Ge) and selenium (Se) in the soil, forage, and serum of P. przewalskii in the Hudong region were significantly lower than those in the Bird Island region (p < 0.05).To further evaluate the therapeutic effects of combined Ge and Se supplementation, this study designated P. przewalskii in the Bird Island region as the control group and those in the Hudong region as the experimental group.The experimental group was orally administered 5 mg/kgBWday of Ge-132 and 1 mg/kgBWday of Na 2 SeO 3 .The results showed significant improvements in antioxidant indicators (T-AOC +36.3%, MDA -50.6%) and immune indicators (IgG +29.8%,IgM +17.1%), and inflammatory factors (IL-6 -31.2%, TNF- -26.5%) were significantly reduced (p<0.05).The combined Ge-Se supplementation enhanced antioxidant function (T-AOC +5.5%, MDA -9.3%) and immunity (IgG +11.0%,IgM +9.8%) significantly more than the best individual supplement (p<0.05).After 30 days of supplementation, antioxidant indices showed no significant differences between groups (p>0.05).In conclusion, the combined application of Ge and Se demonstrated the best therapeutic effect on the antioxidant capacity of P. przewalskii.This discovery not only provided new insights for improving the habitat of P. przewalskii but also represented a significant breakthrough in the conservation efforts for rare species.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.pjoes.com/pdf-208930-129410?filename=Effects of Combined.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147889828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Adsorption and Degradation of Cyanazinein Chinese Soils under DifferentEnvironmental Conditions","authors":"Wangcang Su, Yaolan Niu, Fei Xue, Lanlan Sun, Hongle Xu, Renhai Wu","doi":"10.15244/pjoes/207492","DOIUrl":"https://doi.org/10.15244/pjoes/207492","url":null,"abstract":"Cyanazine (2-(4-chloro-6-ethylamino-1,3,5-triazin-2-ylamino)-2-methylpropiononitrile, Fig. 1), a triazine herbicide, primarily controls various annual gramineous weeds and broad-leaved weeds in corn and sugarcane fields by inhibiting photosynthesis [1,2].Notably, cyanazine is safe for wheat and can be effectively mixed with herbicides such as pyroxasulfone for weed control in wheat fields [3].With the increasing resistance of maize field weeds to ALS-inhibiting herbicides (e.g., nicosulfuron) [4] and HPPD inhibitors (e.g., mesotrione) [5], resulting in decreased weed control efficacy, increased herbicide dosage is required.In contrast, resistance to photosynthesis-inhibiting herbicides such as cyanazine remains rarely reported.Concurrently,","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.pjoes.com/pdf-207492-128632?filename=Adsorption and.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147330315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Degradation of Tinidazole in Water by UV/PSProcess: A Study on Degradation Kinetics,Influencing Factors, and Optimizationfor Most Economical Efficiency","authors":"Xing Zhang, Yizhi Liu, Jinghan Liu, Xinhua Sun, Jie Wan, Zhen Zhou, Yixin Liu, Hezhong Tian","doi":"10.15244/pjoes/205071","DOIUrl":"https://doi.org/10.15244/pjoes/205071","url":null,"abstract":"The degradation of refractory organic pollutants such as tinidazole in water holds significant positive implications for the environment.This study employed a combination of ultraviolet (UV) light and persulfate (PS) to remove tinidazole from aqueous solutions.Compared to the individual effects of UV alone (9.4% removal) and PS alone (negligible degradation), the UV/PS process demonstrated a remarkable ability to degrade tinidazole.The degradation process was found to follow pseudo-firstorder kinetics, with a rate constant of 4.8210 -3 s -1 .Quenching experiments revealed that sulfate radicals played a dominant role in the degradation process.Within a certain range, increasing the concentration of the oxidant and the UV power was observed to enhance the degradation efficiency, while pH was found to have a negligible impact on the degradation.Among common ions in water, low chloride ion concentrations were found to slightly promote degradation, whereas high concentrations inhibited it.In contrast, bicarbonate, sulfate, and nitrate ions had minimal effects on the degradation process.Within a defined range, the degradation process was described by a quadratic polynomial model, with degradation efficiency as the dependent variable and dosages of PS, UV power, and reaction time as independent variables.By integrating the quadratic polynomial model into a Python program, the most economically optimal operational parameters for the UV/PS process were calculated as dosages of PS of 0.4202 mM, UV power of 9.9311 W, and reaction time of 7.0526 min, at which Pol. J. Environ.Stud.Vol.XX, No. X (XXXX), 1-12 the total operating cost reached the minimum (1.3970 CNY/m 3 /order).The reliability of these parameters was subsequently validated through experimental verification.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.pjoes.com/pdf-205071-127109?filename=Degradation of Tinidazole.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147897696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Assessment of Heavy Metal Contamination Levelsand Health Risks in a Mining Areain Sichuan Province, China","authors":"Daiwen Zhu, Quan Li, Binzhou Yan","doi":"10.15244/pjoes/204188","DOIUrl":"https://doi.org/10.15244/pjoes/204188","url":null,"abstract":"Soil and water pollution, particularly from industrial activities like mining, has become a significant environmental concern.Despite extensive research, there are still crucial gaps in understanding the long-term impacts of contaminants from mineral processing plants on local ecosystems and communities.This study aims to address these gaps by systematically evaluating the soil and water quality around a defunct mineral processing facility in Maerkang County, Sichuan Province, China.Through field surveys, sampling, and laboratory analysis, both inorganic and organic pollutants, including heavy metals and hazardous chemicals related to the mining process, were identified.The results indicated that soil and groundwater samples were within the acceptable limits of national standards, suggesting a low immediate risk to human health.However, the leachate from stockpiled tailings had elevated pH levels, classifying it as second-category solid waste that requires treatment.Additionally, the site is located in an area expected to be flooded by a reservoir, necessitating the prompt disposal of accumulated tailings.This research contributes to understanding the environmental risks of past mining activities and provides valuable insights for future land management and remediation in similar areas.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.pjoes.com/pdf-204188-125816?filename=Assessment of Heavy Metal.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147883336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Лей Ма, W. Guo, Xiaohui Sun, Jianqing Shi, Shenghong Liu
{"title":"Preparation and Application of MolecularlyImprinted Polymers for FivePyrethroid Insecticides","authors":"Лей Ма, W. Guo, Xiaohui Sun, Jianqing Shi, Shenghong Liu","doi":"10.15244/pjoes/202195","DOIUrl":"https://doi.org/10.15244/pjoes/202195","url":null,"abstract":"Molecularly imprinted polymers (MIPs) that had high selectivity for five pyrethroid pesticides with high detection and exceedance rates were synthesized through precipitation polymerization using ethyl chrysanthemate and phenyl ether-biphenyl eutectic mixture as double template molecules, acrylamide as a functional monomer, ethylene glycol dimethacrylate as a crosslinking agent, and acetonitrile as a porogen. The imprinted polymers prepared were then characterized and evaluated through scanning electron microscopy (SEM) and an equilibrium adsorption experiment. The results showed that the MIPs had specific adsorption capacities for five pyrethroid pesticides. A solidphase extraction column was prepared using the synthesized polymers as the adsorption material, and a molecularly imprinted solid-phase extraction-gas chromatography equipped with an electron capture detector (MI-SPE-GC-ECD) method was confirmed for the determination of five pyrethroid pesticide residues in agricultural products. A good linear relationship was present between the peak area and the concentration of pyrethroid insecticides within the range of 2-100 μg/kg. The correlation coefficient (R<sup>2</sup>) was greater than 0.9930, and the minimum limits of detection and quantification were 15.5-25.8 and 54.3-88.1 ng/L, respectively. Under different levels of additives, the standard recovery of pyrethroid pesticides in the samples varied from 72.8% to 110.2%, and the relative standard deviation (RSD) was less than 5.5%. In conclusion, this method enables the rapid separation and efficient enrichment of multiple pyrethroid pesticides in agricultural products in a single step.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"35 2","pages":"2727-2737"},"PeriodicalIF":0.0,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.pjoes.com/pdf-202195-124523?filename=Preparation and.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147910883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Degradation of Chloramphenicolby VUV/Peroxymonosulfate Process: Kinetics,Effects of Water Matrix Components,Modeling and Economic Optimization","authors":"Xing Zhang, Jinghan Liu, Yizi Liu, LU Chang-hua, Shuqing Li, Zhen Zhou","doi":"10.15244/pjoes/196730","DOIUrl":"https://doi.org/10.15244/pjoes/196730","url":null,"abstract":"As a cost-effective and wide-spectrum antibiotic with potent antibacterial properties, CAP (chloramphenicol) has been widely used in aquaculture and human medicine in recent years and is difficult to degrade by traditional biological treatment methods. In this study, the kinetics and economy in the oxidization of CAP by the VUV/PMS (peroxymonosulfate) process were investigated. The degradation of CAP was exhibited remarkably by the VUV/PMS process, compared with the individual effects of VUV and PMS. The degradation reaction followed pseudo-zero-order kinetics, with R<sup>2</sup> of 0.993, indicating a relatively constant rate of degradation under certain conditions. Quenching experiments revealed that hydroxyl radicals (•OH) played a predominant role in the reaction. The degradation process was simulated effectively by a quadratic polynomial model, with degradation efficiency as the response variable and dosages of PMS, UV power, and retention time as independent variables, utilizing response surface methodology (RSM). The lowest total operating cost for CAP degradation was determined to be 0.417 USD/m³/order.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"35 1","pages":"961-975"},"PeriodicalIF":0.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.pjoes.com/pdf-196730-123709?filename=Degradation of.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147913451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Analysis of Water-Sand Changes and Influencing\u0000Factors in the Ganjiang River Basin\u0000from 1958-2019","authors":"Siyu Zheng, Jiawei Chen, Jianbo Qiao, Xiaoting Pan, Xiaojuan Xu, Li Zhang, Guihua Liu, Xinchen Gu","doi":"10.15244/pjoes/174482","DOIUrl":"https://doi.org/10.15244/pjoes/174482","url":null,"abstract":"Understanding historical changes of water and sand characteristics in the Ganjiang River basin and their influencing factors is critical task for ecological construction, water resources management, and human production and life in the basin. We here used Mann-Kendall and sliding t-tests to analyze the annual runoff and annual sand transport in the basin based on data from Ganjiang River hydrological stations from 1958 to 2019. Our results show that: (1) the interannual variation of runoff in the Ganjiang River basin from 1958 to 2019 is significant, alternating between flat, dry, and abundant water conditions, with an abrupt change occurring in 1990 at all stations. (2) The annual sand transport at all stations showed a significant decrease, being most significant at Waizhou and Ji'an stations. Abrupt changes in the amount of sand transported at four upstream stations, Ji'an Station, and Waizhou Station were seen during 2002, 1994, and 1997, respectively. (3) Sand transport in the basin varies with runoff, and the two are highly correlated. Factors such as climate change and human activities can affect water and sand changes in the Ganjiang River basin, which requires a thorough understanding of how climate change may impact ecological protection and the strengthening water resources management.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"29 7","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139383043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}