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Characterization of chemical composition of high viscosity heavy oils: Macroscopic properties, and semi-quantitative analysis of molecular composition using high-resolution mass spectrometry 高粘度重油化学成分的表征:宏观特性以及利用高分辨率质谱对分子成分进行半定量分析
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.02.019
{"title":"Characterization of chemical composition of high viscosity heavy oils: Macroscopic properties, and semi-quantitative analysis of molecular composition using high-resolution mass spectrometry","authors":"","doi":"10.1016/j.petsci.2024.02.019","DOIUrl":"10.1016/j.petsci.2024.02.019","url":null,"abstract":"<div><div>Heavy oil is an important resource in current petroleum exploitation, and the chemical composition information of heavy oil is crucial for revealing its viscosity-inducing mechanism and solving practical exploitation issues. In this study, the techniques of high-temperature gas chromatography and high-resolution mass spectrometry equipped with an electrospray ionization source were applied to reveal the chemical composition of typical heavy oils from western, central, and eastern China. The results indicate that these heavy oils display significant variations in their bulk properties, with initial boiling points all above 200 °C. Utilizing pre-treatment and ESI high-resolution mass spectrometry, an analysis of the molecular composition of saturated hydrocarbons, aromatic hydrocarbons, acidic oxygen compounds, sulfur compounds, basic nitrogen compounds, and neutral nitrogen compounds within the heavy oil was conducted. Ultimately, a semi-quantitative analysis of the molecular composition of the heavy oil was achieved by integrating the elemental content. The semi-quantitative analysis results of Shengli-J8 heavy oil and a conventional Shengli crude oil show that Shengli-J8 heavy oil lacks alkanes and low molecular weight aromatic hydrocarbons, which contributes to its high viscosity. Additionally, characteristic molecular sets for different heavy oils were identified based on the semi-quantitative analysis of molecular composition. The semi-quantitative analysis of molecular composition in heavy oils may provide valuable reference data for establishing theoretical models on the viscosity-inducing mechanism in heavy oils and designing viscosity-reducing agents for heavy oil exploitation.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3612-3620"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140044634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of cyclic hydraulic stimulation on pore structure and methane sorption characteristics of anthracite coal: A case study in the Qinshui Basin, China 循环水力刺激对无烟煤孔隙结构和甲烷吸附特性的影响:中国沁水盆地案例研究
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.08.001
Rui-Shuai Ma , Ji-Yuan Zhang , Qi-Hong Feng , Xue-Ying Zhang , Yan-Hui Yang
{"title":"Effect of cyclic hydraulic stimulation on pore structure and methane sorption characteristics of anthracite coal: A case study in the Qinshui Basin, China","authors":"Rui-Shuai Ma ,&nbsp;Ji-Yuan Zhang ,&nbsp;Qi-Hong Feng ,&nbsp;Xue-Ying Zhang ,&nbsp;Yan-Hui Yang","doi":"10.1016/j.petsci.2024.08.001","DOIUrl":"10.1016/j.petsci.2024.08.001","url":null,"abstract":"<div><div>The cyclic hydraulic stimulation (CHS) has proven as a prospective technology for enhancing the permeability of unconventional formations such as coalbeds. However, the effects of CHS on the microstructure and gas sorption behavior of coal remain unclear. In this study, laboratory tests including the nuclear magnetic resonance (NMR), low-temperature nitrogen sorption (LTNS), and methane sorption isotherm measurement were conducted to explore changes in the pore structure and methane sorption characteristics caused by CHS on an anthracite coal from Qinshui Basin, China. The NMR and LTNS tests show that after CHS treatment, meso- and macro-pores tend to be enlarged, whereas micro-pores with larger sizes and transition-pores may be converted into smaller-sized micro-pores. After the coal samples treated with 1, 3, 5 and 7 hydraulic stimulation cycles, the total specific surface area (TSSA) decreased from 0.636 to 0.538, 0.516, 0.505, and 0.491 m<sup>2</sup>/g, respectively. Fractal analysis based on the NMR and LTNS results show that the surface fractal dimensions increase with the increase in the number of hydraulic stimulation cycles, while the volume fractal dimensions exhibit an opposite trend to the surface fractal dimensions, indicating that the pore surface roughness and pore structure connectivity are both increased after CHS treatment. Methane sorption isothermal measurements show that both the Langmuir volume and Langmuir pressure decrease significantly with the increase in the number of hydraulic stimulation cycles. The Langmuir volume and the Langmuir pressure decrease from 33.47 cm<sup>3</sup>/g and 0.205 MPa to 24.18 cm<sup>3</sup>/g and 0.176 MPa after the coal samples treated with 7 hydraulic stimulation cycles, respectively. The increments of Langmuir volume and Langmuir pressure are positively correlated with the increment of TSSA and negatively correlated with the increments of surface fractal dimensions.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3271-3287"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimal depth of in-situ pressure-preserved coring in coal seams considering roadway excavation and drilling disturbance 考虑巷道开挖和钻孔扰动因素的煤层原位保压取心的最佳深度
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.05.014
{"title":"Optimal depth of in-situ pressure-preserved coring in coal seams considering roadway excavation and drilling disturbance","authors":"","doi":"10.1016/j.petsci.2024.05.014","DOIUrl":"10.1016/j.petsci.2024.05.014","url":null,"abstract":"<div><div>Using pressure-preserved coring technique to determine in-situ gas content provides a more precise assessment of gas resource reserves and safeguard of mining safety in coal seams. How coring technique and depth affect the determination of gas content is unclear due to borehole zoning rupture caused by roadway excavation and drilling disturbance. To this end, a proposed coupling model of stress distribution and gas migration was simulated and validated by FLAC<sup>3D</sup> and COMSOL Multiphysics considering superposition effects of roadway excavation and drilling disturbance. The findings indicate that the roadway surrounding rock displays distinct zoning features including stress relief zone, stress concentration zone that is composed of plastic zone, elastic zone, and original stress zone; and the broken situations depending on the borehole peeping are consistent with the corresponding simulation results. On this basis, this study proposes a set of drilling coring depth calculation and prediction model for the gas desorption affected area under engineering disturbance. Optimal depth of coring drilling is not only approach to the in-situ coal bulk, but also can get the balance of the drilling workload and cost controlling. According to the typical mine site geological conditions and the numerical simulation results in this study, if the roadway excavation time is ∼1 year, it is recommended that the pressure-preserved coring depth should be greater than 17 m.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3517-3534"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141140238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient anti-aliasing and anti-leakage Fourier transform for high-dimensional seismic data regularization using cube removal and GPU 利用立方体去除和 GPU 为高维地震数据正则化提供高效抗锯齿和抗泄漏傅立叶变换
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.04.002
{"title":"Efficient anti-aliasing and anti-leakage Fourier transform for high-dimensional seismic data regularization using cube removal and GPU","authors":"","doi":"10.1016/j.petsci.2024.04.002","DOIUrl":"10.1016/j.petsci.2024.04.002","url":null,"abstract":"<div><div>Seismic data is commonly acquired sparsely and irregularly, which necessitates the regularization of seismic data with anti-aliasing and anti-leakage methods during seismic data processing. We propose a novel method of 4D anti-aliasing and anti-leakage Fourier transform using a cube-removal strategy to address the combination of irregular sampling and aliasing in high-dimensional seismic data. We compute a weighting function by stacking the spectrum along the radial lines, apply this function to suppress the aliasing energy, and then iteratively pick the dominant amplitude cube to construct the Fourier spectrum. The proposed method is very efficient due to a cube removal strategy for accelerating the convergence of Fourier reconstruction and a well-designed parallel architecture using CPU/GPU collaborative computing. To better fill the acquisition holes from 5D seismic data and meanwhile considering the GPU memory limitation, we developed the anti-aliasing and anti-leakage Fourier transform method in 4D with the remaining spatial dimension looped. The entire workflow is composed of three steps: data splitting, 4D regularization, and data merging. Numerical tests on both synthetic and field data examples demonstrate the high efficiency and effectiveness of our approach.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3079-3089"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140778175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characteristics, preservation mechanisms, and significance of aragonite in lacustrine shale: A case study from the Jiyang Depression, Bohai Bay Basin 湖相页岩中文石的特征、保存机制及其意义:渤海湾盆地济阳凹陷案例研究
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.05.019
{"title":"Characteristics, preservation mechanisms, and significance of aragonite in lacustrine shale: A case study from the Jiyang Depression, Bohai Bay Basin","authors":"","doi":"10.1016/j.petsci.2024.05.019","DOIUrl":"10.1016/j.petsci.2024.05.019","url":null,"abstract":"<div><div>Aragonite is a metastable mineral, which is easily transformed into calcite, and generally difficult to preserve in the stratum. However, large amounts of aragonites were found in the Paleogene shale of the Jiyang Depression. The characteristics and preservation mechanisms of these aragonites were analyzed through a series of analytical methods, including cathodoluminescence, field-emission scanning electron microscopy (FESEM), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), micro-area carbon and oxygen isotopes, Sr isotopes, and dissolution simulation experiments under high temperature and high pressure. The research results show that: ①Aragonite in the Paleogene shale of the Jiyang Depression is related to algal microbial fossils, primarily composed of coccoliths and characterized by two emission peaks at 420 nm and 480 nm in cathodoluminescence; ②The primary factor allowing biological aragonite to be preserved is the immaturity of the organic matter and the deficiency of abundant organic acids necessary for its dissolution or transformation, which is confirmed by the evidence of organic matter maturity and simulation experiments of organic acid dissolution on aragonite under high-temperature and high-pressure conditions. Additional factors that may aid in the preservation of aragonite are the ideal sedimentation conditions, the defense of organic coating, and the enclosed environment with tiny pores, low porosity, and low permeability; ③These aragonite-rich shales, characterized by coccolithophores, provide a solid evidence for seawater intrusion into terrestrial lake basin, and have a significant implication for the source and storage of shale oil.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3001-3015"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141138172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the combined influence of geological layer property and in-situ stresses on fracture height growth for layered formations 评估地质层特性和原位应力对层状地层断裂高度增长的综合影响
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.07.014
Peng Tan , Zhao-Wei Chen , Liu-Ke Huang , Qing Zhao , Sha-Rui Shao
{"title":"Evaluation of the combined influence of geological layer property and in-situ stresses on fracture height growth for layered formations","authors":"Peng Tan ,&nbsp;Zhao-Wei Chen ,&nbsp;Liu-Ke Huang ,&nbsp;Qing Zhao ,&nbsp;Sha-Rui Shao","doi":"10.1016/j.petsci.2024.07.014","DOIUrl":"10.1016/j.petsci.2024.07.014","url":null,"abstract":"<div><div>Fracture geometry is important when stimulating low-permeability reservoirs for natural gas or oil production. The geological layer (GL) properties and contrasts in in-situ stress are the two most important parameters for determination of the vertical fracture growth extent and containment in layered rocks. However, the method for assessing the cumulative impact on growth in height remains ambiguous. In this research, a 3D model based on the cohesive zone method is used to simulate the evolution of hydraulic fracture (HF) height in layered reservoirs. The model incorporates fluid flow and elastic deformation, considering the friction between the contacting fracture surfaces and the interaction between fracture components. First, an analytical solution that was readily available was used to validate the model. Afterwards, a quantitative analysis was performed on the combined impacts of the layer interface strength, coefficient of interlayer stress difference, and coefficient of vertical stress difference. The results indicate that the observed fracture height geometries can be categorized into three distinct regions within the parametric space: blunted fracture, crossed fracture, and T-shaped fracture. Furthermore, the results explained the formation mechanism of the low fracture height in the deep shale reservoir of the Sichuan Basin, China, as well as the distinction between fracture network patterns in mid-depth and deep shale reservoirs.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3222-3236"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141691111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of temperature and salt resistance silicon dots for effective enhanced oil recovery in tight reservoir 合成耐温耐盐硅点,在致密油藏中有效提高石油采收率
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.05.023
Cheng Liu , Biao Zhou , Bing-Shan Wang , Huan Wang , Qing You , Guang Zhao , Cai-Li Dai
{"title":"Synthesis of temperature and salt resistance silicon dots for effective enhanced oil recovery in tight reservoir","authors":"Cheng Liu ,&nbsp;Biao Zhou ,&nbsp;Bing-Shan Wang ,&nbsp;Huan Wang ,&nbsp;Qing You ,&nbsp;Guang Zhao ,&nbsp;Cai-Li Dai","doi":"10.1016/j.petsci.2024.05.023","DOIUrl":"10.1016/j.petsci.2024.05.023","url":null,"abstract":"<div><div>The intensive development of tight reservoirs has positioned them as a strategic alternative to conventional oil and gas resources. Existing enhanced oil recovery (EOR) methods struggle to effectively exploring reservoir oil, resulting in low recovery rates. Novel and effective means of developing tight reservoirs are urgently needed. Nanomaterials have shown promising applications in improving water flooding efficiency, with in-depth research into mechanisms that lower injection pressure and increase water injection volumes. However, the extent of improvement remains limited. In this study, a silicon quantum dots (Si-QDs) material was synthesized via a hydrothermal synthesis method and used to prepare a nanofluid for the efficient recovery of tight reservoir. The Si-QDs, with an approximate diameter of 3 nm and a spherical structure, were surface functionalized with benzenesulfonic acid groups to enhance the performance. The developed nanofluid demonstrated stability without aggregation at 120 °C and a salinity of 60000 mg/L. Core flooding experiments have demonstrated the attractive EOR capabilities of Si-QDs, shedding light of the EOR mechanisms. Si-QDs effectively improve the wettability of rocks, enhancing the sweeping coefficient of injected fluids and expanding sweeping area. Within this sweeping region, Si-QDs efficiently stripping adsorbed oil from the matrix, thus increasing sweeping efficiency. Furthermore, Si-QDs could modify the state of pore-confined crude oil, breaking it down into smaller particles that are easier to displacement in subsequent stages. Si-QDs exhibit compelling EOR potential, positioning them as a promising approach for effectively developing tight oil reservoirs.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3390-3400"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141781352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seismic modeling by combining the finite-difference scheme with the numerical dispersion suppression neural network 将有限差分方案与数值弥散抑制神经网络相结合的地震建模方法
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.06.014
Hong-Yong Yan
{"title":"Seismic modeling by combining the finite-difference scheme with the numerical dispersion suppression neural network","authors":"Hong-Yong Yan","doi":"10.1016/j.petsci.2024.06.014","DOIUrl":"10.1016/j.petsci.2024.06.014","url":null,"abstract":"<div><div>Seismic finite-difference (FD) modeling suffers from numerical dispersion including both the temporal and spatial dispersion, which can decrease the accuracy of the numerical modeling. To improve the accuracy and efficiency of the conventional numerical modeling, I develop a new seismic modeling method by combining the FD scheme with the numerical dispersion suppression neural network (NDSNN). This method involves the following steps. First, a training data set composed of a small number of wavefield snapshots is generated. The wavefield snapshots with the low-accuracy wavefield data and the high-accuracy wavefield data are paired, and the low-accuracy wavefield snapshots involve the obvious numerical dispersion including both the temporal and spatial dispersion. Second, the NDSNN is trained until the network converges to simultaneously suppress the temporal and spatial dispersion. Third, the entire set of low-accuracy wavefield data is computed quickly using FD modeling with the large time step and the coarse grid. Fourth, the NDSNN is applied to the entire set of low-accuracy wavefield data to suppress the numerical dispersion including the temporal and spatial dispersion. Numerical modeling examples verify the effectiveness of my proposed method in improving the computational accuracy and efficiency.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3157-3165"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141936657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Model-based interpretation of bottomhole pressure records during matrix treatments in layered formations 基于模型解释层状地层基质处理过程中的井底压力记录
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.05.027
{"title":"Model-based interpretation of bottomhole pressure records during matrix treatments in layered formations","authors":"","doi":"10.1016/j.petsci.2024.05.027","DOIUrl":"10.1016/j.petsci.2024.05.027","url":null,"abstract":"<div><div>During injection treatments, bottomhole pressure measurements may significantly mismatch modeling results. We devise a computationally effective technique for interpretation of fluid injection in a wellbore interval with multiple geological layers based on the bottomhole pressure measurements. The permeability, porosity and compressibility in each layer are initially setup, while the skin factor and partitioning of injected fluids among the zones during the injection are found as a solution of the problem. The problem takes into account Darcy flow and chemical interactions between the injected acids, diverter fluids and reservoir rock typical in modern matrix acidizing treatments. Using the synchronously recorded injection rate and bottomhole pressure, we evaluate skin factor changes in each layer and actual fluid placement into the reservoir during different pumping jobs: matrix acidizing, water control, sand control, scale squeezes and water flooding. The model is validated by comparison with a simulator used in industry. It gives opportunity to estimate efficiency of a matrix treatment job, role of every injection stage, and control fluid delivery to each layer in real time. The presented interpretation technique significantly improves accuracy of matrix treatments analysis by coupling the hydrodynamic model with records of pressure and injection rate during the treatment.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3587-3611"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141277569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biological origin and depositional environment of crude oils in the Qiongdongnan Basin: Insights from molecular biomarkers and whole oil carbon isotope 琼东南盆地原油的生物起源与沉积环境:分子生物标志物和全油碳同位素的启示
IF 6 1区 工程技术
Petroleum Science Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.05.026
{"title":"Biological origin and depositional environment of crude oils in the Qiongdongnan Basin: Insights from molecular biomarkers and whole oil carbon isotope","authors":"","doi":"10.1016/j.petsci.2024.05.026","DOIUrl":"10.1016/j.petsci.2024.05.026","url":null,"abstract":"<div><div>Molecular biomarker and whole oil carbon isotope (<em>δ</em><sup>13</sup>C<sub>oil</sub>) analyses were conducted on eleven typical crude oils from the Qiongdongnan Basin to investigate their biological sources and depositional environments. Saturated hydrocarbon biomarkers in most samples are characterized by angiosperm-derived compounds, with aromatic compounds dominated by the naphthalene, phenanthrene, biphenyl, and fluorene series. The related source rocks of these oils were mainly deposited under oxic condition, but a subanoxic–suboxic and enclosed water column condition in the Central Depression during Oligocene. The identification of simonellite and related compounds in the aromatic fractions provides reliable evidence for the input of coniferous gymnosperms. Cadalene may also have a potential association with gymnosperms since it shows a strong positive correlation with simonellite. Evidence from density, n-alkanes, short-chain alkylbenzenes and secondary brine inclusions indicates that the unique crude oil B13-1 may have suffered from thermal alteration. These crude oils (excluding B13-1) can be classified into four types based on the <em>δ</em><sup>13</sup>C<sub>oil</sub> values and molecular biomarkers. Type A oil (solely S34-3) is characterized by non-angiosperm plants, with minor dinoflagellates and increasing contribution from conifer gymnosperms than others. Type B oils (L17-2, L18-1, L25-1, and L25-1W) show heavy <em>δ</em><sup>13</sup>C<sub>oil</sub> (−24 ‰ to −25 ‰) and mixed contributions from both angiosperms and marine algae, with the marine algae contribution increasing. Type C oils (L13-2 and B21-1) share similar biological sources with Type B, but the moderately <em>δ</em><sup>13</sup>Coil (−25‰ to −26‰) and high level of terrestrial biomarkers suggesting a predominant contribution of angiosperms. Type D oils (Y13-1a, Y13-1b, and Y13-4) possess the lightest <em>δ</em><sup>13</sup>C<sub>oil</sub> (mainly below −26‰) and are primarily derived from angiosperms, with mangrove vegetation playing an important role. Spearman correlation analysis among 14 source biomarker parameters with <em>δ</em><sup>13</sup>C<sub>oil</sub> and geological setting of related source rocks implied that the marine algae should be responsible for the heavy <em>δ</em><sup>13</sup>C<sub>oil</sub> in the Type B. The contribution of marine algae in the Central Depression may have been neglected in the past, as it is usually covered by remarkable angiosperm biomarkers.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 5","pages":"Pages 3029-3046"},"PeriodicalIF":6.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141281238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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