{"title":"Effect of austenitizing temperature on microstructure and mechanical properties of medium carbon spring steel","authors":"Qian Yu , Yuliang Zhao , Feiyu Zhao","doi":"10.1016/j.mlblux.2025.100251","DOIUrl":"10.1016/j.mlblux.2025.100251","url":null,"abstract":"<div><div>The influence of austenitizing temperature on the microstructure and mechanical properties of medium carbon spring steel was systematically studied. Microstructural characterization showed that decreasing the austenitizing temperature from 900 °C to 860 °C effectively refined prior austenite grains from 8.8 μm to 5.3 μm, reduced martensite block thickness from 0.9 μm to 0.7 μm, and increased the fraction of high-angle grain boundaries (HAGBs) from 70 % to 76 %. Crystallographic variant analysis revealed increased boundary densities for V1&V2, V1&V3(V5), V1&V4, and V1&V6 pairs in the 860 °C sample with refined PAGS, along with elevated frequencies of V1&V3(V5) and V1&V6 pairs classified as HAGBs, consistent with the K-S orientation relationship. These results demonstrate that reducing the austenitizing temperature from 900 °C to 860 °C significantly affects martensite block size, HAGB fraction, and crystallographic variant pairs, leading to enchanced yield strength from 1563 MPa to 1648 MPa and total elongation from 9.3 % to 9.7 %.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100251"},"PeriodicalIF":2.6,"publicationDate":"2025-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144767242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiangfei Wang , Weijia Chen , Yijun Wen , Yuhan Peng , Siqi Liu , Shiwei He
{"title":"Electrochemical dealloying in ChCl-Urea Deep eutectic solvent: A strategy to fabricate porous FeCoNiAlMo high-entropy alloy with enhanced oxygen evolution reaction activity","authors":"Jiangfei Wang , Weijia Chen , Yijun Wen , Yuhan Peng , Siqi Liu , Shiwei He","doi":"10.1016/j.mlblux.2025.100252","DOIUrl":"10.1016/j.mlblux.2025.100252","url":null,"abstract":"<div><div>High-entropy alloys (HEAs), as a new type of multi-element alloy, have become widely studied electrocatalytic materials in recent years due to their excellent catalytic performance. The experimental material used FeCoNiAlMo HEA with equal atomic ratio as the precursor, and three-dimensional nanostructures were formed by dealloying in choline chloride-urea (ChCl-Urea). The results indicate that Fe<sub>20</sub>Co<sub>20</sub>Ni<sub>20</sub>Al<sub>20</sub>Mo<sub>20</sub> HEA is mainly composed of body-centered cubic (BCC) phase and face-centered cubic (FCC) phase, with BCC phase accounting for a larger proportion. Due to the different corrosion resistance of elements and the difference in element content distribution between the two phases, the FCC phase is preferentially corroded, resulting in a three-dimensional porous morphology. This unique structure synergistically reduces the energy barrier during the hydrolysis dissociation process, giving the material a significant advantage in the oxygen evolution reaction (OER) process. At a current density of 10 mA cm<sup>−2</sup>, the overpotential of the treated alloy is as low as 312 mV, which is lower than the commercial RuO<sub>2</sub>-IrO<sub>2</sub>, and it has lower resistance and higher charge transfer efficiency.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100252"},"PeriodicalIF":2.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hossein Pourrahmani , Thomas B. Ferriday , Raha Razmara , Hossein Madi , Jan Van herle
{"title":"Advanced imaging of gas diffusion layers: A comparison between focused ion beam scanning electron microscopy and X-ray computed tomography","authors":"Hossein Pourrahmani , Thomas B. Ferriday , Raha Razmara , Hossein Madi , Jan Van herle","doi":"10.1016/j.mlblux.2025.100250","DOIUrl":"10.1016/j.mlblux.2025.100250","url":null,"abstract":"<div><div>With the advances in clean technologies, the role of fuel cells and batteries is becoming increasingly vital. Proton exchange membrane fuel cells are known to be the best candidates for low-temperature and portable operations, such as hydrogen cars. The efficiency and longevity of these fuel cells can be feasible through detailed microstructural analysis. In this regard, advanced imaging techniques are being used to visualize the structure of the different layers of PEMFCs including the membrane, catalyst layer, and gas diffusion layer. This study’s focus and novelty is to compare the focused ion beam scanning electron microscopy and X-ray Computed Tomography scanning for the microstructural imaging of the GDL.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100250"},"PeriodicalIF":2.2,"publicationDate":"2025-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144670660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shuzheng Guo , Jingyi Huang , Na Ta , Fengze Cao , Sihua Ha , Shuai He , Jianli He , Luomeng Chao
{"title":"High energy-resolution electron energy loss spectroscopy and near infrared absorption study of cesium tungsten bronze and lanthanum hexaboride","authors":"Shuzheng Guo , Jingyi Huang , Na Ta , Fengze Cao , Sihua Ha , Shuai He , Jianli He , Luomeng Chao","doi":"10.1016/j.mlblux.2025.100249","DOIUrl":"10.1016/j.mlblux.2025.100249","url":null,"abstract":"<div><div>Cs<sub>0.33</sub>WO<sub>3</sub> nanoparticles exhibit strong localized surface plasmon resonance (LSPR), making them effective at absorbing near-infrared (NIR) light. However, effectively tuning the optical absorption of Cs<sub>0.33</sub>WO<sub>3</sub> in the critical NIR range of 800–1000 nm has remained a major challenge. In this study, we employ aberration-corrected electron microscopy to conduct high-resolution electron energy loss spectroscopy (EELS) on both Cs<sub>0.33</sub>WO<sub>3</sub> and LaB<sub>6</sub> nanoparticles, reveal that the surface plasmon resonance in LaB<sub>6</sub> nanoparticles occurs at a higher energy than in Cs<sub>0.33</sub>WO<sub>3</sub>, allowing LaB<sub>6</sub> to absorb NIR light at shorter wavelengths. Based on this, we successfully adjusted the absorption characteristics of Cs<sub>0.33</sub>WO<sub>3</sub> in the range of 800–1000 nm by utilizing the synergistic LSPR tuning of LaB<sub>6</sub> nanoparticles.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100249"},"PeriodicalIF":2.2,"publicationDate":"2025-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
F.A.C. Nobrega , E.A.W. Menezes , R. Reichenbächer , C. Scheffler , R.F. Abreu , E.F. Morais , C.M.B. Cordeiro , A. Spickenheuer , S.C. Amico , A.S.B. Sombra
{"title":"Simple and efficient optical fiber recoating procedure","authors":"F.A.C. Nobrega , E.A.W. Menezes , R. Reichenbächer , C. Scheffler , R.F. Abreu , E.F. Morais , C.M.B. Cordeiro , A. Spickenheuer , S.C. Amico , A.S.B. Sombra","doi":"10.1016/j.mlblux.2025.100248","DOIUrl":"10.1016/j.mlblux.2025.100248","url":null,"abstract":"<div><div>This article describes a rapid method of recoating optical fibers employing the dip-coating technique, using a polypropylene film former with a silane coupling agent, which reacts, yielding a protective film over the core. The silica optical fibers were recoated with film former sizings at concentrations of 5 % and 10 %. Microscopic analysis of the recoated area showed a smooth surface and an increase in diameter of 13.4 % and 16.5 %, respectively, compared to the uncoated fiber. The maximum curvature radius of the uncoated fibers was 3.69 ± 1.70 mm, whereas the fibers recoated with the 5 % and 10 % film former sizings reached a bending radius of 1.71 ± 1.38 mm and 1.55 ± 0.98 mm, representing 53.9 % and 57.9 % reduction, respectively. This shows that recoated optical fibers are more flexible than the uncoated ones. In all, the recoating of optical fibers proposed in this work results in fibers with smooth and flexible surfaces using a simple, cost-effective technique that can be implemented on large-scale processes.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100248"},"PeriodicalIF":2.2,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144563627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"TEM observation of extracted precipitates in T5 heat treated Al–Si–Mg alloy","authors":"Taiki Tsuchiya , Seungwon Lee , Susumu Ikeno , Kenji Matsuda","doi":"10.1016/j.mlblux.2025.100246","DOIUrl":"10.1016/j.mlblux.2025.100246","url":null,"abstract":"<div><div>The precipitation behavior of an Al–6.8 %Si–0.38 %Mg cast alloy subjected to T5 heat treatment was investigated using transmission electron microscopy (TEM). At the peak aging condition of 200 °C, granular and rod-shaped precipitates were observed at the center of the dendrite. Rod-shaped precipitates were successfully extracted after aging at 250 °C for 3.6 ks. Energy-dispersive X-ray spectroscopy (EDS) confirmed that the extracted precipitates had a Mg:Al:Si atomic ratio of approximately 1:4:5, consistent with previously reported Type-A precipitates. Selected area electron diffraction (SAED) analysis further confirmed their hexagonal crystal structure, with lattice parameters <em>a</em> = 0.405 nm and <em>c</em> = 0.67 nm. These findings indicate that Type-A precipitates, which are typically observed in excess-Si Al–Mg–Si alloys, also form in T5-treated Al–Si–Mg cast alloys.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100246"},"PeriodicalIF":2.2,"publicationDate":"2025-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144298665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Y Austernaud , M Novelli , T.H. Kauffmann , P Bocher , T Grosdidier
{"title":"Surface contamination induced by warm severe surface peening using 100C6 steel and ZrO2 shots","authors":"Y Austernaud , M Novelli , T.H. Kauffmann , P Bocher , T Grosdidier","doi":"10.1016/j.mlblux.2025.100245","DOIUrl":"10.1016/j.mlblux.2025.100245","url":null,"abstract":"<div><div>The sample surface contamination induced during Surface Mechanical Attrition Treatment (SMAT) was studied after peening treatments carried out with 100C6 steel and ZrO<sub>2</sub> zirconia shots at room temperature, 523 K, and 773 K. All constituting parts of the treatment device (sonotrode, chamber, shots) contributed to sample surface contamination. Increasing the SMAT temperature led to a higher surface contamination with bigger contaminant debris as well as sample surface oxidation. In particular, several ZrO<sub>2</sub> shots were fragmented at 773 K due to a phase transformation embrittlement under warm condition.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100245"},"PeriodicalIF":2.2,"publicationDate":"2025-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144212677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jurij Urbančič , Huanhuan Shi , Ali Shaygan Nia , Egon Pavlica
{"title":"Semiconducting polymer-MXene blends with improved charge carrier mobilities and their application in field-effect transistors","authors":"Jurij Urbančič , Huanhuan Shi , Ali Shaygan Nia , Egon Pavlica","doi":"10.1016/j.mlblux.2025.100244","DOIUrl":"10.1016/j.mlblux.2025.100244","url":null,"abstract":"<div><div>Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> is the first successfully obtained member of the MXene family. Due to its many excellent properties such as high metallic conductivity, solubility and capacitance, it has attracted a wide interest in potential applications such as supercapacitors and energy storage devices. In the presented work, we have successfully produced various semiconducting thin-films consisting of Poly(3-hexylthiophene-2,5-diyl) (P3HT) organic semiconductor (OS) blended with MXene flakes with different MXenes concentrations. Time-of-flight photoconductivity (TOFP) measurements revealed a 370 % enhancement in charge carrier mobility compared to neat P3HT. Organic field-effect transistors (OFETs) were also fabricated using these blends, showing a 20 % improvement in field-effect mobility. This discrepancy arises due to contact resistance and interface effects in OFETs, which are absent in TOFP measurements. These results highlight the promise of P3HT:MXene blends for advanced electronic applications, where high mobility and straightforward processing are essential.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"25 ","pages":"Article 100244"},"PeriodicalIF":2.2,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144089594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wei Wang , Xiaoju Chen , Xinyu Ye , Bei Ni , Lin Xu , Minmin Chen
{"title":"Eco-friendly gelatin/rice bran polysaccharides packaging films for fruit preservation","authors":"Wei Wang , Xiaoju Chen , Xinyu Ye , Bei Ni , Lin Xu , Minmin Chen","doi":"10.1016/j.mlblux.2025.100243","DOIUrl":"10.1016/j.mlblux.2025.100243","url":null,"abstract":"<div><div>Rice bran polysaccharides (RB) has a wide range of biological activities. However, it is rarely investigated as a food packaging material. The present study aimed to extract RB and prepare gelatin/RB (Ge/RB) film by solution casting method. The results indicated the incorporation of RB into films increased the roughness, tensile strength, and antioxidant activity but decreased the water contact angle of the films. In addition, the film could decrease the weight loss rate of the apple and prevent wound decay of the pear. Therefore, the Ge/RB food packaging film has great potential for food preservation.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"25 ","pages":"Article 100243"},"PeriodicalIF":2.2,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144069220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sion Kim , Kamal Asghar , Miguta Faustine Ngulimi , Bum Kyoung Seo , Changhyun Roh
{"title":"1,3-Diethyl-2-Thiourea as a corrosion inhibitor for carbon steel SA 106 GR.B","authors":"Sion Kim , Kamal Asghar , Miguta Faustine Ngulimi , Bum Kyoung Seo , Changhyun Roh","doi":"10.1016/j.mlblux.2025.100242","DOIUrl":"10.1016/j.mlblux.2025.100242","url":null,"abstract":"<div><div>The corrosion inhibition efficiency of 1,3-diethyl-2-thiourea (DETU) was evaluated in the inorganic-based Hydrazine-Based Reductive Ion Decontamination (HyBRID) solution under actual decontamination temperature conditions. The results showed that adding 0.01 wt% DETU reduced the corrosion depth and rate of carbon steel by ∼30 % (from 9.89 to 6.90 µm and 3.29 to 2.30 µm/h, respectively), and the dissolved iron concentration by ∼27 % (from 193.35 to 140.35 ppm). This inhibition effect is attributed to the strong adsorption of DETU on the carbon steel surface, forming a protective layer. These results suggest that DETU is an effective corrosion inhibitor for structural materials in pressurized heavy water reactors (PHWR) using inorganic acid-based chemical decontamination.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"25 ","pages":"Article 100242"},"PeriodicalIF":2.2,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143899165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}