Liang Wang, Yongxiang Zhang, Mengtong Yan, Junxi Zhang, Hongbo Lu, Mei Lyu, Jun Zhu
{"title":"Low‐threshold Amplified Spontaneous Emission of Dion‐Jacobson Phase Perovskite Films Achieved by Tuning Diamine Cation Size","authors":"Liang Wang, Yongxiang Zhang, Mengtong Yan, Junxi Zhang, Hongbo Lu, Mei Lyu, Jun Zhu","doi":"10.1002/pssr.202400080","DOIUrl":"https://doi.org/10.1002/pssr.202400080","url":null,"abstract":"Dion‐Jacobson (DJ) phase perovskites have received attention in the field of amplified spontaneous radiation (ASE) and lasers due to their excellent structural stability and charge transfer performance. However, the effect of the diamine cation size on the ASE properties of DJ phase perovskite has not been studied. Herein, we systematically study the effect and the results show that tuning the size of the diamine cation can inhibit the formation of the small‐n phases, reduce the surface roughness, and passivate defects of DJ phase perovskite films. Based on those, we realize the low‐threshold ASE (65 μJ cm−2 under nanosecond laser excitation) of the 1,3‐propylenediamine cation (PDA)‐based DJ phase perovskite films. Additionally, the film exhibits excellent photostability. The ASE intensity remains at 90% of the original value after a pulsed laser irradiation of 3000 μJ cm−2 for 120 min. This work provides a strategy to realize high‐performance DJ phase perovskite ASE and lasers.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":" 458","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141364363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Masayuki Imanishi, S. Usami, K. Murakami, K. Okumura, Kosuke Nakamura, K. Kakinouchi, Y. Otoki, Tomio Yamashita, Naohiro Tsurumi, Satoshi Tamura, Hiroshi Ohno, Y. Okayama, Taku Fujimori, Seiji Nagai, Miki Moriyama, Yusuke Mori
{"title":"Characteristics of Vertical Transistors on a GaN Substrate Fabricated via Na‐flux Method and Enlargement of the Substrate Surpassing 6 Inches","authors":"Masayuki Imanishi, S. Usami, K. Murakami, K. Okumura, Kosuke Nakamura, K. Kakinouchi, Y. Otoki, Tomio Yamashita, Naohiro Tsurumi, Satoshi Tamura, Hiroshi Ohno, Y. Okayama, Taku Fujimori, Seiji Nagai, Miki Moriyama, Yusuke Mori","doi":"10.1002/pssr.202400106","DOIUrl":"https://doi.org/10.1002/pssr.202400106","url":null,"abstract":"The Na‐flux method is expected to be a key GaN growth technique for obtainning ideal bulk GaN crystals. Herein we describe the structural quality of the latest GaN crystals grown using the Na‐flux method and, for the first time, the characteristics of a vertical transistor fabricated on a GaN substrate grown using this method. Vertical transistors exhibit normally off operation with a gate voltage threshold exceeding 2 V and a maximum drain current of 3.3 A during the on‐state operation. Additionally, it demonstrates a breakdown voltage exceeding 600 V and a low leakage current during off‐state operation. We also describe that the variation in the on‐resistance can be minimized using GaN substrates with minimal off‐angle variations. This is crucial for achieving the large‐current chips required for future demonstration of actual devices. In addition, the reverse I–V characteristics of the parasitic p–n junction diode structures indicate a reduction in the number of devices with a significant leakage current compared to commercially available GaN substrates. Finally, we demonstrate a circular GaN substrate with a diameter of 161 mm, surpassing 6 in, grown using the Na‐flux method, making it the largest GaN substrate aside from those produced through the tiling technique.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":" 31","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141370066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yingjie Yang, Xiaoning Zhao, Ye Tao, Ya Lin, Zhongqiang Wang
{"title":"ZIF‐67‐derived Co@Carbon polyhedra anchored on reduced graphene oxide with multiple attenuation abilities for full X‐ and Ku‐band microwave absorption","authors":"Yingjie Yang, Xiaoning Zhao, Ye Tao, Ya Lin, Zhongqiang Wang","doi":"10.1002/pssr.202400159","DOIUrl":"https://doi.org/10.1002/pssr.202400159","url":null,"abstract":"High performance microwave absorption (MA) materials are attracting growing attention to solve the expanded electromagnetic interference problems. Herein, zeolitic imidazolate organic frameworks (MOF)‐67 (ZIF‐67) are grown in‐situ on the sheet of graphene oxide (GO) through the coordination of Co2+ with oxygen functional groups. Through carbonization in an inert atmosphere, Co@carbon polyhedra (Co@CP)‐decorated reduced GO composites (Co@CP‐rGO) with a large number of heterogeneous interfaces are successfully obtained. The composites demonstrate excellent MA performance. With a filler loading of 10 wt%, the optimal minimum reflection loss (RL) of the composite can reach ‐54.6 dB. More importantly, the composites with thickness of 3.5 mm and 2.5 mm show the effective absorption bandwidth (EAB, RL < ‐10 dB) of 4.75 GHz (8.18‐12.93 GHz) and 6.56 GHz (11.44GHz‐18GHz), fully covering the X‐band and Ku‐band. It is proposed that the synergistic effect of multiple dielectric loss, magnetic loss, reflections and scattering contributes to the high MA performance.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":" 20","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141370928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Low intensity and low temperature (LILT) effects on the Upright Metamorphic Four‐Junction (UMM4J) solar cells","authors":"Jiaming Zhou, Kelun Zhao, Yanqing Zhang, Chaoming Liu, Xinyi Li, Lijie Sun, Hongquan Zheng, Chunhua Qi, Guoliang Ma, Tianqi Wang, Mingxue Huo","doi":"10.1002/pssr.202400162","DOIUrl":"https://doi.org/10.1002/pssr.202400162","url":null,"abstract":"UMM4J solar cells are evaluated under different LILT conditions. The efficiency findings near Earth’s orbit (1 sun, 300 K), Jupiter (0.032 sun, 123 K), and Saturn (0.01 sun, 100 K) are 26.54%, 29.68%, and 28.27%. According to single diode model, Jsc is linear with light intensity (I), while Voc is linear with the natural logarithm of light intensity (ln(I)). Voc shows a linear relationship with temperature within the range of 150K to 300K, with a temperature coefficient of ∽ ‐7. 7 mV/K. However, Voc displays a sublinear relationship with temperature below 150K.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":"65 s257","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141376344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G.M. Cohen, A. Majumdar, C. Cheng, A. Ray, D. Piatek, L. Gignac, C. Lavoie, A. Grun, H. Cheng, Z-L. Liu, H. Lung, H. Miyazoe, R. L. Bruce, M. BrightSky
{"title":"Low reset current mushroom cell phase‐change memory (PCM) using fiber‐textured homostructure GeSbTe on highly oriented seed layer","authors":"G.M. Cohen, A. Majumdar, C. Cheng, A. Ray, D. Piatek, L. Gignac, C. Lavoie, A. Grun, H. Cheng, Z-L. Liu, H. Lung, H. Miyazoe, R. L. Bruce, M. BrightSky","doi":"10.1002/pssr.202300426","DOIUrl":"https://doi.org/10.1002/pssr.202300426","url":null,"abstract":"We report a low reset current 1T1R mushroom cell phase‐change memory (PCM) device that uses fiber‐textured homostructure GeSbTe (GST) grown on highly‐oriented TiTe2 seed layer. The homostructure device outperformed the industry standard device, that uses doped polycrystalline GST, on most figures of merit. The homostructure devices were also benchmarked against superlattice PCM devices with 10 periods of 5/5nm GST/Sb2Te3 grown on the TiTe2 seed layer, and were found to have same low reset current. We also observed by TEM that the alternating layers of GST/Sb2Te3 and TiTe2/Sb2Te3 in superlattice devices is intermixed in the switched region after the devices are cycled with reset/set pulses. Additionally, when the superlattice device is left in the set state the intermixed switched region crystallinity is textured and exhibits van der Waals gaps. The superlattice PCM devices require a precise layered structure that is hard to yield on a full wafer scale. In contrast, fiber‐textured homostructure PCM cells reported here are easily manufacturable, while providing similarly low reset current and low resistance drift which makes this device suitable for analog AI computation.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":"298 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141386523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Demonstration of near‐size independent EQE for 368 nm UV micro‐LEDs","authors":"Guangying Wang, Shuwen Xie, Yuting Li, Wentao Zhang, Jonathan Vigen, Timothy Shih, Qinchen Lin, Jiarui Gong, Zhenqiang Ma, S. Pasayat, Chirag Gupta","doi":"10.1002/pssr.202400119","DOIUrl":"https://doi.org/10.1002/pssr.202400119","url":null,"abstract":"UV‐ranged micro‐LEDs are being explored for numerous applications due to their high stability and power efficiency. However, previous reports have shown reduced EQE and increased leakage current due to the increase in surface‐to‐volume ratio with a decrease in the micro‐LED size. In this work, we studied the size‐related performance for UV‐A micro‐LEDs, ranging from 8 × 8 µm2 to 100 × 100 µm2. These devices exhibited reduced leakage current with the implementation of ALD based sidewall passivation. A systematic EQE comparison was performed with minimal leakage current and obtained a size‐independent on‐wafer EQE of around 5.5%. Smaller sized devices experimentally showed enhanced EQE at high current density due to their improved heat dissipation capabilities. To the best of authors’ knowledge, this is the highest reported on‐wafer EQE demonstrated in < 10 µm dimensioned 368 nm UV LEDs.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":"51 24","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141103065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tabish Aftab, Osbel Almora, J. Ferré‐Borrull, L. Marsal
{"title":"3D Nanostructured Electrodes based on Anodic Alumina Templates for Stable Pseudo‐capacitors","authors":"Tabish Aftab, Osbel Almora, J. Ferré‐Borrull, L. Marsal","doi":"10.1002/pssr.202400144","DOIUrl":"https://doi.org/10.1002/pssr.202400144","url":null,"abstract":"This study investigates the preparation of nickel nanostructured electrodes for the enhancement of supercapacitor (SC) performance. The nanostructured electrodes were synthesized using nanoporous anodic aluminium oxide (NAA) as a template via the pulsed electrodeposition method. Structural properties were examined using field‐emission scanning electron microscopy (FESEM), while electrochemical characterization was conducted through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The results reveal that Ni nanorod arrays can be obtained embedded in the NAA matrix and with electrical contact with the aluminium substrate. On average, the rods are spaced 90 nm apart, with a diameter of 70 nm and a length of 2 µm. The Ni@NAA electrode exhibit an enlarged active area and exceptional electrochemical performance, demonstrating remarkable stability over 5000 cycles of CV at a scan rate of 50 mV·s‐1. Specific capacitance values exceeding 100 mF·cm‐2 and maximum charging times of less than 10 minutes are reported, highlighting its suitability for high‐power energy devices requiring pseudo‐supercapacitance. The study underscores the significance of nanostructured electrodes in advancing energy storage technologies and presents promising prospects for practical applications.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":"25 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141104432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Goll, Marius Boettle, Joerg Buschbeck, R. Loeffler, Gerhard Schneider
{"title":"High Cerium content Fe‐Ce‐Nd‐B sintered magnets with high coercivity","authors":"D. Goll, Marius Boettle, Joerg Buschbeck, R. Loeffler, Gerhard Schneider","doi":"10.1002/pssr.202400151","DOIUrl":"https://doi.org/10.1002/pssr.202400151","url":null,"abstract":"Ce substitution of Nd in FeNdB sintered magnets is very interesting for reasons of resource efficiency, sustainability and costs. However, the magnetic properties of high Ce‐content magnets are poor. This is mainly due to the lower values of intrinsic magnetic properties of Fe14Ce2B compared to Fe14Nd2B as well as the Laves phase Fe2Ce, which is formed in the grain boundaries and forms flat aggregates for higher Ce‐content. In this paper, sintered magnets with 75 at% degree of substitution of the composition Fe70.9‐[(Ce1‐xLax)0.75Nd0.25]18.8‐B5.8‐M4.5 (M = Co, Ti, Al, Ga, Cu, 0 ≤ × ≤ 0.3) are produced and analyzed. It is shown that a new rare earth rich grain boundary phase is formed adding La and that the Laves phase fraction can be reduced by up to 85%. With increasing La content, the remanence and Curie temperature increase and the temperature coefficient of Hc improves. A coercivity, remanence and maximum energy density of up to µ0Hc = 0.74 T, Jr = 0.98 T and (BH)max = 139.9 kJ/m3 have been achieved.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":"53 20","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141107267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Graphene plasmonic time crystals","authors":"Kwang-Hyon Kim, O. Kang-Hyok","doi":"10.1002/pssr.202400116","DOIUrl":"https://doi.org/10.1002/pssr.202400116","url":null,"abstract":"The concept of photonic crystals has recently been extended to the time domain and attracted great interest. Unfortunately, realizing photonic time crystals is a challenging task due to the practical difficulty in modulating dielectric constants with large modulation depth. This problem can be resolved by using graphene, the conductivity of which is tunable with significantly large contrast. In this report, graphene plasmonic time crystals, as a new kind of photonic time crystals in atomically thin two‐dimensional material, are proposed and their optical properties are investigated. Their bandstructures are analytically calculated and the propagations of graphene plasmons in temporal crystalline structures are numerically evaluated. Periodically driven by temporally modulating the Fermi energy, graphene plasmons exhibit in‐gap amplification and defects‐immune topological edge states, revealing the nature as plasmonic time crystals. Graphene plasmonic time crystals will be realized soon after this proposal due to the possibility of modulating its conductivity with large contrast by simple electrical gating.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":"54 36","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141108624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yang Xiang, Hao Tang, Zihao Zhu, Bo Pang, Tingjun Zhou, H. Zhan, Junyong Kang, Yongliang Zhou
{"title":"First‐principles Study of the Al‐N co‐doped Zincblende ZnO","authors":"Yang Xiang, Hao Tang, Zihao Zhu, Bo Pang, Tingjun Zhou, H. Zhan, Junyong Kang, Yongliang Zhou","doi":"10.1002/pssr.202400104","DOIUrl":"https://doi.org/10.1002/pssr.202400104","url":null,"abstract":"Electronic properties of intrinsic ZnO, N doped ZnO and Al‐N co‐doped ZnO of both hexagonal wurtzite (HW) and zinc blende (ZB) structures were investigated by first‐principles calculations. Both N doped ZB‐ZnO and N doped HW‐ZnO achieve p‐type transition by the introduction of N‐2p states, forming shallow acceptor levels above the valence band. However, the positive impurity formation energy implied the difficulty and instability of N‐doped ZnO. In Al‐N co‐doped ZnO, the Al elements compensate the p‐type doping effect, but partially enhance the solubility of N. Furthermore, the comparison of the electronic properties between HW‐ZnO and ZB‐ZnO, indicated that the ZB structure favors the achieving of p‐type doping.This article is protected by copyright. All rights reserved.","PeriodicalId":20059,"journal":{"name":"physica status solidi (RRL) – Rapid Research Letters","volume":"64 14","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141110403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}