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Advance Research in Organic and Inorganic Chemistry (AROIC)最新文献

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A 5-fold Interpenetrated and Porous Dia-net Metal-Organic Framework Constrcuted from Long and Linear Phenyl-carboxylate Linkers 由长链和线性苯基羧酸链节构建的 5 层互穿、多孔 Dia-net 金属有机框架
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2024-03-14 DOI: 10.54026/aroic/1016
Zheng Yin
{"title":"A 5-fold Interpenetrated and Porous Dia-net Metal-Organic Framework Constrcuted from Long and Linear Phenyl-carboxylate Linkers","authors":"Zheng Yin","doi":"10.54026/aroic/1016","DOIUrl":"https://doi.org/10.54026/aroic/1016","url":null,"abstract":"Interpenetration regulation is of great significance for both the crystal engineering and functional chemistry of MOFs. The combination of long and linear ditopic organic linkers with single or small metal node is effective to produce interpenetration metal-organic framework. Here, a 5-fold interpenetrated and porous dia-net metal-organic framework of [Cd(tpdc)2 ]·3DMF (Cd-MOF, H2 tpdc = 2′,5′-dimethylterphenyl-4,4″-dicarboxylate) was synthesizd under solvothermal reaction, which was structurally characterizaed by single X-ray crystal diffraction, coupled with thermal and luminescence properties study. The compound crystallises in monoclinic P2/c space group with cell parameters of a = 15.7789(4) Å, b = 24.8437(7) Å, c = 26.3720(4) Å, α = 90o , β = 96.5583(19)o , γ = 90o , and V = 23967 Å3 There are 1D channels and porosity of 57.5% for the Cd-MOF, which is a rare example of MOFs with coexistence of high-degree interpenetration and high porosity. The MOF can thermally stable up to 360 o C, with light blue lumiscent emission at 360 nm under a ultraviolet radiation.","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"3 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140243543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal Doping Induced Formation and Dynamic Gas Sorption of a Highly Porous Mesoporous MetalOrganic Framework 金属掺杂诱导高孔介孔金属有机骨架的形成和动态气体吸附
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2023-04-26 DOI: 10.54026/aroic/1015
Zheng Yin
{"title":"Metal Doping Induced Formation and Dynamic Gas Sorption of a Highly Porous Mesoporous MetalOrganic Framework","authors":"Zheng Yin","doi":"10.54026/aroic/1015","DOIUrl":"https://doi.org/10.54026/aroic/1015","url":null,"abstract":"A new high-porosity MOF of [Ni2.3Zn0.7(tzba)3 (H2 O)6 ]·12DMF (NiZn-MOF) processes 2D (3,6)-grid layers constructed from rare [M2 (tz)3 (H2 O)3 ] and [M(COO)3 ] nodes. The metal doping of Ni2+ and Zn2+ are crucial for the formation of the two kinds of metal nodes and subsequent synergistical assembly into the mesoporous MOF, in contrast to the formation of MIL-88-topology resembled compound of {(Me2 NH2 )[Ni3 (μ3 -OH)(tzba)3 (H2 O)3 ]·8DMF (Ni3-MOF) using single Ni2+ as metal source. The regular 2D layers stacked in parallel and ABAB fashion through interlayer hydrogen bonding, leading to a neutral framework with void fraction up to 72.1% and 1D mesoporous hexagonal channels sized at 24.0 Å in diameter. The large gas accessible porosity was revealed by the saturated N2 and CO2 uptake of 720 and 708 cm3 g-1, at 77 K and 195 K, respectively, giving a high Langmuir surface area of 2066 m2 g-1. The varying gas sorption amounts dependent on accommodated solvents and activation temperature, as well as the gate-opening behaviors in sorption isotherms, well confirm the dynamic structure response to guest species of the flexible framework.","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"65 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122492342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Iron and Hafnium Co-Doped Ni3 N Nanostructures as An Active Catalyst for Alkaline Water Oxidation 铁和铪共掺杂ni3n纳米结构作为碱性水氧化的活性催化剂
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2023-02-13 DOI: 10.54026/aroic/1014
Wanru Feng
{"title":"Iron and Hafnium Co-Doped Ni3 N Nanostructures as An Active Catalyst for Alkaline Water Oxidation","authors":"Wanru Feng","doi":"10.54026/aroic/1014","DOIUrl":"https://doi.org/10.54026/aroic/1014","url":null,"abstract":"The exploration of highly efficient electrocatalysts is critical to the oxygen evolution reaction (OER). Here, we synthesized iron and hafnium co-doped Ni3 N (Fe, Hf-Ni3 N) nanostructure and grew on nickel foam substrate to fabricate a threedimensional (3D) electrode. The Fe, Hf-Ni3 N catalyst exhibits an excellent OER performance with a small overpotential of only 198 mV at 10 mA cm-2 and a lower Tafel slope of 89 mV dec-1 in basic electrolyte. This may be due to the fact that the doping of Fe and Hf modulate the electronic interactions of Ni3 N, thus increasing the OER activity. In addition, the Fe, HfNi3 N shows a considerable electrochemical stability, which has not weakened after 105 h operation. This work provides a useful approach for improve the OER performance of catalysts in the future.","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"80 8 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128913599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterizations of Liquid Crystals as A Transdermal Drug Delivery System 液晶作为透皮给药系统的特性研究
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2022-10-06 DOI: 10.54026/aroic/1013
Wesam R Kadhum
{"title":"Characterizations of Liquid Crystals as A Transdermal Drug Delivery System","authors":"Wesam R Kadhum","doi":"10.54026/aroic/1013","DOIUrl":"https://doi.org/10.54026/aroic/1013","url":null,"abstract":"The outermost layer of skin, the stratum corneum, has a role as the primary barrier against water evaporation from the body and drug entry through skin into the body. Thus, overcoming the stratum corneum barrier is important to develop transdermal drug delivery systems. Transdermal administration of drugs represents an excellent alternative to conventional pharmaceutical dosage forms. However, insufficient penetration of the active pharmaceutical substance through the skin is a common problem. Thus, in the present review we discussed the characterizations and the skin permeation enhancing ability of liquid crystal (LC) topical formulations.","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"24 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128578599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
pH Value of Blood: Should It be Considered as A Part of Standard Blood Biochemical Profile? 血液pH值:是否应作为标准血液生化指标的一部分?
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2022-09-12 DOI: 10.54026/aroic/1012
Alexandre A Vetcher
{"title":"pH Value of Blood: Should It be Considered as A Part of Standard Blood Biochemical Profile?","authors":"Alexandre A Vetcher","doi":"10.54026/aroic/1012","DOIUrl":"https://doi.org/10.54026/aroic/1012","url":null,"abstract":"For over a century, physicians considered the pH value of blood as one of the paraments, changes that could alarm serious metabolism deviations. The medical community had developed two parallel approaches, traditional and Stewart, to evaluate acid-base phenomena. Nevertheless, such important parameter is still missing in a Standard Blood Biochemical Profile (SBBP), which is periodically required by Primary Care Physicians (PCP) to ensure the health status of their patients. The current review is devoted to the advantages, that the medical community could obtain after accepting blood pH values as general for analysis, the consideration of technical possibilities of test strips development for digital measurements, and some related issues. Particular interest is associated with the possible connection between the blood pH data and the validity of the theory of Centralized Aerobic-Anaerobic Energy Balance Compensation (CAAEBC).","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"40 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126903038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Green Techniques to Synthesize Schiff Bases 绿色技术合成席夫碱
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2022-06-20 DOI: 10.54026/aroic/1011
Atul R Bendale
{"title":"Green Techniques to Synthesize Schiff Bases","authors":"Atul R Bendale","doi":"10.54026/aroic/1011","DOIUrl":"https://doi.org/10.54026/aroic/1011","url":null,"abstract":"From ancient times, the chemistry of Schiff base-containing molecules has been a fascinating subject of study. They've been found to be a flexible pharmacophore for the creation and development of a wide range of bioactive lead compounds. Schiff bases are compounds containing the imine functional group. Different Schiff base containing byproducts have recently been synthesized and studied for activities such as antioxidant, antibacterial, antituberculosis, anti-inflammatory, antidepressant and anxiolytic activity, antihypertensive, anticonvulsants, anticancer, and antifungal activity. Different green chemistry techniques like-solid state, sonochemical, microwave assisted synthesis for synthesis of Schiff bases are discussed in this review.","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131585734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ingredients Present In Personal Care Products That Need Scrutiny 个人护理产品中需要仔细检查的成分
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2022-03-14 DOI: 10.54026/aroic/1008
David M Lewis
{"title":"Ingredients Present In Personal Care Products That Need Scrutiny","authors":"David M Lewis","doi":"10.54026/aroic/1008","DOIUrl":"https://doi.org/10.54026/aroic/1008","url":null,"abstract":"","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"98 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116325858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phytochemistry and Antiviral Activities of Some Fruit Plant Species As Potential Resources For AntiViral Agents 一些果树的植物化学和抗病毒活性作为抗病毒药物的潜在资源
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2022-03-10 DOI: 10.54026/aroic/1009
Ngbolua Kn
{"title":"Phytochemistry and Antiviral Activities of Some Fruit Plant Species As Potential Resources For AntiViral Agents","authors":"Ngbolua Kn","doi":"10.54026/aroic/1009","DOIUrl":"https://doi.org/10.54026/aroic/1009","url":null,"abstract":"The aim of the present work was to review data on the antiviral activities of some fruit plant species and their macronutrient composition. This was done with the aim of promoting these plants for the management of viral diseases, particularly covid-19. Several fruit plant species are mentioned in the literature for their antiviral properties. These include: Cocos nucifera, Garcinia mangostana, Malus domestica, Mangifera indica, Musa acuminate, Musa balbisiana, Musa paradisiaca, Nephelium lappaceum, Passiflora edulis, Persea americana, Syzygium aromaticum, Syzygium guineense, Syzygium malaccense, Vitis vinifera. Some compounds of the above-mentioned fruit plants can interact with the therapeutic targets of various viruses including SARS-Cov-2 proteases. Others, on the other hand, are known to have immunostimulatory or both antiviral and immunostimulatory activities.","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"21 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114484716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polymeric Substances in Agriculture 农业中的聚合物质
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2022-02-28 DOI: 10.54026/aroic/1007
Waleed Fouad Abobatta
{"title":"Polymeric Substances in Agriculture","authors":"Waleed Fouad Abobatta","doi":"10.54026/aroic/1007","DOIUrl":"https://doi.org/10.54026/aroic/1007","url":null,"abstract":"The agricultural sector is subjected to different challenges particularly abiotic stress due to severe climate conditions. Water shortage is considered the main restricting factor for agricultural production. Polymeric substances could play a key role in improving various plant productivity and providing numerous advantages under light texture soils and dryness conditions. It is maintaining the continuous supply of water and nutrients for the plants, enhancing soil","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129122038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spectroscopic and Computational Study of the Ugi Cinnamic Adduct NGI25 Ugi肉桂加合物NGI25的光谱与计算研究
Advance Research in Organic and Inorganic Chemistry (AROIC) Pub Date : 2022-02-14 DOI: 10.54026/aroic/1006
M. T
{"title":"Spectroscopic and Computational Study of the Ugi Cinnamic Adduct NGI25","authors":"M. T","doi":"10.54026/aroic/1006","DOIUrl":"https://doi.org/10.54026/aroic/1006","url":null,"abstract":"The structure assignment and conformational analysis of cinnamic derivative N-benzyl-N-(2-(cyclohexylamino)-2-oxoethyl) cinnamamide (NGI25) was carried out through Nuclear Magnetic Resonance (NMR) spectroscopy, Molecular Dynamics (MD) and Quantum Mechanics (QM), i.e., semiempirical and Density Functional Theory (DFT) calculations. Specifically, homonuclear (2D-COSY, 2D-NOESY) and heteronuclear (2D-HSQC, 2D-HMBC) spectra were obtained. Through them, the resonant values of the hydrogens and their constituent carbons were identified. After structure identification, NGI25 was subjected to computational calculations to reveal its most favorable conformations. QM, MD were in agreement with the spatial correlations that were observed in 2D-NOESY spectra.","PeriodicalId":193352,"journal":{"name":"Advance Research in Organic and Inorganic Chemistry (AROIC)","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126458818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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