Yue Ding , Tianling Yu , Min He , Yichen Hao , Yaning Wang , Xidong Hao
{"title":"Yttria stabilized-Zirconia based sub-ppb level acetone sensor with LaBaSn2O5+δ sensing electrode","authors":"Yue Ding , Tianling Yu , Min He , Yichen Hao , Yaning Wang , Xidong Hao","doi":"10.1016/j.mlblux.2025.100256","DOIUrl":"10.1016/j.mlblux.2025.100256","url":null,"abstract":"<div><div>For the efficient diagnosis of diabetes via exhaled breath analysis, electrochemical acetone sensors based on mixed potential were fabricated using yttria-stabilized zirconia as the solid electrolyte and LaBaSn<sub>2</sub>O<sub>5</sub>+δ as the sensing electrode (SE) material. To optimize the sensing property, we varied the sintering temperature to modify the electrocatalytic activity of LaBaSn<sub>2</sub>O<sub>5</sub>+δ. Results show that LaBaSn<sub>2</sub>O<sub>5</sub>+δ SE sintered at 800 °C exhibited the highest response of −31 mV when exposed to 100 ppm acetone. The detection limit reached as low as 100 ppb, and a sensitivity of −17 mV/decade was achieved across the acetone concentration range of 2–100 ppm. Additionally, the sensor exhibited excellent selectivity, repeatability, and long-term stability. The excellent sensing performance indicates that the developed acetone sensor can be used for the noninvasive diagnosis of diabetes.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100256"},"PeriodicalIF":2.6,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145044647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Azkar Saeed Ahmad , Zhuoyang Yu , Sizhe Wang , Tong Weng , Wenting Lu , Baihong Sun , Jiewu Song , Qian Zhang , Martin Kunz , Bihan Wang , Elissaios Stavrou
{"title":"High pressure synthesis and structural study of AuGa2 intermetallic compound","authors":"Azkar Saeed Ahmad , Zhuoyang Yu , Sizhe Wang , Tong Weng , Wenting Lu , Baihong Sun , Jiewu Song , Qian Zhang , Martin Kunz , Bihan Wang , Elissaios Stavrou","doi":"10.1016/j.mlblux.2025.100257","DOIUrl":"10.1016/j.mlblux.2025.100257","url":null,"abstract":"<div><div>We report the synthesis of the AuGa<sub>2</sub> intermetallic compound, using a direct reaction of the relevant elements at room temperature and at very low pressure. The pressure needed for the synthesis is ≈ 0.1 GPa, that is at the lower limit of modern large volume presses, routinely used to synthesize other commercially available materials. This study presents a new method of synthesizing AuGa<sub>2</sub>, which is much more cost efficient and environmentally friendly than the previously used high-temperature synthesis techniques, and will open new possibilities of synthesizing other intermetallic compounds using high-pressure athermal techniques.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100257"},"PeriodicalIF":2.6,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145060074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A novel method to fabricate elastin/collagen fiber composites: Proof of concept","authors":"Kosuke Shinokawa , Ayae Sugawara-Narutaki , Jeonghyun Kim , Takeo Matsumoto , Eijiro Maeda","doi":"10.1016/j.mlblux.2025.100255","DOIUrl":"10.1016/j.mlblux.2025.100255","url":null,"abstract":"<div><div>Collagen and elastin are the main fibrous proteins of load-bearing soft tissues, conferring extensibility and strength upon those tissues through their interactions. However, to date, only a few techniques have been developed to fabricate fiber composites made from these proteins. Here we present an original method of fabricating fibrous composites of collagen and elastin and characterize their mechanical behavior. Soluble elastin was electrospun to form a sheet of elastin fibers, which was rolled and submerged in an acidic solution of collagen to permit collagen infiltration. The construct was incubated at 37 °C for 1 h so that collagen fibers self-assembled into the elastin fiber network, forming an elastin/collagen fiber composite. Simultaneous application of static mechanical loading and a chemical cross-linker, genipin, to the construct for an additional 24 h was also performed for fiber alignment. SEM observation revealed that elastin and collagen fibers were well integrated, although effects of mechanical loading to align those fibers were not observed. These elastin/collagen fiber composites possessed mechanical properties between those of collagen and elastin. Tensile properties benefited from collagen, whereas viscoelastic properties were derived from elastin. This method can be applied to development of artificial replacements of load-bearing soft tissues, such as tendon and meniscus.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100255"},"PeriodicalIF":2.6,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145019062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M.T. Normuradov , I.R. Bekpulatov , V.V. Klechkovskaya , Kim Ki Buem , B.D. Igamov , M.S. Lukasov , Gunel Imanova , E.A. Kerimov , Sh.A. Zeynalov
{"title":"Formation of Mn4Si7 thin films by solid-phase ion-plasma method and improvement of their thermoelectric and electrophysical properties","authors":"M.T. Normuradov , I.R. Bekpulatov , V.V. Klechkovskaya , Kim Ki Buem , B.D. Igamov , M.S. Lukasov , Gunel Imanova , E.A. Kerimov , Sh.A. Zeynalov","doi":"10.1016/j.mlblux.2025.100254","DOIUrl":"10.1016/j.mlblux.2025.100254","url":null,"abstract":"<div><div>In this study, Mn<sub>4</sub>Si<sub>7</sub> thermoelectric thin films were deposited on Si(111) and SiO<sub>2</sub>/Si(111) substrates via magnetron sputtering, and their microstructural as well as electrical temperature-dependent properties were thoroughly investigated. The as-deposited films at room temperature exhibited an amorphous structure, which underwent a phase transition to a polycrystalline state upon annealing at 800 K. This annealing process resulted in a significant reduction of surface defects and the formation of a continuous film composed of nanocrystallites with dimensions in the range of 50–100 nm. The presence of the SiO<sub>2</sub> dielectric layer on the substrate induced distinct variations in the film’s microstructure and density, which in turn affected its electrical resistivity and thermoelectric performance. The enhancement of thermoelectric properties observed during the amorphous-to-crystalline phase transition is attributed to the selective scattering mechanism of charge carriers at nanocluster boundaries. These findings provide a critical foundation for achieving high-performance Mn<sub>4</sub>Si<sub>7</sub>-based thermoelectric thin films and expand their potential applications in thermoelectric devices, paving the way for the development of next-generation energy conversion materials.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100254"},"PeriodicalIF":2.6,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144842808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of austenitizing temperature on microstructure and mechanical properties of medium carbon spring steel","authors":"Qian Yu , Yuliang Zhao , Feiyu Zhao","doi":"10.1016/j.mlblux.2025.100251","DOIUrl":"10.1016/j.mlblux.2025.100251","url":null,"abstract":"<div><div>The influence of austenitizing temperature on the microstructure and mechanical properties of medium carbon spring steel was systematically studied. Microstructural characterization showed that decreasing the austenitizing temperature from 900 °C to 860 °C effectively refined prior austenite grains from 8.8 μm to 5.3 μm, reduced martensite block thickness from 0.9 μm to 0.7 μm, and increased the fraction of high-angle grain boundaries (HAGBs) from 70 % to 76 %. Crystallographic variant analysis revealed increased boundary densities for V1&V2, V1&V3(V5), V1&V4, and V1&V6 pairs in the 860 °C sample with refined PAGS, along with elevated frequencies of V1&V3(V5) and V1&V6 pairs classified as HAGBs, consistent with the K-S orientation relationship. These results demonstrate that reducing the austenitizing temperature from 900 °C to 860 °C significantly affects martensite block size, HAGB fraction, and crystallographic variant pairs, leading to enchanced yield strength from 1563 MPa to 1648 MPa and total elongation from 9.3 % to 9.7 %.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100251"},"PeriodicalIF":2.6,"publicationDate":"2025-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144767242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiangfei Wang , Weijia Chen , Yijun Wen , Yuhan Peng , Siqi Liu , Shiwei He
{"title":"Electrochemical dealloying in ChCl-Urea Deep eutectic solvent: A strategy to fabricate porous FeCoNiAlMo high-entropy alloy with enhanced oxygen evolution reaction activity","authors":"Jiangfei Wang , Weijia Chen , Yijun Wen , Yuhan Peng , Siqi Liu , Shiwei He","doi":"10.1016/j.mlblux.2025.100252","DOIUrl":"10.1016/j.mlblux.2025.100252","url":null,"abstract":"<div><div>High-entropy alloys (HEAs), as a new type of multi-element alloy, have become widely studied electrocatalytic materials in recent years due to their excellent catalytic performance. The experimental material used FeCoNiAlMo HEA with equal atomic ratio as the precursor, and three-dimensional nanostructures were formed by dealloying in choline chloride-urea (ChCl-Urea). The results indicate that Fe<sub>20</sub>Co<sub>20</sub>Ni<sub>20</sub>Al<sub>20</sub>Mo<sub>20</sub> HEA is mainly composed of body-centered cubic (BCC) phase and face-centered cubic (FCC) phase, with BCC phase accounting for a larger proportion. Due to the different corrosion resistance of elements and the difference in element content distribution between the two phases, the FCC phase is preferentially corroded, resulting in a three-dimensional porous morphology. This unique structure synergistically reduces the energy barrier during the hydrolysis dissociation process, giving the material a significant advantage in the oxygen evolution reaction (OER) process. At a current density of 10 mA cm<sup>−2</sup>, the overpotential of the treated alloy is as low as 312 mV, which is lower than the commercial RuO<sub>2</sub>-IrO<sub>2</sub>, and it has lower resistance and higher charge transfer efficiency.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100252"},"PeriodicalIF":2.6,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hossein Pourrahmani , Thomas B. Ferriday , Raha Razmara , Hossein Madi , Jan Van herle
{"title":"Advanced imaging of gas diffusion layers: A comparison between focused ion beam scanning electron microscopy and X-ray computed tomography","authors":"Hossein Pourrahmani , Thomas B. Ferriday , Raha Razmara , Hossein Madi , Jan Van herle","doi":"10.1016/j.mlblux.2025.100250","DOIUrl":"10.1016/j.mlblux.2025.100250","url":null,"abstract":"<div><div>With the advances in clean technologies, the role of fuel cells and batteries is becoming increasingly vital. Proton exchange membrane fuel cells are known to be the best candidates for low-temperature and portable operations, such as hydrogen cars. The efficiency and longevity of these fuel cells can be feasible through detailed microstructural analysis. In this regard, advanced imaging techniques are being used to visualize the structure of the different layers of PEMFCs including the membrane, catalyst layer, and gas diffusion layer. This study’s focus and novelty is to compare the focused ion beam scanning electron microscopy and X-ray Computed Tomography scanning for the microstructural imaging of the GDL.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100250"},"PeriodicalIF":2.2,"publicationDate":"2025-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144670660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shuzheng Guo , Jingyi Huang , Na Ta , Fengze Cao , Sihua Ha , Shuai He , Jianli He , Luomeng Chao
{"title":"High energy-resolution electron energy loss spectroscopy and near infrared absorption study of cesium tungsten bronze and lanthanum hexaboride","authors":"Shuzheng Guo , Jingyi Huang , Na Ta , Fengze Cao , Sihua Ha , Shuai He , Jianli He , Luomeng Chao","doi":"10.1016/j.mlblux.2025.100249","DOIUrl":"10.1016/j.mlblux.2025.100249","url":null,"abstract":"<div><div>Cs<sub>0.33</sub>WO<sub>3</sub> nanoparticles exhibit strong localized surface plasmon resonance (LSPR), making them effective at absorbing near-infrared (NIR) light. However, effectively tuning the optical absorption of Cs<sub>0.33</sub>WO<sub>3</sub> in the critical NIR range of 800–1000 nm has remained a major challenge. In this study, we employ aberration-corrected electron microscopy to conduct high-resolution electron energy loss spectroscopy (EELS) on both Cs<sub>0.33</sub>WO<sub>3</sub> and LaB<sub>6</sub> nanoparticles, reveal that the surface plasmon resonance in LaB<sub>6</sub> nanoparticles occurs at a higher energy than in Cs<sub>0.33</sub>WO<sub>3</sub>, allowing LaB<sub>6</sub> to absorb NIR light at shorter wavelengths. Based on this, we successfully adjusted the absorption characteristics of Cs<sub>0.33</sub>WO<sub>3</sub> in the range of 800–1000 nm by utilizing the synergistic LSPR tuning of LaB<sub>6</sub> nanoparticles.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100249"},"PeriodicalIF":2.2,"publicationDate":"2025-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
F.A.C. Nobrega , E.A.W. Menezes , R. Reichenbächer , C. Scheffler , R.F. Abreu , E.F. Morais , C.M.B. Cordeiro , A. Spickenheuer , S.C. Amico , A.S.B. Sombra
{"title":"Simple and efficient optical fiber recoating procedure","authors":"F.A.C. Nobrega , E.A.W. Menezes , R. Reichenbächer , C. Scheffler , R.F. Abreu , E.F. Morais , C.M.B. Cordeiro , A. Spickenheuer , S.C. Amico , A.S.B. Sombra","doi":"10.1016/j.mlblux.2025.100248","DOIUrl":"10.1016/j.mlblux.2025.100248","url":null,"abstract":"<div><div>This article describes a rapid method of recoating optical fibers employing the dip-coating technique, using a polypropylene film former with a silane coupling agent, which reacts, yielding a protective film over the core. The silica optical fibers were recoated with film former sizings at concentrations of 5 % and 10 %. Microscopic analysis of the recoated area showed a smooth surface and an increase in diameter of 13.4 % and 16.5 %, respectively, compared to the uncoated fiber. The maximum curvature radius of the uncoated fibers was 3.69 ± 1.70 mm, whereas the fibers recoated with the 5 % and 10 % film former sizings reached a bending radius of 1.71 ± 1.38 mm and 1.55 ± 0.98 mm, representing 53.9 % and 57.9 % reduction, respectively. This shows that recoated optical fibers are more flexible than the uncoated ones. In all, the recoating of optical fibers proposed in this work results in fibers with smooth and flexible surfaces using a simple, cost-effective technique that can be implemented on large-scale processes.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100248"},"PeriodicalIF":2.2,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144563627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"TEM observation of extracted precipitates in T5 heat treated Al–Si–Mg alloy","authors":"Taiki Tsuchiya , Seungwon Lee , Susumu Ikeno , Kenji Matsuda","doi":"10.1016/j.mlblux.2025.100246","DOIUrl":"10.1016/j.mlblux.2025.100246","url":null,"abstract":"<div><div>The precipitation behavior of an Al–6.8 %Si–0.38 %Mg cast alloy subjected to T5 heat treatment was investigated using transmission electron microscopy (TEM). At the peak aging condition of 200 °C, granular and rod-shaped precipitates were observed at the center of the dendrite. Rod-shaped precipitates were successfully extracted after aging at 250 °C for 3.6 ks. Energy-dispersive X-ray spectroscopy (EDS) confirmed that the extracted precipitates had a Mg:Al:Si atomic ratio of approximately 1:4:5, consistent with previously reported Type-A precipitates. Selected area electron diffraction (SAED) analysis further confirmed their hexagonal crystal structure, with lattice parameters <em>a</em> = 0.405 nm and <em>c</em> = 0.67 nm. These findings indicate that Type-A precipitates, which are typically observed in excess-Si Al–Mg–Si alloys, also form in T5-treated Al–Si–Mg cast alloys.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"26 ","pages":"Article 100246"},"PeriodicalIF":2.2,"publicationDate":"2025-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144298665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}