镧系与（4,7-二氯-1,10-菲罗啉-2,9-二基）双（吡咯烷-1-基甲烷）配合物：均相催化和发光测温双功能材料

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-11-01 DOI:10.1016/j.mencom.2024.10.018

Anastasia V. Orlova , Yiming Yin , Valentine S. Petrov , Pavel S. Lemport , Vladislava Yu. Kozhevnikova , Valentine G. Nenajdenko , Valentina V. Utochnikova

引用次数: 0

摘要

以铕和镱与（4,7-二氯-1,10-菲罗啉-2,9-二基）双（吡咯烷-1-基甲烷酮）配合物为基础，首次获得了同时催化和测量温度的双功能材料。该配合物表现出强烈的可见光和近红外发光，具有均匀催化Henry反应的能力，对温度的发光敏感性高（Sr = 1.7% K−1）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Lanthanide complexes with (4,7-dichloro-1,10-phenanthroline-2,9-diyl)bis(pyrrolidin-1-ylmethanone): bifunctional materials for homogeneous catalysis and luminescent thermometry

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Lanthanide complexes with (4,7-dichloro-1,10-phenanthroline-2,9-diyl)bis(pyrrolidin-1-ylmethanone): bifunctional materials for homogeneous catalysis and luminescent thermometry

The first bifunctional materials for simultaneous catalysis and temperature measurements were obtained based on europium and ytterbium complexes with (4,7-dichloro-1,10- phenanthroline-2,9-diyl)bis(pyrrolidin-1-ylmethanone). The complexes demonstrated intense visible and NIR luminescence, the ability to homogeneously catalyze the Henry reaction, and high luminescence sensitivity to temperature (S_r = 1.7% K⁻¹).

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.