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Catalytic activity of MoO3:V2O5 mixed oxides towards oxidation reactions: the nature of catalytic centers MoO3:V2O5 混合氧化物对氧化反应的催化活性：催化中心的性质
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.029
{"title":"Catalytic activity of MoO3:V2O5 mixed oxides towards oxidation reactions: the nature of catalytic centers","authors":"","doi":"10.1016/j.mencom.2024.09.029","DOIUrl":"10.1016/j.mencom.2024.09.029","url":null,"abstract":"<div><div>Singlet oxygen emission and peroxide generation at the surface of molybdenum–vanadium oxides evidenced that the catalytic activity of a MoO<sub>3</sub>:V<sub>2</sub>O<sub>5</sub> mixed oxide at 70–175 °C was governed by the formation of peroxo groups in the interaction of molecular oxygen with adjacent V<sup>iv</sup> surface centers; the thermolysis of these groups yielded singlet oxygen capable of oxidizing selectively alcohols to aldehydes.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent 在深共晶溶剂中一步两步合成γ-酮砜
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.027
{"title":"One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent","authors":"","doi":"10.1016/j.mencom.2024.09.027","DOIUrl":"10.1016/j.mencom.2024.09.027","url":null,"abstract":"<div><div>Acidic deep eutectic solvent was prepared from choline chloride and trifluoromethanesulfonic acid at room temperature. Reaction between aromatic aldehydes and arylacetylenes in this solvent gave chalcones whose <em>in situ</em> reaction with sodium arenesulfinates in water successfully provided γ-keto sulfones in good yields. This deep eutectic solvent could be easily recovered and reused for several runs.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433877","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Symmetry relationships between hybrid lead halide perovskite-derived phases: vacancy ordering as a key classification factor 混合卤化铅过氧化物衍生相之间的对称关系：作为关键分类因素的空位排序
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.008
{"title":"Symmetry relationships between hybrid lead halide perovskite-derived phases: vacancy ordering as a key classification factor","authors":"","doi":"10.1016/j.mencom.2024.09.008","DOIUrl":"10.1016/j.mencom.2024.09.008","url":null,"abstract":"<div><div>For the first time, based on symmetry group–subgroup relation-ships, an approach is presented to create a clear classification of hybrid lead halides with low-dimensional vacancy-ordered perovskite-related crystal structures to facilitate the identification and prediction of hybrid lead-halide materials that have desired properties.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142431927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel dithieno[3,2-f:2’,3’-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells 作为过氧化物太阳能电池空穴传输材料的新型二噻吩并[3,2-f:2',3'-h]喹喔啉基聚合物
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.010
{"title":"Novel dithieno[3,2-f:2’,3’-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells","authors":"","doi":"10.1016/j.mencom.2024.09.010","DOIUrl":"10.1016/j.mencom.2024.09.010","url":null,"abstract":"<div><div>Two novel conjugated polymers comprised of 2,3-R<sub>2</sub>-di- thieno[3,2-<em>f</em>:2<em>’</em>,3<em>’</em>-<em>h</em>]quinoxaline, where R is 3<em>’</em>-(octyloxy)- phenyl (P1) or 2<em>’</em>-(2-ethylhexyl)thiophen-4<em>’</em>-yl (P2), and 2,1,3-benzothiadiazole have been synthesized using the Stille cross-coupling reaction. The synthesized polymers were investigated as hole transport layer (HTL) materials in perovskite solar cells. Polymer P2 as an HTL material provided improved short-circuit current and open-circuit voltage and, correspondingly, enhanced power conversion efficiency of perovskite solar cells compared to that of polymer P1.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Key features of perovskite solar cells operando stabilization with ionic liquid choline cinnamate 用离子液体胆碱肉桂酸盐稳定过氧化物太阳能电池的主要特征
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.011
{"title":"Key features of perovskite solar cells operando stabilization with ionic liquid choline cinnamate","authors":"","doi":"10.1016/j.mencom.2024.09.011","DOIUrl":"10.1016/j.mencom.2024.09.011","url":null,"abstract":"<div><div>The ionic liquid choline cinnamate was applied for the first time as a defect passivator in light-absorbing layers of perovskite solar cells (PSCs). It was found that bulk passivation with an addition of 0.5% ionic liquid notably enhances the photothermal stability of PSCs, while surface passivation leads to the opposite effect with the loss of device stability, due to the complex origin of the influence of choline cinnamate on the defect structure and microstructure of hybrid halide perovskites.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sol–gel prepared ZnO: UV irradiation effect on structure and surface properties 溶胶凝胶制备的氧化锌：紫外线辐照对结构和表面特性的影响
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.006
{"title":"Sol–gel prepared ZnO: UV irradiation effect on structure and surface properties","authors":"","doi":"10.1016/j.mencom.2024.09.006","DOIUrl":"10.1016/j.mencom.2024.09.006","url":null,"abstract":"<div><div>The effect of UV irradiation on sol–gel prepared ZnO films subjected to mild thermal annealing was investigated, with special attention to their structural and surface properties. Sol–gel processes, including a high-temperature annealing stage, have been adapted to the requirements of flexible electronics for <em>in situ</em> synthesis of semiconductor ZnO films on polymer substrates at lower temperatures due to UV irradiation. Application of UV radiation with emission peaks at 185 and 254 nm to films annealed at 180 °C made it possible to obtain ZnO films with Zn/O ratios of <em>ca</em>. 1, which cannot be achieved by heat treatment alone.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Organocatalytic domino formation of (3R,3aS,9bR)-configured 3-aryl-3a-benzamido-1,3a,4,9b-tetrahydrochromeno[4,3-b]pyrroles in carbon dioxide medium 在二氧化碳介质中有机催化形成 (3R,3aS,9bR)-构型 3-芳基-3a-苯甲酰胺基-1,3a,4,9b-四氢苯并吡喃并[4,3-b]吡咯的多米诺效应
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.022
{"title":"Organocatalytic domino formation of (3R,3aS,9bR)-configured 3-aryl-3a-benzamido-1,3a,4,9b-tetrahydrochromeno[4,3-b]pyrroles in carbon dioxide medium","authors":"","doi":"10.1016/j.mencom.2024.09.022","DOIUrl":"10.1016/j.mencom.2024.09.022","url":null,"abstract":"<div><div>Asymmetric cycloaddition/intramolecular rearrangement domino reaction of 2-(2-hydroxybenzylideneamino)- malonates with 4-arylidene-2-phenyloxazol-5(4<em>H</em>)-ones can be efficiently carried out in sub- or supercritical carbon dioxide to afford (3<em>R</em>,3a<em>S</em>,9b<em>R</em>)-3-aryl-3a-benzamido-4-oxo-1,3a,4,9b-tetrahydrochromeno[4,3-<em>b</em>]pyrrole-2,2(3<em>H</em>)- dicarboxylates in high yields with up to 99% <em>ee</em>. Excellent stereoinduction is provided in this process by the use of bifunctional hybrid organocatalyst consisting of squaramide (thiourea) and chiral tertiary amine units.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pt/C electrocatalysts based on N-doped carbon materials from waste plant biomass 基于从废弃植物生物质中提取的掺杂 N 的碳材料的 Pt/C 电催化剂
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.032
{"title":"Pt/C electrocatalysts based on N-doped carbon materials from waste plant biomass","authors":"","doi":"10.1016/j.mencom.2024.09.032","DOIUrl":"10.1016/j.mencom.2024.09.032","url":null,"abstract":"<div><div>The N-doped carbon material obtained by thermochemical conversion of a polycondensation product of a liquid fraction of humins (a waste product of plant biomass conversion into furan derivatives) with the nitrogen-containing crosslinking component melamine was investigated as a support in Pt/C electrocatalysts for the oxygen reduction reaction.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Does the 57Fe Mössbauer isomer shift depend on the oxidation state of iron? 57Fe 莫斯鲍尔异构体位移是否取决于铁的氧化态？
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.002
{"title":"Does the 57Fe Mössbauer isomer shift depend on the oxidation state of iron?","authors":"","doi":"10.1016/j.mencom.2024.09.002","DOIUrl":"10.1016/j.mencom.2024.09.002","url":null,"abstract":"<div><div>The <sup>57</sup>Fe Mössbauer isomer shift is not directly related to the oxidation state of iron, and therefore the evaluation of the oxidation state of iron from the isomer shift is problematic. The oxidation state affects the isomer shift only to the extent that it affects the Fe–X bond lengths. The isomer shift can be estimated based on the average Fe–X interatomic distance.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Precursor method for the synthesis of highly dispersed ZrO2 doped with scandium 合成掺杂钪的高分散 ZrO2 的前驱体方法
IF 1.8 4区 化学
Mendeleev Communications Pub Date : 2024-09-01 DOI: 10.1016/j.mencom.2024.09.005
{"title":"Precursor method for the synthesis of highly dispersed ZrO2 doped with scandium","authors":"","doi":"10.1016/j.mencom.2024.09.005","DOIUrl":"10.1016/j.mencom.2024.09.005","url":null,"abstract":"<div><div>The solid solutions of Zr<sub>1–</sub><em><sub>x</sub></em>Sc<em><sub>x</sub></em>O<sub>2–</sub><em><sub>δ</sub></em> (0 &lt; <em>x</em> ≤ 0.1) were prepared using a precursor technology, and their structural, optical, and photocatalytic characteristics were studied. Mixed formates synthesized by an original method were used as precursors. Scandium favored the formation of ZrO<sub>2</sub> in tetragonal syngony and increased its photoactivity in the UV range.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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