{"title":"Evaluation of the effectiveness and strength characteristics of Scotchkote® 2400 pipe coating","authors":"","doi":"10.31615/j.corros.prot.2020.97.3-1","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.97.3-1","url":null,"abstract":"The article is concerned with the current problem of restoring the required performance of water pipelines of public water supply systems. The effectiveness of using trenchless pipe rehabilitation technologies is noted. The article analyzes the results of the experiments for determining the strength characteristics of Scotchkote® 2400 protective corrosion resistant coating of pipes that were carried out in the laboratory of the Water Supply and Sanitation Department of the Moscow State University of Civil Engineering with Instron 3345 electromechanical tensile testing machine. The effectiveness of Scotchkote® 2400 protective coating relative to restoring and improving the strength and hydraulic characteristics of worn water pipelines was shown. The author comes to the conclusion that Scotchkote®2400 protective coating is a substantial alternative to cement-sand and other internal coatings, since in many respects it surpasses them owing to the ability of colmatage sealing of large diameter holes; high wear resistance; smooth surface; ability to endure high hydraulic pressures. The coating does not overlap service connections and slightly reduces the diameter of the restored pipelines. Based on the studies, comparative characteristics of Scotchkote® 2400 protective coating spraying technology with the basic methods of trenchless pipeline reconstruction are presented. Mathematical processing of the results of experimental studies of the physicomechanical characteristics of Scotchkote® 2400 coating is given. As a result of the studies, the calculated values of the protective coating thicknesses for partially worn and completely worn out pipelines are obtained and recommended.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84663326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation of the accumulation of alloying elements (Mn, Ni, Mo) on the surface of high-alloy steel in acid medium","authors":"","doi":"10.31615/j.corros.prot.2020.97.3-5","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.97.3-5","url":null,"abstract":"The formation of corrosion products in the surface layers of steel 15KH12VNMF brand was investigated in solutions of hydrochloric, sulfuric, phosphoric, and nitric acids. Comparative data were obtained on the accumulation of impurity alloying elements in surface layers of high-alloy steel 15KH12VNMF brand. The content of alloying elements was defined in the surface layer of steel and corrosion products when holding samples in solutions with a certain concentration for 1 hour. The obtained data indicate that the accumulation of manganese, molybdenum and nickel in the surface layer does not occur in the sulfuric acid solution. The surface layers in the solution of phosphoric acid accumulate intensively alloying impurities, whereas in nitric and hydrochloric acids there is a selective accumulation. The surface films on the steel 15KH12VNMF brand in solutions of hydrochloric, sulfuric, phosphoric, nitric acids were Identified at high concentrations and times of incubation. It was established that the rate of manganese accumulation in hydrochloric acid is constant, regardless of the acid concentration. For nickel and molybdenum, the rate of accumulation increases at initial concentrations, and tends to its constant value at high concentrations. In sulfuric acid solutions, the amount of manganese on the surface depends not only on the concentration, but also on the holding time. The accumulation of nickel and molybdenum on the surface of the plate depends as on the concentration and the time. It was determined that in solutions of phosphoric acid the accumulation of manganese occurs only at the primary time, in the future remains constant. The accumulation of nickel and molybdenum on the surface depends as on the concentration and the time and has a similar character. The data are obtained that the accumulation of manganese, nickel, molybdenum on the surface of the sample in solutions of nitric acid with increasing concentration occurs regardless of the holding time of the sample.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"27 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89698879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Bactericidal properties of a combined corrosion inhibitor in the presence of SRB","authors":"","doi":"10.31615/j.corros.prot.2020.97.3-3","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.97.3-3","url":null,"abstract":"The bactericidal properties of the combined inhibitor with respect to two types of Desulfovibrio desulfuricans and Desulfomicrobium sulfate-reducing bacteria were studied. The effect of the inhibitor on the number of bacterial cells and the formation of hydrogen sulfide in Postgate nutrient Postgate “B” was evaluated. It has been shown that the combined inhibitor exhibits a bacteriostatic effect on to sulphate-reducing bacteria. It was revealed that the degree of suppression of the number of microorganisms Desulfovibrio desulfuricans at a concentration of the combined inhibitor 100,0 mg/L is higher than Desulfomicrobium. In the latter case, to achieve this effect, 120,0 mg/L concentration of the combined inhibitor is required. The studied combination inhibitor causes the inhibition of hydrogen diffusion in steel St3 in the MI medium saturated with H2S and CO2 separately and together, and also contributes to preserving the ductile properties of the steel St3 after exposure to solutions compared to non-inhibited media.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"236 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73361833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"New software for corrosion research based on IPC series potentiostats","authors":"","doi":"10.31615/j.corros.prot.2020.97.3-6","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.97.3-6","url":null,"abstract":"The developed IPC-CorrMeter software is intended for studying corrosion of metals, alloys, and coatings and estimating the efficiency of anti-corrosion protection by emulating the operation of a “Corrosimeter” device in potentiostats of the IPC series that allows implementing well-known and reliable corrosion-electrochemical methods, such as linear polarization resistance, zero resistance amperometry, and potentiometry in the existing serial IPC potentiostats. The advantages of the new software include: a possibility of continuous automatic use of these methods in the study of corrosion processes, obtaining results almost in real time mode, high sensitivity and a wide adjustable range of measurements of the rates of general and pitting corrosion (from 1 nm to tens of mm per year), no absence of any restrictions regarding the RAM size of the device. Quantitative dependences of the general and pitting corrosion rate of steel St3 in water are obtained in the presence of the industrial СARTEС-28B corrosion inhibitor for hydraulic testing of mud pumps. They confirm the reliability, accuracy, high sensitivity, and validity of the IPC-CorrMeter software and equipment for researching metal corrosion and allow evaluating the efficiency of anti-corrosion protection agents, as well as the high efficiency of this inhibitor.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76263829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Surface modification of ferrosilide alloys for anode earthing","authors":"","doi":"10.31615/j.corros.prot.2020.97.3-4","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.97.3-4","url":null,"abstract":"It is known that the disadvantages of ferrosilide earthing devices are their fragility, which leads to their frequent mechanical damage. Their fragility is increased with increasing silicon content. The solution to this problem is to reduce the content of silicon in the alloy, but this greatly increases the rate of dissolution of the resulting alloy. As a result, the possibility of reducing the dissolution rate of ferrosilides with a silicon content of 9…12% due to thermal oxidation and treatment in a phosphoric acid medium was studied. The most promising method for anode grounding conductors is the method of processing materials in orthophosphoric and metaphosphoric acids with the formation on the surface of a phase of iron silicide highly resistant to anodic dissolution due to selective etching of the alloy. The relationship between the phase composition of the films showed that mainly phases of silicon oxide (SiO2) and magnetite (Fe3O4) predominate in the alloys, as a result of which the dissolution rate is significantly reduced. As a result of heat treatment of ferrosilide alloys with a silicon content of less than 14%, a decrease in the dissolution rate does not occur due to the high porosity of the formed films and the presence of phases that do not have protective properties. The anodic dissolution rate is the lower, when the grain size of the alloy used is the larger.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"20 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83509875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Research universal combined inhibitor for the oil and gas industry","authors":"M. B. Adigezalova","doi":"10.31615/j.corros.prot.2020.96.2-4","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.96.2-4","url":null,"abstract":"Using the gravimetric method, the inhibitory efficiency of the combined inhibitor with respect to hydrogen sulfide and carbon dioxide corrosion of St3 steel in model produced water MI was studied. Corrosion tests were carried out in 0,5 liter sealed vessels on St3 samples of size 30х20х1. Gossypol resin + MARZA was used as a multifunctional combined inhibitor. Diesel fuel and kerosene were used as solvent. It has been established that the protective effect of using a multi-functional combined inhibitor in formation water with oil containing hydrogen sulfide and carbon dioxide using kerosene as a solvent ranges from 75 to 96 and for diesel as 80 to 100. The combined inhibitor allows to achieve in the MI medium containing hydrogen sulfide and carbon dioxide in the process of daily testing the corrosion rate of steel is about 0,04 g/m2·h. only in a concentration of not less than 70 mg/l. However, with an increase in the duration of the test by an order of magnitude, a similar corrosion rate is observed already at an inhibitor concentration of 50 mg/l. The same is characteristic of carbon dioxide and hydrogen sulfide - carbon dioxide solutions.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"32 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75376948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Markelov, N. Mineeva, A. P. Akol´zin, B. Kochurov, M. Grigorieva, E. A. Chukmasova
{"title":"Models and functioning «alive geofilters» based on the geoecological framework","authors":"D. Markelov, N. Mineeva, A. P. Akol´zin, B. Kochurov, M. Grigorieva, E. A. Chukmasova","doi":"10.31615/j.corros.prot.2020.96.2-5","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.96.2-5","url":null,"abstract":"The territory and its natural frame are the arena of all chemical, biological, technical interactions and processes, and the wind and rain are their natural propellers. The cartographic image of space, as an integral indicator of processes, phenomena, carries the function of a guide mark in the basis of control and regulation of durability and protection of structures in the natural frame. This article presents the results of a city life support system simulation in the light of the concept of forecasting and managing the risk of the danger of air pollution, including in the practice of anti-corrosion protection. Monitoring of the surveillance and control system grows into the life support system of the territory. “Technologies at a glance” provide: an assessment of the fields and halos of danger from air pollution (real and predicted state maps), modeling “alive geofilters”, namely, purification methods, preventive protection measures, formation of city breeze corridors or wind tunnels.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"515 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86866826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. I. Aliyeva, L. M. Efendiyeva, V. Abbasov, G. Rustamli, S. Akhmedbekova
{"title":"The complexes of synthetic and petroleum acids N-derivatives as steel acidic corrosion inhibitors","authors":"L. I. Aliyeva, L. M. Efendiyeva, V. Abbasov, G. Rustamli, S. Akhmedbekova","doi":"10.31615/j.corros.prot.2020.96.2-2","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.96.2-2","url":null,"abstract":"Oxy- and petroleum acids were synthesized by liquid-phase oxidation of naphthen-paraffin concentrate, separated from diesel fraction of Azerbaijani oils mixture with atmospheric oxygen in the presence of heterogeneous catalytic systems. As the catalyst aluminum nano-oxide modified by Cr ,Co, Mn transition metals was used. The oxidation was carried out in reactor of bubble type in the interval of temperature 135…140 ºС during 5 h. Their imidazoline derivatives were obtained by the use of the synthesized acids and polyamines, and the complexes were prepared on the basis of them and aliphatic monobasic acids (formic and acetic) at equal molar ratio. Their influence was studied on the kinetics of the corrosion process of C1018 steel samples in 1% solution of NaCl, saturated by CO2 at 50 °С. The complexes were tested as inhibitors of carbon dioxide corrosion at concentration of 25 and 50 ppm in 20 h. According to obtained data, the usage of different concentrations of complexes decreases corrosion rate and metal loss (up to 9…10 times). The values of surface coverage (θ) and the extent of inhibition efficiency (IE, %) of corrosion process of steel example in CO2-medium in presence of prepared complexes were calculated. IR spectra of surface layer of used electrodes were recorded before and after adding prepared complexes into corrosion medium. As a result of the studies it was determined, that the obtained complexes had high prospects for use (protection degree 97…98%) as CO2-corrosion inhibitors in suppressing of carbon dioxide corrosion of steel equipment.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"41 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82360686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Determination of the priority of withdrawal to repair of equipment of anti-corrosive protection on the section of the gas pipeline in the conditions of restriction of financing","authors":"S. Sabanov, S. Nikulin, E. L. Karnavskiy","doi":"10.31615/j.corros.prot.2020.96.2-1","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.96.2-1","url":null,"abstract":"Based on the experience of the operating organizations and results of previous studies, it is determined, that the more rational criterion for the withdrawal in the repair of insulation coating on the section of the pipeline is the reserve of the current from the nominal value, and the criterion of withdrawal in the repair of anode grounding is a reserve of voltage from the nominal value. It has been revealed that with data on changes in the output parameters of the cathode protection station and protection potential at the control point for a certain period, it is possible to predict the change in the factor of influence of the station at this point for a certain period and, therefore, to predict changes in the modes of operation of this station and the technical condition of the anti-corrosion protection system at the specified required range of maintenance level of protective potential. Based on the above conclusions, algorithms have been developed to assess the residual resource of the anti-corrosion protection system on the gas pipeline site and make management decisions on its extension based on the received values in the conditions funding restrictions. Also, an algorithm has been developed to determine the residual resource of the anti-corrosion protection system with the most effective redistribution of parameters between the cathode protection stations and an algorithm that allows to determine the priority of output in the repair of the system elements.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"116 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87717964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. S. Adilova, Andrey B. Drovosekov, A. Aliev, A. Shiryaev
{"title":"Electrodeposition of Ni-W-P alloy","authors":"S. S. Adilova, Andrey B. Drovosekov, A. Aliev, A. Shiryaev","doi":"10.31615/j.corros.prot.2020.95.1-7","DOIUrl":"https://doi.org/10.31615/j.corros.prot.2020.95.1-7","url":null,"abstract":"Influence of sodium hypophosphite admixture to electrolyte for deposition of Ni-W alloy on the coating composition, morphology, structure and microhardness is investigated. Antisymbatic dependence of tungsten and phosphorus content in Ni-W and Ni-W-P alloys on the sodium hypophosphite concentration in the electrolyte is observed, namely, at higher sodium hypophosphite concentration in the electrolyte solution the coatings are become poorer in tungsten whereas phosphorus content is increased. Phosphorus incorporation into the alloy leads to globular morphology of the surface of coatings. The minimal roughness was obtained at high hypophosphite concentrations in the electrolyte (7.5 and 10 g/L). As-deposited Ni-W and Ni-W-P alloys possess nanocrystalline structure manifested in broad X-ray diffraction peaks. Addition of 2.5…5 g/L of hypophosphite markedly weakens Ni reflections (200) and (220), the (111) peaks becomes broader. In addition, a Ni3P phase is appeared in the coatings. Thermal treatment in vacuum at 400 °С induces growth of nickel crystallites. Microhardness of as-deposited coatings is weakly dependent on sodium hypophosphite concentration in the electrolyte and is in the range 3.8…4.2 GPa. Thermal treatment of Ni-W-P alloys at 400 °С during 1 h increases microhardness up to 5.9…8.8 GPa.","PeriodicalId":20323,"journal":{"name":"Practice of Anticorrosive Protection","volume":"137 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77941231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}