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Photocatalytic degradation of textile dye with titanium (IV) doped tungsten oxide nanoparticles 掺杂钛 (IV) 的纳米氧化钨光催化降解纺织染料
Materials protection Pub Date : 2024-03-15 DOI: 10.62638/zasmat1037
Shree H.K. Ranjin, Nidhi Pathak, Charu Lata Dube Dube
{"title":"Photocatalytic degradation of textile dye with titanium (IV) doped tungsten oxide nanoparticles","authors":"Shree H.K. Ranjin, Nidhi Pathak, Charu Lata Dube Dube","doi":"10.62638/zasmat1037","DOIUrl":"https://doi.org/10.62638/zasmat1037","url":null,"abstract":"Water pollution from textile industries is a major concern with respect to the availability of clean drinking water. The removal of textile (organic) dyes through photocatalytic degradation with pure WO3 and titanium (IV) doped tungsten oxide [Ti (IV)-WO3] nanospheres were studied under visible light. The WO3 and Ti (IV)-WO3 nanospheres were synthesized via microwave-assisted method at microwave power of 160 W for the duration of 20 mins. The as synthesised WO3 and Ti (IV)-WO3 nanospheres were characterized for their structural, microstructural, and spectroscopic properties by using powder X-ray diffraction (XRD), UV–Visible (UV-Vis) spectroscopy, Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM) and High-resolution transmission electron microscopy (HR-TEM). The X-ray diffractograms confirmed the formation of highly pure WO3 and Ti (IV)-WO3 nanospheres. The average crystallite size of WO3 and Ti (IV)-WO3 nanospheres were calculated as 53.37 nm and 35.24 nm respectively using Debye Scherrer equation. The bandgap of Ti (IV)-WO3 was found to be decreased to 2.5 eV from 3.2 eV (WO3) respectively. It can be deduced that Ti (IV)-WO3 can be utilized as efficient visible light (λ>420 nm) driven photocatalyst as the bandgap was < 3 eV. The agglomerated spherical nanoparticles were seen for WO3 and Ti (IV)-WO3 in the HR-TEM images. The photocatalytic activity of textile dye was analyzed by UV-Vis spectrophotometer under visible light. The photocatalytic organic dye degradation was investigated. The enhanced photocatalytic activity of titanium (IV) doped tungsten oxide (10 wt%) was observed to be ~100% in 100 mins. This makes titanium (IV) doped tungsten oxide nanospheres, a potential nanomaterial for water purification.","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"123 17","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140237706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ELECTROCHEMICAL CHARACTERISTICS OF SIX ALUMINUM GALVANIC ANODE ALLOYS IN THE SEA 海中六种铝电阳极合金的电化学特性
Materials protection Pub Date : 1971-09-01 DOI: 10.3323/JCORR1954.21.8_376
T. Lennox, R. Groover, M. Peterson
{"title":"ELECTROCHEMICAL CHARACTERISTICS OF SIX ALUMINUM GALVANIC ANODE ALLOYS IN THE SEA","authors":"T. Lennox, R. Groover, M. Peterson","doi":"10.3323/JCORR1954.21.8_376","DOIUrl":"https://doi.org/10.3323/JCORR1954.21.8_376","url":null,"abstract":"THE ELECTROCHEMICAL CHARACTERISTICS OF SIX TYPES OF ALUMINUM GALVANIC ANODE ALLOYS UNDER SIMILAR SERVICE CONDITIONS IN SEA WATER ARE DISCUSSED AND ARE COMPARED WITH ZINC ANODES AND PREVIOUSLY REPORTED DATA FOR ALUMINUM ANODES. THE DATA WERE OBTAINED ON COMMERCIAL PRODUCTION ANODES. THE EXPERIMENT INCLUDED 41 ALUMINUM ANODES AND 3 ZINC CONTROL ANODES. /MPP/","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"1971-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.3323/JCORR1954.21.8_376","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69570154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
DISSOLVED HYDROGEN ANALYZER--A TOOL FOR BOILER CORROSION STUDIES 溶解氢分析仪——锅炉腐蚀研究的工具
Materials protection Pub Date : 1971-05-01 DOI: 10.3323/JCORR1954.21.11_530
C. Jacklin, D G Wiltsey
{"title":"DISSOLVED HYDROGEN ANALYZER--A TOOL FOR BOILER CORROSION STUDIES","authors":"C. Jacklin, D G Wiltsey","doi":"10.3323/JCORR1954.21.11_530","DOIUrl":"https://doi.org/10.3323/JCORR1954.21.11_530","url":null,"abstract":"Several types of waterside corrosion can attack a boiler. In many cases, the only evidence of this corrosion before tube failure is increased hydrogen in the steam. A continuous record of this hydrogen can be obtained with dissolved hydrogen analyzers which utilize the hydrogen's high thermal conductivity to detect as little as 0.2 ppb in steam. Rate of metal loss can be calculated from the amount of hydrogen in the steam, and the pattern of hydrogen release often indicates the type of corrosion. A well planned test program includes tests for sources of hydrogen other than corrosion.","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"1971-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.3323/JCORR1954.21.11_530","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69570142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PERFORMANCE OF VARIOUS COATING SYSTEMS IN A MARINE ENVIRONMENT 各种涂层系统在海洋环境中的性能
Materials protection Pub Date : 1970-11-01 DOI: 10.3323/jcorr1954.21.3_129
W. Singleton
{"title":"PERFORMANCE OF VARIOUS COATING SYSTEMS IN A MARINE ENVIRONMENT","authors":"W. Singleton","doi":"10.3323/jcorr1954.21.3_129","DOIUrl":"https://doi.org/10.3323/jcorr1954.21.3_129","url":null,"abstract":"TESTS WITH COATED STEEL PANELS THAT WERE IMMERSED, SEMI- IMMERSED, AND EXPOSED AT THE SPLASH ZONE LEVEL IN A MARINE ENVIRONMENT ARE DISCUSSED. PERFORMANCE OF THE COATINGS TESTED WAS NOTED ON VARIOUS SURFACE PREPARATIONS. DATA ARE RELATED TO COMPARATIVE COSTS, MAKING ECONOMIC EVALUATION POSSIBLE. /AUTHOR/","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"1970-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.3323/jcorr1954.21.3_129","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69570149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
FAILURE-SAFE DESIGN WITH HIGH STRENGTH STEELS FOR SALT WATER APPLICATIONS 采用高强度钢的故障安全设计,适用于盐水应用
Materials protection Pub Date : 1970-08-01 DOI: 10.3323/JCORR1954.20.11-12_539
R. Judy, R. J. Goode
{"title":"FAILURE-SAFE DESIGN WITH HIGH STRENGTH STEELS FOR SALT WATER APPLICATIONS","authors":"R. Judy, R. J. Goode","doi":"10.3323/JCORR1954.20.11-12_539","DOIUrl":"https://doi.org/10.3323/JCORR1954.20.11-12_539","url":null,"abstract":"PROCEDURES WERE DEVELOPED FOR DETERMINING THE APPROXIMATE FLAW SIZE-STRESS LEVEL REQUIREMENTS FOR FAST FRATCURE, WHICH HAVE PROVEN USEFUL FOR ENGINEERING USAGE OF STEELS. THIS REPORT PROVIDES A PRELIMINARY ANALYSIS OF THE INTERPRETABILITY OF FRACTURE MECHANICS METHODS TO FAILURE SAFE DESIGN FOR STRUCTURES OF HIGH STRENGTH STEELS SUBJECT TO SALT WATER STRESS CORROSION CRACKING. /AUTHOR/","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"1970-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.3323/JCORR1954.20.11-12_539","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69570136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on Notch Plasticity May Contribute to the Understanding of Stress Corrosion Cracking 对缺口塑性的研究有助于对应力腐蚀开裂的认识
Materials protection Pub Date : 1969-05-01 DOI: 10.5006/0010-9312-25.5.193
J. Spretnak, C. A. Griffis
{"title":"Research on Notch Plasticity May Contribute to the Understanding of Stress Corrosion Cracking","authors":"J. Spretnak, C. A. Griffis","doi":"10.5006/0010-9312-25.5.193","DOIUrl":"https://doi.org/10.5006/0010-9312-25.5.193","url":null,"abstract":"RESEARCH JUST COMPLETED AT THE OHIO STATE UNIVERSITY ON FACTORS LIMITING PLASTIC STRAIN UNDER A NOTCH (OR CRACK) MAY PROVE IMPORTANT IN ELUCIDATING CERTAIN ASPECTS OF PLASTIC ZONE BEHAVIOR IN STRESS CORROSION CRACKING. IT WAS FOUND THAT THE PLASTIC ZONE AT THE TIP OF THE CRACK EXPANDS ON LOADING UNTIL A CRITICAL STRAIN AT THE NOTCH ROOT IS ATTAINED. AT THIS STRAIN, THE MATERIAL UNDERGOES A RHEOLOGICAL TRANSFORMATION INTO FLUID-LIKE FLOW (VISCO- PLASTIC), IN WHICH IT IS SUSCEPTIBLE TO LOCALIZATION OF FLOW ALONG \"CHARACTERISTICS\" (SLIP LINES IN FIELDS), WHICH ARE DIRECTIONS OF CRITICAL MAXIMUM SHEAR STRESS AND ALSO DIRECTION OF PURE SHEAR. PLASTIC INSTABILITIES MAY BE MOUNTED ALONG THESE DIRECTIONS. WEAK INSTABILITIES LEAD TO STABLE SLOW CRACK PROPAGATION; STRONG INSTABILITIES LEAD TO UNSTABLE FAST PROPAGATION (BRITTLE FRACTURE). AGGRESSIVE CHEMICAL ENVIRONMENTS MAY AFFECT ONE OR BOTH OF THESE NEW MATERIAL PARAMETERS WHICH HAVE BEEN DISCLOSED, NAMELY THE CRITICAL STRAIN AT WHICH FLOW IS CONCENTRATED ALONG CHARACTERISTICS AND THE NATURE OF THE INSTABILITIES (STRONG OR WEAK) THAT CAN BE GENERATED ALONG CHARACTERISTICS. PLASTIC ZONE BEHAVIOR, THUS, INVOLVES METALLURGICAL STRUCTURE, RHEOLOGY, AND FORMAL PLASTICITY THEORY. /AUTHOR/","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"25 1","pages":"193-193"},"PeriodicalIF":0.0,"publicationDate":"1969-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.5006/0010-9312-25.5.193","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70849772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
CORROSION INHIBITORS FOR ALUMINUM 铝用缓蚀剂
Materials protection Pub Date : 1966-07-01 DOI: 10.3323/JCORR1954.15.11_495
A. Roebuck, T. R. Pritchett
{"title":"CORROSION INHIBITORS FOR ALUMINUM","authors":"A. Roebuck, T. R. Pritchett","doi":"10.3323/JCORR1954.15.11_495","DOIUrl":"https://doi.org/10.3323/JCORR1954.15.11_495","url":null,"abstract":"INHIBITORS PROVIDING CATHODIC PROTECTION, ANODIC PROTECTION OF OVERALL GROSS PROTECTION MAY BE CHOSEN BY AN EVALUATION OF THEIR CURRENT-POTENTIAL RELATIONSHIPS AS DERIVED BY POTENTIODYNAMIC MEASUREMENTS. INHIBITORS MUST BE CAREFULLY CHOSEN TO FIT THE PARTICULAR APPLICATION REQUIRED. THE 5000 SERIES ALLOYS, CONTAINING MAGNESIUM AS THE MAJOR ALLOYING ELEMENT, ARE SHOWN TO HAVE GREATER CORROSION RESISTANCE IN SALINE MEDIA THAN DO THE 1100 OR HIGH-PURITY ALLOYS. JEL-TYPE INHIBITORS SUCH AS AGAR-AGAR, BLOCK THE CATHODIC REACTIONS, CAUSING MARKED CATHODIC POLARIZATION. AMINE INHIBITORS ALSO AFFECT THE CATHODIC CHARACTERISTICS. THEY SHOULD PROVE USEFUL IN INHIBITING ALUMINUM CORROSION IN ACID MEDIA. CHROMATES ARE EFFECTIVE ANODIC INHIBITORS. THE INCREASED EFFECTIVENESS OF NICKEL CHROMATE OVER POTASSIUM CHROMATE INDICATED THAT THE EFFECTIVENESS OF CHROMATES WAS NOT ENTIRELY DUE TO THEIR OXIDIZING ABILITY. /AUTHOR/","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.3323/JCORR1954.15.11_495","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69570103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
A METHOD FOR DETERMINING BRIDGE PAINTING CYCLES 确定桥梁粉刷周期的方法
Materials protection Pub Date : 1965-06-01 DOI: 10.3323/JCORR1954.15.2_72
C. Kirsch
{"title":"A METHOD FOR DETERMINING BRIDGE PAINTING CYCLES","authors":"C. Kirsch","doi":"10.3323/JCORR1954.15.2_72","DOIUrl":"https://doi.org/10.3323/JCORR1954.15.2_72","url":null,"abstract":"FACTORS INFLUENCING EFFECTIVENESS, COST, AND TIME CYCLES FOR BRIDGE PAINTING ARE DISCUSSED. STRUCTURAL, ENVIRONMENTAL , AND CHEMICAL FACTORS OF THE PAINT SYSTEM ARE CONSIDERED IN THE MATHEMATICAL MODEL DESCRIBED. HOW MATHEMATICAL EVALUATION CAN AFFECT THE DECISION OF OPTIMUM PAINTING CYCLE TIMES IS SHOWN. THE PROCEDURE HAS BEEN USED BY PORT OF NEW YORK AUTHORITY, TUNNELS AND BRIDGES DEPARTMENT, TO EVALUATE PAINTING CYCLES FOR NEW YORK BRIDGES.","PeriodicalId":18284,"journal":{"name":"Materials protection","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.3323/JCORR1954.15.2_72","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69570107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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