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Rock physical characteristics of deep dolomite under complex geological conditions: A case study of 4th Member of Sinian Dengying Formation in the Sichuan Basin, China 复杂地质条件下深部白云岩的岩石物理特征:四川盆地四川盆地四川盆地四川盆地四川盆地四川盆地四川盆地四川盆地
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.03.015
{"title":"Rock physical characteristics of deep dolomite under complex geological conditions: A case study of 4th Member of Sinian Dengying Formation in the Sichuan Basin, China","authors":"","doi":"10.1016/j.petsci.2024.03.015","DOIUrl":"10.1016/j.petsci.2024.03.015","url":null,"abstract":"<div><p>The deep-ultra deep carbonate reservoir in China, commonly subjected to modification of multi-stage diagenesis, has extremely high heterogeneity. Conventional rock physics analysis cannot accurately identify the elastic responses of reservoir. Here, the rock physics properties of the dolomite from the 4th Member of the Sinian Dengying Formation are experimentally measured, and the change law of rock physics characteristics is investigated within the framework of the diagenetic processes by the analysis of the elastic and petrologic characteristics, pore structure, and sedimentary environments. The results show that the differentiated diagenesis results in different pore structure characteristics and micro-texture characteristics of the rock. The microbial dolomite of the algal mound-grain beach facies is subjected to the contemporaneous microbial dolomitization and seepage-reflux dolomitization, penecontemporaneous selective dissolution, burial dolomitization, and hydrothermal dolomitization. The resultant crystalline dolomite is found with one main type of the dolomite crystal contact boundaries, and the dissolution pore is extensive development. The siliceous, muddy, and limy dolomite of the inter-beach sea environment mainly experiences the weak capillary concentration dolomitization, intensive mechanical compaction-induced densification, and burial dolomitization. Such crystalline dolomite is observed with four types of contact boundaries, namely the dolomite contact, clay contact, quartz contact, and calcite contact boundaries, and porosity mostly attributed to residual primary inter-granular or crystalline pores. The samples with the same crystal boundary condition have consistent correlations between the compressional- and shear-wave velocities, and between the compressional-wave velocity and the velocity ratio. Additionally, the variation of the acoustic velocity with effective pressure and the intensity of pore-scale fluid-related dispersion are controlled by the differentiation of pore structure types of the samples. The varied effects of soft pores like micro-cracks on the compressional- and shear-wave velocity causes considerable changes in the relationships between the compressional- and shear-wave velocities, compressional-wave velocity and velocity ratio, and porosity and acoustic velocity. This research is an attempt to demonstrate a novel method for investigating the rock physics variation of rock during the geological process, and the obtained findings can provide the rock physics basis for seismic prediction of the characteristics of deep carbonate reservoirs.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000700/pdfft?md5=b9b83b73eb757e9ddc36b63b04769c39&pid=1-s2.0-S1995822624000700-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140770129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
TOC 技术选择委员会
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/S1995-8226(24)00216-4
{"title":"TOC","authors":"","doi":"10.1016/S1995-8226(24)00216-4","DOIUrl":"10.1016/S1995-8226(24)00216-4","url":null,"abstract":"","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624002164/pdfft?md5=53adc145246b2cd1251ef34e4ef29fb0&pid=1-s2.0-S1995822624002164-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142050062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Similarities and differences in inherent mechanism and characteristic frequency between the one-dimensional poroelastic model and the layered White model 一维孔弹性模型与分层怀特模型在内在机理和特征频率方面的异同
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.04.001
{"title":"Similarities and differences in inherent mechanism and characteristic frequency between the one-dimensional poroelastic model and the layered White model","authors":"","doi":"10.1016/j.petsci.2024.04.001","DOIUrl":"10.1016/j.petsci.2024.04.001","url":null,"abstract":"<div><p>The similarities and differences in inherent mechanism and characteristic frequency between the one-dimensional (1D) poroelastic model and the layered White model were investigated. This investigation was conducted under the assumption that the rock was homogenous and isotropic at the mesoscopic scale. For the inherent mechanism, both models resulted from quasi-static flow in a slow P-wave diffusion mode, and the differences between them originated from saturated fluids and boundary conditions. On the other hand, for the characteristic frequencies of the models, the characteristic frequency of the 1D poroelastic model was first modified because the elastic constant and formula for calculating it were misused and then compared to that of the layered White model. Both of them moved towards higher frequencies with increasing permeability and decreasing viscosity and diffusion length. The differences between them were due to the diffusion length. The diffusion length for the 1D poroelastic model was determined by the sample length, whereas that for the layered White model was determined by the length of the representative elementary volume (REV). Subsequently, a numerical example was presented to demonstrate the similarities and differences between the models. Finally, published experimental data were interpreted using the 1D poroelastic model combined with the Cole-Cole model. The prediction of the combined model was in good agreement with the experimental data, thereby validating the effectiveness of the 1D poroelastic model. Furthermore, the modified characteristic frequency in our study was much closer to the experimental data than the previous prediction, validating the effectiveness of our modification of the characteristic frequency of the 1D poroelastic model. The investigation provided insight into the internal relationship between wave-induced fluid flow (WIFF) models at macroscopic and mesoscopic scales and can aid in a better understanding of the elastic modulus dispersion and attenuation caused by the WIFF at different scales.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624001006/pdfft?md5=418fe361bd55e946d196f35bef439aa5&pid=1-s2.0-S1995822624001006-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140760976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation of dynamic characteristics of leaching tubing for solution mining of salt cavern carbon and energy storage 用于盐穴碳溶液开采和储能的浸出管动态特性实验研究
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.06.015
Yin-Ping Li , Xin-Bo Ge , Xi-Lin Shi , Hong-Ling Ma
{"title":"Experimental investigation of dynamic characteristics of leaching tubing for solution mining of salt cavern carbon and energy storage","authors":"Yin-Ping Li ,&nbsp;Xin-Bo Ge ,&nbsp;Xi-Lin Shi ,&nbsp;Hong-Ling Ma","doi":"10.1016/j.petsci.2024.06.015","DOIUrl":"10.1016/j.petsci.2024.06.015","url":null,"abstract":"<div><p>Salt caverns are extensively utilized for storing various substances such as fossil energy, hydrogen, compressed air, nuclear waste, and industrial solid waste. In China, when the salt cavern is leached through single-well water solution mining with oil as a cushion, engineering challenges arise with the leaching tubing, leading to issues like damage and instability. These problems significantly hinder the progress of cavern construction and the control of cavern shape. The primary cause of this is the flow-induced vibration instability of leaching tubing within a confined space, which results in severe bending or damage to the tubing. This study presents a model experimental investigation on the dynamic characteristics of leaching tubing using a self-developed liquid-solid coupling physical model experiment apparatus. The experiment utilizes a silicone-rubber pipe (SRP) and a polycarbonate pipe (PCP) to examine the effects of various factors on the dynamic stability of cantilevered pipes conveying fluid. These factors include external space constraint, flexural rigidity, medium outside the pipe, overhanging length, and end conditions. The experiments reveal four dynamic response phenomena: water hammer, static buckling, chaotic motion, and flutter instability. The study further demonstrates that the length of the external space constraint has a direct impact on the flutter critical flow velocity of the cantilevered pipe conveying fluid. Additionally, the flutter critical flow velocity is influenced by the end conditions and different external media.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S199582262400178X/pdfft?md5=2c0116389c4ac1bef22fcf08ca8ea7f6&pid=1-s2.0-S199582262400178X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142050063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs 大陆页岩油藏原位转换中的流体生产数值评估
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.05.025
{"title":"Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs","authors":"","doi":"10.1016/j.petsci.2024.05.025","DOIUrl":"10.1016/j.petsci.2024.05.025","url":null,"abstract":"<div><p>In-situ conversion presents a promising technique for exploiting continental oil shale formations, characterized by highly fractured organic-rich rock. A 3D in-situ conversion model, which incorporates a discrete fracture network, is developed using a self-developed thermal-flow-chemical (TFC) simulator. Analysis of the model elucidates the in-situ conversion process in three stages and defines the transformation of fluids into three distinct outcomes according to their end stages. The findings indicate that kerogen decomposition increases fluid pressure, activating fractures and subsequently enhancing permeability. A comprehensive analysis of activated fracture permeability and heating power reveals four distinct production modes, highlighting that increasing heating power correlates with higher cumulative fluid production. Activated fractures, with heightened permeability, facilitate the mobility of heavy oil toward production wells but hinder its cracking, thereby limiting light hydrocarbon production. Additionally, energy efficiency research demonstrates the feasibility of the in-situ conversion in terms of energy utilization, especially when considering the surplus energy from high-fluctuation energy sources such as wind and solar power to provide heating.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624001559/pdfft?md5=e077223e7565e5f6acb7baa64ab3d660&pid=1-s2.0-S1995822624001559-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141512036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of inter-well interference in shale gas reservoirs by a robust production data analysis method based on deconvolution 基于解卷积的稳健生产数据分析方法对页岩气藏井间干扰的研究
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.03.003
{"title":"Study of inter-well interference in shale gas reservoirs by a robust production data analysis method based on deconvolution","authors":"","doi":"10.1016/j.petsci.2024.03.003","DOIUrl":"10.1016/j.petsci.2024.03.003","url":null,"abstract":"<div><p>In order to overcome the defects that the analysis of multi-well typical curves of shale gas reservoirs is rarely applied to engineering, this study proposes a robust production data analysis method based on deconvolution, which is used for multi-well inter-well interference research. In this study, a multi-well conceptual trilinear seepage model for multi-stage fractured horizontal wells was established, and its Laplace solutions under two different outer boundary conditions were obtained. Then, an improved pressure deconvolution algorithm was used to normalize the scattered production data. Furthermore, the typical curve fitting was carried out using the production data and the seepage model solution. Finally, some reservoir parameters and fracturing parameters were interpreted, and the intensity of inter-well interference was compared. The effectiveness of the method was verified by analyzing the production dynamic data of six shale gas wells in Duvernay area. The results showed that the fitting effect of typical curves was greatly improved due to the mutual restriction between deconvolution calculation parameter debugging and seepage model parameter debugging. Besides, by using the morphological characteristics of the log-log typical curves and the time corresponding to the intersection point of the log-log typical curves of two models under different outer boundary conditions, the strength of the interference between wells on the same well platform was well judged. This work can provide a reference for the optimization of well spacing and hydraulic fracturing measures for shale gas wells.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S199582262400058X/pdfft?md5=895885a8dd74a164607af2ce8dce7b53&pid=1-s2.0-S199582262400058X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140106428","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Prediction and quantification of effective gas source rocks in a lacustrine basin: Western Depression in the Liaohe Subbasin, China 湖沼盆地有效气源岩的预测与量化:辽河次级盆地西部凹陷
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.03.007
{"title":"Prediction and quantification of effective gas source rocks in a lacustrine basin: Western Depression in the Liaohe Subbasin, China","authors":"","doi":"10.1016/j.petsci.2024.03.007","DOIUrl":"10.1016/j.petsci.2024.03.007","url":null,"abstract":"<div><p>Due to limited data on the geochemical properties of natural gas, estimations are needed for the effective gas source rock in evaluating gas potential. However, the pronounced heterogeneity of mudstones in lacustrine successions complicates the prediction of the presence and geochemical characteristics of gas source rocks. In this paper, the Liaohe Subbasin of Northeast China is used as an example to construct a practical methodology for locating effective gas source rocks in typical lacustrine basins. Three types of gas source rocks, microbial, oil-type, and coal-type, were distinguished according to the different genetic types of their natural gas. A practical three-dimensional geological model was developed, refined, and applied to determine the spatial distribution of the mudstones in the Western Depression of the Liaohe Subbasin and to describe the geochemical characteristics (the abundance, type, and maturation levels of the organic matter). Application of the model in the subbasin indicates that the sedimentary facies have led to heterogeneity in the mudstones, particularly with respect to organic matter types. The effective gas source rock model constructed for the Western Depression shows that the upper sequence (SQ2) of the Fourth member (Mbr 4) of the Eocene Shahejie Formation (Fm) and the lower and middle sequences (SQ3 and SQ4) of the Third member (Mbr 3) form the principal gas-generating interval. The total volume of effective gas source rocks is estimated to be 586 km<sup>3</sup>. The effective microbial, oil-type, and coal-type gas source rocks are primarily found in the shallow western slope, the central sags, and the eastern slope of the Western Depression, respectively. This study provides a practical approach for more accurately identifying the occurrence and geochemical characteristics of effective natural gas source rocks, enabling a precise quantitative estimation of natural gas reserves.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000621/pdfft?md5=f98b4bf7e06b6fe89f22c243ea60160a&pid=1-s2.0-S1995822624000621-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140170940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel fracture-cavity reservoir outcrop geological knowledge base construction method considering parameter collection and processing, mutual transformation of data-knowledge, application and update 一种考虑参数采集与处理、数据知识相互转换、应用与更新的新型裂隙-空腔储层露头地质知识库构建方法
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.02.009
{"title":"A novel fracture-cavity reservoir outcrop geological knowledge base construction method considering parameter collection and processing, mutual transformation of data-knowledge, application and update","authors":"","doi":"10.1016/j.petsci.2024.02.009","DOIUrl":"10.1016/j.petsci.2024.02.009","url":null,"abstract":"<div><p>This study endeavors to formulate a comprehensive methodology for establishing a Geological Knowledge Base (GKB) tailored to fracture-cavity reservoir outcrops within the North Tarim Basin. The acquisition of quantitative geological parameters was accomplished through diverse means such as outcrop observations, thin section studies, unmanned aerial vehicle scanning, and high-resolution cameras. Subsequently, a three-dimensional digital outcrop model was generated, and the parameters were standardized. An assessment of traditional geological knowledge was conducted to delineate the knowledge framework, content, and system of the GKB. The basic parameter knowledge was extracted using multiscale fine characterization techniques, including core statistics, field observations, and microscopic thin section analysis. Key mechanism knowledge was identified by integrating trace elements from filling, isotope geochemical tests, and water-rock simulation experiments. Significant representational knowledge was then extracted by employing various methods such as multiple linear regression, neural network technology, and discriminant classification. Subsequently, an analogy study was performed on the karst fracture-cavity system (KFCS) in both outcrop and underground reservoir settings. The results underscored several key findings: (1) Utilization of a diverse range of techniques, including outcrop observations, core statistics, unmanned aerial vehicle scanning, high-resolution cameras, thin section analysis, and electron scanning imaging, enabled the acquisition and standardization of data. This facilitated effective management and integration of geological parameter data from multiple sources and scales. (2) The GKB for fracture-cavity reservoir outcrops, encompassing basic parameter knowledge, key mechanism knowledge, and significant representational knowledge, provides robust data support and systematic geological insights for the intricate and in-depth examination of the genetic mechanisms of fracture-cavity reservoirs. (3) The developmental characteristics of fracture-cavities in karst outcrops offer effective, efficient, and accurate guidance for fracture-cavity research in underground karst reservoirs. The outlined construction method of the outcrop geological knowledge base is applicable to various fracture-cavity reservoirs in different layers and regions worldwide.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000451/pdfft?md5=1dd23800f03569b62fc9b995e83b42ce&pid=1-s2.0-S1995822624000451-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139926617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption behavior of CO2/H2S mixtures in calcite slit nanopores for CO2 storage: An insight from molecular perspective 用于二氧化碳封存的方解石狭缝纳米孔中 CO2/H2S 混合物的吸附行为:从分子角度看问题
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.03.016
{"title":"Adsorption behavior of CO2/H2S mixtures in calcite slit nanopores for CO2 storage: An insight from molecular perspective","authors":"","doi":"10.1016/j.petsci.2024.03.016","DOIUrl":"10.1016/j.petsci.2024.03.016","url":null,"abstract":"<div><p>It is acknowledged that injecting CO<sub>2</sub> into oil reservoirs and saline aquifers for storage is a practical and affordable method for CO<sub>2</sub> sequestration. Most CO<sub>2</sub> produced from industrial exhaust contains impurity gases such as H<sub>2</sub>S that might impact CO<sub>2</sub> sequestration due to competitive adsorption. This study makes a commendable effort to explore the adsorption behavior of CO<sub>2</sub>/H<sub>2</sub>S mixtures in calcite slit nanopores. Grand Canonical Monte Carlo (GCMC) simulation is employed to reveal the adsorption of CO<sub>2</sub>, H<sub>2</sub>S as well as their binary mixtures in calcite nanopores. Results show that the increase in pressure and temperature can promote and inhibit the adsorption capacity of CO<sub>2</sub> and H<sub>2</sub>S in calcite nanopores, respectively. CO<sub>2</sub> exhibits stronger adsorption on calcite surface than H<sub>2</sub>S. Electrostatic energy plays the dominating role in the adsorption behavior. Electrostatic energy accounts for 97.11% of the CO<sub>2</sub>-calcite interaction energy and 56.33% of the H<sub>2</sub>S-calcite interaction energy at 10 MPa and 323.15 K. The presence of H<sub>2</sub>S inhibits the CO<sub>2</sub> adsorption in calcite nanopores due to competitive adsorption, and a higher mole fraction of H<sub>2</sub>S leads to less CO<sub>2</sub> adsorption. The quantity of CO<sub>2</sub> adsorbed is lessened by approximately 33% when the mole fraction of H<sub>2</sub>S reaches 0.25. CO<sub>2</sub> molecules preferentially occupy the regions near the pore wall and H<sub>2</sub>S molecules tend to reside at the center of nanopore even when the molar ratio of CO<sub>2</sub> is low, indicating that CO<sub>2</sub> has an adsorption priority on the calcite surface over H<sub>2</sub>S. In addition, moisture can weaken the adsorption of both CO<sub>2</sub> and H<sub>2</sub>S, while CO<sub>2</sub> is more affected. More interestingly, we find that pure CO<sub>2</sub> is more suitable to be sequestrated in the shallower formations, i.e., 500–1500 m, whereas CO<sub>2</sub> with H<sub>2</sub>S impurity should be settled in the deeper reservoirs.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000839/pdfft?md5=fbc869fcf56d4e0651d0267fcedcd8fb&pid=1-s2.0-S1995822624000839-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140281221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
OFC OFC
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-08-01 DOI: 10.1016/S1995-8226(24)00214-0
{"title":"OFC","authors":"","doi":"10.1016/S1995-8226(24)00214-0","DOIUrl":"10.1016/S1995-8226(24)00214-0","url":null,"abstract":"","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":null,"pages":null},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624002140/pdfft?md5=8fd7feac2f44ae86b26214a3b8217ed0&pid=1-s2.0-S1995822624002140-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142050061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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