A. Konstantinov, A. Chizhikov, M. Antipov, P. Bazhin, N. Y. Khomenko
{"title":"Study of the effect of high-temperature annealing on the structure and properties of a composite material based on TiC/TiB2/Ti3SiC2","authors":"A. Konstantinov, A. Chizhikov, M. Antipov, P. Bazhin, N. Y. Khomenko","doi":"10.17073/1683-4518-2023-8-48-53","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-8-48-53","url":null,"abstract":"","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"55 24","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139196925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Acid-resistant material was obtained on the basis of metallurgy waste without the use of traditional natural materials","authors":"V. Abdrakhimov, E. Abdrakhimova","doi":"10.17073/1683-4518-2023-6-44-51","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-6-44-51","url":null,"abstract":"Acid-resistant material is obtained on the basis of metallurgy wastes ― clay part of «tails» of gravity of zircon-ilmenite ores, used as clay binder and ferrochromic aluminothermic slag, used as a repellent without using natural traditional materials. It has been found that the introduction of ferrochromic aluminothermic slag into the ceramic compositions contributes to the formation of highly refractory minerals (corundum, magnesia spinel, chromium oxide, bonite and mayenite), which increase chemical, physical and mechanical indices at a firing temperature of 1300 °C acid stops.","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":" 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139197584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. K. Logacheva, O. Averkova, A. Ziganshin, K. Logachev, E. Popov
{"title":"Determination of the influence of the incoming flow on the vortex zones at the entrance to the suction sockets. Part 1. The Axisymmetric problem","authors":"A. K. Logacheva, O. Averkova, A. Ziganshin, K. Logachev, E. Popov","doi":"10.17073/1683-4518-2023-6-67-71","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-6-67-71","url":null,"abstract":"The features of the construction of a computational algorithm for calculating circular suction sockets in the conditions of an incoming flow by the method of discrete vortex rings are considered. Flow patterns are given at different ratios of the incoming and intake air flow velocities. The dependences of the characteristic sizes of vortex zones arising at the inlet to the suction-sockets on the velocity of the incoming flow, the length and angle of inclination of the socket are determined. Expressions are obtained for the critical velocity of the incoming flow, at which the flow separation mode for the first vortex zone changes from separation inside the bell to separation outside it. The obtained results can be useful for the construction of local suction systems, profiled according to the found outlines of vortex zones.","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"33 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139202311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of calcium aluminate-based additive on properties of periclase-carbon refractories for steelteeming ladles","authors":"A. O. Migashkin","doi":"10.17073/1683-4518-2023-8-38-43","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-8-38-43","url":null,"abstract":"Premature decommissioning of steel-teeming ladle lining due to critical localized damage, whichi significantly reduces the functional properties of the lining, is one of the most acute problems in modern metallurgy. The main type of products used for steel-teeming ladle lining is periclase-carbon. In order to improve corrosion resistance and resistance to thermomechanical loads, additional additives, such as spinel, and high alumina CMA cement, are introduced into the periclase-carbon products. In this paper, the effect of calcium aluminate-based additive on the properties of periclasecarbon refractories is investigated. It is assumed that there is a potential for the formation of magnesium aluminate spinel (MA) in periclase-carbon products with calcium-aluminate additives during heat treatment. Fused periclase was used as the raw material, the carbon component was represented by natural flake graphite in an amount of 10 wt% and a combined binder. An additive based on calcium aluminates was introduced, with a fractional size from 0 to 3 mm, while the amount of main fractions of fused periclase was reduced by the corresponding amount of the additive introduced. The compressive strength, apparent porosity, and bending strength values before and after coking firing were analyzed. The thermal coefficient of linear expansion, phase composition and microstructure of the products were also investigated.","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"344 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139204579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Using the surface energy of nanoparticles to produce high-strength concrete","authors":"A. M. Sycheva","doi":"10.17073/1683-4518-2023-8-21-27","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-8-21-27","url":null,"abstract":"The article considers a method for activating cement hardening processes using nanomaterials due to the magnitude of their surface energy: when injected into concrete, nanoparticles dump it due to the desire to transition to a stable state. Such activity leads to a significant gain in strength, hardness and the production of high-strength concrete. It is shown that such an effect can be achieved by surface impregnation of concrete with sols (colloidal solutions) based on SiO2 nanoparticles. It is advisable to start impregnation from the third day of hardening under normal conditions. At this age, the main heat of the cement's own exothermic hardening reaction has already been released into the environment, and the introduction of additional energy will not cause a shift in equilibrium towards slowing down the hardening processes in accordance with the Le-Chatelier principle. The results of physico-chemical studies of concrete after hardening, explaining this effect, are presented.","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"36 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139205118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Bykova, A. D. Markov, Y. Kuznetsov, I. N. Kravchenko, A. N. Belyakov, A. M. Makarov
{"title":"Effect of electrolyte composition on the structure and tribological properties of ceramic coatings obtained by microarc oxidation","authors":"A. Bykova, A. D. Markov, Y. Kuznetsov, I. N. Kravchenko, A. N. Belyakov, A. M. Makarov","doi":"10.17073/1683-4518-2023-10-31-39","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-10-31-39","url":null,"abstract":"<jats:p>.</jats:p>","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139208286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Obtaining and investigation of a heat-resistant binder with the additive of metakaolin in the conditions of Uzbekistan","authors":"Aida Ruzmetova, Zabibulla Babaev, Mirzhalil Yunusov","doi":"10.17073/1683-4518-2023-7-28-32","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-7-28-32","url":null,"abstract":"The purpose of the work is to obtain a heat-resistant binder with the addition of metakaolin from mineral and man-made raw materials of the Aral Sea region. The results of obtaining alumina cement using kaolin, limestone and alumina-containing waste are presented. Effective compositions of alumina cement in the kaolin-limestone-alumina-containing waste system have been developed. To improve the physico-mechanical properties of a heat-resistant binder, the preparation of metakaolin with its subsequent addition during clinker grinding was investigated. The reliability of the obtained results is confirmed by the use of modern physico-chemical methods.","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"979 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139204242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The defects of structural and phase transformations in polycrystalline cerium dioxide under heating in vacuum and in air","authors":"A. E. Solovyeva","doi":"10.17073/1683-4518-2023-7-42-51","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-7-42-51","url":null,"abstract":"Structural changes in cerium dioxide, when heated in vacuum in the range of 25‒1600 °C, in air in the range of 25‒1500 °C, and during successive annealing in the range of 1600‒2100 °C in air, followed by quenching in water, were studied. In the crystal lattice of CeO2‒х, the F → F1 phase transformation in vacuum proceeds in the range of 1100‒1600 °C; additionally, at 1200 °C, X-ray lines of the C-type Ce2O3 phase appear. The thermal expansion coefficient of phases of the fluorite type F and F1 in the range of 25‒1500 °C in air, as well as phases of the fluorite type F, F1 and type C Ce2O3 in the range of 25‒1600 °C are determined in vacuum and their dependence on the change in the oxygen content in the CeO2‒х crystal lattice was found. The kinetic conditions for reduction of cerium dioxide in vacuum and oxidation in air are different. The cubic structure of the fluorite type F CeO2‒х, when the samples are heated in air, is preserved up to 1800 °C with the content of anionic vacancies, at 1900 °C the transformation F → F1 occurs. The formation of loops, edge and screw dislocations in the structure of cerium dioxide grains after annealing of samples in the range of 1900‒2100 °C in air were discovered for the first time. The decomposition of the structure F1 into cerium oxide phases of types F and C proceeds at 2100 °C along the height and boundaries of screw dislocations. It was found that fragments of the C-type phase of cerium oxide are located on loops along the height of screw dislocations, which indicates the movement and evaporation of these fragments. When the samples are oxidized at 1600 °C in air, the black-colored C Ce2O3‒х phase in a gradient of different concentrations moves along certain trajectories to opposite ones. grain boundaries, abuts against dislocation loops, bends them, and oxidizes to phases F1 and F. In the structure of polycrystalline cerium dioxide, when heated in vacuum and in air, certain concentrations of defects control phase transformations.","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"100 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139204475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. I. Malkin, N. A. Drokin, V, S. Kiiko, A. N. Korotkov, V. A. Chchetkin
{"title":"Electrodynamic properties of (BeO + TiO2)- ceramics in the centimeter wavelength range","authors":"A. I. Malkin, N. A. Drokin, V, S. Kiiko, A. N. Korotkov, V. A. Chchetkin","doi":"10.17073/1683-4518-2023-10-45-52","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-10-45-52","url":null,"abstract":"<jats:p>.</jats:p>","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"120 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139200702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. L. Ugolkov, N. A. Koval’chuk, A. Osipov, L. Mezentseva, A. Akatov
{"title":"Ceramic composites based on zircon and zirconium dioxide","authors":"V. L. Ugolkov, N. A. Koval’chuk, A. Osipov, L. Mezentseva, A. Akatov","doi":"10.17073/1683-4518-2023-9-28-33","DOIUrl":"https://doi.org/10.17073/1683-4518-2023-9-28-33","url":null,"abstract":"Ceramic composites (1 ‒ x)ZrSiO4‒xZrO2 with low thermal conductivity were obtained by sintering nanosized powders in the range of 1000‒1300 °C in air. The fracture surface of ceramic samples after sintering at 1300 °C was investigated and their thermal behavior was studied by dilatometry. The chemical resistance of composites by leaching in distilled water was evaluated. In the future, such ceramic composites can be used as matrices for the purpose of long-term, environmentally safe storage and subsequent final isolation from the environment of individual isotopes of actinide-rare earth fraction of high-level waste (HLW).","PeriodicalId":19463,"journal":{"name":"NOVYE OGNEUPORY (NEW REFRACTORIES)","volume":"32 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139201899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}