Materials Letters: XPub Date : 2026-06-01Epub Date: 2026-02-05DOI: 10.1016/j.mlblux.2026.100263
Farrukh Saleem , Zhao Chengxu , Yao Zaiqi , Wenbin Shangguan , Yao Xiaohu , Cheng Zhixiong , Yuan Chengyi , Haroon Ahmed , Tang Xiangmin , Tianzhi Luo
{"title":"Microstructure characterization on tensile properties of closed-cell aluminum foam","authors":"Farrukh Saleem , Zhao Chengxu , Yao Zaiqi , Wenbin Shangguan , Yao Xiaohu , Cheng Zhixiong , Yuan Chengyi , Haroon Ahmed , Tang Xiangmin , Tianzhi Luo","doi":"10.1016/j.mlblux.2026.100263","DOIUrl":"10.1016/j.mlblux.2026.100263","url":null,"abstract":"<div><div>Due to high mechanical efficiency, closed-cell aluminum foam (CCAF) is suitable for lightweight structures and energy absorption applications. However, mechanical behavior of CCAF has not been fully apprehended in microstructure parameters. For this reason, closed-cells structure-performance of CCAF has been investigated by using comprehensive experimental and microstructure characterization method. Scanning electron microscopy and energy dispersive X-ray spectroscopy has been used to evaluate the morphology, deformation mechanism and crack propagation of CCAF. The results have shown that increase in relative densities is directly related to increase in yield strength, young's modulus and ultimate tensile strength due to improvement of load distribution and reduction of stress concentration in dense cell walls of CCAF.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"27 ","pages":"Article 100263"},"PeriodicalIF":2.6,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146189531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2026-06-01Epub Date: 2026-05-25DOI: 10.1016/j.mlblux.2026.100274
Wiktor Kuklewski, Muhammad Saleem Akhtar, Gabriela Komorowska, Grzegorz Cieślak, Tomasz Wejrzanowski
{"title":"Multi–component Cr–Mn–Fe–Co–Ni oxide as bifunctional electrode for alkaline water splitting","authors":"Wiktor Kuklewski, Muhammad Saleem Akhtar, Gabriela Komorowska, Grzegorz Cieślak, Tomasz Wejrzanowski","doi":"10.1016/j.mlblux.2026.100274","DOIUrl":"10.1016/j.mlblux.2026.100274","url":null,"abstract":"<div><div>In this work, a mixed transition metal oxide layer, composed of Cr–Mn–Fe–Co–Ni was synthesized on the nickel foam via a one-step microwave-assisted hydrothermal method and investigated as a bifunctional electrode for alkaline water electrolysis. Morphological analysis indicated the deposition of oxide layer on nickel foam. The synthesized material exhibited favorable catalytic performance compared with bare nickel foam, particularly toward the oxygen evolution reaction (OER) in 1 M KOH. The catalyst delivered OER performance of η10 = 236 mV and η100 = 306 mV, with a Tafel slope of 70 mV dec<sup>−1</sup>. For HER, η10 = 157 mV and η100 = 260 mV were obtained, with a Tafel slope of 107 mV dec<sup>−1</sup>. These results demonstrate the potential of the Cr–Mn–Fe–Co–Ni oxide as an efficient bifunctional electrocatalyst for alkaline water splitting.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"27 ","pages":"Article 100274"},"PeriodicalIF":2.6,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148178117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2026-06-01Epub Date: 2026-02-05DOI: 10.1016/j.mlblux.2026.100264
Minsu Kim , Hiroaki Tatsumi , Sang-Wook Kim , Ji-Hyun Kim , Soong-Keun Hyun , Hiroshi Nishikawa
{"title":"Effect of lotus-type porous cu on reliability of ag-sintered joints during thermal cycling","authors":"Minsu Kim , Hiroaki Tatsumi , Sang-Wook Kim , Ji-Hyun Kim , Soong-Keun Hyun , Hiroshi Nishikawa","doi":"10.1016/j.mlblux.2026.100264","DOIUrl":"10.1016/j.mlblux.2026.100264","url":null,"abstract":"<div><div>This study examines the effect of unidirectional porous copper (lotus Cu) on the reliability of Ag-sintered interfaces between Si and Cu during thermal cycling. In high-performance wide-bandgap semiconductor power modules, the large coefficient of thermal expansion (CTE) mismatch generates significant thermomechanical stresses, leading to interfacial degradation. Lotus Cu, with high vertical thermal conductivity and a low elastic modulus was proposed as an alternative joint material. Si/sintered Ag/lotus Cu and Si/sintered Ag/bulk Cu joints were fabricated via Ag particle paste and evaluated through thermal cycling tests (−55 °C to 150 °C). After 500 cycles, bulk Cu joints exhibited extensive delamination, whereas lotus Cu joints maintained bonding area with only localized interfacial damage. These results suggest that the unique pore structure of lotus Cu can redistribute thermal stress, provide more complex crack propagation paths, and potentially improve the reliability of the Si/Cu joint.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"27 ","pages":"Article 100264"},"PeriodicalIF":2.6,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146189528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2026-06-01Epub Date: 2026-06-04DOI: 10.1016/j.mlblux.2026.100275
Bruno Peixoto , Aron Rodrigues , Maiara Ferreira , Tamires de Souza , Thalita de Sousa , Syntia Cotrim , Flávio Colman , Yutao Xing , Rita Colman
{"title":"Comparative study of toluene oxidation over reduced graphene oxide-supported Pt and Ni catalysts","authors":"Bruno Peixoto , Aron Rodrigues , Maiara Ferreira , Tamires de Souza , Thalita de Sousa , Syntia Cotrim , Flávio Colman , Yutao Xing , Rita Colman","doi":"10.1016/j.mlblux.2026.100275","DOIUrl":"10.1016/j.mlblux.2026.100275","url":null,"abstract":"<div><div>Reduced graphene oxide (rGO) was prepared from graphite by modified Hummers oxidation followed by two-step thermal reduction and used as support for Pt and Ni catalysts in toluene oxidation. The protocol produced few-layer rGO with residual oxygenated anchoring groups and with a 23-fold increase in Brunauer-Emmett-Teller (BET) surface area. Pt/rGO (1 wt% Pt) and Ni/rGO (10 wt% Ni) were obtained by wet impregnation. XRD, Raman, FTIR, BET, SEM-EDS, TGA and H<sub>2</sub>-TPR linked structure, dispersion and reducibility to catalytic behavior. Scherrer analysis gave apparent coherent-domain sizes of 9.4 nm for Pt<sup>0</sup>(111) and 9.3 nm for Ni<sup>0</sup>(200). Pt/rGO reached T<sub>50</sub> ≈ 255 °C and 99% conversion at 400 °C, whereas Ni/rGO reached 55% at 400 °C. Time-on-stream tests confirmed stable operation and CO<sub>2</sub> as the only carbon-containing product detected. The results demonstrate that rGO can serve as a practical carbon support for noble and non-noble metal formulations in VOC oxidation, while emphasizing the central role of metal reducibility, dispersion and metal-support interaction.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"27 ","pages":"Article 100275"},"PeriodicalIF":2.6,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148241043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2026-06-01Epub Date: 2026-01-06DOI: 10.1016/j.mlblux.2026.100262
M.S. Archana , S. Jayalekshmi , S. Deepa , Nandakumar Kalarikkal
{"title":"Electrospun Polyaniline-Graphene/PVA Composite Nanofiber: Structural, Morphological and Thermal Characteristics","authors":"M.S. Archana , S. Jayalekshmi , S. Deepa , Nandakumar Kalarikkal","doi":"10.1016/j.mlblux.2026.100262","DOIUrl":"10.1016/j.mlblux.2026.100262","url":null,"abstract":"<div><div>Electrospun nanofibers with high surface area and tunable morphology are promising platforms for advanced functional materials. In this work, polyaniline (PANI)–graphene composites were blended with poly vinyl alcohol (PVA) and fabricated into nanofibers via electrospinning. Structural, chemical, morphological, and thermal properties were systematically investigated using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The results reveal enhanced molecular ordering and strong interfacial interactions among PANI, graphene, and PVA, along with bead-free nanofibers exhibiting an average diameter of ∼32 nm with a narrow size distribution. TGA demonstrates improved thermal stability with delayed degradation compared to PANI/PVA systems reported in literature, attributed to the stabilizing role of graphene. These findings indicate that materials based on PANI–graphene/PVA nanofibers can serve as a tunable composite platform, which with appropriate compositional or surface modifications may be further developed for specific functional applications.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"27 ","pages":"Article 100262"},"PeriodicalIF":2.6,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145950221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2025-12-01Epub Date: 2025-07-12DOI: 10.1016/j.mlblux.2025.100249
Shuzheng Guo , Jingyi Huang , Na Ta , Fengze Cao , Sihua Ha , Shuai He , Jianli He , Luomeng Chao
{"title":"High energy-resolution electron energy loss spectroscopy and near infrared absorption study of cesium tungsten bronze and lanthanum hexaboride","authors":"Shuzheng Guo , Jingyi Huang , Na Ta , Fengze Cao , Sihua Ha , Shuai He , Jianli He , Luomeng Chao","doi":"10.1016/j.mlblux.2025.100249","DOIUrl":"10.1016/j.mlblux.2025.100249","url":null,"abstract":"<div><div>Cs<sub>0.33</sub>WO<sub>3</sub> nanoparticles exhibit strong localized surface plasmon resonance (LSPR), making them effective at absorbing near-infrared (NIR) light. However, effectively tuning the optical absorption of Cs<sub>0.33</sub>WO<sub>3</sub> in the critical NIR range of 800–1000 nm has remained a major challenge. In this study, we employ aberration-corrected electron microscopy to conduct high-resolution electron energy loss spectroscopy (EELS) on both Cs<sub>0.33</sub>WO<sub>3</sub> and LaB<sub>6</sub> nanoparticles, reveal that the surface plasmon resonance in LaB<sub>6</sub> nanoparticles occurs at a higher energy than in Cs<sub>0.33</sub>WO<sub>3</sub>, allowing LaB<sub>6</sub> to absorb NIR light at shorter wavelengths. Based on this, we successfully adjusted the absorption characteristics of Cs<sub>0.33</sub>WO<sub>3</sub> in the range of 800–1000 nm by utilizing the synergistic LSPR tuning of LaB<sub>6</sub> nanoparticles.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100249"},"PeriodicalIF":2.2,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2025-12-01Epub Date: 2025-07-03DOI: 10.1016/j.mlblux.2025.100248
F.A.C. Nobrega , E.A.W. Menezes , R. Reichenbächer , C. Scheffler , R.F. Abreu , E.F. Morais , C.M.B. Cordeiro , A. Spickenheuer , S.C. Amico , A.S.B. Sombra
{"title":"Simple and efficient optical fiber recoating procedure","authors":"F.A.C. Nobrega , E.A.W. Menezes , R. Reichenbächer , C. Scheffler , R.F. Abreu , E.F. Morais , C.M.B. Cordeiro , A. Spickenheuer , S.C. Amico , A.S.B. Sombra","doi":"10.1016/j.mlblux.2025.100248","DOIUrl":"10.1016/j.mlblux.2025.100248","url":null,"abstract":"<div><div>This article describes a rapid method of recoating optical fibers employing the dip-coating technique, using a polypropylene film former with a silane coupling agent, which reacts, yielding a protective film over the core. The silica optical fibers were recoated with film former sizings at concentrations of 5 % and 10 %. Microscopic analysis of the recoated area showed a smooth surface and an increase in diameter of 13.4 % and 16.5 %, respectively, compared to the uncoated fiber. The maximum curvature radius of the uncoated fibers was 3.69 ± 1.70 mm, whereas the fibers recoated with the 5 % and 10 % film former sizings reached a bending radius of 1.71 ± 1.38 mm and 1.55 ± 0.98 mm, representing 53.9 % and 57.9 % reduction, respectively. This shows that recoated optical fibers are more flexible than the uncoated ones. In all, the recoating of optical fibers proposed in this work results in fibers with smooth and flexible surfaces using a simple, cost-effective technique that can be implemented on large-scale processes.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100248"},"PeriodicalIF":2.2,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144563627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2025-12-01Epub Date: 2025-07-30DOI: 10.1016/j.mlblux.2025.100252
Jiangfei Wang , Weijia Chen , Yijun Wen , Yuhan Peng , Siqi Liu , Shiwei He
{"title":"Electrochemical dealloying in ChCl-Urea Deep eutectic solvent: A strategy to fabricate porous FeCoNiAlMo high-entropy alloy with enhanced oxygen evolution reaction activity","authors":"Jiangfei Wang , Weijia Chen , Yijun Wen , Yuhan Peng , Siqi Liu , Shiwei He","doi":"10.1016/j.mlblux.2025.100252","DOIUrl":"10.1016/j.mlblux.2025.100252","url":null,"abstract":"<div><div>High-entropy alloys (HEAs), as a new type of multi-element alloy, have become widely studied electrocatalytic materials in recent years due to their excellent catalytic performance. The experimental material used FeCoNiAlMo HEA with equal atomic ratio as the precursor, and three-dimensional nanostructures were formed by dealloying in choline chloride-urea (ChCl-Urea). The results indicate that Fe<sub>20</sub>Co<sub>20</sub>Ni<sub>20</sub>Al<sub>20</sub>Mo<sub>20</sub> HEA is mainly composed of body-centered cubic (BCC) phase and face-centered cubic (FCC) phase, with BCC phase accounting for a larger proportion. Due to the different corrosion resistance of elements and the difference in element content distribution between the two phases, the FCC phase is preferentially corroded, resulting in a three-dimensional porous morphology. This unique structure synergistically reduces the energy barrier during the hydrolysis dissociation process, giving the material a significant advantage in the oxygen evolution reaction (OER) process. At a current density of 10 mA cm<sup>−2</sup>, the overpotential of the treated alloy is as low as 312 mV, which is lower than the commercial RuO<sub>2</sub>-IrO<sub>2</sub>, and it has lower resistance and higher charge transfer efficiency.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100252"},"PeriodicalIF":2.6,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials Letters: XPub Date : 2025-12-01Epub Date: 2025-10-23DOI: 10.1016/j.mlblux.2025.100259
Joel Renaud Ngouanom Gnidakouong , Arnaud Takungang Kamdem , Bertrand Sitamtze Youmbi , Claude Valery Ngayihi Abbe
{"title":"Optimizing piezoresistive response of carbon nanotube-cellulose nanocrystal composites","authors":"Joel Renaud Ngouanom Gnidakouong , Arnaud Takungang Kamdem , Bertrand Sitamtze Youmbi , Claude Valery Ngayihi Abbe","doi":"10.1016/j.mlblux.2025.100259","DOIUrl":"10.1016/j.mlblux.2025.100259","url":null,"abstract":"<div><div>This study explores the effect of straining angle on the piezoresistive behaviour of carbon nanotube (CNT)-cellulose nanocrystal (CNC) composites. By varying the angle between the directions of strain and tunnelling distance, the research investigates the impact on composite strain sensing sensitivity. Additionally, the optimal CNC weight fraction that maximizes the piezoresistive performance under elastic strain is determined using a polynomial interpolation of a validated analytical model. The findings indicate that the ideal case is when the direction of strain is parallel to the average tunnelling distance direction, and 0.5 % is the optimal CNC weight content for elastic strains. These findings may provide valuable insights for designing high-performance and sustainable strain sensors based on CNT-CNC composites.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100259"},"PeriodicalIF":2.6,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145415825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}